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11. 发明授权

US06831144B2 Anionic polymerization process, and process for producing a polymer by the anionic polymerization process 有权
标题翻译：阴离子聚合方法和通过阴离子聚合方法制备聚合物的方法
公开(公告)号：US06831144B2
公开(公告)日：2004-12-14
申请号：US10372766
申请日：2003-02-26
申请人： Kenichi Hamada , Kazushige Ishiura , Masaji Kato , Sachie Yaginuma
发明人： Kenichi Hamada , Kazushige Ishiura , Masaji Kato , Sachie Yaginuma
IPC分类号： C08F452
CPC分类号： C08F297/02 , C08F4/48
摘要： In anionic polymerization using an anionic polymerization initiator, a tertiary organoaluminum compound (A) having in the molecule thereof a chemical structure represented by a general formula: Al—O—Ar wherein Ar represents an aromatic ring, and at least one Lewis base (B) selected from the group consisting of an ether compound and a tertiary polyamine compound are caused to be present in the polymerization system. In this way, the polar monomer can be polymerized with a high polymerization initiation efficiency and a high living polymerization property and at a high polymerization rate even if the used polymerization initiator is suitable for industrial use and a relatively mild cooling condition or a temperature condition near room temperature is adopted as a polymerization temperature condition.
摘要翻译：在使用阴离子聚合引发剂的阴离子聚合中，在分子中具有由通式Al-O-Ar表示的化学结构的叔有机铝化合物（A），其中Ar表示芳香环，和至少一个路易斯碱（B ）选自由醚化合物和叔胺化合物组成的组。以这种方式，即使使用的聚合引发剂适用于工业用途和相对温和的冷却条件或温度条件附近，极性单体可以以高聚合引发效率和高活性聚合性能和高聚合速率聚合采用室温作为聚合温度条件。

12. 发明授权

US06767976B2 Process for polymerizing a methacrylic ester or an acrylic ester 有权
标题翻译：聚合甲基丙烯酸酯或丙烯酸酯的方法
公开(公告)号：US06767976B2
公开(公告)日：2004-07-27
申请号：US10452379
申请日：2003-06-03
申请人： Kenichi Hamada , Kazushige Ishiura , Toru Takahashi , Sachie Yaginuma , Makoto Akai , Tomohiro Ono , Kenji Shachi
发明人： Kenichi Hamada , Kazushige Ishiura , Toru Takahashi , Sachie Yaginuma , Makoto Akai , Tomohiro Ono , Kenji Shachi
IPC分类号： C08F452
CPC分类号： C08F4/48 , C08F4/52 , C08F20/18 , C08F212/08 , C08F297/026 , C08F220/14 , C08F2220/1825
摘要： (1) A methacrylic ester or an acrylic ester is anionically polymerized, using a polymerization initiator compound comprising an addition reaction product of a conjugated diene compound and an organic alkali metal compound, in the presence of a tertiary organoaluminum compound having in the molecule thereof a chemical structure represented by a formula: Al—O—Ar wherein Ar represents an aromatic ring; or (2) a methacrylic ester or an acrylic ester is anionically polymerized, using a polymerization initiator compound comprising an addition reaction product of an organic alkali metal compound and a compound having a 1,1-diaryl-1-alkene structure, by adding the ester in the form of a mixture with the above-mentioned specific tertiary organoaluminum compound to the polymerization system. In this way, various species of the esters can be anionically polymerized with a high initiation efficiency and a high living polymerization property in a solvent which can easily be recovered and reused under a mild cooling condition, using an organic alkali metal compound which has relatively good convenience.
摘要翻译：（1）使用包含共轭二烯化合物和有机碱金属化合物的加成反应产物的聚合引发剂化合物，在其分子内具有叔有机铝化合物的存在下，将甲基丙烯酸酯或丙烯酸酯阴离子聚合由下式表示的化学结构：Al-O-Ar，其中Ar表示芳环; 或（2）甲基丙烯酸酯或丙烯酸酯通过使用包含有机碱金属化合物与具有1,1-二芳基-1-烯烃结构的化合物的加成反应产物的聚合引发剂化合物进行阴离子聚合，酯与上述特定的叔有机铝化合物的混合物形式与聚合体系形成。以这种方式，可以使用具有相对较好的有机碱金属化合物，在温和的冷却条件下，可以在溶剂中以高起始效率和高活性聚合性阴离子聚合各种物质，其可以容易地回收和重复使用方便。

13. 发明授权

US06555637B1 Anionic polymerization process, and process for producing a polymer by the anionic polymerization process 有权
标题翻译：阴离子聚合方法和通过阴离子聚合方法制备聚合物的方法
公开(公告)号：US06555637B1
公开(公告)日：2003-04-29
申请号：US09638149
申请日：2000-08-15
申请人： Kenichi Hamada , Kazushige Ishiura , Masaji Kato , Sachie Yaginuma
发明人： Kenichi Hamada , Kazushige Ishiura , Masaji Kato , Sachie Yaginuma
IPC分类号： C08F452
CPC分类号： C08F297/02 , C08F4/48
摘要： In anionic polymerization using an anionic polymerization initiator, a tertiary organoaluminum compound (A) having in the molecule thereof a chemical structure represented by a general formula: Al—O—Ar wherein Ar represents an aromatic ring, and at least one Lewis base (B) selected from the group consisting of a tertiary polyamine compound, are caused to be present in the polymerization system. In this way, the polar monomer can be polymerized with a high polymerization initiation efficiency and a high living polymerization property and at a high polymerization rate even if the used polymerization initiator is suitable for industrial use, and a relatively mild cooling condition or a temperature condition near room temperature is adopted as a polymerization temperature condition.
摘要翻译：在使用阴离子聚合引发剂的阴离子聚合中，在分子中具有由通式Al-O-Ar表示的化学结构的叔有机铝化合物（A），其中Ar表示芳香环，和至少一个路易斯碱（B ）选自由叔胺化合物组成的组中。以这种方式，即使使用的聚合引发剂适用于工业上使用，也可以以相当温和的冷却条件或温度条件，极性单体以高聚合引发效率和高活性聚合性聚合，并以高聚合速率聚合采用近室温作为聚合温度条件。

14. 发明授权

US06878789B2 Preparation process of acrylic acid ester polymer 有权
标题翻译：丙烯酸酯聚合物的制备方法
公开(公告)号：US06878789B2
公开(公告)日：2005-04-12
申请号：US09960287
申请日：2001-09-24
申请人： Naohiko Uchiumi , Kenichi Hamada , Masaji Kato , Tomohiro Ono , Sachie Yaginuma , Kazushige Ishiura
发明人： Naohiko Uchiumi , Kenichi Hamada , Masaji Kato , Tomohiro Ono , Sachie Yaginuma , Kazushige Ishiura
IPC分类号： C08F4/46 , C08F4/54 , C08F20/12 , C08F297/02 , C08F120/18
CPC分类号： C08F297/026 , C08F20/12
摘要： A process for the preparation of an acrylic acid ester polymer, includes carrying out polymerization of an acrylic acid ester or block copolymerization of an acrylic acid ester and another (meth)acrylic monomer in the presence of an organolithium compound and an organoaluminum compound represented by the following formula (I): AlR1R2R3 (I) wherein R1 represents an alkyl group having at least 3 carbon atoms, an alkoxy group having at least 3 carbon atoms or an aryloxy group, R2 and R3 each independently represent an aryloxy group or may be coupled together to form an arylenedioxy group. The process makes it possible to heighten the reaction rate and living properties upon polymerization and heighten the block formation efficiency upon block copolymerization.
摘要翻译：一种制备丙烯酸酯聚合物的方法，包括在有机锂化合物和有机铝化合物的存在下，进行丙烯酸酯的聚合或丙烯酸酯与另一（甲基）丙烯酸类单体的嵌段共聚合下式（I）：其中R 1表示具有至少3个碳原子的烷基，具有至少3个碳原子的烷氧基或芳氧基，R 2和R 3各自独立地表示芳氧基或可以连接在一起形成亚芳基二氧基。该方法可以在聚合时提高反应速率和活性，并且在嵌段共聚时提高嵌段形成效率。

15. 发明授权

US06329480B1 Preparation process of acrylic acid ester polymer 有权
标题翻译：丙烯酸酯聚合物的制备方法
公开(公告)号：US06329480B1
公开(公告)日：2001-12-11
申请号：US09274473
申请日：1999-03-23
申请人： Naohiko Uchiumi , Kenichi Hamada , Masaji Kato , Tomohiro Ono , Sachie Yaginuma , Kazushige Ishiura
发明人： Naohiko Uchiumi , Kenichi Hamada , Masaji Kato , Tomohiro Ono , Sachie Yaginuma , Kazushige Ishiura
IPC分类号： C08F446
CPC分类号： C08F297/026 , C08F20/12
摘要： A process for the preparation of an acrylic acid ester polymer, includes carrying out polymerization of an acrylic acid ester or block copolymerization of an acrylic acid ester and another (meth)acrylic monomer in the presence of an organolithium compound and an organoaluminum compound represented by the following formula (I): AlR1R2R3 (I) wherein R1 represents an alkyl group having at least 3 carbon atoms, an alkoxy group having at least 3 carbon atoms or an aryloxy group, R2 and R3 each independently represent an aryloxy group or may be coupled together to form an arylenedioxy group. The process makes it possible to increase the reaction rate and living properties upon polymerization and increase the block formation efficiency upon block copolymerization.
摘要翻译：一种制备丙烯酸酯聚合物的方法，包括在有机锂化合物和有机铝化合物的存在下，进行丙烯酸酯的聚合或丙烯酸酯与另一（甲基）丙烯酸类单体的嵌段共聚合下式（I）：其中R 1表示具有至少3个碳原子的烷基，具有至少3个碳原子的烷氧基或芳氧基，R 2和R 3各自独立地表示芳氧基，或者可以连接在一起形成亚芳基二氧基。该方法可以提高聚合反应速率和活性，并且增加嵌段共聚时的嵌段形成效率。

16. 发明授权

US06737493B2 Biocompatible material 有权
标题翻译：生物相容性材料
公开(公告)号：US06737493B2
公开(公告)日：2004-05-18
申请号：US10131072
申请日：2002-04-25
申请人： Akira Mochizuki , Kenichi Shimura , Takao Anzai , Kazushige Ishiura , Kenichi Hamada
发明人： Akira Mochizuki , Kenichi Shimura , Takao Anzai , Kazushige Ishiura , Kenichi Hamada
IPC分类号： C08F11800
CPC分类号： C08F120/28
摘要： To provide a biocompatible material with a high level of safety at a low cost. The biocompatible material has a polymer synthesized from monomers by an anionic polymerization, wherein the polymer has a ratio (Mw/Mn) of a weight-average molecular weight (Mw) to a number-average molecular weight (Mn) in a range of 1.0 to 1.5, in which the weight-average molecular weight is 40,000 or more, and each of the monomers is represented by a following general formula (1): where R1 is a hydrogen atom or a methyl group; R2 is a C1-C4 alkylene group; and R3 is a C1-C4 alkyl group.
摘要翻译：以低成本提供具有高水平安全性的生物相容性材料。生物相容性材料具有通过阴离子聚合由单体合成的聚合物，其中聚合物的重均分子量（Mw）与数均分子量（Mn）之比（Mw / Mn）在1.0的范围内至1.5，其中重均分子量为40,000以上，并且各单体由以下通式（1）表示：其中R 1是氢原子或甲基; R 2是C 1 -C 4亚烷基; 且R 3为C 1 -C 4烷基。

17. 发明授权

US06630554B1 Process for polymerizing a methacrylic ester or an acrylic ester 有权
标题翻译：聚合甲基丙烯酸酯或丙烯酸酯的方法
公开(公告)号：US06630554B1
公开(公告)日：2003-10-07
申请号：US09664336
申请日：2000-09-18
申请人： Kenichi Hamada , Kazushige Ishiura , Toru Takahashi , Sachie Yaginuma , Makoto Akai , Tomohiro Ono , Kenji Shachi
发明人： Kenichi Hamada , Kazushige Ishiura , Toru Takahashi , Sachie Yaginuma , Makoto Akai , Tomohiro Ono , Kenji Shachi
IPC分类号： C08F452
CPC分类号： C08F4/48 , C08F4/52 , C08F20/18 , C08F212/08 , C08F297/026 , C08F220/14 , C08F2220/1825
摘要： (1) A methacrylic ester or an acrylic ester is anionically polymerized, using a polymerization initiator compound comprising an addition reaction product of a conjugated diene compound and an organic alkali metal compound, in the presence of a tertiary organoaluminum compound having in the molecule thereof a chemical structure represented by a formula: Al—O—Ar wherein Ar represents an aromatic ring; or (2) a methacrylic ester or an acrylic ester is anionically polymerized, using a polymerization initiator compound comprising an addition reaction product of an organic alkali metal compound and a compound having a 1,1-diaryl-1-alkene structure, by adding the ester in the form of a mixture with the above-mentioned specific tertiary organoaluminum compound to the polymerization system. In this way, various species of the esters can be anionically polymerized with a high initiation efficiency and a high living polymerization property in a solvent which can easily be recovered and reused under a mild cooling condition, using an organic alkali metal compound which has relatively good convenience.
摘要翻译：（1）使用包含共轭二烯化合物和有机碱金属化合物的加成反应产物的聚合引发剂化合物，在其分子内具有叔有机铝化合物的存在下，将甲基丙烯酸酯或丙烯酸酯阴离子聚合由下式表示的化学结构：Al-O-Ar，其中Ar表示芳环; 或（2）甲基丙烯酸酯或丙烯酸酯通过使用包含有机碱金属化合物与具有1,1-二芳基-1-烯烃结构的化合物的加成反应产物的聚合引发剂化合物进行阴离子聚合，酯与上述特定的叔有机铝化合物的混合物形式与聚合体系形成。这样，各种酯可以在溶剂中以高引发效率和高活性聚合性阴离子聚合，使用有利的碱金属化合物，在温和的冷却条件下容易回收和再次使用。

18. 发明授权

US06228946B1 Block copolymer and polymer composition comprising the same 有权
标题翻译：嵌段共聚物和包含其的聚合物组合物
公开(公告)号：US06228946B1
公开(公告)日：2001-05-08
申请号：US09343519
申请日：1999-06-30
申请人： Koji Kitayama , Kenichi Hamada , Makoto Akai , Kazushige Ishiura
发明人： Koji Kitayama , Kenichi Hamada , Makoto Akai , Kazushige Ishiura
IPC分类号： C08F2502
CPC分类号： C08L53/005 , C08F297/02 , C08F297/026 , C08L2666/02 , C08L2666/04
摘要： A block copolymer comprising, in a main chain thereof, a crystalline polymer block A obtained by hydrogenation of at least 80% of unsaturated bonds of a butadiene-based polymer block having a 1,2-bond content less than 20%, a polymer block B having a glass transition point of 20° C. or lower and a polymer block C composed mainly of a methacrylate ester unit and/or an acrylate ester unit and having a glass transition point exceeding 20° C. has good elastomeric properties, excellent weather resistance, solvent resistance and heat resistance and has good affinity with each of a polar polymer and non-polar polymer. A polymer composition comprising said block copolymer effectively exhibits the above-described characteristics of the block copolymer.
摘要翻译：一种嵌段共聚物，在其主链中包含通过氢化至少80％的具有小于20％的1,2-键含量的丁二烯基聚合物嵌段的不饱和键获得的结晶聚合物嵌段A，聚合物嵌段 B的玻璃化转变点为20℃以下，主要由甲基丙烯酸酯单元和/或丙烯酸酯单元构成的玻璃化转变点超过20℃的聚合物嵌段C具有良好的弹性，良好的天气电阻，耐溶剂性和耐热性，并且与极性聚合物和非极性聚合物中的每一种具有良好的亲和性。包含所述嵌段共聚物的聚合物组合物有效地表现出上述嵌段共聚物的特性。

19. 发明授权

US6096435A Thermoplastic polymer composition having a thermoplastic elastic polymer and a block copolymer 失效
标题翻译：具有热塑性弹性聚合物和嵌段共聚物的热塑性聚合物组合物
公开(公告)号：US6096435A
公开(公告)日：2000-08-01
申请号：US35873
申请日：1998-03-06
申请人： Kazuhiko Maekawa , Masanari Uno , Atsushi Itoh , Hiroshi Hayashihara , Kazushige Ishiura , Shigeru Kawahara , Shiroh Kishii
发明人： Kazuhiko Maekawa , Masanari Uno , Atsushi Itoh , Hiroshi Hayashihara , Kazushige Ishiura , Shigeru Kawahara , Shiroh Kishii
IPC分类号： B32B27/30 , C08L23/02 , C08L53/02 , C09J153/02 , B23B27/08 , C08L31/02 , C08L53/00 , B23B27/30
CPC分类号： C08L23/02 , C08L53/02 , C08L53/025
摘要： A thermoplastic polymer composition is provided that includes 100 parts by weight of a block copolymer and/or its hydrogenate having polymer blocks of an aromatic vinyl compound and polymer blocks of a conjugated diene compound, and from 5 to 95 parts by weight of a block copolymer having polymer blocks of an aromatic vinyl compound and/or an olefinic compound and polymer blocks having a constitutional unit derived from a (meth) acrylic compound, a laminate containing a layer of the composition, and a hot-melt adhesive that includes the composition. Because it has good melt adhesiveness, the composition of the invention can firmly adhere in melt to various polar or non-polar materials. Using the composition, it is easy to produce laminates having a layer of the composition and a layer of some other material, through melt shaping or any other melt adhesion techniques. Since the composition of the invention is satisfactorily elastic and flexible, the laminates having a layer of the composition on their surface are flexible and elastic and have a good feel, and, in addition, they are safe because of their shock absorbability and cushionability.
摘要翻译：提供一种热塑性聚合物组合物，其包含100重量份的嵌段共聚物和/或其具有芳族乙烯基化合物的聚合物嵌段和共轭二烯化合物的聚合物嵌段的氢化物和5至95重量份的嵌段共聚物具有芳族乙烯基化合物和/或烯烃化合物的聚合物嵌段和具有衍生自（甲基）丙烯酸类化合物的结构单元的聚合物嵌段，含有该组合物的层的层压体和包含该组合物的热熔性粘合剂。因为具有良好的熔融粘合性，所以本发明的组合物可以熔融地牢固地粘附到各种极性或非极性材料中。使用该组合物，通过熔融成型或任何其它熔融粘附技术，易于制备具有组合物层和一些其它材料层的层压体。由于本发明的组合物具有令人满意的弹性和柔性，所以在其表面上具有组合物层的层压体是柔性和弹性的并且具有良好的手感，并且由于它们的冲击吸收性和缓冲性，它们是安全的。

20. 发明授权

US6028147A Block copolymer, process for producing the same and resin composition of the same 有权
标题翻译：嵌段共聚物，其制造方法及其树脂组合物
公开(公告)号：US6028147A
公开(公告)日：2000-02-22
申请号：US158282
申请日：1998-09-22
申请人： Atsuhisa Ogawa , Kenji Shachi , Atsushi Itou , Kazushige Ishiura
发明人： Atsuhisa Ogawa , Kenji Shachi , Atsushi Itou , Kazushige Ishiura
IPC分类号： C08F297/00 , C08L23/08 , C08L29/04 , C08L53/00 , C08L77/00 , C08L101/00 , C08F259/02
CPC分类号： C08L23/08 , C08F297/00 , C08L53/00 , C08L77/00 , C08L23/0846 , C08L29/04
摘要： Herein disclosed are a block copolymer having an isobutylene-based polymer block and a vinylic aromatic hydrocarbon-based polymer block and containing a styrenic unit having a halogenated saturated aliphatic hydrocarbon group on the benzene ring at 0.01 to 2 mol % on a basis of the total structural units and being capable of markedly improving the performance of a synthetic resin when the block copolymer is blended with the synthetic resin; a process for producing the block copolymer; and a resin composition position containing the block copolymer.
摘要翻译：本文公开了具有异丁烯类聚合物嵌段和乙烯基芳香族烃类聚合物嵌段的嵌段共聚物，其含有在苯环上具有卤化饱和脂肪族烃基的苯乙烯单元，其含量为0.01〜2摩尔％结构单元，并且当嵌段共聚物与合成树脂共混时能够显着提高合成树脂的性能; 一种制备嵌段共聚物的方法; 和含有嵌段共聚物的树脂组合物位置。

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