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21. 发明专利

JPH0619074B2 失效
公开(公告)号：JPH0619074B2
公开(公告)日：1994-03-16
申请号：JP18936386
申请日：1986-08-12
申请人： CATALYSTS & CHEM IND CO
发明人： SATO GORO , KOMATSU MICHIO , YOSHITOME HIROO , HIRAI TOSHIHARU
IPC分类号： H01B1/20 , C09D5/24 , H01B1/22

22. 发明专利

JPH0516906B2 失效
公开(公告)号：JPH0516906B2
公开(公告)日：1993-03-05
申请号：JP5389784
申请日：1984-03-21
申请人： CATALYSTS & CHEM IND CO
发明人： SATO GORO , OGATA MASAMITSU , HIRAI TOSHIHARU
IPC分类号： C10G11/02 , B01J29/06 , B01J29/08 , C10G11/00 , C10G11/05
摘要： Impregnation of a crystalline aluminosilicate-containing racking catalyst with a metal component of Group IVB enhanes the catalytic activity, gasoline selectivity and thermal and ydrothermal stability of the catalyst, and further improves the atalyst's capacity of producing a high-octane gasoline.

23. 发明专利

JPS63190175A BASE MATERIAL HAVING TRANSPARENT FILM 失效
公开(公告)号：JPS63190175A
公开(公告)日：1988-08-05
申请号：JP2383387
申请日：1987-02-03
申请人： CATALYSTS & CHEM IND CO
发明人： SATO GORO , KOMATSU MICHIO , HIRAI TOSHIHARU , MIHARA KEIICHI
IPC分类号： H01L21/316 , C03C17/25 , C08J7/04 , C09D1/00 , C23C18/12
摘要： PURPOSE:To form a transparent film having superior scratch resistance by adding an oxyacid salt of zirconium and a silicon alkoxide or a deriv. thereof to a mixed soln. consisting of water and an org. solvent, further adding nonsettleable silica sol as required, mixing them and applying the resulting soln. to the surface of glass, plastics or the like. CONSTITUTION:An oxyacid salt of zirconium such as zirconium oxychloride or zirconium oxynitrate and a silicon alkoxide represented by a formula SiHa(OR)b (where a=0-3, b=1-4 and R is 1-8C alkoxy) or a deriv. thereof are added to a mixed soln. consisting of water and an org. solvent such as methanol or ethanol. After nonsettleable silica sol is further added as required, they are uniformly mixed and the resulting soln. is applied to the surface of a substrate of glass, plastics or the like. An SiO2-base film having superior scratch resistance, adhesion and transparency is formed without requiring baking at high temp.

24. 发明专利

JPS63143705A TRANSPARENT CONDUCTING COAT LIQUID COMPOSITION AND BASE MATERIAL HAVING TRANSPARENT CONDUCTING FILM 失效
公开(公告)号：JPS63143705A
公开(公告)日：1988-06-16
申请号：JP28892386
申请日：1986-12-05
申请人： CATALYSTS & CHEM IND CO
发明人： SATO GORO , KOMATSU MICHIO , HIRAI TOSHIHARU , MIHARA KEIICHI
IPC分类号： C09D1/00 , H01B1/16 , H01B5/00 , H01B5/14 , H01B13/00

25. 发明专利

JPS63130674A COATING FLUID COMPOSITION 失效
公开(公告)号：JPS63130674A
公开(公告)日：1988-06-02
申请号：JP27675886
申请日：1986-11-21
申请人： CATALYSTS & CHEM IND CO
发明人： SATO GORO , KOMATSU MICHIO , HIRAI TOSHIHARU , MIHARA KEIICHI
IPC分类号： H01L21/316 , C03C17/25 , C08J7/06 , C09D1/00 , C09D5/24 , H01L21/027 , H01L21/30
摘要： PURPOSE:To obtain the title composition which can form a coating film with excellent durability, strength, and adhesiveness without deteriorating the transparency of a transparent base material such as glass or synthetic resin, by uniformly mixing the zirconium salt of an oxy acid with water, a specified stabilizer, and a specified diluent. CONSTITUTION:0.1-20wt%, on a ZrO2 basis, zirconium salt of an oxy acid (e.g., zirconium oxychloride or zirconium oxynitrate) is mixed with water in an amount sufficient to provide a weight ratio of H2O to ZrO2 of 0.1-1, and the balance of a stabilizer. As stabilizer, N-methyl-2-pyrrolidone, N,N- dimethylformamide, morpholine, methyl Cellosolve, ethyl Cellosolve, ethylene glycol, etc. are suitably used. The mixture thus obtained is uniformly diluted with a diluent (e.g., methanol or n-propanol) to give an objective coating fluid composition. In addition, a conductive substance, etc., can be incorporated into this composition.

26. 发明专利

JPS62230617A TIN OXIDE SOL AND PRODUCTION THEREOF 失效
公开(公告)号：JPS62230617A
公开(公告)日：1987-10-09
申请号：JP7528386
申请日：1986-04-01
申请人： CATALYSTS & CHEM IND CO
发明人： SATO GORO , KOMATSU MICHIO , KOYANAGI TSUGUO , YOSHITOME HIROO , HIRAI TOSHIHARU , MIHARA KEIICHI
IPC分类号： C01G19/02 , C08K9/02 , C09C1/00 , C09D5/24
摘要： PURPOSE:To obtain the titled sol which provides a highly electrically-conductive transparent coating film without damaging transparency of substrate and has extremely improved long-term stability, by heat-treating tin oxide powder (doped with different element) in an aqueous solution of an acid or an alkali. CONSTITUTION:(A) =5wt% (based on the component A) acid such as mineral acid, (hydroxy)carboxylic acid, etc., or alkali such as alkali metallic hydroxide (e.g. KOH), etc., and heat-treated at 30-200 deg.C at normal pressure or under pressure to give aqueous sol of tin oxide wherein colloidal particles which have =60% based on the total particles of particles with

27. 发明专利

JP2006339113A Manufacturing method of chain-shaped conductive fine particle, chain-shaped conductive fine particle, paint for transparent conductive coating formation, and base material with transparent conductive coating 有权
标题翻译：链形导电精细颗粒，链形导电精细颗粒，透明导电涂层涂料和透明导电涂料基材的制造方法
公开(公告)号：JP2006339113A
公开(公告)日：2006-12-14
申请号：JP2005165710
申请日：2005-06-06
申请人： Catalysts & Chem Ind Co Ltd , 触媒化成工業株式会社
发明人： MATSUDA MASAYUKI , KUMAZAWA MITSUAKI , HIRAI TOSHIHARU
IPC分类号： H01B13/00 , C09D5/24 , C09D7/12 , C09D201/00 , H01B1/20 , H01B5/00 , H01B5/14
摘要： PROBLEM TO BE SOLVED: To provide a manufacturing method of chain-shaped conductive fine particle and a usage of the chain-shaped conductive fine particle. SOLUTION: In the manufacturing method of the chained conductive particulate, after a pH of aqueous dispersion liquid of the conductive fine particle is adjusted to 2 to 5, a density of a solid content is adjusted to 10 to 40 wt.%, and the dispersion liquid of conductive fine particle is hydrolyzed by adding hydrolytic organic silicon compound expressed in the following formula (1) and alcohol. In the formula (1): R 1 a Si(OR 2 ) 4-a , R 1 and R 2 denote a hydrogen atom, halogen atom, and organic group with the carbon number of 1 to 10 selected from substituted or non-substituted hydrocarbon groups, wherein (a) is an integer of 0 to 3. The pH adjustment is made by treating with an H-type ion exchange resin. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供链状导电性微粒的制造方法和链状导电性微粒的用途。解决方案：在链状导电颗粒的制造方法中，将导电性微粒的水分散液的pH调节至2〜5之后，将固体成分的密度调整为10〜40重量％并且通过加入下式（1）表示的水解有机硅化合物和醇将导电性细颗粒的分散液水解。在式（1）中：R 1 S（OR SP＆gt; 2＆lt; SP＆gt;） > 1 和R 2 表示氢原子，卤素原子和碳数为1至10的选自取代或未取代的烃基的有机基团，其中（a）为 0〜3的整数。通过用H型离子交换树脂处理进行pH调节。版权所有（C）2007，JPO＆INPIT

28. 发明专利

JP2006143535A Zirconia sol and its manufacturing method 有权
标题翻译： ZIRCONIA SOL及其制造方法
公开(公告)号：JP2006143535A
公开(公告)日：2006-06-08
申请号：JP2004336595
申请日：2004-11-19
申请人： Catalysts & Chem Ind Co Ltd , 触媒化成工業株式会社
发明人： HIYOUHAKU YUJI , HIRAI TOSHIHARU
IPC分类号： C01G25/02 , B01J13/00
摘要： PROBLEM TO BE SOLVED: To manufacture a zirconia sol in a colloid region having a uniform particle size distribution and being excellent in stability.
SOLUTION: A method to manufacture the sol in which fine zirconia particles whose mean particle diameter is 5-100 nm are dispersed comprises steps (a)-(e); (a) a step to prepare the dispersion liquid of a zirconium hydroxide gel by adding an alkali aqueous solution in a zirconium compound aqueous solution in the presence of a particle growth regulator, (b) a step to wash the zirconium hydroxide gel, (c) a step to age the dispersion liquid of the washed zirconium hydroxide gel, (d) a step to wash the aged zirconium hydroxide gel and (e) a step to treat the washed dispersion liquid of the zirconium hydroxide gel hydrothermally in the presence of the particle growth regulator. The particle growth regulator is a carboxylic acid or a hydroxycarboxylic acid and the hydrothermal treatment is performed in the range of 100-250°C.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：待解决的问题：在具有均匀粒度分布且稳定性优异的胶体区域中制造氧化锆溶胶。解决方案：制造其平均粒径为5-100nm的细小氧化锆颗粒分散的溶胶的方法包括步骤（a） - （e）; （a）在粒子生长调节剂的存在下，通过在锆化合物水溶液中添加碱性水溶液来制备氢氧化锆凝胶的分散液的步骤，（b）洗涤氢氧化锆凝胶的步骤，（c ）洗涤的氢氧化锆凝胶的分散液的老化步骤，（d）洗涤老化的氢氧化锆凝胶的步骤和（e）在存在氢氧化锆存在下水热处理氢氧化锆凝胶的洗涤分散液的步骤颗粒生长调节剂。颗粒生长调节剂是羧酸或羟基羧酸，水热处理在100-250℃的范围内进行。版权所有（C）2006，JPO＆NCIPI

29. 发明专利

JP2006016480A Curable composition and transparent substrate having cured coated film of the composition 审中-公开
标题翻译：具有组合物的固化涂膜的可固化组合物和透明基材
公开(公告)号：JP2006016480A
公开(公告)日：2006-01-19
申请号：JP2004195252
申请日：2004-07-01
申请人： Catalysts & Chem Ind Co Ltd , Sumitomo Chemical Co Ltd , 住友化学株式会社 , 触媒化成工業株式会社
发明人： OCHIAI SHINSUKE , KUMAZAWA MITSUAKI , HIRAI TOSHIHARU
IPC分类号： C08G65/18 , B32B9/00 , C08K9/06 , C08L71/02 , C09C1/28 , C09C3/12 , C09D5/00 , C09D7/12 , C09D171/00 , C09D183/06
摘要： PROBLEM TO BE SOLVED: To provide a curable composition capable of forming a coating film excellent in hardness and close adhesion and capable of constituting a stable coating hardly forming precipitation, and also a transparent substrate having the cured coated film excellent in hardness and close adhesion by using the same on its surface.
SOLUTION: This curable composition is constituted by a cationic polymerizable compound with porous silica fine particles of which surfaces are modified with an organic group. The coated film obtained by curing the curable composition is formed on the surface of the transparent substrate. As the cationic polymerizable compound, a compound having at least 2 oxetane rings in its molecule, a compound having silyl group in its molecule or its hydrolytic condensate is used preferably.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供一种能够形成硬度和密合性优异并且能够形成几乎不形成沉淀的稳定涂层的涂膜的固化性组合物，以及具有硬度和硬度优异的固化涂膜的透明基材，在其表面上使用相同的粘合力。解决方案：该可固化组合物由具有多孔二氧化硅细颗粒的阳离子可聚合化合物构成，其表面用有机基团改性。通过固化可固化组合物获得的涂膜形成在透明基板的表面上。作为阳离子聚合性化合物，优选使用分子中具有至少2个氧杂环丁烷环的化合物，分子中具有甲硅烷基的化合物或其水解缩合物。版权所有（C）2006，JPO＆NCIPI

30. 发明专利

JP2005139026A Chain-like antimony oxide fine particles, method for producing dispersion including the fine particles, and application of the dispersion 有权
标题翻译：链式抗氧化精细颗粒，生产包含微细颗粒的分散体的方法和分散体的应用
公开(公告)号：JP2005139026A
公开(公告)日：2005-06-02
申请号：JP2003376812
申请日：2003-11-06
申请人： Catalysts & Chem Ind Co Ltd , 触媒化成工業株式会社
发明人： MURAGUCHI MAKOTO , MATSUDA MASAYUKI , NISHIDA HIROYASU , HIRAI TOSHIHARU
IPC分类号： B32B27/18 , C01G30/00
摘要： PROBLEM TO BE SOLVED: To provide a dispersion including dispersed chain-like antimony oxide fine particles which can be suitably used for forming a transparent coating which exhibits high electric conductivity, transparency, and therefore excellent antistatic characteristics because the antimony oxide fine particles (colloid) having a very small average particle diameter and a very narrow particle diameter distribution are connected in a chain form, and to provide a method for producing the same.
SOLUTION: In the chain-like antimony oxide fine particles, the antimony oxide fine particles having an average particle diameter of 5 to 50 nm are connected in a chain form, and the average number of connected particles is within a range of 2 to 30. The method for producing the dispersion including the chain-like antimony oxide fine particles includes the steps of: preparing an antimonic acid (gel) dispersion by treating an aqueous solution of an alkali antimonate with a cation exchange resin; and treating the dispersion with an anion exchange resin and/or adding a base to the dispersion.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：解决的问题：为了提供一种分散链状氧化锑微粒，其可适用于形成透明涂层，其透明性高，因此具有优异的抗静电特性，因为氧化锑微粒具有非常小的平均粒径和非常窄的粒径分布的（胶体）以链形式连接，并提供其制造方法。解决方案：在链状氧化锑微粒中，平均粒径为5〜50nm的氧化锑微粒以链状连接，平均连接粒子数在2以下的范围内 30.包含链状氧化锑微粒的分散体的制造方法包括以下步骤：通过用阳离子交换树脂处理碱金属锑酸盐水溶液来制备锑酸（凝胶）分散体; 并用阴离子交换树脂处理分散体和/或向分散体加入碱。版权所有（C）2005，JPO＆NCIPI

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