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    • 11. 发明授权
    • Bayer process for production of alumina trihydrate
    • 拜耳法生产三水合氧化铝
    • US06391277B1
    • 2002-05-21
    • US09529402
    • 2000-07-05
    • Bassam El KadiPhilippe Clerin
    • Bassam El KadiPhilippe Clerin
    • C01F700
    • C01F7/144
    • An improvement in the Bayer process for producing alumina trihydrate in which bauxite ore is digested in a mixture with a digestion sodium aluminate liquor to produce a slurry, the slurry is settled to remove undigested residues therefrom and produce a pregnant liquor of sodium aluminate and alumina trihydrate is precipitated from the pregnant liquor in the presence of alumina trihydrate recycled as seed. When beginning the precipitation, an aliquot of the pregnant liquor with recycled alumina trihydrate is removed, subjected to mechanical action of an intensity and for a time sufficient to cause formation of seeds, and returned with the formed seeds to the beginning of the precipitation.
    • 用于生产氧化铝三水合物的拜耳方法的改进,其中铝酸铝矿石在与消化铝酸钠液体的混合物中消化以产生浆料,淤浆沉降以除去未消化的残余物,并产生铝酸钠和三水合氧化铝 在作为种子再循环的三水合氧化铝的存在下从怀疑液体中沉淀出来。 当开始沉淀时,除去具有再循环氧化铝三水合物的怀孕液体的等分试样,经受强度的机械作用并持续一段足以引起种子形成的时间,并且用形成的种子返回到沉淀开始。
    • 13. 发明授权
    • Process for the production of aluminum hydroxide of improved whiteness
    • 用于生产改善白度的氢氧化铝的方法
    • US06827923B1
    • 2004-12-07
    • US10110301
    • 2002-06-04
    • Neil Brown
    • Neil Brown
    • C01F700
    • C01F7/46C01P2004/61C01P2006/12C01P2006/22C01P2006/62C09C1/407
    • Aluminium hydroxide of high whiteness is produced by (i) heating aluminium hydroxide obtained from the Bayer process to a temperature of 300 to 700° C. (ii) dissolving the soluble fraction of the thus obtained activated product at 85 to 275° C. in aqueous sodium hydroxide to form a sodium aluminate liquor containing an undissolved residue of very fine boehmite, (iii) filtering said sodium aluminate liquor to obtain a clear solution of sodium aluminate supersaturated with respect to dissolved alumina, (iv) cooling said clear solution to 50 to 80° C. and seeding with crystallized aluminium hydroxide to induce further crystallization, and (v) separating, washing and drying the produced aluminium hydroxide crystals.
    • 通过(i)将从拜耳法得到的氢氧化铝加热至300〜700℃的温度,生成高白度的氢氧化铝。(ii)将由此得到的活性成分的可溶成分在85〜275℃下溶解, 氢氧化钠水溶液以形成含有非常细勃姆石的未溶解残余物的铝酸钠液体,(iii)过滤所述铝酸钠溶液以获得相对于溶解的氧化铝过饱和的铝酸钠的澄清溶液,(iv)将所述澄清溶液冷却至50 至80℃,并用结晶的氢氧化铝接种以进一步结晶,和(v)分离,洗涤和干燥所生产的氢氧化铝晶体。
    • 16. 发明授权
    • Aluminum trihydrate crystals and improved method for the production thereof
    • 三水合铝晶体及其制备方法
    • US06599489B2
    • 2003-07-29
    • US09824137
    • 2001-04-02
    • Robert P. MahoneyWilliam B. Schnieders, Jr.
    • Robert P. MahoneyWilliam B. Schnieders, Jr.
    • C01F700
    • C01F7/145
    • The present invention provides an improved process for the production of alumina trihydrate crystals. Through the addition of a hydroxamated polymer at various stages of the process for production of these alumina trihydrate crystals, an upward shift in the particle size distribution of the alumina trihydrate crystals occurs. In one embodiment, the hydroxamated polymer is added to a filtered aqueous solution, which comprises no more than about 10 mg of insoluble solids per liter. In another embodiment, the hydroxamated polymer is added to an aqueous solution comprising insoluble solids after precipitation of alumina trihydrate crystals has commenced. Optionally, alumina trihydrate seed crystals may be added to the aqueous solution to initiate or encourage crystal formation.
    • 本发明提供了制备三水合氧化铝晶体的改进方法。 通过在生产这些三水合氧化铝晶体的方法的各个阶段添加异羟肟酸聚合物,发生三水合氧化铝晶体的粒度分布向上移动。 在一个实施方案中,将异羟肟化聚合物加入到过滤的水溶液中,每升不超过约10mg不溶固体。 在另一个实施方案中,在开始沉淀三水合氧化铝晶体之后,将异羟肟酰聚合物加入到包含不溶性固体的水溶液中。 任选地,可将三水合氧化铝晶种加入到水溶液中以引发或促进晶体形成。
    • 18. 发明授权
    • Process for recycling waste aluminum dross
    • 回收废铝渣的工艺
    • US06296817B1
    • 2001-10-02
    • US09404987
    • 1999-09-22
    • Hyung-Kyu ParkHoo-In LeeEui-Pak Yoon
    • Hyung-Kyu ParkHoo-In LeeEui-Pak Yoon
    • C01F700
    • C04B33/138C01F7/0693C04B18/023C04B28/06C04B33/1328C04B35/62204C04B35/6303C04B35/66Y02P20/142Y02P40/69Y02W30/94C04B18/14
    • Disclosed is the recycling of aluminum dross. Aluminum dross is crushed into particles which are size-classified on the basis of 1 mm. The aluminum dross particles equal to or smaller than 1 mm in size are leached with an aqueous sodium hydroxide solution to give a leachate which contains sodium aluminate as a result of the reaction the aluminum metal of the aluminum dross particles with sodium hydroxide. The aluminum dross particles greater than 1 mm in size are remelted to recover aluminum metal. In the leachate, a small quantity of aluminum hydroxide is seeded, followed by hydrolyzing the sodium aluminate to obtain aluminum hydroxide. Meanwhile, the leachate is filtered to obtain a residue. This residue is subjected to washing, drying and roasting. The mixing of the roasted residue with aggregate and alumina cement gives alumina castable refractories. It is economically very advantageous in that aluminum dross is reused as a raw material for aluminum hydroxide and for alumina castable refractories, instead of being discarded. Also, hydrogen gas can be obtained as a by-product in the process of recycling.
    • 披露了铝渣的回收利用。 铝渣被粉碎成基于1mm的尺寸分级的颗粒。 使用氢氧化钠水溶液浸提等于或小于1mm的铝渣渣,由于铝渣与铝氢氧化物的反应而产生含有铝酸钠的浸出液。 大于1mm的铝渣渣被重熔以回收铝金属。 在渗滤液中,接种少量氢氧化铝,然后水解铝酸钠,得到氢氧化铝。 同时,将渗滤液过滤以获得残留物。 将该残余物进行洗涤,干燥和焙烧。 焙烧的残渣与骨料和氧化铝水泥的混合产生氧化铝可浇铸的耐火材料。 在经济上非常有利的是,铝渣被用作氢氧化铝和氧化铝可浇铸耐火材料的原料,而不是被丢弃。 此外,在回收过程中可以获得作为副产物的氢气。