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    • 18. 发明授权
    • Electrolytic cation exchange membrane
    • 电解阳离子交换膜
    • US4486277A
    • 1984-12-04
    • US493574
    • 1983-05-11
    • Haruhisa MiyakeManabu SuharaHiroshi MoriYoshihiko Saito
    • Haruhisa MiyakeManabu SuharaHiroshi MoriYoshihiko Saito
    • C25B13/08C08J5/22C25B1/14C25B13/00
    • C08J5/2281C08J2327/18
    • An electrolytic cation exchange membrane comprises a first film made of a fluorinated polymer having cation exchange groups and a second film laminated thereon, made of a fluorinated polymer having carboxylic acid groups as its ion exchange groups and containing the following repeating units (A), (B) and (C) and having a smaller thickness and greater specific electric resistance than the first film; ##STR1## where each of X and X' is --F, --Cl or --CF.sub.3, R.sub.f is a perfluoroalkyl group having from 1 to 10 carbon atoms, M is hydrogen or an alkali metal and Y is selected from the group consisting of --CF.sub.2).sub.x, --O--CF.sub.2).sub.x, ##STR2## where each of x and y is an integer of from 0 to 10 and Z is --F or R.sub.f as defined above, provided that B/A+B+C (molar ratio) and C/A+B+C (molar ratio) are from 0.01 to 0.3 and from 0.05 to 0.5, respectively.
    • 电解阳离子交换膜包括由具有阳离子交换基团的氟化聚合物制成的第一膜和层压在其上的第二膜,由具有羧酸基的氟化聚合物作为其离子交换基团并含有以下重复单元(A),( B)和(C),并且具有比第一膜更小的厚度和更大的比电阻; (C)其中X和X'各自为-F,-Cl或-CF 3,R f为具有1至10个碳原子的全氟烷基,M(C 1 -C 6) 是氢或碱金属,Y选自-CF 2)x,-O-CF 2)x,其中x和y各自为0至10的整数,Z为-F或 只要B / A + B + C(摩尔比)和C / A + B + C(摩尔比)分别为0.01至0.3和0.05至0.5,则定义如上。