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21. 发明申请

WO2006045687A1 1-BUTENE POLYMER AND PROCESS FOR THE PREPARATION THEREOF 审中-公开
标题翻译： 1-BOTENE聚合物及其制备方法
公开(公告)号：WO2006045687A1
公开(公告)日：2006-05-04
申请号：PCT/EP2005/054916
申请日：2005-09-29
申请人： BASELL POLYOLEFINE GMBH , RESCONI, Luigi , TONTI, Maria Silvia , MORHARD, Friederike
发明人： RESCONI, Luigi , TONTI, Maria Silvia , MORHARD, Friederike
IPC分类号： C08F10/08 , C08F4/6592
CPC分类号： C08F10/08 , C08F4/65912 , C08F110/08 , C08F210/08 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F2500/03 , C08F2500/12 , C08F2500/15 , C08F2500/17
摘要： A 1-butene polymer optionally containing from 0 to 30% by mol of derived units of ethylene, propylene or alpha-olefÊn of formula CH2=CHZ, wherein Z is a C 3 -C 20 linear or branched alkyl radical, having the following features: a) distribution of molecular weight (Mw/Mn) lower than 4; b) Melt flow rate (MFR) measured according to ISO 1133 (190°C, 2.16kg); c) Intrinsic viscosity (IV) measured in tetrahidronaftalene (THN) at 135°C lower than 0.8 dl/g; d) melting point higher than 100°C; e) isotactic pentads (mmmm) measured with 13 C-NMR operating at 100.61 MHz higher than 90%; f) 4,1 insertions not detectable at a C 13 -NMR operating at 100.61 MHz; and g) a yellowness index lower than 0. A process for preparing such a 1-butene polymer using a particular metallocene-based catalyst system is also disclosed in the present invention.
摘要翻译：任选地含有0至30摩尔％的式CH 2 = CHZ的乙烯，丙烯或α-烯烃的衍生单元的1-丁烯聚合物，其中Z为C 3 -C 20 具有以下特征：a）分子量（Mw / Mn）低于4的分布; b）根据ISO 1133（190℃，2.16kg）测量的熔体流动速率（MFR）; c）在135℃下在四氯苯腈（THN）中测量的特性粘度（IV）低于0.8dl / g; d）熔点高于100℃; e）以100.61MHz高于90％的13 C-NMR测量的全同立构五单元组（mmmm）; f）在100.61MHz操作的C 13 NMR下不能检测到4,1个插入; 和g）黄色指数低于0.在本发明中还公开了使用特定的茂金属系催化剂体系制备这种1-丁烯聚合物的方法。

22. 发明申请

WO2005023891A1 MULTISTEP PROCESS FOR PREPARING HETEROPHASIC PROPYLENE COPOLYMERS 审中-公开
标题翻译：制备异构丙烯共聚物的多步骤方法
公开(公告)号：WO2005023891A1
公开(公告)日：2005-03-17
申请号：PCT/EP2004/008902
申请日：2004-08-06
申请人： BASELL POLYOLEFINE GMBH , PELLICONI, Anteo , TONTI, Maria, Silvia , RESCONI, Luigi
发明人： PELLICONI, Anteo , TONTI, Maria, Silvia , RESCONI, Luigi
IPC分类号： C08F297/08
CPC分类号： C08F10/00 , C08F4/65912 , C08F210/06 , C08F297/08 , C08F297/083 , C08L23/0815 , C08L23/14 , C08L2207/02 , C08L2308/00 , C08F4/65916 , C08F4/65927 , C08F2/001 , C08L2666/06 , C08F210/16 , C08F210/08 , C08F2500/18 , C08F2500/26
摘要： A multistage process comprising the step of polymerizing propylene in the presence the presence of a catalysts system, comprising one or more metallocene compound of formula (I): wherein M is an atom of a transition metal; p is an integer from 0 to 3, X, same or different, is a hydrogen atom, a halogen atom, or a hydrocarbon group; L is a divalent bridging R 1 and R 2 , are C 1 -C 20 -alkyl radicals; T, equal to or different from each other, is a moiety of formula (Ilb) or (Ila): wherein R 3 , R 4 , R 5 , R 6 , R 7 , R 3’ , R 4’ , R 5’ ,R 6’ and R 7’ , are hydrogen atoms or hydrocarbon groups; with the proviso that at least one among R 3 , R 4 , R 5 , R 6 , R 7 is different from hydrogen; R 11 is a hydrogen atom or a hydrocarbon group; R 8 , R 9 and R 10 , are hydrogen atoms or hydrocarbon groups; and further comprising the step of contacting, under polymerization conditions, in a gas phase, ethylene and one or more comonomers. Where the amount of the polymer obtained in the first step ranges from 5% by weight and 90% by weight, of the polymer obtained in the whole process.
摘要翻译：一种多级方法，包括在存在催化剂体系的情况下聚合丙烯的步骤，所述催化剂体系包含一种或多种式（I）的茂金属化合物：其中M是过渡金属的原子; p为0〜3的整数，X相同或不同，为氢原子，卤素原子或烃基; L是二价桥连R 1和R 2是C 1 -C 20 - 烷基; T是相同或不同的，是式（IIb）或（IIa）的部分：其中R 3，R 4，R 5，R 6，R 7，R R 4，R 5，R 6和R 7均为氢原子或烃基; 条件是R 3，R 4，R 5，R 6，R 7中的至少一个不同于氢; R 11是氢原子或烃基; R 8，R 9和R 10是氢原子或烃基; 并且还包括在聚合条件下在气相中接触乙烯和一种或多种共聚单体的步骤。如果在第一步骤中获得的聚合物的量为5重量％和90重量％，则在整个工艺中获得的聚合物。

23. 发明申请

WO2005023889A1 MULTISTEP PROCESS FOR PREPARING HETEROPHASIC PROPYLENE COPOLYMERS 审中-公开
标题翻译：制备异构丙烯共聚物的多步骤方法
公开(公告)号：WO2005023889A1
公开(公告)日：2005-03-17
申请号：PCT/EP2004/008759
申请日：2004-08-04
申请人： BASELL POLYOLEFINE GMBH , RESCONI, Luigi , FERRARI, Paolo , CECCHIN, Giuliano
发明人： RESCONI, Luigi , FERRARI, Paolo , CECCHIN, Giuliano
IPC分类号： C08F297/08
CPC分类号： C08F10/00 , C08F4/65912 , C08F210/06 , C08F297/08 , C08F297/083 , C08L23/0815 , C08L23/14 , C08L2207/02 , C08L2308/00 , C08F4/65927 , C08F4/027 , C08F2/001 , C08L2666/06 , C08F210/16 , C08F210/08 , C08F2500/18 , C08F2500/17 , C08F2500/15
摘要： A multistage process for obtaining an heterophasic propylene polymer comprising the following steps: step a) contacting under polymerization conditions propylene and optionally ethylene or one or more alpha olefins in the presence of a catalysts system, supported on a porous organic polymer, comprising: ii) one or more metallocene compounds of formula (1) wherein: M is an atom of a transition metal; p is an integer from 0 to 3; X, same or different, is a hydrogen atom, a halogen atom, or a hydrocarbon group; L is a divalent bridging group; R 1 , is a linear or branched, saturated or unsaturated C 1 -C 20 -alkyl radical; R 2 is a branched C 1 -C 20 -alkyl radical; T, equal to or different from each other is a moiety of formula : wherein: the atom marked with the symbol bonds the atom marked with the same symbol in the compound of formula (I); R 5 -R 13 , equal to or different from each other, are hydrogen atoms or hydrocarbon groups; ii) an alumoxane or a compound capable of forming an alkyl metallocene cation; and optionally iii) an organo aluminum compound; step b) contacting, under polymerization conditions, in a gas phase, ethylene and one or more alpha olefins and optionally in the presence of an additional organo aluminum compound.
摘要翻译：用于获得多相丙烯聚合物的多阶段方法包括以下步骤：步骤a）在负载在多孔有机聚合物上的催化剂体系存在下，在聚合条件下使丙烯和任选的乙烯或一种或多种α-烯烃接触，包括：ii）一种或多种式（1）的茂金属化合物，其中：M是过渡金属的原子; p是0至3的整数; X相同或不同，是氢原子，卤素原子或烃基; L是二价桥基; R 1是直链或支链饱和或不饱和的C 1 -C 20 - 烷基; R 2是支链C 1 -C 20 - 烷基; T是相同或不同的，是下式的部分：其中：标记有符号的原子与式（I）化合物中与相同符号标记的原子键合; R 5〜R 13彼此相同或不同，为氢原子或烃基; ii）铝氧烷或能够形成烷基茂金属阳离子的化合物; 和任选地iii）有机铝化合物; 步骤b）在聚合条件下，在气相，乙烯和一种或多种α-烯烃中以及任选地在另外的有机铝化合物的存在下接触。

24. 发明申请

WO2005095474A1 PROCESS FOR POLYMERIZING 1-HEXENE OR HIGHER ALPHA-OLEFINS 审中-公开
标题翻译：聚合1-HEXENE或更高的ALPHA-OLEFINS的方法
公开(公告)号：WO2005095474A1
公开(公告)日：2005-10-13
申请号：PCT/EP2005/002481
申请日：2005-03-08
申请人： BASELL POLYOLEFINE GMBH , RESCONI, Luigi , CIACCIA, Eleonora , MORHARD, Friederike , PELLEGATTI, Giampaolo
发明人： RESCONI, Luigi , CIACCIA, Eleonora , MORHARD, Friederike , PELLEGATTI, Giampaolo
IPC分类号： C08F210/14
CPC分类号： C08F210/14 , C08F4/65912 , Y10S526/943 , C08F4/65927 , C08F210/08 , C08F2500/17 , C08F2500/03 , C08F210/06
摘要： A process for preparing a polymer containing derived units of one or more alpha olefins of formula CH 2 =CHW wherein W is a C 3 -C 10 hydrocarbon radical and optionally from 0 to 81% by mol of derived units of propylene or 1-buténe, comprising contacting under polymerization conditions one or more alpha olefins of formula CH 2 =CHW and optionally propylene or 1-butene in the presence of a catalyst system obtainable by contacting: a) a metallocene compound of formula (I), wherein M, X, L, T 1 , T 2 , T 3 and R l are described in the text; and (b) an alumoxane or a compound capable of forming an alkyl metallocene cation.
摘要翻译：一种制备含有一种或多种式CH 2 = CHW的α-烯烃的衍生单元的聚合物的方法，其中W是C 3 -C 10烃基和任选地0至81摩尔％的丙烯或1-丁烯衍生单元，包括接触在聚合条件下，在催化剂体系存在下，式CH 2 = CHW的α-烯烃和任选的丙烯或1-丁烯可通过以下方式获得：a）式（I）的茂金属化合物，其中M，X，L，T <1>，T 2，T 3和R 1在文中描述; 和（b）铝氧烷或能够形成烷基茂金属阳离子的化合物。

25. 发明申请

WO2005095473A1 PROCESS FOR POLYMERIZING 1-HEXENE OR HIGHER ALPHA-OLEFINS 审中-公开
标题翻译：聚合1-HEXENE或更高的ALPHA-OLEFINS的方法
公开(公告)号：WO2005095473A1
公开(公告)日：2005-10-13
申请号：PCT/EP2005/002480
申请日：2005-03-08
申请人： BASELL POLYOLEFINE GMBH , RESCONI, Luigi , CIACCIA, Eleonora , MORHARD, Friederike , PELLEGATTI, Giampaolo?
发明人： RESCONI, Luigi , CIACCIA, Eleonora , MORHARD, Friederike , PELLEGATTI, Giampaolo?
IPC分类号： C08F210/14
CPC分类号： C08F210/14 , C08F4/65912 , Y10S526/943 , C08F4/65927 , C08F210/06 , C08F2500/17 , C08F2500/03 , C08F210/08
摘要： A process for preparing a polymer containing derived units of one or more alpha olefins of formula CH 2 =CHW wherein W is a C 3 -C 10 hydrocarbon radical and optionally from 0 to 81 % by mol of derived units of propylene or 1-butene, comprising contacting under polymerization conditions one or more alpha olefins of formula CH 2 =CHW and optionally propylene or 1-butene in the presence of a catalyst system obtainable by contacting: a) a metallocene compound of formula (I) wherein M, X, L, T, R1, R 2 , R 7 and R 8 are described in the text; and (b) an alumoxane or a compound capable of forming an alkyl metallocene cation.
摘要翻译：一种制备含有一种或多种式CH 2 = CHW的α-烯烃的衍生单元的聚合物的方法，其中W是C 3 -C 10烃基和任选地0至81摩尔％的丙烯或1-丁烯的衍生单元，包括接触在聚合条件下，一种或多种式CH2 = CHW的α-烯烃和任选的丙烯或1-丁烯在催化剂体系存在下可通过以下方式获得：a）式（I）的茂金属化合物，其中M，X，L，T， R 1，R 2，R 7和R 8如文中所述; 和（b）铝氧烷或能够形成烷基茂金属阳离子的化合物。

26. 发明申请

WO2005023892A1 MULTISTEP PROCESS FOR PREPARING HETEROPHASIC PROPYLENE COPOLYMERS 审中-公开
标题翻译：制备异构丙烯共聚物的多步骤方法
公开(公告)号：WO2005023892A1
公开(公告)日：2005-03-17
申请号：PCT/EP2004/008903
申请日：2004-08-06
申请人： BASELL POLYOLEFINE GMBH , PELLICONI, Anteo , TONTI, Maria, Silvia , RESCONI, Luigi
发明人： PELLICONI, Anteo , TONTI, Maria, Silvia , RESCONI, Luigi
IPC分类号： C08F297/08
CPC分类号： C08F210/06 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F297/08 , C08F297/083 , C08L23/0815 , C08L23/14 , C08L2207/02 , C08L2308/00 , C08F4/027 , C08F4/65927 , C08F2/001 , C08L2666/06 , C08F210/16 , C08F210/08 , C08F2500/18 , C08F2500/26
摘要： A multistage process comprising the following steps: a) polymerizing propylene with optionally one or more monomers selected from ethylene and alpha olefins of formula CH 2 =CHT 1 , wherein T 1 is a C 2 -C 20 alkyl radical in the presence of a catalysts system, supported on an inert carrier comprising: i) a transition metal compound containing a ligand having a cyclopentadienyl skeleton; and ii) an alumoxane or a compound capable of forming an alkyl metallocene cation; b) contacting, under polymerization conditions, in a gas phase, ethylene with one or more alpha olefins of fonnula CH 2 =CHT 1 , wherein T 1 is a C 2 -C 20 alkyl radical, and optionally a non-conjugated diene, in the presence of the polymer obtained in step a), in the presence of a weigh ratio hydrogen/hethylene higher than 1 ppm and optionally in the presence of an additional organo aluminum compound; wherein the amount of the polymer obtained in step a) ranges from 5% by weight and 90% by weight of the polymer obtained in the whole process and the amount of polymer obtained in step b) ranges from 10% by weight and 95% by weight of the polymer obtained in the whole process.
摘要翻译：一种多级方法，包括以下步骤：a）将丙烯与任选的一种或多种选自乙烯和式CH 2 = CHT 1的α-烯烃的单体聚合，其中T 1为C 2 -C 20烷基，催化剂体系，负载在惰性载体上，包括：i）含有具有环戊二烯基骨架的配体的过渡金属化合物; 和ii）铝氧烷或能够形成烷基茂金属阳离子的化合物; b）在聚合条件下，在气相中使乙烯与一种或多种CH 2 = CHT 1的α-烯烃接触，其中T 1是C 2 -C 20烷基，和任选的非共轭二烯，在步骤a）中获得的聚合物的存在下，在高于1ppm的氢/亚乙烯的重量比存在下，并且任选地在另外的有机铝化合物的存在下; 其中在步骤a）中获得的聚合物的量在整个方法中获得的聚合物的5重量％和90重量％的范围内，并且步骤b）中获得的聚合物的量为10重量％和95重量％在整个过程中获得的聚合物的重量。

27. 发明申请

WO2004099269A3 PROCESS FOR POLYMERIZING 1-BUTENE 审中-公开
公开(公告)号：WO2004099269A3
公开(公告)日：2004-11-18
申请号：PCT/EP2004/005078
申请日：2004-05-07
申请人： BASELL POLYOLEFINE GMBH , RESCONI, Luigi
发明人： RESCONI, Luigi
IPC分类号： C08F10/08
摘要： A process for polymerizing 1-butene, optionally with up to 3 0% by mol of ethylene, propylene or an alpha olefin of formula CH 2 =CHT wherein T is a C 3 -C lo alkyl group, in the presence of a catalyst system obtainable by contacting a metallocene compound of formula (I) Wherein M is an atom of a transition metal; X, is a hydrogen atom, a halogen atoms or a hydrocarbon group; R 1 , R 2 , R 5 , R 6 , R 7 , R 8 and R 9 are hydrogen atoms or hydrocarbon groups; with the proviso that at least one of R 6 or R 7 is a C 1 -C 20 alkyl group; R 3 and R 4 are C 1 -C 20 alkyl groups; and an alumoxane and/or a compound capable of forming an alkyl metallocene cation.

28. 发明申请

WO2004078804A3 CATALYST SYSTEM FOR THE POLYMERIZATION OF OLEFINS 审中-公开
公开(公告)号：WO2004078804A3
公开(公告)日：2004-09-16
申请号：PCT/EP2004/001847
申请日：2004-02-24
申请人： BASELL POLYOLEFINE GMBH , BUSICO, Vincenzo , GUARDASOLE, Mauro , CIPULLO, Roberta , RESCONI, Luigi , MORINI, Giampiero
发明人： BUSICO, Vincenzo , GUARDASOLE, Mauro , CIPULLO, Roberta , RESCONI, Luigi , MORINI, Giampiero
IPC分类号： C08F110/02
摘要： A heterogeneous catalyst component obtainable by contacting: (a) a solid Lewis acid of formula MR 1 a wherein M is a metal of group 1-12 of the Periodic Table of the Elements; R 1 is a fluorine, chlorine, bromine or iodine atom; and a is equal to the valence of the metal M; and (b) at least one ionic compound of formula (I) [((T) p R 2 ) n M l (R 3 ) m ] - [D] + (I) wherein: M I is an element belonging to group 13 of the Periodic Table of the Elements; R 3 , equal to or different from each other, are halogen atoms, halogenated C 6 -C 20 aryl and halogenated C 7 -C 20 alkylaryl groups; two R 1 groups, can also form with the element M one condensed ring; R 2 , equal to or different from each other, are hydrocarbon groups; T is a Lewis base in its neutral form; n ranges from 1 to 4; m ranges from 0 to 3; and m+n= 4; p ranges from 1 to 10; and [D] + is a monovalent cation.

29. 发明申请

WO2004050724A1 PROCESS FOR PREPARING 1-BUTENE POLYMERS 审中-公开
标题翻译：制备1-丁烯聚合物的方法
公开(公告)号：WO2004050724A1
公开(公告)日：2004-06-17
申请号：PCT/EP2003/012236
申请日：2003-11-03
申请人： BASELL POLYOLEFINE GMBH , RESCONI, Luigi , CASCIO INGURGIO, Antonio
发明人： RESCONI, Luigi , CASCIO INGURGIO, Antonio
IPC分类号： C08F10/08
CPC分类号： C08F10/08 , C07F17/00 , C08F4/65912 , C08F110/08 , Y10S526/943 , C08F4/65927 , C08F2500/17 , C08F2500/20 , C08F2500/03
摘要： A process for obtaining 1-butene polymers optionally containing up to 30% by mol of ethylene, propylene or an alpha-olefin of formula CH 2 =CHZ, wherein Z is a C 3 -C 10 alkyl group s, comprising the step of contacting under polymerization conditions 1-butene and optionally ethylene, propylene or said alpha-olefin, in the presence of a catalyst system obtainable by contacting: a) a metallocene compound of formula (I): R 3 R 2 R 4 0 R~ Rs MXp LLR 6 R 5 R' O R 2 R 4 (I) wherein: M is an atom of a transition metal belonging to group 3, 4, 5, 6 or to the lanthanide or actinide groups in the Periodic Table of the Elements; p is an integer from 0 to 3; X, is a hydrogen atom, a halogen atom, or a hydrocarbon group; R 1 is a hydrocarbon group; RZ, R 3 and R 6 are hydrogen atoms or hydrocarbon groups; R 4 and R 5 join to form a condensed saturated or unsaturaded 4-7 membered ring; and L is a divalent bridging group; and b) an alumoxane or a compound able to form an alkylmetallocene cation.
摘要翻译：一种获得任选含有至多30摩尔％乙烯，丙烯或式CH 2 = CHZ的α-烯烃（其中Z为C 3 -C 10烷基）的1-丁烯聚合物的方法，包括在聚合条件下接触的步骤 1-丁烯和任选的乙烯，丙烯或所述α-烯烃，在催化剂体系存在下可通过以下方式获得：a）式（I）的茂金属化合物：R 3 R 2 R 4 R 〜Rs MXp LLR 6 R 5 R'OR 2 R 4（I）其中：M是属于第3,4,5,6族的过渡金属的原子或镧系元素或锕系元素小组在元素周期表中; p是0至3的整数; X是氢原子，卤素原子或烃基; R 1是烃基; R 3，R 3和R 6是氢原子或烃基; R 4和R 5连接形成稠合的饱和或不饱和4-7元环; L是二价桥基; 和b）铝氧烷或能够形成烷基茂金属阳离子的化合物。

30. 发明申请

WO2003057705A1 PREPARATION OF SILICON-BRIDGED METALLOCENE COMPOUNDS 审中-公开
标题翻译：硅系金属化合物的制备
公开(公告)号：WO2003057705A1
公开(公告)日：2003-07-17
申请号：PCT/EP2002/014899
申请日：2002-12-30
申请人： BASELL POLYOLEFINE GMBH , RESCONI, Luigi , GUIDOTTI, Simona , BALBONI, Davide
发明人： RESCONI, Luigi , GUIDOTTI, Simona , BALBONI, Davide
IPC分类号： C07F17/00
CPC分类号： C07F17/00 , Y10S526/943
摘要： A process for obtaining silicon-bridged metallocene compounds comprising the following steps: a) reacting, at a temperature of between 10° C and 70° C, the starting ligand with about 2 molar equivalents of an alkylating agent; b) after the reaction has been completed, adding at least 2 molar equivalents of an alkylating agent that can be also different from the first one; and c) reacting, at a temperature of between 10° C and 70° C, the product obtained from step b) with at least 1 molar equivalent of a compound of formula ML' s , wherein M is a transition metal; s is an integer corresponding to the oxidation state of the metal; and L' is an halogen atom selected from chlorine, bromine and iodine.
摘要翻译：一种获得硅桥联的茂金属化合物的方法，包括以下步骤：a）在10℃至70℃的温度下使起始配体与约2摩尔当量的烷基化剂反应; b）反应完成后，加入至少2摩尔当量的也可以不同于第一种烷基化剂的烷基化剂; 和c）在10℃至70℃的温度下，将从步骤b）得到的产物与至少1摩尔当量的式ML's化合物反应，其中M为过渡金属; s是与金属的氧化态对应的整数; L'是选自氯，溴和碘的卤素原子。

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