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    • 13. 发明申请
    • POLYURETHANE ARTICLES, COLORANTS, AND SUCH ARTICLES COMPRISING NOVEL HIGH TOLUENE DIISOCYANATE-STABLE BLUE COLORANTS
    • 聚氨酯制品,着色剂和包含新型高甲苯二异氰酸酯稳定性蓝色着色剂的这类制品
    • WO2005000910A2
    • 2005-01-06
    • PCT/US2004/016971
    • 2004-06-01
    • MILLIKEN & COMPANYXIA, Jusong
    • XIA, Jusong
    • C08F
    • C08G18/4615C08G18/7664C08G63/6852C08K5/0041C08L75/04C09B1/201C09B69/00C09B69/101
    • An inventive blue colorant comprising a chromophore having at least one hydroxy group-terminated polyester chain attached, through a suitable alkylamino linking group (or groups), to the 1- position, the 4- position, or both, of an anthraquinone backbone and having at least one hindering group in a secondary position in relation to said amino linking group is provided. Such colorants exhibit excellent amine/base stability and thermal stability, effective colorations, excellent low extraction rates, high lightfastness levels, particularly when incorporated within certain media and/or on the surface of certain polyurethane substrates, and, most importantly excellent stability in the presence of excess of diisocyanates. The polyester chain or chains can be conveniently tailored to increase the solubility or compatibility in different types of polyurethane resin precursors thereby permitting the introduction of such excellent coloring chromophores within diverse polyurethane media and/or or diverse polyurethane substrates as well as provides a liquid colorant which facilitates handling. Compositions and articles comprising such inventive colorants are provided as well as methods for producing such inventive colorants.
    • 本发明的蓝色着色剂包含具有至少一个通过合适的烷基氨基连接基团(或多个基团)连接到1位,4位或4位的羟基末端聚酯链的发色团 提供了一种蒽醌骨架并且相对于所述氨基连接基团在第二位置具有至少一个阻碍基团。 这种着色剂表现出优异的胺/碱稳定性和热稳定性,有效的着色,优异的低萃取率,高耐光水平,特别是当掺入某些介质和/或某些聚氨酯基材表面时,以及最重要的是在存在 过量的二异氰酸酯。 聚酯链可以方便地定制以增加在不同类型的聚氨酯树脂前体中的溶解性或相容性,从而允许在不同的聚氨酯介质和/或不同的聚氨酯基材内引入这种优异的着色发色团,并提供液体着色剂 有利于处理。 提供了包含这些本发明着色剂的组合物和制品以及用于制备这些本发明着色剂的方法。