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21. 发明授权

US07659351B2 Water- and oil-repellent fluoroacrylates 失效
标题翻译：拒水拒油氟代丙烯酸酯
公开(公告)号：US07659351B2
公开(公告)日：2010-02-09
申请号：US11688074
申请日：2007-03-19
申请人： Gregg A. Caldwell , John C. Clark , David J. Kinning , Alan R. Kirk , Thomas P. Klun , Ramesh C. Kumar , Roger A. Mader , George G I. Moore , Zai-Ming Qiu , Richard B. Ross
发明人： Gregg A. Caldwell , John C. Clark , David J. Kinning , Alan R. Kirk , Thomas P. Klun , Ramesh C. Kumar , Roger A. Mader , George G I. Moore , Zai-Ming Qiu , Richard B. Ross
IPC分类号： C08F12/20
CPC分类号： C08F220/38 , C07C271/20 , C07C271/28 , C07C311/09 , Y10T442/2287
摘要： Fluoroacrylates comprise the reaction product of: (a) at least one fluorochemical alcohol represented by the formula: CnF2n+1—X—OH wherein: n=1 to 4, R=hydrogen or an alkyl group of 1 to 4 carbon atoms, m=2 to 8, Rf=CnF2n+1, y=0 to 6, and q=1 to 8; (b) at least one unbranched symmetric diusocyanate; and (c) at least one hydroxy-terminated alkyl (meth)acrylate or 2-fluoro acrylate monomer having 2 to about 30 carbon atoms in its alkylene portion.
摘要翻译：氟代丙烯酸酯包括以下反应产物：（a）至少一种由式CnF2n + 1-X-OH表示的含氟醇，其中：n = 1-4，R =氢或1-4个碳原子的烷基，m = 2〜8，Rf = CnF2n + 1，y = 0〜6，q = 1〜8; （b）至少一种非支化对称二异氰酸酯; 和（c）至少一个羟基封端的（甲基）丙烯酸烷基酯或其亚烷基部分具有2至约30个碳原子的2-氟丙烯酸酯单体。

22. 发明授权

US07253241B2 Fluorochemical containing low adhesion backsize 有权
标题翻译：含有低附着力的含氟化合物
公开(公告)号：US07253241B2
公开(公告)日：2007-08-07
申请号：US11027602
申请日：2004-12-28
申请人： James P. DiZio , David J. Kinning , George G. I. Moore
发明人： James P. DiZio , David J. Kinning , George G. I. Moore
IPC分类号： C08F18/20 , C08F20/22
CPC分类号： C08F214/18 , C08F220/18 , C08L31/04 , C08L33/08 , C08L33/16 , C08L33/20 , C08L35/06 , Y10T428/28 , Y10T428/2848 , Y10T428/2852 , C08L2666/04
摘要： In one aspect, the invention provides a water-based release coating composition comprising a mixture of (A.) from about 5 to about 100 wt % of a polymer comprising the reaction product of (a.) from 1 to about 15 wt % of a fluorinated monomer selected from the group consisting of monomers according to the general formula: RfX—OC(O)—C(R)═CH2, wherein Rf represents a perfluorinated aliphatic group having 3 or 4 carbon atoms, X is an organic divalent linking group, and R represents a hydrogen or methyl group, (b.) from about 40 to about 70 wt % of an alkyl (meth)acrylate, wherein the alkyl group contains from 16 to 22 carbon atoms, (c.) from about 3 to about 20 wt % of (meth)acrylic acid, (d.) from about 20 to about 40 wt % acrylonitrile, and (e.) from 0 to about 15 wt % of vinyl monomer, other than acrylonitrile, wherein the sum of (a.) through (e.) equals 100%; and (B.) from 0 to about 95 wt % of an extender polymer, wherein the sum of (A.) and (B.) is 100% and wt % is based on the total amount of solids in the composition.
摘要翻译：在一个方面，本发明提供一种水性剥离涂料组合物，其包含（A）约5至约100重量％的聚合物的混合物，所述聚合物包含（a。）的反应产物，所述反应产物为（a。）1至约15重量％选自以下通式的单体的氟化单体：<？in-line-formula description =“In-line Formulas”end =“lead”？> R X X-OC （O）-C（R）-CH 2，<βin-line-formula description =“In-line Formulas”end =“tail”？>其中R 1 f 表示具有3或4个碳原子的全氟化脂族基团，X是有机二价连接基团，R表示氢或甲基，（b。）约40至约70重量％的（甲基）丙烯酸烷基酯，其中烷基含有16至22个碳原子，（c）约3至约20重量％的（甲基）丙烯酸，（d。）约20至约40重量％的丙烯腈，（e） 0至约15重量％的乙烯基单体，除了丙烯腈，其中（a 通过（e。）等于100％; 和（B.）0至约95重量％的增量聚合物，其中（A.）和（B.）的总和为100％，wt％基于组合物中固体的总量。

23. 发明授权

US06857737B2 UV ink printed graphic article 有权
标题翻译： UV油墨印刷图案
公开(公告)号：US06857737B2
公开(公告)日：2005-02-22
申请号：US10328523
申请日：2002-12-23
申请人： Jeffrey O. Emslander , David J. Kinning , Stephen P. Polski , Caroline M. Ylitalo
发明人： Jeffrey O. Emslander , David J. Kinning , Stephen P. Polski , Caroline M. Ylitalo
IPC分类号： B41M5/00 , B41M5/50 , B41M5/52 , B41J2/01
CPC分类号： B41M5/52 , B41M5/508 , B41M5/5254 , B41M5/5281 , C08L2666/02 , C08L2666/06 , C08L2666/20 , C09D175/04 , C09J7/29 , C09J133/10 , C09J133/12 , C09J133/14 , C09J2201/162 , C09J2203/334 , C09J2205/31
摘要： In one aspect, the invention provides an imaged article that includes A) an image receptive layer bonded to a core layer and B) an image on the image receptive layer, the image including a UV-curable or UV-cured ink and methods of using the imaged article.
摘要翻译：一方面，本发明提供了一种成像制品，其包括：A）结合到芯层的图像接收层和B）图像接收层上的图像，该图像包括可UV固化或UV固化的墨水和使用的方法成像的文章。

24. 发明授权

US06800341B2 Solvent inkjet ink receptive films 有权
标题翻译：溶剂喷墨油墨接受膜
公开(公告)号：US06800341B2
公开(公告)日：2004-10-05
申请号：US10441868
申请日：2003-05-20
申请人： Jeffrey O. Emslander , David J. Kinning , Caroline M. Ylitalo
发明人： Jeffrey O. Emslander , David J. Kinning , Caroline M. Ylitalo
IPC分类号： B41M540
CPC分类号： B41M5/52 , B41M5/508 , B41M5/5254 , B41M5/5281 , Y10T428/24802 , Y10T428/28 , Y10T428/31507 , Y10T428/31551 , Y10T428/31725 , Y10T428/31786 , Y10T428/31855
摘要： In one aspect, the invention provides an image receptor medium which comprises an extruded image receptive layer that is receptive to solvent-based inkjet ink. Image receptive layers of the invention comprise a blend of an ink absorptive resin and a carrier resin. The ink absorptive resin is compatible with the carrier resin and had a Hildebrand Solubility Parameter within about 3.1 (MPa)1/2 of that of the solvent of the ink. In another aspect, the invention provides an image receptor medium which comprises a coextruded or extrusion coated image receptive layer and a core layer bonded together. In other aspects, the invention provides methods of printing images and methods of making an extrusion coated or coextruded image receptor medium.
摘要翻译：在一个方面，本发明提供一种图像接收介质，其包含可接受溶剂型喷墨油墨的挤出图像接收层。本发明的感光层包括吸墨树脂和载体树脂的共混物。油墨吸收树脂与载体树脂相容，并且在墨水溶剂的约3.1（MPa）1/2的范围内具有希尔德布兰德溶解度参数。在另一方面，本发明提供一种图像接收介质，其包括共挤出或挤出涂覆的图像接受层和结合在一起的芯层。在其他方面，本发明提供了印刷图像的方法和制备挤出涂布或共挤出图像受体介质的方法。

25. 发明授权

US06793859B2 Solvent inkjet ink receptive films 有权
公开(公告)号：US06793859B2
公开(公告)日：2004-09-21
申请号：US10441756
申请日：2003-05-20
申请人： Jeffrey O. Emslander , David J. Kinning , Diane L. Regnier , Caroline M. Ylitalo
发明人： Jeffrey O. Emslander , David J. Kinning , Diane L. Regnier , Caroline M. Ylitalo
IPC分类号： B29C4706
CPC分类号： B41M5/52 , B41M5/508 , B41M5/5254 , B41M5/5281 , Y10T428/24802 , Y10T428/28 , Y10T428/31507 , Y10T428/31551 , Y10T428/31725 , Y10T428/31786 , Y10T428/31855
摘要： In one aspect, the invention provides an image receptor medium which comprises an extruded image receptive layer that is receptive to solvent-based inkjet ink. Image receptive layers of the invention comprise a blend of an ink absorptive resin and a carrier resin. The ink absorptive resin is compatible with the carrier resin and had a Hildebrand Solubility Parameter within about 3.1 (MPa)1/2 of that of the solvent of the ink. In another aspect, the invention provides an image receptor medium which comprises a coextruded or extrusion coated image receptive layer and a core layer bonded together. In other aspects, the invention provides methods of printing images and methods of making an extrusion coated or coextruded image receptor medium.

26. 发明授权

US06589636B2 Solvent inkjet ink receptive films 有权
标题翻译：溶剂喷墨油墨接受膜
公开(公告)号：US06589636B2
公开(公告)日：2003-07-08
申请号：US09896497
申请日：2001-06-29
申请人： Jeffrey O. Emslander , David J. Kinning , Diane L. Regnier , Caroline M. Ylitalo
发明人： Jeffrey O. Emslander , David J. Kinning , Diane L. Regnier , Caroline M. Ylitalo
IPC分类号： B32B2714
CPC分类号： B41M5/52 , B41M5/508 , B41M5/5254 , B41M5/5281 , Y10T428/24802 , Y10T428/28 , Y10T428/31507 , Y10T428/31551 , Y10T428/31725 , Y10T428/31786 , Y10T428/31855
摘要： In one aspect, the invention provides an image receptor medium which comprises an extruded image receptive layer that is receptive to solvent-based inkjet ink. Image receptive layers of the invention comprise a blend of an ink absorptive resin and a carrier resin. The ink absorptive resin is compatible with the carrier resin and had a Hildebrand Solubility Parameter within about 3.1 (MPa)1/2 of that of the solvent of the ink. In another aspect, the invention provides an image receptor medium which comprises a coextruded or extrusion coated image receptive layer and a core layer bonded together. In other aspects, the invention provides methods of printing images and methods of making an extrusion coated or coextruded image receptor medium.
摘要翻译：在一个方面，本发明提供一种图像接收介质，其包含可接受溶剂型喷墨油墨的挤出图像接收层。本发明的感光层包括吸墨树脂和载体树脂的共混物。油墨吸收树脂与载体树脂相容，并且在墨水溶剂的约3.1（MPa）1/2的范围内具有希尔德班德溶解度参数。在另一方面，本发明提供一种图像接收介质，其包括共挤出或挤出涂覆的图像接受层和结合在一起的芯层。在其他方面，本发明提供了印刷图像的方法和制备挤出涂布或共挤出图像受体介质的方法。

27. 发明授权

US06465081B2 Image receptor sheet 失效
公开(公告)号：US06465081B2
公开(公告)日：2002-10-15
申请号：US09835689
申请日：2001-04-16
申请人： Manisha Sarkar , James P. DiZio , David J. Kinning , John W. Vanderzanden
发明人： Manisha Sarkar , James P. DiZio , David J. Kinning , John W. Vanderzanden
IPC分类号： B32B2714
CPC分类号： B41M5/504 , B41M5/508 , B41M5/5236 , B41M5/5254 , Y10T428/25 , Y10T428/254 , Y10T428/31551 , Y10T428/31786 , Y10T428/31855
摘要： A liquid ink repellent coating adapted to prevent transfer of fluid image forming ink droplets between imaged sheets in a stack of multiple printed impressions. The repellent coating comprises a polymeric composition having a surface energy less than about 30 mJ/m2 and an insoluble particulate filler as a matting agent.

28. 发明授权

US5753346A Cationically co-curable polysiloxane release coatings 失效
标题翻译：阳离子共可聚合的聚硅氧烷脱模涂层
公开(公告)号：US5753346A
公开(公告)日：1998-05-19
申请号：US747475
申请日：1996-11-12
申请人： Charles M. Leir , William R. Berggren , William R. Bronn , David J. Kinning , Olester Benson, Jr.
发明人： Charles M. Leir , William R. Berggren , William R. Bronn , David J. Kinning , Olester Benson, Jr.
IPC分类号： C08L83/06 , C08F2/50 , C08L83/04 , C08L83/07 , C09D4/06 , C09D183/04 , C09D183/06 , C09D183/08 , C09D183/10 , C09J7/02 , B32B9/04 , C08J7/04
CPC分类号： C09J7/0228 , C09D183/06 , C09D183/08 , C09D183/10 , C09D4/06 , C09J7/0232 , C09J2205/31 , C09J2483/005 , Y10T428/24388 , Y10T428/24446 , Y10T428/31598 , Y10T428/31601 , Y10T428/31663 , Y10T428/31667 , Y10T442/2098 , Y10T442/2107
摘要： The invention provides a radiation curable release coating composition comprising: (a) about 1 to about 50 percent by weight of a cationically reactive polydiorganosiloxane liquid rubber having the following formula: ##STR1## wherein R are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, aryl, and substituted aryl wherein at least about 50% of the total number of silicon atoms have two methyl groups bonded thereto; E is an organic monovalent functional group comprising from about 1 to about 20 carbon atoms having at least one cationically co-reactive functional group; a and b both represent integers, wherein the sum of a plus b is an integer of about 10 to about 1200; b has a value ranging from about 0 to about 0.2 a; a is an integer of about 10 to about 1000; and M is a silyl group which must contain at least one cationically co-reactive functional group when b=0 and may contain at least one cationically co-reactive group when b is greater than 0; (b) about 50 to about 99 percent by weight of at least one cationically co-reactive monomer copolymerizable with said cationically co-reactive functional group of said polydiorganosiloxane liquid rubber; wherein the percentages of (a) and (b) are based on the total weight of (a) plus (b); and (c) about 0.5 to about 4 parts by weight of a photoactive radiation activatable cationically reactive catalyst based on the weight of (a) plus (b). The invention also provides release coatings and methods of making release coatings.
摘要翻译：本发明提供了一种可辐射固化的脱模涂料组合物，其包含：（a）约1至约50重量％的具有下式的阳离子反应性聚二有机硅氧烷液体橡胶：其中R是可以相同的一价部分，选自烷基，取代的烷基，芳基和取代的芳基的不同，其中硅原子总数的至少约50％具有与其键合的两个甲基; E是包含具有至少一个阳离子共反应性官能团的约1至约20个碳原子的有机单价官能团; a和b均表示整数，其中加号b的和为约10至约1200的整数; b的值为约0至约0.2a; a为约10至约1000的整数; 当b = 0时，M是甲硅烷基，其必须含有至少一个阳离子共反应性官能团，当b大于0时可以含有至少一个阳离子共反应基团; （b）约50至约99重量％的至少一种可与所述聚二有机硅氧烷液体橡胶的所述阳离子共反应性官能团共聚的阳离子共反应性单体; 其中（a）和（b）的百分比基于（a）加（b）的总重量; 和（c）基于（a）加（b）的重量，约0.5至约4重量份的光活性辐射可激活阳离子反应催化剂。本发明还提供了剥离涂层和制备剥离涂层的方法。

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