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21. 发明专利

CA867390A PRODUCTION OF CARBONYL COMPOUNDS SUBSTITUTED IN .alpha.-POSITION 未知
公开(公告)号：CA867390A
公开(公告)日：1971-03-30
申请号：CA867390D
申请人： BASF AG
发明人： METZGER HORST , KOENIG HORST , REIF WERNER

22. 发明专利

GB1136747A Continuous photooximation of cyclododecane 未知
公开(公告)号：GB1136747A
公开(公告)日：1968-12-18
申请号：GB1722566
申请日：1966-04-20
申请人： BASF AG
发明人： BEER LUDWIG , PAPE MARTIN , METZGER HORST
IPC分类号： B01J19/12
摘要： 1,136,747. Cyclododecane oxime. BADISCHE ANILIN- & SODA-FABRIK A.G. 20 April, 1966 [21 April, 1965], No. 17225/66. Heading C2C. Cyclododecane is converted to its oxime by treating a solution of cyclododecane in chlorobenzene with a nitrosating agent and with light having a wavelength of 360-600 millimicrons while mixing the reaction mixture with turbulence, the cyclododecane oxime being removed from the reaction mixture outside the reaction zone by extraction with strong sulphuric acid. Suitable nitrosating agents are, for example, nitrosyl chloride or compounds which form nitrosyl chloride in the reaction medium. If desired, the process may be carried out in the presence of hydrogen chloride.

23. 发明专利

GB1087603A Production of ªŠ-cyanocaproic acid 未知
公开(公告)号：GB1087603A
公开(公告)日：1967-10-18
申请号：GB505265
申请日：1965-02-05
申请人： BASF AG
发明人： METZGER HORST , PAPE MARTIN
摘要： e -Cyanocaproic acid is obtained by reacting a -cyanocyclohexanone with an alkali metal glycolate in a glycol as solvent at 150 DEG -250 DEG C., with substantial exclusion of water, i.e. more than 50 mole per cent of the alkali metal ions present being in the form of glycolate. The preferred reaction temperature is 150 DEG -250 DEG C.

24. 发明专利

CA737520A PURIFICATION OF ACRYLAMIDE 未知
公开(公告)号：CA737520A
公开(公告)日：1966-06-28
申请号：CA737520D
申请人： BASF AG
发明人： METZGER HORST , BEER LUDWIG , BRUNNMUELLER FRIEDRICH

25. 发明专利

FR1423579A 未知
公开(公告)号：FR1423579A
公开(公告)日：1966-01-03
申请号：FR4601
申请日：1965-02-05
申请人： BASF AG
发明人： METZGER HORST , PAPE MARTIN

26. 发明专利

FR1408203A 未知
公开(公告)号：FR1408203A
公开(公告)日：1965-08-13
申请号：FR969639
申请日：1964-04-03
申请人： BASF AG
发明人： METZGER HORST , KOENIG HORST
IPC分类号： C08G18/38

27. 发明专利

CA697452A PRODUCTION OF ALPHA-MONOCHLORO-CARBOXYLIC ACIDS 未知
公开(公告)号：CA697452A
公开(公告)日：1964-11-10
申请号：CA697452D
申请人： BASF AG
发明人： SCHICKH OTTO VON , METZGER HORST

28. 发明专利

FR1365110A 未知
公开(公告)号：FR1365110A
公开(公告)日：1964-06-26
申请号：FR943588
申请日：1963-08-02
申请人： BASF AG
发明人： METZGER HORST

29. 发明专利

GB948544A Production of ªÏ-laurolactam 未知
公开(公告)号：GB948544A
公开(公告)日：1964-02-05
申请号：GB4658361
申请日：1961-12-29
申请人： BASF AG
发明人： METZGER HORST , URBACH HANS
IPC分类号： C07D20060101
摘要： o -Laurolactam is prepared by mixing cyclododecane carboxylic acid or an alkali metal or alkaline earth metal salt thereof with at least one, and up to two, equivalents of nitroacting agent derived from nitrous acid in the presence of at least one mole of sulphuric acid and/or oleum per mole of cyclododecane carboxylic acid. Suitable nitrosating agents are, for example, nitrosyl chloride, alkyl nitrites, sodium nitrite, dinitrogen trioxide or, preferably, nitrosylsulphonic acid or anhydride. The reaction temperature in general is 0 DEG to 150 DEG C, but it is recommendable to use at least 35 DEG C., and the reaction may be initiated by addition of a small amount, e.g. 1 to 20% by weight, of o -laurolactam to the mixture of reactants or by temporarily increasing the reaction temperature. In a preferred embodiment the nitrosating agent in sulphuric acid or oleum solution is introduced into a solution or suspension of cyclododecane carboxylic acid, or salt thereof, in sulphuric acid or a solvent, e.g. cyclohexane, at such a rate that CO2 escapes continuously. After the complete addition the mixture is stirred for a short time and poured on to ice or into water to precipitate the o -laurolactam. The cyclododecane carboxylic acid or alkali metal or alkaline earth metal salts thereof may be prepared by the trimerisation of butadiene to cyclododecatriene (1, 5, 9), conversion of the trimer into monohydroxymethyl cyclododecane by the oxo synthesis and oxidation of the last mentioned compound to the acid by, for example, alkali fusion.

30. 发明专利

CA650055A PRODUCTION OF OMEGA-AMINODODECANE ACID LACTAM, AND A NEW INTERMEDIATE COMPOUND THEREIN 未知
公开(公告)号：CA650055A
公开(公告)日：1962-10-09
申请号：CA650055D
申请人： BASF AG
发明人： SCHICKH OTTO VON , METZGER HORST

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