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    • 23. 发明授权
    • Process for fabricating a semiconductor device having a high reliability
dielectric material
    • 制造具有高可靠性电介质材料的半导体器件的工艺
    • US5407870A
    • 1995-04-18
    • US71885
    • 1993-06-07
    • Yoshio OkadaPhilip J. Tobin
    • Yoshio OkadaPhilip J. Tobin
    • H01L21/28H01L21/336H01L29/51H01L21/285
    • H01L21/28273H01L21/28167H01L21/28176H01L29/511H01L29/66825
    • A process for fabricating a high-reliability composite dielectric layer (19) includes the formation of a first oxynitride layer (14) on the surface (12) of a silicon substrate (10). The formation of the first oxynitride layer (14) is followed by an oxidation step to form a silicon dioxide layer (16) at the surface (12) of the substrate (10) and underlying the first oxynitride layer (14). The composite dielectric layer (19) is completed by exposing the substrate (10) to nitrous oxide, and diffusing a nitrogen bearing species through both the silicon dioxide layer (16) and the first oxynitride layer (14) to form a second oxynitride layer (18) underlying the silicon dioxide layer (16). The composite dielectric layer (19) exhibits a nitrogen-rich region at the interface between second oxynitride layer (18) and the silicon substrate (10). A second nitrogen rich region is also formed near the surface of the first oxynitride layer (14).
    • 制造高可靠性复合电介质层(19)的工艺包括在硅衬底(10)的表面(12)上形成第一氮氧化物层(14)。 第一氮氧化物层(14)的形成之后是氧化步骤,以在衬底(10)的表面(12)处形成二氧化硅层(16),并且位于第一氮氧化物层(14)下方。 通过将基板(10)暴露于一氧化二氮并通过二氧化硅层(16)和第一氮氧化物层(14)两者扩散含氮物质来形成复合介电层(19),以形成第二氮氧化物层 18)位于二氧化硅层(16)下面。 复合电介质层(19)在第二氧氮化物层(18)和硅衬底(10)之间的界面处显示富氮区域。 在第一氮氧化物层(14)的表面附近还形成有第二富氮区域。
    • 26. 发明授权
    • Capped dual metal gate transistors for CMOS process and method for making the same
    • 用于CMOS工艺的双金属栅极晶体管及其制造方法
    • US06894353B2
    • 2005-05-17
    • US10209523
    • 2002-07-31
    • Srikanth B. SamavedamPhilip J. Tobin
    • Srikanth B. SamavedamPhilip J. Tobin
    • H01L21/8238H01L29/76
    • H01L21/823835H01L21/823814H01L21/823842H01L21/823864
    • A first gate (120) and a second gate (122) are preferably PMOS and NMOS transistors, respectively, formed in an n-type well (104) and a p-type well (106). In a preferred embodiment first gate (120) includes a first metal layer (110) of titanium nitride on a gate dielectric (108), a second metal layer (114) of tantalum silicon nitride and a silicon containing layer (116) of polysilicon. Second gate (122) includes second metal layer (114) of a tantalum silicon nitride layer on the gate dielectric (108) and a silicon containing layer (116) of polysilicon. First spacers (124) are formed adjacent the sidewalls of the gates to protect the metals from chemistries used to remove photoresist masks during implant steps. Since the chemistries used are selective to polysilicon, the spacers (124) need not protect the polysilicon capping layers, thereby increasing the process margin of the spacer etch process. The polysilicon cap also facilitates silicidation of the gates.
    • 第一栅极(120)和第二栅极(122)分别优选分别形成在n型阱(104)和p型阱(106)中的PMOS和NMOS晶体管。 在优选实施例中,第一栅极(120)包括在栅极电介质(108)上的氮化钛的第一金属层(110),氮化硅钽的第二金属层(114)和多晶硅的含硅层(116)。 第二栅极(122)包括栅极电介质(108)上的氮化硅钽层的第二金属层(114)和多晶硅的含硅层(116)。 邻近门的侧壁形成第一间隔物(124),以在植入步骤期间保护用于去除光致抗蚀剂掩模的化学物质的金属。 由于使用的化学物质对多晶硅是选择性的,间隔物(124)不需要保护多晶硅覆盖层,从而增加间隔物蚀刻工艺的工艺边缘。 多晶硅帽也有利于栅极的硅化。