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    • 25. 发明授权
    • Silicide composite with niobium-based metallic phase and
silicon-modified laves-type phase
    • 具有铌基金属相和硅改性的菱形相的硅化物复合材料
    • US5932033A
    • 1999-08-03
    • US133365
    • 1998-08-12
    • Melvin Robert JacksonBernard Patrick Bewlay
    • Melvin Robert JacksonBernard Patrick Bewlay
    • C22C27/02C22C29/18
    • C22C29/18C22C27/02
    • A silicide-based composite toughened with a niobium-based metallic phase, and further containing a phase that significantly improves the oxidation resistance of the composite. The oxidation-resistant phase is a chromium-based Laves-type phase modified with silicon, which has been shown to greatly increase the oxidation resistance of silicide-based composites at temperatures of up to 1200 C. The oxidation-resistant silicide-based composite generally contains one or more silicide intermetallic phases, each of which is an M.sub.5 Si.sub.3 -type phase where M is Nb+Ti+Hf. The niobium-based metallic phase contains niobium, titanium, hafnium, chromium, aluminum and silicon. The silicon-modified Laves-type phase is of the Cr.sub.2 M type where M is Nb+Ti+Hf. A silicide-based composite contains, in atomic percent, about 12-25% titanium, about 6-12% hafnium, about 15-25% chromium, about 1-8% aluminum and about 12-20% silicon, with the balance essentially niobium.
    • 一种用铌基金属相增韧的硅化物基复合材料,并且还含有显着提高复合材料的抗氧化性的相。 耐氧化相是用硅改性的基于铬的Laves型相,其已经显示出在高达1200℃的温度下大大提高了硅化物基复合材料的抗氧化性。基于耐氧化硅化物的复合材料通常 含有一个或多个硅化物金属间相,每一个都是M5Si3型相,其中M是Nb + Ti + Hf。 铌基金属相包含铌,钛,铪,铬,铝和硅。 硅改性的Laves型相是Cr2M型,其中M是Nb + Ti + Hf。 硅化物基复合材料以原子百分比含有约12-25%的钛,约6-12%的铪,约15-25%的铬,约1-8%的铝和约12-20%的硅,余量基本上 铌。