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    • 23. 发明授权
    • Photographic element with cellulose derivative polymer
    • 具有纤维素衍生聚合物的摄影元件
    • US5212051A
    • 1993-05-18
    • US719433
    • 1991-06-24
    • Kentaro ShiratsuchiHideki Takaki
    • Kentaro ShiratsuchiHideki Takaki
    • C08B11/187C08G81/02G03C1/04G03C8/54
    • C08B11/187G03C1/04G03C8/54Y10T428/31931Y10T428/31971
    • A photographic element comprising a support having thereon at least one layer comprising a polymer obtained by copolymerizing a repeating unit represented by the following general formula (I) and a copolymerizable cellulose derivative represented by the following general formula (II):--A).sub.x (B).sub.y (I)wherein A represents a repeating unit derived from an ethylenically unsaturated monomer having --COOH group, --SO.sub.3 H group or --PO(OH).sub.2 group in the molecular structure; and B represents a repeating unit derived from a copolymerizable ethylenically unsaturated monomer; ##STR1## wherein (R.sup.1)s each independently represents (i) a hydrogen atom, (ii) a monovalent organic bonding group such as an ester group or an ether group or (iii) a monovalent organic bonding group represented by the following general formula (III), with the proviso that (R.sup.1)s do not all hydrogen atom at the same time; and n represents a number of 20 to 800; ##STR2## wherein R.sup.2 represents hydrogen atom or an alkyl group having 1 to 6 carbon atoms; and L represents a bivalent organic bonding group, and wherein the percentage by weight of the component represented by general formula (I) in the copolymer is from 5 to 95; the percentage by weight of the component represented by general formula (III) based on the weight of the component represented by general formula (II) is from 0.00001 to 10; x and y represent each the percentage by weight of each monomer component in the copolymer and x is in the range of 1 to 95 and y is in the range of 5 to 99.
    • 24. 发明授权
    • Photographic element
    • 摄影元素
    • US5023162A
    • 1991-06-11
    • US382365
    • 1989-07-20
    • Junichi YamanouchiKentaro ShiratsuchiYukio KarinoTakeshi Shibata
    • Junichi YamanouchiKentaro ShiratsuchiYukio KarinoTakeshi Shibata
    • G03C1/835G03C8/56
    • G03C1/835G03C8/56Y10S430/142
    • A photographic element comprising a polymer mordant containing a repeating unit containing a tertiary amino group or a quaternary ammonium salt and at least one reprating unit represented by the formula (I) or (II): ##STR1## wherein R.sup.1 represents a hydrogen atom or an alkyl group having from 1 to 6 carbon atoms R.sup.2, R.sup.3, R.sup.4 and R.sup.5, which may be the same or different, each represent an alkyl group or substituted alkyl group; R.sup.6, R.sup.7, and R.sup.8, which may be the same or different, each represent hydrogen, an alkyl group or a substituted alkyl group; R.sup.11 represents an alkyl group, a substituted alkyl group, an alkoxy group, a substituted alkoxy group, an acylamino group or a halogen atom; R.sup.12 and R.sup.13, which may be the same or different, each represent an alkyl group or a substituted alkyl group; L.sup.1 and L.sup.3, which may be the same or different, each represent a divalent connecting group having from 1 to 20 carbon atoms; and n represents an integer of 0 or 1, wherein the proportion of the repeating unit containing a tertiary amino group or a quaternary ammonium salt in the polymer is in the range of from 10 to 90 mol %, and the proportion of the at least one repeating unit represented by formula (I) or (II) in the polymer is in the range of of 10 to 90 mol %.
    • 一种照相元件,包括含有含有叔氨基或季铵盐的重复单元的聚合物媒染剂和由式(I)或(II)表示的至少一种重新定量单元:(I) )其中R 1表示氢原子或具有1至6个碳原子的烷基,可以相同或不同的R 2,R 3,R 4和R 5各自表示烷基或取代的烷基; R 6,R 7和R 8可以相同或不同,各自表示氢,烷基或取代的烷基; R11表示烷基,取代的烷基,烷氧基,取代的烷氧基,酰氨基或卤素原子; R 12和R 13可以相同或不同,各自表示烷基或取代的烷基; L1和L3可以相同或不同,各自表示具有1至20个碳原子的二价连接基团; n表示0或1的整数,其中,所述聚合物中含有叔氨基或季铵盐的重复单元的比例为10〜90摩尔%,所述至少一种 在聚合物中由式(I)或(II)表示的重复单元在10至90摩尔%的范围内。