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    • 25. 发明专利
    • 無電解Ni−Bめっき皮膜及び機械部品
    • Ni-B电镀薄膜和机器部分
    • JP2015030885A
    • 2015-02-16
    • JP2013161663
    • 2013-08-02
    • 日本カニゼン株式会社Nippon Kanizen Kk
    • WATANABE SUMITAKA
    • C23C18/34
    • 【課題】熱処理を施さなくても、ビッカース硬度(HV)850以上の高い硬度を有し且つクラックのない無電解ニッケルめっき皮膜を提供すること。【解決手段】ホウ素を0.25重量%〜2.0重量%を含む無電解Ni−Bめっき皮膜であって、皮膜面と入射ビームとのなす角度及び皮膜面と反射ビームとのなす角度が等しい条件で行ったディフラクトメータ法によるX線回折図形においてNiの{111}面の強度F{111}とNiの{200}面の強度F{200}との比OF=F{111}/F{200}が0.1〜20の範囲内であることを特徴とする無電解Ni−Bめっき皮膜である。【選択図】なし
    • 要解决的问题:提供具有850以上的维氏硬度(HV)的高硬度但不进行热处理的无裂纹的化学镀镍膜。解决方案:无电镀Ni-B镀膜含有硼 为0.25重量%至2.0重量%,其特征在于,Ni的{111}面的强度F {111}与强度F {200的比例OF = F {111} / F {200} 在Ni的{200}面的}为0.1〜20的范围内,在X射线衍射图中,通过衍射法,在膜面和入射光束之间形成的角度和角度 在膜面和反射光束之间形成的相等。
    • 27. 发明专利
    • Electroless nickel plating film and electroless nickel plating solution
    • 电镀镍镀层和电镀镍镀层溶液
    • JP2013014809A
    • 2013-01-24
    • JP2011149138
    • 2011-07-05
    • Nippon Kanizen Kk日本カニゼン株式会社
    • WATANABE KENJIWATANABE SUMITAKA
    • C23C18/36C23C18/50
    • PROBLEM TO BE SOLVED: To provide an electroless nickel plating solution which can minimize the contamination of an electroless plating film with environmentally hazardous substances other than nickel, yet has excellent stability, and can provide a plating film having excellent mechanical properties.SOLUTION: The electroless nickel plating film contains 0.5-4 wt.% phosphorus, 0.01-2 wt.% boron, and 0.1-5 wt.% tin. The electroless nickel plating film can be obtained by using the electroless nickel plating solution containing 0.04-0.2 mol/L of nickel ions, 0.09-0.5 mol/L of hypophosphite ions, 1-80 mmol/L of tetrahydro borate ions, and 50-1,000 μmol/L of divalent tin ions.
    • 要解决的问题:提供一种化学镀镍溶液,其可以使除镍以外的环境有害物质的化学镀膜的污染最小化,但是具有优异的稳定性,并且可以提供具有优异的机械性能的电镀膜。 解决方案:化学镀镍膜含有0.5-4重量%的磷,0.01-2重量%的硼和0.1-5重量%的锡。 可以通过使用含有0.04-0.2mol / L的镍离子,0.09〜0.5mol / L的次磷酸根离子,1-80mmol / L的四氢硼酸根离子的无电镀镍溶液和50〜 1,000μmol/ L的二价锡离子。 版权所有(C)2013,JPO&INPIT
    • 28. 发明专利
    • Device for prolonging lifetime of electroless nickel-plating liquid
    • 用于延长电镀镍液的寿命的装置
    • JP2007291465A
    • 2007-11-08
    • JP2006122255
    • 2006-04-26
    • Nippon Kanizen KkTokyo Institute Of Technology国立大学法人東京工業大学日本カニゼン株式会社
    • KOJIMA TAKASHIYAMAMOTO MAKIKONEMOTO KENICHIMINAGAWA YOSHIETANIOKA AKIHIKO
    • C23C18/16B01D61/44B01D61/58C02F1/469C23C18/31C23C18/36
    • PROBLEM TO BE SOLVED: To provide a device for prolonging the lifetime of an electroless nickel-plating liquid capable of reducing the amount of a waste liquid and reducing losses of raw material components by increasing the use frequency of continuous circulation of an electroless Ni plating liquid. SOLUTION: A first negative ion exchange membrane 4 which permeates hypophosphite ions, phosphite ions, and SO 4 2- but does not permeate organic acid ions, and a first positive ion exchange membrane 5 which permeates Na+ but does not permeate Ni 2+ are alternately arranged in a first electrodialysis unit 1 connected to a Ni plating liquid tank 21. A second negative ion exchange membrane 14 which permeates hypophosphite ions and organic acid ions but does not permeate phosphate ions and SO 4 2- and a second positive ion exchange membrane which permeates H + but does not permeate Ni 2+ are alternately arranged in a second electrodialysis unit 11 connected to its first concentration chamber 7. A second concentration chamber 17 is connected to the Ni plating liquid tank 21. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供一种能够延长化学镀镍液的寿命的装置,其能够通过增加无电镀的连续循环的使用频率来减少废液的量并减少原料成分的损失 镀镍液。 解决方案:渗透次磷酸根离子,亚磷酸根离子和SO 3 S 2,但不渗透有机酸离子的第一负离子交换膜4和第一 在与Ni镀液槽21连接的第一电渗析单元1中交替排列渗透Na +但不渗透Ni +的阳离子交换膜5,第二负离子交换膜14渗透次磷酸盐 离子和有机酸离子,但不渗透磷酸根离子和第二阳离子交换膜,其渗透H + ,但是 不渗透Ni 2 + 交替排列在与其第一浓缩室7连接的第二电渗析单元11中。第二浓度室17连接到Ni镀液槽21。 C)2008,JPO&INPIT
    • 29. 发明专利
    • Part of rotary machine and rotary machine
    • 旋转机和旋转机的一部分
    • JP2007071032A
    • 2007-03-22
    • JP2005255481
    • 2005-09-02
    • Mitsubishi Heavy Ind LtdNippon Kanizen Kk三菱重工業株式会社日本カニゼン株式会社
    • YASUI TOYOAKIYAMADA YOSHIKAZUHANANAKA KATSUYASUHATA SATOSHITSURUSAKI YUZOISUMI OSAMUSAITO KAZUHIDENEMOTO KENICHISUZUKI YUKIHARU
    • F01D5/28F04D29/30F04D29/38
    • PROBLEM TO BE SOLVED: To effectively restrain sticking of a particulate included in gas in a rotary machine for treating the gas including silica, iron oxide and other particulates. SOLUTION: This moving blade 23 includes a first fluororesin including plating coating film 12 and a second fluororesin including plating coating film 14 formed as a film on this surface. The first fluororesin including plating coating film 12 includes a first fluororesin particle 13P by a first plating matrix 13M, and a part of the first fluororesin particle 13P is also exposed from a surface of the first plating matrix 13M. In the second fluororesin including plating coating film 14, a second fluororesin particle 14P having a diameter smaller than the first fluororesin particle 13P is included in a second plating matrix 13M, and a part of the second fluororesin particle 14P and the first fluororesin particle 13P is also exposed from a surface of the second plating matrix 14M. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:为了有效地抑制气体中包含的颗粒在用于处理包括二氧化硅,氧化铁和其它颗粒的气体的旋转机械中的粘附。 解决方案:该移动刀片23包括第一氟树脂,其包括镀覆膜12和在该表面上形成为膜的镀覆膜14的第二氟树脂。 包括电镀覆膜12的第一氟树脂包括通过第一电镀基质13M的第一氟树脂颗粒13P,并且第一氟树脂颗粒13P的一部分也从第一电镀基质13M的表面露出。 在包括电镀覆膜14的第二氟树脂中,第二镀层基质13M中包含直径小于第一氟树脂颗粒13P的第二氟树脂颗粒14P,第二氟树脂颗粒14P和第一氟树脂颗粒13P的一部分 也从第二电镀基体14M的表面露出。 版权所有(C)2007,JPO&INPIT
    • 30. 发明专利
    • Surface treatment agent for electroless nickel plating film, protective film, product having the protective film, and their production method
    • 用于电镀镍镀层的表面处理剂,保护膜,具有保护膜的产品及其生产方法
    • JP2005146411A
    • 2005-06-09
    • JP2004257959
    • 2004-09-06
    • Nippon Kanizen Kk日本カニゼン株式会社
    • SUZUKI SATOSHITAKEUCHI YOSHIHIKOYAMAMOTO KYOSUKE
    • C23C22/42C23C28/00
    • C23C28/322C23C28/345
    • PROBLEM TO BE SOLVED: To provide a surface treatment agent for electroless nickel plating capable of forming a protective film having corrosion resistance and discoloration resistance equal to those of a protective film formed with a chromic acid-based surface treatment agent, to provide a protective film on the surface of an electroless nickel plating film, to provide its production method, and to provide a product having a nickel plating film coated with the protective film.
      SOLUTION: The surface treatment agent for electroless nickel plating film is composed of an aqueous solution containing, by mass, a 0.1 to 10% molybdenum compound, a 0.01 to 5% tungsten compound, a 0.1 to 12% phosphoric compound, a 0.01 to 3% sulfuric compound and a 0.01 to 12% silicic compound, and forms a protective film comprising 30 to 90% oxygen, 0.1 to 30% silicon, 0.01 to 18% nickel and 5 to 50% phosphorus on an electroless nickel plating film.
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:提供一种能够形成具有与由铬酸类表面处理剂形成的保护膜相同的耐腐蚀性和耐变色性的保护膜的化学镀镍表面处理剂,以提供 在化学镀镍膜的表面上的保护膜,以提供其制造方法,并提供具有涂覆有保护膜的镀镍膜的产品。 解决方案:化学镀镍表面处理剂由含有0.1〜10%的钼化合物,0.01〜5%的钨化合物,0.1〜12%的磷化合物, 0.01〜3%的硫化合物和0.01〜12%的硅化合物,并且在化学镀镍膜上形成包含30〜90%的氧,0.1〜30%的硅,0.01〜18%的镍和5〜50%的磷的保护膜 。 版权所有(C)2005,JPO&NCIPI