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11. 发明授权

US5424907A Solid electrolytic capacitors and method for manufacturing the same 失效
标题翻译：固体电解电容器及其制造方法
公开(公告)号：US5424907A
公开(公告)日：1995-06-13
申请号：US18579
申请日：1993-02-17
申请人： Toshikuni Kojima , Masao Fukuyama , Yasuo Kudoh , Koichi Yoshida
发明人： Toshikuni Kojima , Masao Fukuyama , Yasuo Kudoh , Koichi Yoshida
IPC分类号： H01G9/02 , H01G9/025 , H01G4/005 , H01G9/04
CPC分类号： H01G9/025 , H01G11/56 , Y02E60/13 , Y10T29/417
摘要： Solid electrolytic capacitors comprise a valve metal member having a dielectric film, with or without a conductive underlying layer, formed on the member, and a conductive polymer film formed on the layer. The conductive polymer film is formed by electrolytic polymerization of a polymerizable monomer contained in a system which comprises the monomer, a support electrolyte, and at least one member selected from silicic acids and silicates with or without phenol compounds. By this, the life of the capacitor even under high temperature and high humidity conditions is significantly improved. Methods for fabricating such capacitors are also described.
摘要翻译：固体电解电容器包括具有电介质膜的阀金属构件，其具有或不具有形成在构件上的导电性下层，以及形成在该层上的导电聚合物膜。导电聚合物膜是通过包含在包含单体，支持电解质和至少一种选自具有或不具有酚化合物的硅酸和硅酸盐的组分的体系中的可聚合单体的电解聚合形成的。由此，即使在高温高湿条件下电容器的使用寿命也明显提高。还描述了制造这种电容器的方法。

12. 发明授权

US5187650A Solid electrolytic capacitors and method for manufacturing the same 失效
标题翻译：固体电解电容器及其制造方法
公开(公告)号：US5187650A
公开(公告)日：1993-02-16
申请号：US868362
申请日：1992-04-14
申请人： Yasuo Kudoh , Masao Fukuyama , Toshikuni Kojima , Norishige Nanai
发明人： Yasuo Kudoh , Masao Fukuyama , Toshikuni Kojima , Norishige Nanai
IPC分类号： H01G9/02 , H01G9/025
CPC分类号： H01G9/025 , H01G9/012 , H01G9/028 , Y10T29/12
摘要： Solid electrolytic capacitors comprise a valve metal member having a dielectric oxide film and a conductive underlying layer formed on the member in this order, and a conductive polymer film formed on the layer. The conductive polymer film is formed by electrolytic polymerization of a polymerizable monomer contained in a system containing the monomer and a support electrolyte consisting of a compound having at least one nitro group. By this, high temperature stability of the capacitor is significantly improved. Alternatively, the electrolytic polymerization may be effected in a system which comprises a monomer, a support electrolyte and a phenol or phenoxide derivative having at least one nitro group. Methods for fabricating such capacitors are also described.

13. 发明授权

US4660939A Electrochromic display device 失效
标题翻译：电致变色显示装置
公开(公告)号：US4660939A
公开(公告)日：1987-04-28
申请号：US647490
申请日：1984-09-05
申请人： Sohji Tsuchiya , Wataru Fujikawa , Toshikuni Kojima , Sadashi Higuchi , Akio Yamashita
发明人： Sohji Tsuchiya , Wataru Fujikawa , Toshikuni Kojima , Sadashi Higuchi , Akio Yamashita
IPC分类号： G02F1/155 , G02F1/01
CPC分类号： G02F1/155
摘要： In an electrochromic display device including a pair of opposed substrates, a display electrode formed on one of the substrates and a counter electrode formed on the other substrate, the response speed and display life of the device are improved by its novel counter electrode structure including a low conductive film arranged to face the display electrode and a high conductive film arranged to uncover, adjoin or cover the former. Alternatively, the low conductive film is embedded in the high conductive film to face the display electrode. Each of the conductive films is essentially made of In.sub.2 O.sub.3, In.sub.2 O.sub.3 --SnO.sub.2 or SnO.sub.2. The high conductive film may be made of Au, Ag or Pt. Where the low conductive film is an insulating film, it is sandwiched by the high conductive films. The insulating film is made of a metal oxide, metal fluoride or metal nitride. The difference in electric resistance between the low and high conductive films is selected 10 times or more. This novel counter electrode structure reduces the leakage current and provides a uniform current density distribution thus ensuring an improved response speed and display life.
摘要翻译：在包括一对相对基板的电致变色显示装置中，形成在一个基板上的显示电极和形成在另一个基板上的对电极，通过其新颖的对电极结构改善了该装置的响应速度和显示寿命，布置成面对显示电极的低导电膜和布置成露出，邻接或覆盖前者的高导电膜。或者，低导电膜嵌入到高导电膜中以面对显示电极。每个导电膜基本上由In2O3，In2O3-SnO2或SnO2制成。高导电膜可以由Au，Ag或Pt制成。低导电膜是绝缘膜时，被高导电膜夹在中间。绝缘膜由金属氧化物，金属氟化物或金属氮化物制成。低导电膜和高导电膜之间的电阻差为10倍以上。这种新型的对电极结构减少了泄漏电流并且提供均匀的电流密度分布，从而确保了改进的响应速度和显示寿命。

14. 发明授权

US5895606A Conductive polymer composition comprising polypyrrole and composite dopant 失效
标题翻译：包含聚吡咯和复合掺杂剂的导电聚合物组合物
公开(公告)号：US5895606A
公开(公告)日：1999-04-20
申请号：US602645
申请日：1996-02-16
申请人： Yasuo Kudoh , Toshikuni Kojima , Kenji Akami
发明人： Yasuo Kudoh , Toshikuni Kojima , Kenji Akami
IPC分类号： C08G73/02 , C08G73/06 , H01B1/12
CPC分类号： C08G73/0611 , C08G73/0266 , H01B1/127 , H01B1/128
摘要： A conductive polymer composition comprises a conjugated double bond-bearing polymer and a composite dopant consisting essentially of an organic anion derived from an anionic surface active agent and an inorganic anion derived from a transition metal salt. A process for preparing the conductive polymer composition is also described wherein the polymerizable proceeds rapidly in coexistence of the organic anion and the inorganic anion. Addition of fine particle of an oxide is effective in film formation on substrates.
摘要翻译：导电聚合物组合物包含共轭双键聚合物和基本上由衍生自阴离子表面活性剂的有机阴离子和衍生自过渡金属盐的无机阴离子组成的复合掺杂剂。还描述了制备导电聚合物组合物的方法，其中可聚合物在有机阴离子和无机阴离子共存下快速进行。添加氧化物的细颗粒对于在基底上的成膜是有效的。

15. 发明授权

US4679124A Solid electrolytic capacitors 失效
标题翻译：固体电解电容器
公开(公告)号：US4679124A
公开(公告)日：1987-07-07
申请号：US818592
申请日：1986-01-13
申请人： Susumu Yoshimura , Yasuo Kudoh , Soji Tsuchiya , Toshikuni Kojima , Shohzoh Takahashi
发明人： Susumu Yoshimura , Yasuo Kudoh , Soji Tsuchiya , Toshikuni Kojima , Shohzoh Takahashi
IPC分类号： H01G9/02 , H01G9/028 , H01G9/05
CPC分类号： H01G9/028
摘要： A solid electrolytic capacitor comprising an anodized valve metal anode and a cathode provided in face-to-face relation with the anode, between which a layer of a solid electrolyte is provided. The solid electrolyte consists essentially of a tetracyanoquinodimethane complex salt and neutral tetracyanoquinodimethane. In order to suppress generation of toxic gases such as HCN, polyhydric alcohols may be further added to the solid electrolyte.
摘要翻译：一种固体电解电容器，包括阳极氧化阀金属阳极和与阳极面对面地设置的阴极，在该电极之间设有一层固体电解质。固体电解质基本上由四氰基醌二甲烷配盐和中性四氰基醌二甲烷组成。为了抑制HCN等有毒气体的产生，可以将多元醇进一步添加到固体电解质中。

16. 发明授权

US06719813B2 Solid electrolytic capacitor and its manufacturing method 有权
标题翻译：固体电解电容器及其制造方法
公开(公告)号：US06719813B2
公开(公告)日：2004-04-13
申请号：US10173572
申请日：2002-06-18
申请人： Toshikuni Kojima , Kenji Kuranuki , Kazuo Tadanobu , Takuhisa Sugimoto , Yasuhiro Kobatake
发明人： Toshikuni Kojima , Kenji Kuranuki , Kazuo Tadanobu , Takuhisa Sugimoto , Yasuhiro Kobatake
IPC分类号： H01G900
CPC分类号： H01G9/15 , H01G9/012 , H01G9/028 , Y10T29/417
摘要： A solid electrolytic capacitor having (A) a capacitor element including an oxide layer 1 formed on a part of an outer surface of a valve metal anode body, a solid electrolyte layer 2 formed on the oxide layer layer, and a cathode conductor layer 3 formed on the solid electrolyte layer, and an anode lead out area on a remaining part of the anode body, (B) lead terminals connected to the cathode and the anode lead out area of the capacitor element, and (C) a packaging resin encapsulating the capacitor element with parts of the lead terminals exposed outside. The solid electrolytic capacitor has a first separation strip 6 and a second separation strip 7 formed on a part of the roughened surface layer and also has insulating material 8 on the respective surfaces of the first and the second separation strips.
摘要翻译：一种固体电解电容器，其具有（A）电容器元件，电容器元件包括形成在阀金属阳极体的外表面的一部分上的氧化物层1，形成在氧化物层层上的固体电解质层2和形成的阴极导体层3 在阳极体的剩余部分上的固体电解质层和阳极引出区域，（B）连接到电容器元件的阴极和阳极引出区域的引线端子，（C）包封树脂电容器元件，引线端子的部分暴露在外面。固体电解电容器具有形成在粗糙化表面层的一部分上的第一分离条6和第二分离条7，并且在第一和第二分离条的各个表面上也具有绝缘材料8。

17. 发明授权

US06206937B1 Solid electrolytic capacitors comprising a conductive layer made of a polymer of pyrrole or its derivative and method for making the same 失效
标题翻译：包含由吡咯的聚合物或其衍生物制成的导电层的固体电解电容器及其制造方法
公开(公告)号：US06206937B1
公开(公告)日：2001-03-27
申请号：US09148321
申请日：1998-09-04
申请人： Yasuo Kudoh , Kenji Akami , Toshikuni Kojima , Yasue Matsuya , Hiroshi Shimada , Chiharu Hayashi
发明人： Yasuo Kudoh , Kenji Akami , Toshikuni Kojima , Yasue Matsuya , Hiroshi Shimada , Chiharu Hayashi
IPC分类号： H01G900
CPC分类号： H01G9/025 , H01G9/0036 , H01G9/028 , H01G9/0425 , H01G11/48 , H01G11/56 , Y02E60/13 , Y10T29/417
摘要： A solid electrolytic capacitor comprising comprises a pair of electrodes, and a dielectric film provided between the paired electrodes wherein at least one of the paired electrodes comprising a first conductive polymer layer which is made of a polymer of a member selected from the group consisting of pyrrole and derivatives thereof, the first conductive polymer layer being doped with a mixed dopant of a polyvalent anion and a monovalent anion consisting of a sulfonate ion dissociated from an anionic surface active agent. The conductive polymer layer may have a double-layered or a multi-layered structure wherein a second and/or third conductive polymer layer is made of a doped polymer of a thiophene derivative. A method for making the capacitors are also described.
摘要翻译：一种固体电解电容器，包括一对电极和设置在所述成对电极之间的电介质膜，其中所述成对电极中的至少一个包括第一导电聚合物层，所述第一导电聚合物层由选自吡咯的成员的聚合物制成其衍生物，第一导电聚合物层掺杂有多价阴离子和由阴离子表面活性剂分离的磺酸根离子组成的一价阴离子的混合掺杂剂。导电聚合物层可以具有双层或多层结构，其中第二和/或第三导电聚合物层由噻吩衍生物的掺杂聚合物制成。还描述了制造电容器的方法。

18. 发明授权

US5812367A Solid electrolytic capacitors comprising a conductive layer made of a polymer of pyrrole or its derivative 失效
标题翻译：包含由吡咯或其衍生物的聚合物制成的导电层的固体电解电容器
公开(公告)号：US5812367A
公开(公告)日：1998-09-22
申请号：US840445
申请日：1997-04-01
申请人： Yasuo Kudoh , Kenji Akami , Toshikuni Kojima , Yasue Matsuya , Hiroshi Shimada , Chiharu Hayashi
发明人： Yasuo Kudoh , Kenji Akami , Toshikuni Kojima , Yasue Matsuya , Hiroshi Shimada , Chiharu Hayashi
IPC分类号： H01G9/00 , H01G9/02 , H01G9/025 , H01G9/042
CPC分类号： H01G9/025 , H01G11/48 , H01G11/56 , H01G9/0036 , H01G9/028 , H01G9/0425 , Y02E60/13 , Y10T29/417
摘要： A solid electrolytic capacitor is composed of a pair of electrodes and a dielectric film therebetween, wherein one electrode includes a conducting polymer doped with a polyvalent anion and a monovalent anion. The conducting polymer layer may have a multi-layer structure wherein a second or third conductive polymer layer is made of doped thiophene or derivative thereof.
摘要翻译：固体电解电容器由一对电极和介电膜构成，其中一个电极包括掺杂有多价阴离子和一价阴离子的导电聚合物。导电聚合物层可以具有多层结构，其中第二或第三导电聚合物层由掺杂噻吩或其衍生物制成。

19. 发明授权

US06774554B1 Cathode ray tube 失效
标题翻译：阴极射线管
公开(公告)号：US06774554B1
公开(公告)日：2004-08-10
申请号：US09645741
申请日：2000-08-24
申请人： Toshikuni Kojima , Masanori Morii , Hiromi Wakasono
发明人： Toshikuni Kojima , Masanori Morii , Hiromi Wakasono
IPC分类号： H01J2988
CPC分类号： H01J29/88 , H01J2229/882
摘要： A cathode ray tube includes a bulb including a front panel and a funnel, and an electron gun. The front panel includes a color selection mechanism and phosphors on an inner surface thereof. The funnel includes a conductive layer on an inner wall thereof. The electron gun is accommodated in a neck portion of the funnel. The conductive layer is divided into at least two regions, each of which has a different electric potential. A high electric potential conductive layer having a high electric potential, an insulating region, a resistive layer, and a low electric potential conductive layer having an electric potential lower than that of the high electric potential conductive layer are formed in this order from the panel side to the electron gun side. With this configuration, the two conductive layers do not interfere with each other because of discharge or the like and are independent, and stable voltage can be maintained. Thus, an electrostatic lens can be formed.
摘要翻译：阴极射线管包括具有前面板和漏斗的灯泡和电子枪。前面板包括在其内表面上的选色机构和荧光体。漏斗在其内壁上包括导电层。电子枪容纳在漏斗的颈部。导电层被分成至少两个区域，每个区域具有不同的电位。从面板侧依次形成电位低于高电位导电层电位的电位高电位的导电层，绝缘区域，电阻层，低电位导电层到电子枪一侧。利用这种结构，两个导电层由于放电等而不彼此干涉，并且是独立的，并且可以保持稳定的电压。因此，可以形成静电透镜。

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