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    • 24. 发明授权
    • Method for producing glass thin film
    • 制造玻璃薄膜的方法
    • US5660611A
    • 1997-08-26
    • US463866
    • 1995-06-05
    • Shinji IshikawaAkira UranoHaruhiko AikawaChizai HiroseHiroo KanamoriMasahide Saitoh
    • Shinji IshikawaAkira UranoHaruhiko AikawaChizai HiroseHiroo KanamoriMasahide Saitoh
    • C03B19/14C03C17/00C03C17/02C23C14/10C23C16/44C23C16/453C03B37/07C03C25/02
    • C03B19/1453C03B19/14C03B19/1415C03C17/001C03C17/02C23C14/10C23C16/44C23C16/453C03B2207/90
    • A method for producing an oxide glass thin film is provided, in which volatilization of additives in a porous film from which the thin film is formed is effectively suppressed, and which the oxide glass film has a desired arrangement of refractive index with a low optical loss. According to this method, glass fine particles mainly containing SiO.sub.2 with a first additive are deposited on a substrate to form a porous thin film. A gas containing a second additive is supplied to a first chamber and heated to a first predetermined temperature profile to provide a heated gas containing an oxide. After disposing the substrate in a second chamber communicated with the first chamber, the substrate is heated to make the deposited porous glass into transparent glass while controlling a temperature in the second chamber according to a second temperature profile. A carrier gas is flowed from the first chamber to the second chamber to transfer the heated gas and oxide from the first chamber to the second chamber during heating. The temperature of the first predetermined temperature profile is maintained higher than the temperature of the second predetermined temperature profile at the same time. In addition, the heated gas contains a component that is also present in the first additive.
    • 提供了一种制造氧化物玻璃薄膜的方法,其中有效地抑制了形成薄膜的多孔膜中的添加剂的挥发,并且氧化物玻璃薄膜具有期望的折射率排列,光损耗低 。 根据该方法,将主要含有SiO 2的第一添加剂的玻璃微粒子沉积在基板上,形成多孔薄膜。 将含有第二添加剂的气体供应到第一室并加热至第一预定温度分布,以提供含有氧化物的加热气体。 在将基板设置在与第一室连通的第二室中之后,基板被加热以使沉积的多孔玻璃成为透明玻璃,同时根据第二温度曲线控制第二室中的温度。 载气从第一室流到第二室,以在加热期间将加热的气体和氧化物从第一室转移到第二室。 第一预定温度曲线的温度同时保持高于第二预定温度曲线的温度。 此外,加热气体含有也存在于第一添加剂中的成分。
    • 29. 发明授权
    • Method for producing porous glass preform for optical fiber
    • 光纤多孔玻璃预制棒的制造方法
    • US5238479A
    • 1993-08-24
    • US984734
    • 1992-12-04
    • Yuichi OhgaToshio DanzukaHiroo KanamoriHiroshi Yokota
    • Yuichi OhgaToshio DanzukaHiroo KanamoriHiroshi Yokota
    • C03B37/014
    • C03B37/0142C03B2201/31C03B2203/22C03B2203/26C03B2207/06C03B2207/20C03B2207/24C03B2207/26C03B2207/28C03B2207/50
    • The invention is a method for producing a porous preform for use in the fabrication of an optical fiber at least two burners synthesize glass soot particles, one of which generates a double-layer flame and one of which is used for forming a core part of the preform. The method comprises the steps of supplying SiCl.sub.4 and optionally GeCl.sub.4 to the inner flame of the double-layer flame, and only SiCl.sub.4 to an outer flame of the double-layer flame to flame hydrolyze the supplied compounds and synthesize glass soot particles. Compounds SiCl.sub.4 and GeCl.sub.4 as glass-forming raw materials are supplied to the burner for forming the core part of the preform by depositing the generated glass soot particles on the lower end of a rotating starting member. The generated porous preform comprises a core part containing at least partly GeO.sub.2, and a surface having a low concentration of GeO.sub.2 which reduces cracking or peeling.
    • 本发明是用于制造用于制造光纤的多孔预制棒的方法,至少两个燃烧器合成玻璃烟灰颗粒,其中一个产生双层火焰,其中一个用于形成 预制件。 该方法包括以下步骤:向双层火焰的内部火焰提供SiCl 4和任选的GeCl 4,并且仅将SiCl 4与双层火焰的外部火焰直接火焰水解所提供的化合物并合成玻璃烟灰颗粒。 作为玻璃形成原料的化合物SiCl4和GeCl4通过将生成的玻璃烟灰颗粒沉积在旋转起始构件的下端而供给到用于形成预成型体的芯部的燃烧器。 生成的多孔预制件包括至少部分含有GeO 2的核心部分和具有低浓度GeO 2的表面,其减少开裂或剥离。