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21. 发明授权

US6083468A Method of manufacturing a hydrogenation catalyst 失效
标题翻译：制造氢化催化剂的方法
公开(公告)号：US6083468A
公开(公告)日：2000-07-04
申请号：US155908
申请日：1998-10-08
申请人： Daniel Heineke , Gunther Achhammer , Heinz-Walter Schneider , Alfred Thome
发明人： Daniel Heineke , Gunther Achhammer , Heinz-Walter Schneider , Alfred Thome
IPC分类号： B01J23/42 , B01J37/20 , C01B21/14 , C01C1/00
CPC分类号： B01J23/42 , C01B21/1418
摘要： A hydrogenation catalyst is prepared by reduction of platinum in an oxidation state of not less than two using a reducing agent in an aqueous medium in the presence of a carbon-containing support after partial poisoning, where use is made of a compound of the general formula I ##STR1## where X, Y and Z can be identical or different and are hydrogen, C.sub.1 -C.sub.18 -alkyl, C.sub.5 -C.sub.10 -cycloalkyl, halogen, hydroxyl, C.sub.1 -C.sub.6 -alkoxy and --NR'R", where R, R' and R" can be identical or different and can be hydrogen, C.sub.1 -C.sub.18 -alkyl or C.sub.5 -C.sub.10 -cycloalkyl. Such a hydrogenation catalyst can be used for preparing hydroxylammonium salts and the process for preparing the above catalysts can also be used for regenerating hydrogenation catalysts based on platinum.
摘要翻译： PCT No.PCT / EP97 / 01617 Sec。 371日期：1998年10月8日 102（e）日期1998年10月8日PCT 1997年4月1日PCT PCT。出版物WO97 / 37758 日期：1997年10月16日氢化催化剂是通过在部分中毒后在含碳载体存在下，在水性介质中使用还原剂还原不少于2的铂的氢化催化剂，其中使用其中X，Y和Z可以相同或不同，为氢，C 1 -C 18 - 烷基，C 5 -C 10 - 环烷基，卤素，羟基，C 1 -C 6 - 烷氧基和-NR'R“的通式I化合物，其中R，R'和R“可以相同或不同，并且可以是氢，C 1 -C 18 - 烷基或C 5 -C 10 - 环烷基。这种氢化催化剂可用于制备羟铵盐，并且制备上述催化剂的方法也可用于再生基于铂的氢化催化剂。

22. 发明授权

US5882619A Preparation of a hydrogenation catalyst using M(OR).sub.m X.sub.n 失效
标题翻译：使用M（OR）mXn制备氢化催化剂
公开(公告)号：US5882619A
公开(公告)日：1999-03-16
申请号：US756477
申请日：1996-11-26
申请人： Daniel Heineke , Karsten Eller , Heinz-Walter Schneider , Alfred Thome
发明人： Daniel Heineke , Karsten Eller , Heinz-Walter Schneider , Alfred Thome
IPC分类号： C01B21/14 , B01J21/18 , B01J23/42 , B01J27/08 , B01J31/30 , B01J31/40 , B01J35/10 , B01J37/04 , C07B61/00 , C07F7/00 , C07F7/28 , C01B21/20 , B01J20/34
CPC分类号： B01J31/30 , B01J21/18 , B01J23/42 , B01J27/08 , B01J31/0212 , B01J31/1616 , B01J31/4038 , B01J2231/641
摘要： A carbon-containing catalyst support is prepared by treating the carbon-containing catalyst support with a compound of the formula IM(OR).sub.m X.sub.n Iwhere M is Ti or Zr, X is Cl or Br, and R is C.sub.1 -C.sub.20 -alkyl, and m and n are integers from zero to four, where the sum of m and n is equal to four.
摘要翻译：通过用式IM（OR）mXn I的化合物处理含碳催化剂载体来制备含碳催化剂载体，其中M为Ti或Zr，X为Cl或Br，R为C1-C20烷基，并且m和n是从零到四的整数，其中m和n之和等于4。

23. 发明授权

US4745228A Preparation of cyclic ketones 失效
标题翻译：环酮的制备
公开(公告)号：US4745228A
公开(公告)日：1988-05-17
申请号：US65959
申请日：1987-06-24
申请人： Martin Decker , Rolf Fischer , Wolfgang Franzischka , Rudolf Kummer , Heinz-Walter Schneider , Uwe Vagt
发明人： Martin Decker , Rolf Fischer , Wolfgang Franzischka , Rudolf Kummer , Heinz-Walter Schneider , Uwe Vagt
IPC分类号： C07C45/48 , C07C45/00 , C07C45/51
CPC分类号： C07C45/48
摘要： Cyclic ketones of the formula ##STR1## where n is an integer from 4 to 6, are prepared by converting an aliphatic dicarboxylate of the formulaR.sup.1 OCC--(CH.sub.2).sub.n --COOR.sup.2 IIwhere n has the above meaning, R.sup.1 and R.sup.2 are each alkyl, cycloalkyl, aralkyl or aryl and R.sup.2 may furthermore be hydrogen, at from 150.degree. to 450.degree. C. over a solid oxide catalyst.
摘要翻译：通过将式R 1 OCC-（CH 2）n -COOR 2 II的脂肪族二羧酸酯转化为其中n具有上述含义，R1和R2各自为烷基，其中n为4-6的整数，其中n为4至6的整数的式，环烷基，芳烷基或芳基，R2可以为氢，在固体氧化物催化剂上为150-450℃。

24. 发明授权

US4586987A Obtaining C.sub.1 -C.sub.4 -alkyl pentenoates by distillation 失效
标题翻译：通过蒸馏获得戊烯酸C1-C4烷基酯
公开(公告)号：US4586987A
公开(公告)日：1986-05-06
申请号：US721810
申请日：1985-04-10
申请人： Heinz-Walter Schneider , Rudolf Kummer , Otto Leman , Paul Panitz
发明人： Heinz-Walter Schneider , Rudolf Kummer , Otto Leman , Paul Panitz
IPC分类号： B01J31/00 , B01J31/20 , C07B61/00 , C07C67/38 , C07C69/533 , B01D3/34 , C07C67/54
CPC分类号： C07C67/54
摘要： C.sub.1 -C.sub.4 -alkyl pentenoates are obtained from reaction mixtures which contain this and which are obtained by reacting butadiene, or a butadiene-containing hydrocarbon mixture, with carbon monoxide and a C.sub.1 -C.sub.4 -alkanol, in the presence of a cobalt carbonyl catalyst and a tertiary nitrogen base at elevated temperatures and under superatmospheric pressure by a process in which(a) the liquid reaction mixture freed from excess carbon monoxide is treated with hydrogen at elevated temperatures and under from 5 to 80 bar,(b) hydrocarbons are distilled off from the resulting liquid reaction mixture,(c) the C.sub.1 -C.sub.4 -alkyl pentenoate, the alkanol and the nitrogen base are then distilled off under reduced pressure, and(d) the C.sub.1 -C.sub.4 -alkyl pentenoate is obtained by fractional distillation from the distillate containing this compound, the alkanol and the tertiary nitrogen base.
摘要翻译：由含有这一点的反应混合物获得戊烯酸C 1 -C 4烷基酯，其通过使丁二烯或含丁二烯的烃混合物与一氧化碳和C 1 -C 4烷醇在羰基钴催化剂存在下反应获得，在高温和超大气压下，通过一种方法，（a）在高温和5至80巴下用氢处理脱除过量一氧化碳的液体反应混合物，（b）将烃蒸馏掉，从所得液体反应混合物中，（c）戊烯酸C 1 -C 4烷基酯，然后在减压下蒸馏除去链烷醇和氮碱，并且（d）戊烯酸C1-C4烷基酯是通过从含有该化合物的馏出物，链烷醇和叔氮碱。

25. 发明授权

US4537987A Preparation of pure monoesters of adipic acid 失效
标题翻译：己二酸纯单酯的制备
公开(公告)号：US4537987A
公开(公告)日：1985-08-27
申请号：US629766
申请日：1984-07-11
申请人： Heinz-Walter Schneider , Wolfgang Richter , Walter Disteldorf , Rudolf Kummer
发明人： Heinz-Walter Schneider , Wolfgang Richter , Walter Disteldorf , Rudolf Kummer
IPC分类号： B01J31/00 , B01J31/20 , B01J31/24 , C07B61/00 , C07C67/313 , C07C67/38 , C07C67/39 , C07C69/44 , C07C69/67
CPC分类号： C07C67/39
摘要： Pure monoesters of adipic acid are prepared by a process in which(a) a pentenoate is reacted with carbon monoxide and hydrogen at from 90.degree. to 140.degree. C. and under from 5 to 300 bar in the presence of a carbonyl complex of cobalt or of rhodium, and a 5-formylvalerate is separated off, and(b) the 5-formylvalerate thus obtained is oxidized with molecular oxygen, or with a gas containing this, at from 20.degree. to 100.degree. C. under from 1 to 10 bar.
摘要翻译：己二酸的纯单酯通过以下方法制备，其中（a）戊烯酸酯与一氧化碳和氢气在90至140℃和5至300巴下在钴或羰基络合物存在下反应的铑，并分离出5-甲酰基戊酸酯，（b）将所得的5-甲酰基戊酸酯用分子氧或含有该气体的气体在20至100℃下在1至10巴。

26. 发明授权

US4360692A Preparation of formylvalerates 失效
标题翻译：甲酰戊酸的制备
公开(公告)号：US4360692A
公开(公告)日：1982-11-23
申请号：US205569
申请日：1980-11-10
申请人： Rudolf Kummer , Heinz-Walter Schneider
发明人： Rudolf Kummer , Heinz-Walter Schneider
IPC分类号： B01J31/00 , B01J31/20 , C07B61/00 , C07C67/38 , C07C69/67
CPC分类号： C07C67/347 , C07C67/38
摘要： An improved process for the preparation of alkyl formylvalerates, wherein butadiene or a butadiene-containing hydrocarbon mixture is reacted, in a first stage, with carbon monoxide and alkanols in the presence of cobalt carbonyl complexes and, per mole of butadiene, from 0.5 to 2 moles of tertiary nitrogen bases having a pK.sub.a of from 3 to 11, at from 80.degree. to 150.degree. C. and from 300 to 2,000 bar, and, in a second stage, the resulting alkyl pentenoate is reacted with carbon monoxide and hydrogen in the presence of cobalt carbonyl complexes at from 100.degree. to 160.degree. C. and from 100 to 300 bar, the improvement being that tertiary nitrogen bases, excess alkanols and any unconverted hydrocarbons are distilled off from the reaction mixture obtained in the first stage, with the proviso that the reaction mixture is treated, before or during the distillation, with gases containing molecular oxygen, and the residual reaction mixture containing alkyl pentenoate and cobalt catalyst is used in the second stage.
摘要翻译：一种改进的制备烷基甲酰基戊酸酯的方法，其中丁二烯或含丁二烯的烃混合物在第一阶段中与一氧化碳和链烷醇在钴羰基络合物和每摩尔丁二烯的存在下反应，为0.5至2 具有pKa为3至11，80至150℃和300至2,000巴的叔氮碱的摩尔数，并且在第二阶段中，使得到的戊烯酸烷基酯与一氧化碳和氢气在在100至160℃和100至300巴存在钴羰基络合物，其改进是从第一阶段获得的反应混合物中蒸馏掉叔氮碱，过量链烷醇和任何未转化的烃，条件是反应混合物在蒸馏之前或期间用含有分子氧的气体进行处理，并且含有戊烯酸烷基酯和钴催化剂的残余反应混合物用于第二阶段

27. 发明授权

US4113754A Isolation and regeneration of rhodium-containing catalysts from distillation residues of hydroformylation reactions 失效
标题翻译：从加氢甲酰化反应的蒸馏残余物中分离和再生含铑催化剂
公开(公告)号：US4113754A
公开(公告)日：1978-09-12
申请号：US780297
申请日：1977-03-23
申请人： Rudolf Kummer , Heinz-Walter Schneider , Kurt Schwirten
发明人： Rudolf Kummer , Heinz-Walter Schneider , Kurt Schwirten
IPC分类号： B01J31/40 , B01J38/68 , B01J38/74 , C07B61/00 , C07C45/00 , C07C45/50 , C07C47/02 , C07C67/00 , C07F15/00
CPC分类号： B01J31/4046 , B01J31/20 , B01J31/24 , B01J31/2404 , C07C45/50 , B01J2231/321 , B01J2531/822 , Y02P20/582 , Y02P20/584
摘要： The isolation and regeneration of catalysts of type I or IIclRh(CO)(PR.sub.3).sub.2 Ihrh(CO)(PR.sub.3).sub.3 II,where the R's are identical or different hydrocarbon radicals, to give the catalysts in a pure form, is effected by regenerating aqueous rhodium salt solutions, as obtained on treating distillation residues of hydroformylation mixtures with oxygen-containing mineral acids and peroxides, by a method wherein the said aqueous rhodium salt solutions are treated with a cation exchanger, the latter is then separated from the solution, the absorbed rhodium ions are desorbed with hydrochloric acid, the hexachlororhodate solutions, containing hydrochloric acid, are reacted, in the presence of a water-soluble organic solvent and a tertiary phosphine PR.sub.3, with carbon monoxide, or with compounds which eliminate carbon monoxide, at from 0.degree. to 150.degree. C and from 1 to 5 bars, and the resulting complexes I or, if the process is carried out under hydrogenating conditions, the resulting complexes II, are separated off.
摘要翻译：分离和再生I或II型ClRh（CO）（PR3）2I HRh（CO）（PR3）3II的催化剂，其中R是相同或不同的烃基，得到纯形式的催化剂，是通过通过其中所述水合铑盐溶液用阳离子交换剂处理的方法，在用含氧无机酸和过氧化物处理加氢甲酰化混合物的蒸馏残余物时获得的再生铑水溶液溶液，然后将该铑盐溶液与溶液分离，吸收的铑离子用盐酸解吸，含有盐酸的六氯乙酸溶液在水溶性有机溶剂和叔膦PR3存在下与一氧化碳或与一氧化碳消除的化合物反应， 0至150℃和1至5巴，所得的络合物I或如果该方法在氢化条件下进行，则得到的络合物II为sepa 评分。

28. 发明授权

US4766237A Preparation of 6-aminocaproates 失效
标题翻译： 6-氨基己酸酯的制备
公开(公告)号：US4766237A
公开(公告)日：1988-08-23
申请号：US7578
申请日：1987-01-28
申请人： Hans-Martin Hutmacher , Franz J. Broecker , Franz Merger , Rolf Fischer , Uwe Vagt , Heinz-Walter Schneider , Wolfgang Richter , Wolfgang Harder , Claus-Ulrich Priester
发明人： Hans-Martin Hutmacher , Franz J. Broecker , Franz Merger , Rolf Fischer , Uwe Vagt , Heinz-Walter Schneider , Wolfgang Richter , Wolfgang Harder , Claus-Ulrich Priester
IPC分类号： C07B61/00 , B01J21/16 , B01J23/00 , B01J23/74 , B01J23/755 , B01J25/02 , C07C67/00 , C07C227/00 , C07C227/04 , C07C227/08 , C07C229/08 , C07C67/30
CPC分类号： C07C227/08
摘要： In an improved process for the preparation of 6-aminocaproates by reacting a 5-formylvalerate with ammonia and hydrogen using an alkanol as a solvent in the presence of a hydrogenation catalyst at elevated temperatures and under superatmospheric pressure, the improvement comprises carrying out the reaction at from 40.degree. to 95.degree. C.
摘要翻译：在氢化催化剂存在下，在升高的温度和超大气压下，通过使用烷醇作为溶剂使5-甲酰基戊酸与氨和氢反应制备6-氨基己酸酯的改进方法，其改进包括在从40℃到95℃

29. 发明授权

US4454358A Continuous production of ethanol and plural stage distillation of the same 失效
标题翻译：连续生产乙醇和多级蒸馏相同
公开(公告)号：US4454358A
公开(公告)日：1984-06-12
申请号：US337683
申请日：1982-01-07
申请人： Rudolf Kummer , Volker Taglieber , Heinz-Walter Schneider
发明人： Rudolf Kummer , Volker Taglieber , Heinz-Walter Schneider
IPC分类号： C07C29/132 , B01J31/00 , B01J31/20 , C07B61/00 , C07C27/00 , C07C27/04 , C07C29/149 , C07C29/80 , C07C29/92 , C07C31/08 , C07C67/00 , B01D3/00
CPC分类号： C07C29/80 , C07C29/149 , C07C67/08 , C07C67/36 , C07C67/54 , Y02P20/52 , Y10S203/06 , Y10S203/20
摘要： Ethanol is produced continuously via the carbonylation of methanol, by(a) carbonylating methanol, in a reactor R, in the presence of a carbonyl complex of a metal of group VIII of the periodic table and of a halogen compound,(b) separating, in a distillation column D1, the reactor discharge, into a top fraction comprising methyl acetate, methanol, dimethyl ether and an organohalogen compound, and into a bottom fraction comprising water, small quantities of acetic acid and the catalyst, if the latter is not in a fixed bed, the residence time being so adjusted that the greater part of the acetic acid reacts with the methanol present to give methyl acetate,(c) separating the top fraction from D1, in a distillation column D2, into a top fraction comprising small quantities of methyl acetate, methanol, dimethyl ether and the organo-halogen compound, and a bottom fraction comprising methyl acetate and methanol, and recycling the top fraction to reactor R,(d) distilling off, via the top of distillation column D3, the greater part of the water from the bottom fraction from D1and removing this water from circulation, and recycling to reactor R the bottom fraction consisting of small quantities of water, acetic acid and the catalyst,(e) using hydrogen to hydrogenate, in the hydrogenation reactor H, the bottom fraction from D2, in a conventional manner, to give a mixture of methanol and ethanol, and(f) separating the mixture into ethanol and methanol in a distillation column D4, and recycling the methanol to reactor R.
摘要翻译：通过（a）在反应器R中羰基化甲醇，在周期表第VIII族金属的羰基络合物和卤素化合物的存在下，连续生产乙醇，（b）分离，在蒸馏塔D1中，反应器排出成为包含乙酸甲酯，甲醇，二甲醚和有机卤素化合物的顶级馏分，并进入包含水，少量乙酸和催化剂的底部馏分，如果后者不在固定床，停留时间如此调节，使得大部分乙酸与存在的甲醇反应得到乙酸甲酯，（c）将蒸馏塔D2中的顶馏分与D1分离成包含小分子的顶馏分数量的乙酸甲酯，甲醇，二甲醚和有机卤素化合物，以及包含乙酸甲酯和甲醇的底部馏分，并将顶部馏分再循环到反应器R中，（d）通过顶部o蒸馏 f蒸馏塔D3，来自D1的底部馏分的大部分水从循环中除去，并且将反应器R再循环到由少量水，乙酸和催化剂组成的底部馏分，（e）使用氢气以常规方式在氢化反应器H中将来自D2的塔底馏分氢化，得到甲醇和乙醇的混合物，和（f）将混合物在蒸馏塔D4中分离成乙醇和甲醇，并将甲醇再循环至反应器

30. 发明授权

US4350572A Purification of carboxylic acid esters containing aldehydes and/or acetals 失效
标题翻译：含醛和/或缩醛的羧酸酯的纯化
公开(公告)号：US4350572A
公开(公告)日：1982-09-21
申请号：US204637
申请日：1980-11-06
申请人： Rudolf Kummer , Volker Taglieber , Franz-Josef Weis , Heinz-Walter Schneider
发明人： Rudolf Kummer , Volker Taglieber , Franz-Josef Weis , Heinz-Walter Schneider
IPC分类号： C07C67/48 , C07C67/38 , C07C67/56 , C07C67/60 , C07C69/44 , B01D3/34
CPC分类号： C07C67/60
摘要： A process for purifying carboxylic acid esters which have been obtained by reacting olefinically unsaturated compounds with carbon monoxide and alkanols and which contain aldehydes or acetals, wherein the said esters are treated with a strongly acidic agent, with or without addition of water.
摘要翻译：通过使烯属不饱和化合物与一氧化碳和链烷醇反应并且含有醛或缩醛而获得的羧酸酯的方法，其中所述酯用强酸性剂处理，或不加入水。

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