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    • 21. 发明授权
    • Phthalocyanine compounds for ink-jet printing
    • 用于喷墨打印的酞菁化合物
    • US06332918B1
    • 2001-12-25
    • US09250179
    • 1999-02-16
    • Mark Kenworthy
    • Mark Kenworthy
    • C09D1102
    • C09D11/322C09B47/26
    • Phthalocyanine compounds of Formula (1) have utility as colorants in inks for ink-jet printing, where Formula (1) represents: which comprises any form of the compound: such as salt; stereoisomer, zwitterion, polymorph, complex, isotopic form, combinations thereof in the same species and mixtures thereof; where: M represents H, metal, halometal, oxymetal and/or hydroxymetal; k is the inverse of half of the valency of M; Pc represents a phthalocyanine nucleus of Formula (2): L represents a linking group comprising an optionally substituted C1-30carbyl; A represents —O—, —S— or —NR3—, where R3 independently comprises H or optionally substituted C1-30carbyl; R1 comprises at least one group independently selected from: an optional substituent and optionally substituted C1-15carbyl; R2 comprises optionally substituted C1-30carbyl that comprises at least one alkyl group substituted by at least one of: hydroxy, carboxy and sulpho; z represents an integer from 0 to 4; w represents an integer from 1 to 5; and the sum of w +z is from 1 to 5; and x and y each independently represent a non-zero number; and the mean of the sum of x +y is from about 1 to about 6; where the optional substituents comprise at least one of: carboxy, sulpho, hydroxy, amino, mercapto, cyano, nitro and halo.
    • 式(1)的酞菁化合物在用于喷墨印刷的油墨中具有着色剂的用途,其中式(1)表示:其包含任何形式的化合物如盐; 立体异构体,两性离子,多晶型物,复合物,同位素形式,它们在同一物种及其混合物中的组合; 其中:M表示H,金属,卤素,氧化金属和/或羟基金属; k是M的化合价的一半的倒数; Pc表示式(2)的酞菁核:L表示包含任选取代的C1- 30碳原子; A表示-O - , - S-或-NR 3 - ,其中R 3独立地包含H或任选取代的C 1-30碳酰基; R 1包含至少一个独立地选自以下的基团:任选的取代基和任选取代的C 1-6烃基; R 2包括 任选取代的C 1-30碳基,其包含至少一个被至少一个被羟基,羧基和磺基取代的烷基; z表示0至4的整数; w表示1〜5的整数, w + z的和为1〜5; andx和y各自独立地表示非零数; 并且x + y之和的平均值为约1至约6;其中任选的取代基包括以下中的至少一个:羧基,磺基,羟基,氨基,巯基,氰基,硝基和卤素。
    • 22. 发明授权
    • Ink compositions containing disazo dyes
    • 含有双偶氮染料的油墨组合物
    • US5820661A
    • 1998-10-13
    • US831938
    • 1997-04-02
    • Peter GregoryMark KenworthyAndrew Hunter Morris Renfrew
    • Peter GregoryMark KenworthyAndrew Hunter Morris Renfrew
    • C09B43/40C09B62/09C09B62/44C09D11/00D06P5/30G03G9/09C09D11/02
    • C09D11/328C09B43/40C09B62/09C09B62/4415D06P5/30G03G9/091G03G9/0914Y10T428/24802
    • An ink composition comprising: (i) a dye of Formula (1) or a salt thereof: ##STR1## wherein: A is optionally substituted phenylene; B and E each independently is optionally substituted phenylene or optionally substituted naphthylene; D is a coupling component; each R.sup.1 independently is H or optionally substituted alkyl; X is a labile or non-labile atom or group; each Z independently is --OR.sup.3, --SR.sup.3, --NR.sup.4 R.sup.5 or --Y--SO.sub.3 H in which Y is O or S; and R.sup.3, R.sup.4 and R.sup.5 each independently is H, optionally substituted alkyl, optionally substituted alkenyl, cycloalkyl, optionally substituted aralkyl, optionally substituted aryl or R.sup.4 or R.sup.5 together with the nitrogen atom to which they are attached form a 5 or 6 membered ring; and (ii) a medium comprising a low melting point solid, an organic solvent, or a mixture of water and one or more water-soluble organic solvent(s). Also claimed is a process for ink jet printing using the inks, a process for ink jet printing of textiles using the inks and a toner containing a dye with at least one group of Formula (1).
    • 一种油墨组合物,其包含:(i)式(1)的染料或其盐:式(1)ESO 2 NHCH 2 CH 2 Z其中:A是任选取代的亚苯基; B和E各自独立地为任选取代的亚苯基或任选取代的亚萘基; D是耦合元件; 每个R 1独立地是H或任选取代的烷基; X是不稳定或不稳定的原子或组; 各Z独立地为-OR3,-SR3,-NR4R5或-Y-SO3H,其中Y为O或S; 并且R 3,R 4和R 5各自独立地为H,任选取代的烷基,任选取代的烯基,环烷基,任选取代的芳烷基,任选取代的芳基或R 4或R 5与它们所连接的氮原子一起形成5或6元环; 和(ii)包含低熔点固体,有机溶剂或水与一种或多种水溶性有机溶剂的混合物的介质。 还要求保护的是使用油墨的喷墨印刷方法,使用该油墨的纺织品的喷墨印刷方法和含有至少一种式(1)的染料的调色剂。
    • 24. 发明授权
    • Monoazo dyestuffs, a composition and an ink for ink jet printing comprising them
    • 单色染料,包含它们的组合物和用于喷墨印刷的油墨
    • US06488752B1
    • 2002-12-03
    • US09623082
    • 2000-08-28
    • Mark KenworthyRonald Wynford Kenyon
    • Mark KenworthyRonald Wynford Kenyon
    • C09D1100
    • C09D11/328C09B44/08
    • Compounds of Formula (1) and salts and tautomers thereof, inks containing a compound of Formula (1), an ink jet printing process using the inks, substrates printed with the inks and ink jet printer cartridges containing the inks: wherein: R1 and R2 each independently is H, optionally substituted alkyl, optionally substituted aryl or optionally substituted arylalkyl; each W and each X independently is —COOH, —SO3H, —PO3H2 or alkyl substituted by one or more groups selected from —COOH, —SO3H and —PO3H2; each Y and each Z independently is a substituent other than those defined for W and X; a and d each independently is 1 to 5; b and c each independently is 0 to 4; (a+b) has a value of 5 or less; and (c+d) has a value of 5 or less.
    • 式(1)的化合物及其盐和互变异构体,含有式(1)化合物的油墨,使用油墨的喷墨印刷方法,用油墨印刷的基材和含有油墨的喷墨打印机墨盒:其中:R1和R2 各自独立地为H,任选取代的烷基,任选取代的芳基或任选取代的芳基烷基;每个W和每个X独立地是-COOH,-SO 3 H,-PO 3 H 2或被一个或多个选自-COOH,-SO 3 H和-PO 3 H 2的基团取代的烷基 ;每个Y和每个Z独立地是除了对W和X定义的取代基以外的取代基; a和d各自独立地为1至5; b和c各自独立地为0至4;(a + b)的值为5或 减; 和(c + d)的值为5以下。
    • 26. 发明授权
    • Phthalocyanine compounds used in inks for ink jet printing
    • 用于喷墨印刷油墨的酞菁化合物
    • US06235097B1
    • 2001-05-22
    • US09486832
    • 2000-03-02
    • Mark KenworthyPeter Gregory
    • Mark KenworthyPeter Gregory
    • C09D1102
    • C09D11/328C09B47/20C09B47/24
    • Suitable phthalocyanine compounds of Formula (1) have utility as colorants in inks for ink-jet printing, where Formula (1) represents: which comprises any form of the compound: such as salt; stereoisomer, zwitterion, polymorph, complex, isotopic form, combinations thereof in the same species and mixtures thereof; where: M represents a metal or H; Pc represents a phthalocyanine nucleus of Formula (2): L represents a linking group comprising an optionally substituted C1-30hydrocarbyl; A represents a group comprising at least one of: amino and optionally substituted C1-30hydrocarbyl comprising at least one protonable nitrogen atom; but where A comprises other than an alkyl group substituted by at least one of: hydroxy, carboxy and sulpho; R1 represents a group independently comprising at least one of: an optional substituent and optionally substituted C1-5hydrocarbyl; z represents an integer from 0 to 4; w represents an integer from 1 to 5; and the sum of w+z is from 1 to 5; and x and y each independently represent a non-zero number; and the mean of the sum of x+y is from about 1 to about 6; where the optional substituents comprise at least one of: carboxy, sulpho, hydroxy, amino, mercapto, cyano, nitro and halo.
    • 式(1)的合适的酞菁化合物可用作喷墨印刷用油墨中的着色剂,其中式(1)表示:其包含任何形式的化合物如盐; 立体异构体,两性离子,多晶型物,复合物,同位素形式,它们在同一物种及其混合物中的组合; 其中:M表示金属或H; Pc表示式(2)的酞菁核:L表示包含任选取代的C 1-30烃基的连接基团; A表示包含至少一个氨基和任选取代的C 1-30烃基 包含至少一个可质子化的氮原子; 但是其中A不包括被至少一个羟基,羧基和磺基取代的烷基; R 1表示独立地包含任选的取代基和任选取代的C 1-5烃基中的至少一个的基团; z表示0至 4; w表示1〜5的整数, w + z的和为1〜5; andx和y各自独立地表示非零数; 并且x + y之和的平均值为约1至约6;其中任选的取代基包括以下中的至少一个:羧基,磺基,羟基,氨基,巯基,氰基,硝基和卤素。