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11. 发明授权

US4942196A Cathodically depositable electrodeposition paints 失效
标题翻译：阴极沉积电沉积涂料
公开(公告)号：US4942196A
公开(公告)日：1990-07-17
申请号：US351072
申请日：1989-05-12
申请人： Willibald Paar , Rudolf Schipfer , Johann Gmoser
发明人： Willibald Paar , Rudolf Schipfer , Johann Gmoser
IPC分类号： C09D5/44 , C09D163/00
CPC分类号： C09D5/4492
摘要： Cathodically depositable electrodeposition paints contain binder combinations of cationic film-forming resins with organic titanium compounds which are obtained by reacting tetraalkyl orthotitanates or titanium acetyl acetonates with compounds containing at least one phenolic hydroxyl group. The stoved paint films exhibit an excellent anticorrosion effect on non-pretreated sheet steel.
摘要翻译：阴极沉积的电沉积涂料含有阳离子成膜树脂与有机钛化合物的粘合剂组合，其通过使原钛酸四烷基酯或乙酰丙酮钛与含有至少一个酚羟基的化合物反应而获得。烤漆膜对未预处理的钢板表现出优异的防腐蚀效果。

12. 发明授权

US4789696A Catalyzed cationic paint binders 失效
标题翻译：催化阳离子涂料粘合剂
公开(公告)号：US4789696A
公开(公告)日：1988-12-06
申请号：US98892
申请日：1987-09-21
申请人： Willibald Paar , Johann Gmoser
发明人： Willibald Paar , Johann Gmoser
IPC分类号： C08G18/24 , C08G59/68 , C09D5/44 , C09D201/00 , C09D3/58 , C08L63/10
CPC分类号： C08G59/681 , C08G18/242 , C09D5/4492
摘要： Cationic paint binders, particularly binders of the type used in cathodic electrodeposition coatings which crosslink through transesterification, transamidation, transurethanization, or through the reaction of chain end double bonds catalyzed with a condensation product of a dialkyltinoxide and a compound carrying at least one hydroxyl group are described. The hydroxyl compounds are the aliphatic alcohols, phenols, alkanolamines, or the reaction products of primary amines with monoepoxy compounds. The catalysts of the invention provide very good stability and good compatibility in aqueous cationic paint materials.
摘要翻译：阳离子涂料粘合剂，特别是用于通过酯交换，酰胺转移，氨基甲酸酯化或通过二烷基氧化锡与携带至少一个羟基的化合物的缩合产物催化的链末端双键反应的阴极电沉积涂料中所用类型的粘合剂，描述。羟基化合物是脂族醇，酚，链烷醇胺，或伯胺与单环氧化合物的反应产物。本发明的催化剂提供非常好的稳定性和在阳离子水性阳离子涂料中的良好相容性。

13. 发明授权

US4568709A Cathodically depositable electrodeposition paint binders based on reaction products of epoxy resin-amino adduct with formaldehyde and phenols 失效
标题翻译：基于环氧树脂 - 氨基加合物与甲醛和酚的反应产物的阴极沉积电沉积涂料粘合剂
公开(公告)号：US4568709A
公开(公告)日：1986-02-04
申请号：US712515
申请日：1985-03-18
申请人： Willibald Paar , Johann Gmoser , Helmut Honig , Wolfgang Daimer
发明人： Willibald Paar , Johann Gmoser , Helmut Honig , Wolfgang Daimer
IPC分类号： C08G14/14 , C09D5/44 , C08G18/80 , C08G59/14 , C09D3/58
CPC分类号： C09D5/4419 , C08G14/14 , Y10S524/901
摘要： Cathodically depositable electrodeposition paint binders comprising the reaction product of an epoxy resin with at least two epoxy groups with amines carrying primary amino groups and, optionally, with a carboxylic acid compound to provide an epoxy resin-amino adduct which is then reacted with a phenol and formaldehyde. The binders have excellent corrosion resistance and crosslink to provide coating films at relatively low stoving temperatures without splitting off of substances harmful to the environment.
摘要翻译：阴极沉积的电沉积涂料粘合剂，其包含环氧树脂与至少两个环氧基团的反应产物和携带伯氨基的胺，以及任选地与羧酸化合物反应以提供环氧树脂 - 氨基加合物，然后与苯酚和甲醛。粘合剂具有优异的耐腐蚀性和交联性，以在相对低的烘烤温度下提供涂膜，而不会分解对环境有害的物质。

14. 发明授权

US4845170A Self-crosslinking cationic paint binders containing urea groups and process of manufacture 失效
标题翻译：含有尿素基团的自交联阳离子涂料粘合剂及其制造方法
公开(公告)号：US4845170A
公开(公告)日：1989-07-04
申请号：US128446
申请日：1987-12-03
申请人： Willibald Paar , Michael Honel , Johann Gmoser
发明人： Willibald Paar , Michael Honel , Johann Gmoser
IPC分类号： C08G18/54 , C08G18/80 , C08G18/83 , C08G59/12 , C08G59/14 , C08G59/62 , C09D5/44 , C09D163/00 , H01B3/40
CPC分类号： H01B3/40 , C08G18/544 , C08G18/8061 , C08G18/831 , C08G59/12 , C08G59/1433 , C08G59/623 , C09D163/00 , C09D5/4419 , Y10S524/901
摘要： A process for producing self-crosslinking cationic paint binders, water-dilutable upon protonation, on the basis of urea group carrying reaction products of modified phenols and epoxy resins as well as with the binders produced according to the process and their use in stoving paints, particularly in electrodeposition paints is described. The process is characterized in that either an aminoalkylation product of a phenol and a semi-blocked diisocyanate carrying an average of at least one secondary amino group, or a substituted urea prepared from a semi-blocked diisocyanate and an amine, which is further reacted with formaldehyde and a phenol, are reacted with an epoxy compound. The paints formulated with these products, at stoving temperatures of from 150.degree. to 170.degree. C., give films with excellent corrosion resistance and adhesion.
摘要翻译：用于生产自交联阳离子涂料粘合剂的方法，其基于质子化水可稀释，基于带有改性酚和环氧树脂的反应产物的脲基，以及根据该方法生产的粘合剂及其在烘烤油漆中的用途，特别是在电沉积涂料中。该方法的特征在于，苯酚的氨基烷基化产物和平均具有至少一个仲氨基的半封端二异氰酸酯或由半嵌段二异氰酸酯和胺制备的取代脲，其进一步与甲醛和苯酚与环氧化合物反应。在150〜170℃的烘箱温度下，用这些产品配制的油漆，具有优良的耐腐蚀性和附着力。

15. 发明授权

US08445585B2 Aqueous coating binders for corrosion protection, wood and concrete 有权
标题翻译：水性涂料粘合剂用于防腐蚀，木材和混凝土
公开(公告)号：US08445585B2
公开(公告)日：2013-05-21
申请号：US12524785
申请日：2008-01-08
申请人： Willi Paar , Roland Feola , Johann Gmoser , Rosemaria Grasboeck
发明人： Willi Paar , Roland Feola , Johann Gmoser , Rosemaria Grasboeck
IPC分类号： C08G69/44
CPC分类号： C08L63/00 , C09D163/00 , C08L2666/18
摘要： This invention relates to binder mixtures comprising mass fractions of from 70% to 98% of chain-extended epoxy amine adducts A and from 2% to 30% of carboxy functional polyesters B that contain a limited amount of aromatic constituents in mass fractions of up to 15% and have an acid number of from 4 mg/g to 50 mg/g, a method of making these binder mixtures, and a method of use thereof in coatings for metals, wood, cardboard, plaster, and concrete.
摘要翻译：本发明涉及粘合剂混合物，其包含70％至98％的链延伸的环氧胺加合物A和2％至30％的羧基官能聚酯B的质量分数，其含有质量分数的有限量的芳族组分直至 15％，酸值为4mg / g至50mg / g，制备这些粘合剂混合物的方法及其在金属，木材，纸板，石膏和混凝土的涂料中的使用方法。

16. 发明申请

US20100069563A1 Aqueous Coating Binders for Corrosion Protection, Wood and Concrete 有权
标题翻译：用于腐蚀防护，木材和混凝土的水性涂料粘合剂
公开(公告)号：US20100069563A1
公开(公告)日：2010-03-18
申请号：US12524785
申请日：2008-01-08
申请人： Willi Paar , Roland Feola , Johann Gmoser , Rosemaria Grasboeck
发明人： Willi Paar , Roland Feola , Johann Gmoser , Rosemaria Grasboeck
IPC分类号： C09D163/00
CPC分类号： C08L63/00 , C09D163/00 , C08L2666/18
摘要： This invention relates to binder mixtures comprising mass fractions of from 70% to 98% of chain-extended epoxy amine adducts A and from 2% to 30% of carboxy functional polyesters B that contain a limited amount of aromatic constituents in mass fractions of up to 15% and have an acid number of from 4 mg/g to 50 mg/g, a method of making these binder mixtures, and a method of use thereof in coatings for metals, wood, cardboard, plaster, and concrete.
摘要翻译：本发明涉及粘合剂混合物，其包含70％至98％的链延伸的环氧胺加合物A和2％至30％的羧基官能聚酯B的质量分数，其含有质量分数的有限量的芳族组分直至 15％，酸值为4mg / g至50mg / g，制备这些粘合剂混合物的方法及其在金属，木材，纸板，石膏和混凝土的涂料中的使用方法。

17. 发明授权

US06372108B1 Binders for use in cathodic electrodeposition coatings, process for their preparation and cathodic electrodeposition coating compositions containing same 失效
标题翻译：用于阴极电沉积涂料的粘合剂，其制备方法和含有它们的阴极电沉积涂料组合物
公开(公告)号：US06372108B1
公开(公告)日：2002-04-16
申请号：US09571144
申请日：2000-05-16
申请人： Helmut Hoenig , Roland Feola , Johann Gmoser , Robert Thausz
发明人： Helmut Hoenig , Roland Feola , Johann Gmoser , Robert Thausz
IPC分类号： C25D1306
CPC分类号： C08G59/56 , C09D5/4434 , C09D163/00
摘要： Novel alkaline polymeric binders, preferably amino epoxy binders, for use in cathodic electrodeposition coatings have a number average molecular mass of 1000 to 3000, an amine value of 150 to 250 mg KOH/g binder and 50 to 230 milliequivalents/100 g binder of beta-hydroxyalkyl urethane groups of the formula HOCnH2nOC(O)NH— where n=2 to 3, as well as processes for making such binders; aqueous compositions, particularly cathodic electrodeposition compositions containing such binders (which provide improved throwing power); and process of using such compositions, particularly on automotive bodies and parts thereof, are disclosed.
摘要翻译：用于阴极电沉积涂层的新型碱性聚合物粘合剂，优选氨基环氧粘合剂的数均分子量为1000至3000，胺值为150至250mg KOH / g粘合剂和50至230毫当量/ 100g粘合剂的β （O）NH-，其中n = 2至3的羟基烷基氨基甲酸酯基团以及制备这种粘合剂的方法; 含水组合物，特别是含有这种粘合剂的阴极电沉积组合物（其提供改进的抛光力）; 并且公开了使用这种组合物，特别是汽车车身及其部件的方法。

18. 发明授权

US06207733B1 Capped amines as hardeners for monocomponent (1c) epoxy resin systems which can be diluted with water 失效
标题翻译：封闭的胺作为可用水稀释的单组分（1c）环氧树脂体系的硬化剂
公开(公告)号：US06207733B1
公开(公告)日：2001-03-27
申请号：US09307974
申请日：1999-05-10
申请人： Roland Feola , Friedrich Mueller , Johann Gmoser
发明人： Roland Feola , Friedrich Mueller , Johann Gmoser
IPC分类号： C08K336
CPC分类号： C08G59/4014 , C08G18/3256
摘要： Capped amine hardeners for epoxy resins, which are reaction products of amines A having at least two primary amino groups, cyclic alkylene carbonates B, aliphatic carbonyl compounds C and compounds D having at least two groups which react with hydroxyl groups, such that in the first step, 0.1 to 1 mol of the primary amino groups for each 1 mol of the amine A are converted to hydroxyalkylurethane groups by reaction with the cyclic alkylene carbonate B, and the remaining primary amino groups are converted by reaction with the aliphatic carbonyl compound C in a second step to give ketimine or aldimine groups, and finally in the third step at least two of the molecules formed from A, B, and C are linked through reaction of the hydroxyl groups of the hydroxyalkylurethane groups with compound D. These capped amine hardeners are suitable for formulating water-dilutable monocomponent epoxy resin systems. The amines are released by addition of water, and are available for the curing reaction with the epoxy groups. Coatings formulated on the basis of this system are characterized by a very low content of auxiliary solvent. The cured coating films show outstanding leveling and film properties.
摘要翻译：作为具有至少两个伯氨基的胺A的反应产物的环氧树脂的包封胺固化剂，环状亚烷基碳酸酯B，脂族羰基化合物C和具有至少两个与羟基反应的基团的化合物D，使得在第一通过与环状碳酸亚烷酯B反应将每1mol胺A的0.1〜1mol的伯氨基转化为羟基烷基氨基甲酸酯基，其余的伯氨基通过与脂肪族羰基化合物C反应而转化第二步产生酮亚胺或醛亚胺基团，最后在第三步中，由A，B和C形成的分子中的至少两个分子通过羟基烷基氨基甲酸酯基团的羟基与化合物D反应而连接。这些封端的胺固化剂适用于配制水可稀释的单组分环氧树脂体系。通过添加水释放胺，并且可用于与环氧基团的固化反应。在该系统的基础上配制的涂料的特征在于非常低的辅助溶剂含量。固化的涂膜显示出优异的流平性和膜性能。

19. 发明申请

US20130150486A1 CATALYST FOR URETHANE BOND FORMATION 审中-公开
标题翻译： URETHANE BOND形成催化剂
公开(公告)号：US20130150486A1
公开(公告)日：2013-06-13
申请号：US13819025
申请日：2011-08-31
申请人： Roland Feola , Norbert Cvetko , Johann Gmoser , Willy Paar
发明人： Roland Feola , Norbert Cvetko , Johann Gmoser , Willy Paar
IPC分类号： C07F7/28 , C09D163/00
CPC分类号： C07F7/28 , C07F7/003 , C08G18/544 , C08G18/643 , C08G18/8064 , C09D163/00 , C09D175/04
摘要： The invention relates to titanium compounds ABC comprising tetravalent titanium A, a moiety derived from a glycol B by removing two hydrogen atoms from hydroxyl groups, and a moiety derived from an N-alkylol-β-hydroxyamine C synthesised by reacting a β-hydroxyamine C12 with an aldehyde C3, to a process for their preparation, and to a method of use thereof as a curing catalyst in coating compositions.
摘要翻译：本发明涉及包含四价钛A的钛化合物ABC，通过从羟基除去两个氢原子衍生自二醇B的部分，以及衍生自通过β-羟基胺C12合成的N-羟烷基-β-羟胺C的部分与醛C3一起用于其制备方法，以及其作为涂料组合物中的固化催化剂的使用方法。

20. 发明授权

US09527995B2 Polyester resins 有权
标题翻译：聚酯树脂
公开(公告)号：US09527995B2
公开(公告)日：2016-12-27
申请号：US13511943
申请日：2010-11-22
申请人： Roland Feola , Johann Gmoser , Oliver Etz
发明人： Roland Feola , Johann Gmoser , Oliver Etz
IPC分类号： C08G63/16 , C08L67/02 , C08L61/06 , C08G63/12 , C08G63/20 , C08L67/00
CPC分类号： C08L61/06 , C08G63/12 , C08G63/20 , C08L67/00 , C08L67/02 , C08L2666/16
摘要： A polyester AB is disclosed comprising moieties derived from di- or polyfunctional organic acid compounds A and moieties derived from di- or polyfunctional organic hydroxy compounds B, wherein the compounds A comprise “hard” acid compounds Al selected from the group consisting of isophthalic acid, trimellithic acid anhydride, hexahydrophthalic acid, cyclohexane-1,4-dicarboxylic acid, and tetrahydrophthalic acid, and soft acid compounds A2 selected from the group consisting of adipic acid, dimer fatty acids, and sebacic acid, and the compounds B comprise “hard” hydroxyfunctional compounds selected from the group consisting of trimethylolpropane, 1,2-bishydroxymethyl cyclohexane, and 1,2-dihydroxy-propane, and soft hydroxyfunctional compounds B2 selected from the group consisting of 1,4-butanediol, 1,6-hexanediol, 2,2′-dihydroxydiethyl ether, and 1,2-bis(2-hydroxypropoxy)-propane, and coating compositions prepared from this polyester together with crosslinkers selected from the group consisting of isocyanates, capped isocyanates, aminoplast crosslinkers, and phenoplast crosslinkers, as well as their application in coating of metal substrates.
摘要翻译：公开了一种聚酯AB，其包含衍生自二官能或多官能有机酸化合物A的部分和衍生自二官能或多官能有机羟基化合物B的部分，其中化合物A包含“硬”酸化合物A1，其选自间苯二甲酸，偏苯三酸酐，六氢邻苯二甲酸，环己烷-1,4-二羧酸和四氢邻苯二甲酸，以及选自己二酸，二聚脂肪酸和癸二酸的软酸化合物A2，化合物B包含“硬” 选自三羟甲基丙烷，1,2-二羟甲基环己烷和1,2-二羟基丙烷的羟基官能化合物和选自1,4-丁二醇，1,6-己二醇，2 ，2'-二羟基二乙基醚和1,2-双（2-羟基丙氧基） - 丙烷，以及由该聚酯制备的涂料组合物和选自由异氰酸酯，封端的异氰酸酯，氨基塑料交联剂和酚醛树脂交联剂组成的组，以及它们在金属基材的涂覆中的应用。

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