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11. 发明授权

US07176267B2 Fluorine-containing polyether monomer, and polymer and surface treatment agent comprising the same 有权
标题翻译：含氟聚醚单体，以及包含其的聚合物和表面处理剂
公开(公告)号：US07176267B2
公开(公告)日：2007-02-13
申请号：US10485467
申请日：2002-07-26
申请人： Ikuo Yamamoto , Nobuo Fukita
发明人： Ikuo Yamamoto , Nobuo Fukita
IPC分类号： C08F16/24
CPC分类号： C08G65/3322 , C08F20/28 , C08F220/28 , C08F290/06 , C08F290/062 , C08G65/007 , C08G65/226 , C08G65/331 , C08L2205/05 , D06M15/277 , D06M2200/10 , D06M2200/11 , D06M2200/12
摘要： A fluorine-containing polymer which is an active component of a surface treatment agent having excellent water- and oil-repellency is constituted by a fluorine-containing polyether monomer of the formula: wherein Rf is a perfluoroalkyl group having 1 to 18 carbon atoms, R is hydrogen or a methyl group, A1 is a divalent linear or branched aliphatic group having 1 to 20 carbon atoms, A2 is a direct bond, or a divalent linear or branched aliphatic group having 1 to 10 carbon atoms which may have an ether linkage, X is a trivalent linear or branched aliphatic group having 2 to 5 carbon atoms, and n is from 1 to 100.
摘要翻译：作为具有优异的防水拒油性的表面处理剂的活性成分的含氟聚合物由下式的含氟聚醚单体构成：其中，Rf为碳原子数1〜18的全氟烷基，R 是氢或甲基，A 1是具有1至20个碳原子的二价直链或支链脂族基团，A 2是直接键，或二价线性或可以具有醚键的具有1〜10个碳原子的支链脂肪族基团，X是碳原子数2〜5的3价直链或支链脂肪族基团，n为1〜100。

12. 发明授权

US06750277B1 Composition and treatment agent 有权
标题翻译：成分和处理剂
公开(公告)号：US06750277B1
公开(公告)日：2004-06-15
申请号：US09355673
申请日：1999-08-19
申请人： Masayuki Yamana , Ikuo Yamamoto , Masato Kashiwagi , Koji Kubota
发明人： Masayuki Yamana , Ikuo Yamamoto , Masato Kashiwagi , Koji Kubota
IPC分类号： C08K504
CPC分类号： C08K5/06 , C08K5/10 , C09K3/18 , D06M15/277 , D06M15/285 , D06M2200/11 , D06M2200/12
摘要： A composition comprising (A) a copolymer which comprises (I) repeating units which are derived from a monomer having a fluoroalkyl group, a carbon-carbon double bond, (II) optional repeating units which are derived from a monomer having at least two urethane or urea bonds and a carbon-carbon double bond, but no fluorine atom, (III) optional repeating units which are derived from a monomer, the homopolymer of which having a glass transition temperature (Tg) of 50° C. or less, (IV) optional repeating units which are derived from a monomer having a hydrophilic group and a carbon-carbon double bond, and (V) optional repeating units which are derived from a monomer having a chlorine atom and a carbon-carbon double bond; and (B) a film-forming auxiliary can impart high water and oil repellency by drying at room temperature (0 to 30° C.) without requiring a heat treatment step.
摘要翻译：一种组合物，其包含（A）共聚物，其包含（I）衍生自具有氟烷基的单体的重复单元，碳 - 碳双键，（II）任选的重复单元，其衍生自具有至少两个氨基甲酸酯的单体或脲键和碳 - 碳双键，但不含氟原子，（III）衍生自单体的任选的重复单元，其均聚物的玻璃化转变温度（Tg）为50℃以下（（Tg） IV）衍生自具有亲水基团和碳 - 碳双键的单体的任选重复单元，和（V）衍生自具有氯原子和碳 - 碳双键的单体的任选的重复单元; 和（B）成膜助剂可以通过在室温（0〜30℃）下干燥而赋予高斥水斥油性，而不需要热处理步骤。

13. 发明授权

US5525150A Mold release agent 失效
标题翻译：脱模剂
公开(公告)号：US5525150A
公开(公告)日：1996-06-11
申请号：US170210
申请日：1994-02-22
申请人： Masayuki Yamana , Ikuo Yamamoto , Shingo Fujiwara
发明人： Masayuki Yamana , Ikuo Yamamoto , Shingo Fujiwara
IPC分类号： B29C33/62 , B29K71/00 , C08K5/00 , C08K5/521 , C08L71/02 , C10M173/02 , C10N30/06 , C10N40/36 , C09K3/00 , B28B7/36
CPC分类号： B29C33/62 , B29K2071/00
摘要： A water-based mold release agent, which contains a halogen-containing polyether having at least one functional group as a main component, gives no environmental pollution, has excellent dispersibility, storage stability and mold releasability and gives a good surface state to a shaped article of a polymeric material.
摘要翻译： PCT No.PCT / JP93 / 00544 Sec。 371日期：1994年2月22日 102（e）日期1994年2月22日PCT提交1993年4月27日PCT公布。第WO93 / 22121号公报日期：1993年11月11日。含有具有至少一个官能团作为主要成分的含卤聚醚的水性脱模剂不产生环境污染，分散性优异，保存稳定性和脱模性良好与聚合材料的成型制品的良好的表面状态。

14. 发明授权

US5378453A Composition for preventing graying of the hair and restoring grayed hair to its natural color 失效
标题翻译：用于防止头发变灰并将灰色头发恢复为其自然颜色的组合物
公开(公告)号：US5378453A
公开(公告)日：1995-01-03
申请号：US206675
申请日：1994-03-07
申请人： Keikichi Sugiyama , Koji Takada , Ikuo Yamamoto
发明人： Keikichi Sugiyama , Koji Takada , Ikuo Yamamoto
IPC分类号： A61K8/00 , A61K8/60 , A61K31/675 , A61P17/00 , A61Q5/00 , A61Q5/10 , A61Q7/00 , A61K7/06
CPC分类号： A61K8/606 , A61Q5/10 , Y10S514/88 , Y10S514/881
摘要： A composition for preventing graying of the hair and restoring grayed hair to its natural color comprises an effective amount of one member selected from the group consisting of cAMP compounds such as 8-butylthio cAMP-Na or 8-methoxy cAMP-Na and water. The composition can prevent graying of the hair and restoring grayed hair to its natural color upon application to the scalp, the effective component is very stable even in the form of compositions containing water and the composition does not cause quality deteriorations such as giving out of bad smell.
摘要翻译：用于防止毛发变灰并将灰白色毛发恢复为其天然色彩的组合物包含有效量的选自由c-cAMP化合物如8-丁硫基cAMP-Na或8-甲氧基cAMP-Na和水组成的组中的一种。该组合物可以防止头发变灰，并将灰头发恢复到其头皮上的自然颜色，即使以含有水的组合物的形式，有效成分也非常稳定，并且组合物不会引起质量恶化，例如不良闻。

15. 发明授权

US5214216A Fluorine-containing polyether and nonionic surfactant comprising the same 失效
标题翻译：含氟聚醚和含有它的非离子表面活性剂
公开(公告)号：US5214216A
公开(公告)日：1993-05-25
申请号：US556419
申请日：1990-07-24
申请人： Takashi Tohzuka , Sueyoshi Ishikawa , Ikuo Yamamoto
发明人： Takashi Tohzuka , Sueyoshi Ishikawa , Ikuo Yamamoto
IPC分类号： B01F17/00 , C08G65/00
CPC分类号： C08G65/00 , B01F17/0035
摘要： A fluorine-containing polyether of the formula:R.sub.f --X--A (I)orA--X--R'.sub.f --X--A (II)wherein R.sub.f and R'.sub.f are each a linear group containing a perfluoroalkyl polyether group, X is --CF.sub.2 COO--, --C.sub.2 F.sub.4 COO-- or --CF.sub.2 CF.sub.2 -- and A is a group containing a polyalkylene glycol group. The polyether can be used as a nonionic surfactant which is compatible with a perfluoroalkyl polyether.
摘要翻译：具有下式的含氟聚醚：Rf-XA（I）或AX-R'f-XA（II）其中Rf和R'f各自为含有全氟烷基聚醚基团的线性基团，X为-CF 2 COO-， C2F4COO-或-CF2CF2-，A是含有聚亚烷基二醇基的基团。聚醚可以用作与全氟烷基聚醚相容的非离子表面活性剂。

16. 发明授权

US08927667B2 Fluorosilicones and fluorine- and silicon-containing surface treatment agent 有权
标题翻译：氟硅氧烷和含氟和硅的表面处理剂
公开(公告)号：US08927667B2
公开(公告)日：2015-01-06
申请号：US12866074
申请日：2009-02-04
申请人： Ikuo Yamamoto , Tetsuya Masutani , Shinichi Minami , Peter Cheshire Hupfield , Avril E. Surgenor , Samantha Reed
发明人： Ikuo Yamamoto , Tetsuya Masutani , Shinichi Minami , Peter Cheshire Hupfield , Avril E. Surgenor , Samantha Reed
IPC分类号： C08F283/12 , C08F18/20
CPC分类号： C08F283/12 , C08F290/068 , C08F290/148 , C08L51/003 , C08L51/085 , C09D151/003 , C09D151/085 , C08L2666/02
摘要： A fluorosilicone reaction product of a vinyl functional organopolysiloxane and a fluorine-containing monomer, and methods of preparing the fluorosilicone are disclosed. The fluorosilicone products are suitable for application to substrates such as textiles, particularly fabrics, to impart oil repellent properties to the textile. The fluorosilicone reaction product is prepared from (A) a fluorine-containing monomer of the formula CH2═C(X)COOYRf, and (B) a vinyl functional organopolysiloxane.
摘要翻译：公开了一种乙烯基官能的有机聚硅氧烷和含氟单体的氟硅酮反应产物，以及氟硅氧烷的制备方法。氟硅氧烷产品适用于纺织品，特别是织物等基材，以赋予纺织品防油性能。氟硅酮反应产物由（A）式为CH2 = C（X）COOYRf的含氟单体和（B）乙烯基官能的有机聚硅氧烷制备。

17. 发明授权

US08394887B2 Fluoropolymer having S-sulfate group and water/oil repellent composition containing the polymer 有权
标题翻译：含有硫酸盐基的含氟聚合物和含有该聚合物的斥水斥油剂组合物
公开(公告)号：US08394887B2
公开(公告)日：2013-03-12
申请号：US11912714
申请日：2006-04-06
申请人： Kiyoshi Yamauchi , Shinichi Minami , Ikuo Yamamoto
发明人： Kiyoshi Yamauchi , Shinichi Minami , Ikuo Yamamoto
IPC分类号： C08L27/12 , C08F18/20 , C08F12/30
CPC分类号： D06M15/3566 , C08F220/22 , C08F220/24 , C08F220/38 , C09D133/16 , D06M15/277 , D06M2200/11 , D06M2200/12 , Y10T428/23986
摘要： A fluoropolymer comprising: (A) repeating unit derived from an S-sulfate monomer having an —S—SO3— group and carbon to carbon double bond; and (B) repeating unit derived from a fluoromonomer having a fluorine atom and carbon to carbon double bond. This fluoropolymer can be a constituent of water/oil repellent agent having excellent water/oil repelling capability, and is stable in air and permits an arbitrary control of crosslinking.
摘要翻译：一种含氟聚合物，其包含：（A）衍生自具有-S-SO 3 - 基团和碳 - 碳双键的S-硫酸酯单体的重复单元; 和（B）衍生自具有氟原子和碳碳双键的含氟单体的重复单元。该含氟聚合物可以是具有优异的斥水斥油能力的防斥油剂的成分，在空气中稳定，可以任意控制交联。

18. 发明授权

US07678155B2 Water- and oil-repellent treatment of textile 有权
标题翻译：防水和拒油处理纺织品
公开(公告)号：US07678155B2
公开(公告)日：2010-03-16
申请号：US10408777
申请日：2003-04-08
申请人： Ikuo Yamamoto , Kayo Kusumi , Mitsuhiro Usugaya , Ryosuke Hara , Takahito Kanbara
发明人： Ikuo Yamamoto , Kayo Kusumi , Mitsuhiro Usugaya , Ryosuke Hara , Takahito Kanbara
IPC分类号： D06M11/07 , D06M11/58 , D06M13/53
CPC分类号： D06M15/277 , D06M11/05 , D06M13/46 , D06M15/41 , D06M2200/11 , D06M2200/12 , Y10T428/23986 , Y10T428/2933 , Y10T442/2172 , Y10T442/2189 , Y10T442/227
摘要： Excellent water- and oil-repellency and soil releasability can be obtained by a method of preparing a treated textile, having steps of: (1) preparing a treatment liquid containing a water- and oil-repellent agent and a stain blocking agent, (2) adjusting pH of the treatment liquid to at most 7, (3) applying the treatment liquid to a textile, (4) treating the textile with steam, and (5) washing the textile with water and dehydrating the textile, wherein the water- and oil-repellent agent contains at least one fluorine-containing compound selected from the group consisting of a fluorine-containing polymer and a fluorine-containing low molecular weight compound, and the water- and oil-repellent agent or the treatment liquid contains a cationic emulsifying agent.
摘要翻译：通过制备经处理的织物的方法可以获得优异的拒水拒油性和污垢释放性，其具有以下步骤：（1）制备含有拒水拒油剂和防污剂的处理液（2 ）将处理液的pH调节至最多7，（3）将处理液施加到纺织品上，（4）用蒸汽处理织物，（5）用水洗涤织物并使织物脱水，防油剂含有选自含氟聚合物和含氟低分子化合物中的至少一种含氟化合物，防水防油剂或处理液含有阳离子性乳化剂。

19. 发明授权

US07638575B2 Surface treating agent, fluorine-containing monomer and fluorine-containing polymer 有权
标题翻译：表面处理剂，含氟单体和含氟聚合物
公开(公告)号：US07638575B2
公开(公告)日：2009-12-29
申请号：US10594011
申请日：2005-03-25
申请人： Ikuo Yamamoto , Yutaka Ohira , Yoshio Funakoshi , Shinichi Minami
发明人： Ikuo Yamamoto , Yutaka Ohira , Yoshio Funakoshi , Shinichi Minami
IPC分类号： C08L27/12
CPC分类号： C08F214/18 , C07C323/12 , C08F120/24 , C08F120/38 , C08F220/24 , C08F220/38 , C09D5/1668 , C09D133/16 , C09K3/18 , D06M15/277 , D06M15/295 , D06M2200/10 , D06M2200/11 , D06M2200/12 , D21H17/11 , D21H21/16 , Y10T442/2287
摘要： Disclosed is a surface treating agent containing fluorine-containing polymer having: (A) a repeating unit derived from a fluorine-containing compound which is represented by the following formula: CH2═C(—X)—C(═O)—Y—[—(CH2)m-Z-]p—(CH2)n-Rf (I) (wherein X is a hydrogen atom or a methyl group), (B) a repeating unit derived from a monomer containing no fluorine atom, if necessary and (C) a repeating unit derived from a crosslinkable monomer, if necessary. This surface treating agent has excellent water repellency, oil repellency and antifouling property.
摘要翻译：公开了含有含氟聚合物的表面处理剂，其具有：（A）由下式表示的含氟化合物的重复单元：CH2-C（-X）-C（-O）-Y- [ - （CH 2）m Z-] p-（CH 2）n -R f（I）（其中X为氢原子或甲基），（B）衍生自不含氟原子的单体的重复单元，如果需要，（C）衍生自交联性单体的重复单元。该表面处理剂具有优异的防水性，防油性和防污性。

20. 发明授权

US07442829B2 Fluorine-containing monomer, fluorine-containing polymer and surface treating agent 有权
标题翻译：含氟单体，含氟聚合物和表面处理剂
公开(公告)号：US07442829B2
公开(公告)日：2008-10-28
申请号：US10594148
申请日：2005-03-25
申请人： Ikuo Yamamoto , Yutaka Ohira , Yoshio Funakoshi , Shinichi Minami , Ginjiro Tomizawa
发明人： Ikuo Yamamoto , Yutaka Ohira , Yoshio Funakoshi , Shinichi Minami , Ginjiro Tomizawa
IPC分类号： A61K31/195 , C07C229/48 , C07C61/08
CPC分类号： C07C317/18 , C07C229/30 , C07C255/23 , C07C323/12 , C08F214/18 , Y10T428/23986 , Y10T442/20 , Y10T442/2287
摘要： Disclosed is a fluorine-containing polymer having: (A) a repeating unit derived from a fluorine-containing monomer which is represented by the following formula: CH2═C(—X)—C(═O)—Y—[—(CH2)m-Z-]p—(CH2)n—Rf (I) (B) a repeating unit derived from a monomer containing no fluorine atom, and if necessary (C) a repeating unit derived from a crosslinkable monomer. This fluorine containing polymer has excellent water repellency, oil repellency and antifouling property.
摘要翻译：公开了一种含氟聚合物，其具有：（A）由下式表示的含氟单体衍生的重复单元：＆lt;线内配方说明=“在线式”末端=“铅” -C（ - ） - （ - O）-Y - [ - （CH 2）2） - [ （I）<βin-line-formula description =“In-line Formulas”end =“尾”→（B）衍生自不含氟原子的单体的重复单元，必要时（C）来自交联性单体的重复单元。该含氟聚合物具有优异的防水性，拒油性和防污性。

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