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21. 发明授权

US5779741A Fluroescent whitening agents 失效
标题翻译：荧光增白剂
公开(公告)号：US5779741A
公开(公告)日：1998-07-14
申请号：US847998
申请日：1997-04-21
申请人： Jean-Pierre Bacher , Claude Eckhardt , Dieter Reinehr
发明人： Jean-Pierre Bacher , Claude Eckhardt , Dieter Reinehr
IPC分类号： C07D251/52 , C07D251/68 , C07D251/70 , C11D3/395 , D06L3/12 , D06M13/07 , C07D251/40
CPC分类号： D06L3/1214 , C07D251/68 , D06L3/1257 , D06M13/07 , D06M2101/06
摘要： The present invention provides a compound having the formula: ##STR1## in which M is hydrogen, sodium, potassium, calcium, magnesium, ammonium, mono-, di-, tri- or tetra-C.sub.1 -C.sub.4 alkylammonium, mono-, di- or tri-C.sub.1 -C.sub.4 hydroxyalkylammonium or ammonium that is di- or tri-substituted by a mixture of C.sub.1 -C.sub.4 alkyl and C.sub.1 -C.sub.4 hydroxyalkyl groups; R.sub.1 is a group having the formula: ##STR2## in which M has its previous significance and n is 1 or 2; and R.sub.2 is O--C.sub.1 -C.sub.12 alkyl or N(R.sub.3)(R.sub.4) in which R.sub.3 and R.sub.4, independently, are hydrogen, C.sub.1 -C.sub.2 alkyl or C.sub.1 -C.sub.4 hydroxyalkyl, or R.sub.3 and R.sub.4, together with the nitrogen atom, are the atoms required to form a pyrrolidine, piperidine or morpholine group. The compounds of formula (1) are particularly useful as fluorescent whitening agents for cotton in discontinuous processes, in the course of which an acidic treatment, especially a finishing treatment using a polymer resin, occurs.
摘要翻译：本发明提供具有下式的化合物：其中M是氢，钠，钾，钙，镁，铵，一，二，三或四-C1 C4烷基铵，由C1-C4烷基和C1-C4羟烷基的混合物二或三取代的单，二或三-C 1 -C 4羟烷基铵或铵; R1是具有下式的组：其中M具有其先前的含义，n是1或2; 并且R 2为O-C 1 -C 12烷基或N（R 3）（R 4），其中R 3和R 4独立地是氢，C 1 -C 2烷基或C 1 -C 4羟烷基，或者R 3和R 4与氮原子一起是所需的原子以形成吡咯烷，哌啶或吗啉基团。式（1）的化合物特别可用作不连续工艺中用于棉花的荧光增白剂，其中酸性处理，特别是使用聚合物树脂的整理处理发生。

22. 发明授权

US5468884A Liquid detergent compositions 失效
标题翻译：液体洗涤剂组合物
公开(公告)号：US5468884A
公开(公告)日：1995-11-21
申请号：US152331
申请日：1993-11-12
申请人： Claude Eckhardt
发明人： Claude Eckhardt
IPC分类号： C11D3/20 , C11D3/00 , C11D3/34 , C11D3/37 , C11D3/42 , C11D17/08 , D06L3/12 , C11D1/83
CPC分类号： D06L3/1257 , C11D3/0021 , C11D3/3776 , C11D3/42 , D06L3/1214 , D06L3/125
摘要： The invention describes novel highly concentrated, aqueous liquid detergent compositions comprisinga) 0.01 to 2% by weight of dibenzofuranyl biphenyls of formula (1) ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are each independently of one another a sulfonic acid radical, hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, CN, phenoxy or benzyloxy, with the proviso that only one of R.sub.1 to R.sub.5 is a sulfonic acid radical,b) 6 to 22% by weight of water, based on the weight of the detergent composition, andc) suffactants,and to their preparation and use for pretreating and washing textile fabrics.
摘要翻译：本发明描述了新的高度浓缩的含水液体洗涤剂组合物，其包含a）0.01至2重量％的式（1）的二苯并呋喃基联苯（1）其中R 1，R 2，R 3，R 4和R 5各自独立地为磺酸基，氢，C 1 -C 4烷基，C 1 -C 4烷氧基，卤素，CN，苯氧基或苄氧基，条件是R 1至R 5中只有一个是磺酸基，b）6至22重量％的水，基于洗涤剂组合物的重量，以及c）腋下剂及其制备和用于预处理和洗涤纺织织物。

23. 发明授权

US5145991A Distyrylbiphenyl compounds 失效
标题翻译：二苯乙烯基联苯化合物
公开(公告)号：US5145991A
公开(公告)日：1992-09-08
申请号：US701299
申请日：1991-05-13
申请人： Kurt Weber , Claude Eckhardt
发明人： Kurt Weber , Claude Eckhardt
IPC分类号： C11D3/395 , C07C309/32 , C07C309/39 , C07C309/59 , C09B23/00 , C09B23/14 , C09B57/00 , C11D3/42 , D06L3/12 , D21H21/28
CPC分类号： C07C309/32 , C07C309/39 , C07C309/59
摘要： Distyrylbiphenyl compounds of formula ##STR1## wherein R.sub.1, R.sub.3, R.sub.6 and R.sub.7 are halogen, hydrogen, C.sub.1 -C.sub.4 alkyl or cyano, and M.sup..sym. is a salt-forming cation, are used as fluorescent whitening agents in solid and, preferably, liquid, detergent compositions. They are distinguished by good white effects and insignificant spotting behavior.
摘要翻译：其中R 1，R 3，R 6和R 7为卤素，氢，C 1 -C 4烷基或氰基，M（+）为成盐阳离子的二苯乙烯基联苯化合物用作荧光增白剂固体，优选液体洗涤剂组合物。它们的特征在于良好的白色效应和不显着的斑点行为。

24. 发明授权

US4540518A Zinc and aluminum phthalocyanines 失效
标题翻译：锌和铝酞菁
公开(公告)号：US4540518A
公开(公告)日：1985-09-10
申请号：US431457
申请日：1982-09-30
申请人： Claude Eckhardt , Gerd Holzle
发明人： Claude Eckhardt , Gerd Holzle
IPC分类号： C09B47/24 , C09B47/26 , C09B47/32 , C09B67/42 , C09B69/00 , C11D3/00 , C11D3/39 , C11D3/395 , D06L1/12 , D06L3/00 , D06L3/04 , D06L3/12 , D06M13/00 , D06M13/02 , D06M13/244 , D06M13/248 , D06M13/262 , D06M13/322 , D06M13/325 , D06M13/35 , D06M13/463 , D06M13/47 , D06M13/473
CPC分类号： D06L3/1285 , C09B47/32 , C11D3/0063
摘要： The invention discloses fabric conditioning compositions which contain, as bleach photoactivator, an aluminium or zinc phthalocyanine which is substituted by cationic water-solubilizing groups, and also cationic fabric conditioners such as cationic surfactants, softeners, antistatic agents, fluorescent whitening agents and/or microbicides. The invention also provides a method of washing, rinsing and bleaching fabrics utilizing the compositions of the invention, as well as novel aluminium and zinc phthalocyanines which contain quaternary ammonium groups and ternary sulfonium groups as substituents.
摘要翻译：本发明公开了含有阳离子水溶性基团取代的铝或锌酞菁作为漂白光活化剂的织物调理组合物，还包括阳离子织物调理剂如阳离子表面活性剂，软化剂，抗静电剂，荧光增白剂和/或杀微生物剂。本发明还提供了使用本发明组合物洗涤，漂洗和漂白织物的方法，以及含有季铵基和三元锍基作为取代基的新型铝和锌酞菁。

25. 发明授权

US4311605A Compositions for treating textiles 失效
标题翻译：用于处理纺织品的组合物
公开(公告)号：US4311605A
公开(公告)日：1982-01-19
申请号：US189486
申请日：1980-09-22
申请人： Claude Eckhardt , Richard von Rutte
发明人： Claude Eckhardt , Richard von Rutte
IPC分类号： C11D3/395 , C11D3/00 , C11D3/42 , C11D7/54 , C11D7/50
CPC分类号： C11D3/0063 , C11D3/42
摘要： The invention provides compositions for improving the appearance of used textiles which contains a photoactivator and a fluorescent whitening agent which is a distyrylbiphenylsulfonic acid or a salt thereof and/or a 4,4'-bis-(1,2,3-triazol-2-yl)-2,2'-stilbenesulfonic acid or a salt thereof. The invention also provides soaking, detergent or rinsing liquors containing such compositions as well as a method of improving the appearance of used textiles which comprises the use of the compositions and liquors of the invention.
摘要翻译：本发明提供了用于改善使用的纺织品的外观的组合物，其包含光活化剂和作为二苯乙烯基联苯磺酸或其盐的荧光增白剂和/或4,4'-双 - （1,2,3-三唑-2-基） - 基）-2,2'-联苯磺酸或其盐。本发明还提供含有这种组合物的浸泡，洗涤剂或漂洗液以及改进使用的纺织品的外观的方法，其包括使用本发明的组合物和液体。

26. 发明授权

US4147648A Brightening compositions 失效
标题翻译：增白组合物
公开(公告)号：US4147648A
公开(公告)日：1979-04-03
申请号：US810534
申请日：1977-06-27
申请人： Franz Gunter , Claude Eckhardt
发明人： Franz Gunter , Claude Eckhardt
IPC分类号： C09B57/00 , C09B67/46 , C11D3/42 , D06L3/12 , C11D9/44
CPC分类号： D06L3/125 , C11D3/42
摘要： A brightening composition consisting of a mixture of brighteners and 0 to 99.995% by weight of a commercially available washing agent, said mixture containing at least two brighteners of the formula ##STR1## in which A and B independently of one another denote a radical of the formula ##STR2## in which M represents hydrogen or an ammonium, alkaline earth metal, amine salt or alkali metal ion, as well as a process for brightening organic textiles are disclosed.
摘要翻译：由光亮剂和0至99.995重量％的市售洗涤剂的混合物组成的增亮组合物，所述混合物含有至少两种式（IMAGE）的增白剂，其中A和B彼此独立地表示基团公开了其中M表示氢或铵，碱土金属，胺盐或碱金属离子的式“IMAGE”，以及增亮有机纺织品的方法。

27. 发明授权

US6117189A Protective method 失效
标题翻译：保护方法
公开(公告)号：US6117189A
公开(公告)日：2000-09-12
申请号：US438591
申请日：1995-05-10
申请人： Dieter Reinehr , Peter Fankhauser , Claude Eckhardt
发明人： Dieter Reinehr , Peter Fankhauser , Claude Eckhardt
IPC分类号： C09K3/00 , C11D1/62 , C11D3/42 , D06L3/12 , D06M11/00
CPC分类号： C09B23/148 , C11D1/62 , C11D3/42 , D06L3/12 , D06L3/1207 , D06L3/1257 , D06M2200/25 , Y10T442/2582 , Y10T442/259 , Y10T442/2607
摘要： The present invention relates to a method for the improvement of the sun protection factor (SPF) of textile fiber material, comprising applying to the textile fiber material a detergent comprising at least one fluorescent whitening agent, which absorbs radiation in the wavelength range 280-400 nm, preferably by washing the textile fiber material with a detergent containing said fluorescent whitening agent.
摘要翻译：本发明涉及一种改善纺织纤维材料的防晒因子（SPF）的方法，包括向纺织纤维材料施加含有至少一种荧光增白剂的洗涤剂，该荧光增白剂吸收波长范围280-400的辐射 nm，优选通过用含有荧光增白剂的洗涤剂洗涤纺织纤维材料。

28. 发明授权

US5741920A Inhibition of re-absorption of migrating dyes in the wash liquor 失效
标题翻译：在洗涤液中抑制迁移染料的再吸收
公开(公告)号：US5741920A
公开(公告)日：1998-04-21
申请号：US469596
申请日：1995-06-06
申请人： Claude Eckhardt , Dieter Reinehr
发明人： Claude Eckhardt , Dieter Reinehr
IPC分类号： C07F13/00 , C11D3/00 , C11D3/16 , C11D3/26 , C11D3/34 , C11D3/39 , C11D3/395 , D06L3/02 , D06M13/02 , D06M13/50 , D06M13/503
CPC分类号： C11D3/3932 , C11D3/0021
摘要： A process for inhibiting the re-absorption of migrating dyes in the wash liquor comprises introducing into a wash liquor containing a peroxide-containing detergent, from 0.5 to 150 mg, per liter of wash liquor, of one or more manganese compounds having the formula (1), (2), (3), (4), (5), (6) or (7) as defined in the specification. The manganese compounds do not exhaust at all on to cotton, polyamide or polyester fibres so that the compounds cannot lead to fibre discolouration problems.
摘要翻译：用于抑制洗涤液中迁移染料的再吸收的方法包括将含有过氧化物的洗涤剂的洗涤液引入每升洗涤液0.5至150mg的一种或多种具有式（ 1），（2），（3），（4），（5），（6）或（7）。锰化合物完全不排放到棉，聚酰胺或聚酯纤维上，使得化合物不能导致纤维变色问题。

29. 发明授权

US5688758A Textile treatment 失效
标题翻译：纺织品处理
公开(公告)号：US5688758A
公开(公告)日：1997-11-18
申请号：US662091
申请日：1996-06-12
申请人： Dieter Reinehr , Claude Eckhardt
发明人： Dieter Reinehr , Claude Eckhardt
IPC分类号： D06L3/12 , C09B57/00 , C11D3/42 , C11D3/60 , D06B20060101 , D06B1/00 , D06M20060101 , D06M11/00 , D06M13/00 , D06M13/02 , D06M13/07 , D06M13/244 , D06M13/282 , D06M13/285 , D06M13/288 , D06M13/322 , D06M13/325 , D06M13/352 , D06M13/388 , D06M13/402 , D06M13/46 , D06M13/463 , D06M13/467 , D06M13/47 , D06M13/473 , D06M101/00 , D06M101/02 , D06M101/04 , D06M101/10 , D06M101/12 , D06M101/16 , D06M101/18 , D06M101/22 , D06M101/28 , D06M101/30 , D06M101/32 , D06M101/34 , D06P20060101 , D06M13/248
CPC分类号： C11D3/42 , D06L3/12 , D06L3/1207 , D06L3/1257 , D06M2200/25
摘要： There is provided a stable, concentrated fabric rinse composition comprising 0.3 to 10, preferably 0.3 to 3% by weight of a fluorescent whitening agent which is compatible with a fabric care ingredient, preferably a cationic, amphoteric or anionic fluorescent whitening agent, based on the total weight of the composition, and optionally a fabric care ingredient, preferably a fabric softener, a stain release or stain repellant ingredient or a water-proofing agent, the remainder being substantially water. The fabric rinse composition is preferably a fabric softener composition comprising 5 to 25, preferably 10 to 20% by weight of a cationic fabric softening agent and 0.3 to 10, preferably 0.3 to 3% by weight of a cationic, amphoteric or anionic fluorescent whitening agent, each based on the total weight of the composition, the remainder being substantially water. The present invention also provides method for the treatment of a textile article, comprising applying, to the previously washed article, the said fabric rinse composition, preferably the rinse cycle fabric softener composition, whereby the sun protection factor, and other properties such as the tear Strength and lighffastness of articles so treated can be significantly increased.
摘要翻译：提供了一种稳定的浓缩织物漂洗组合物，其包含0.3至10重量％，优选0.3至3重量％的荧光增白剂，其与织物护理成分，优选阳离子，两性或阴离子荧光增白剂相容，基于组合物的总重量和任选的织物护理成分，优选织物柔软剂，防污剂或防污剂成分或防水剂，其余部分基本上为水。织物漂洗组合物优选为织物柔软剂组合物，其包含5至25重量％，优选10至20重量％的阳离子织物软化剂和0.3至10重量％，优选0.3至3重量％的阳离子，两性或阴离子荧光增白剂，各自基于组合物的总重量，其余基本上是水。本发明还提供了一种用于处理纺织制品的方法，其包括向先前洗涤的制品施加所述织物漂洗组合物，优选漂洗循环织物柔软剂组合物，由此防晒因子和其它性质如撕裂如此处理的物品的强度和亮度可以显着提高。

30. 发明授权

US5269815A Process for the fluorescent whitening of hydrophobic textile material with disperse fluorescent whitening agents from super-critical carbon dioxide 失效
标题翻译：使用超临界二氧化碳的分散荧光增白剂对疏水纺织材料进行荧光增白的方法
公开(公告)号：US5269815A
公开(公告)日：1993-12-14
申请号：US976243
申请日：1992-11-13
申请人： Wolfgang Schlenker , Dieter Werthemann , Claude Eckhardt
发明人： Wolfgang Schlenker , Dieter Werthemann , Claude Eckhardt
IPC分类号： D06L3/12 , D06M23/10 , D06P3/52 , D06P5/20 , C09K11/06 , D06P3/54
CPC分类号： D06L3/12 , D06M23/105 , Y10S8/922
摘要： A process for the fluorescent whitening of hydrophobic textile materials, especially polyesters, wherein the textile material is treated with disperse fluorescent whitening agents in supercritical CO.sub.2.
摘要翻译：一种用于疏水纺织材料，特别是聚酯的荧光增白的方法，其中纺织材料用分散荧光增白剂在超临界CO 2中处理。

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