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    • 13. 发明授权
    • Benzothiazolemonoazo dyes
    • 苯并噻唑单偶氮染料
    • US5608042A
    • 1997-03-04
    • US594487
    • 1996-01-31
    • Kiyoshi HimenoToshio HiharaRyouichi Sekioka
    • Kiyoshi HimenoToshio HiharaRyouichi Sekioka
    • C09B29/00C09B29/08D06P3/54C09B29/045C09B29/09
    • C09B29/0813C09B29/0088D06P3/54Y10S8/922
    • A monoazo dye of the following formula (I): ##STR1## wherein R is phenyl, phenoxy or benzyl, and D is a group of the formula (D1), (D2), (D3) or (D4): ##STR2## wherein each of X.sup.1, X.sup.2 and X.sup.3, which are independent of one another, is hydrogen or chlorine, X.sup.4 is hydrogen, chlorine, methyl or --NHCOR.sup.1, wherein R.sup.1 is C.sub.1-4 alkyl or phenyl; ##STR3## wherein X.sup.4 is as defined above, Y.sup.1 is hydrogen, chlorine or C.sub.1-4 alkoxy; ##STR4## wherein X.sup.5 is hydrogen, halogen, methyl or --NHZ, wherein Z is C.sub.1-4 alkylsurfonyl, C.sub.1-4 alkylcarbonyl, phenylsulfonyl, phenylcarbonyl, C.sub.1-2 alkoxy C.sub.1-2 alkylcarbonyl or aminocarbonyl, Y.sup.2 is hydrogen, methyl or C.sub.1-2 alkoxy, and Q.sup.1 is cyano or C.sub.1-4 alkylcarbonyl; ##STR5## wherein P is formyl, nitro or cyano, Q.sup.2 is cyano or nitro, T is halogen, methyl, phenyl or methylsulfonyl, X.sup.5 is as defined above, and Y.sup.3 is hydrogen or C.sub.1-2 alkoxy.
    • 下式(I)的单偶氮染料:其中R是苯基,苯氧基或苄基,D是式(D1),(D2),(D3)或(D4)的基团: (D1)其中X 1,X 2和X 3彼此独立地为氢或氯,X 4为氢,氯,甲基或-NHCOR 1,其中R 1为C 1-4烷基或苯基; (D2)其中X4如上所定义,Y 1是氢,氯或C 1-4烷氧基; (D3)其中X5是氢,卤素,甲基或-NHZ,其中Z是C1-4烷基磺酰基,C1-4烷基羰基,苯基磺酰基,苯基羰基,C1-2烷氧基C1-2烷基羰基或氨基羰基,Y2是氢, 甲基或C 1-2烷氧基,Q 1为氰基或C 1-4烷基羰基; (D4)其中P是甲酰基,硝基或氰基,Q2是氰基或硝基,T是卤素,甲基,苯基或甲基磺酰基,X5如上所定义,Y 3是氢或C 1-2烷氧基。
    • 16. 发明授权
    • Thiophene-type monoazo dyes
    • 噻吩型单偶氮染料
    • US5527888A
    • 1996-06-18
    • US399660
    • 1995-03-07
    • Kiyoshi HimenoToshio HiharaRyouichi Sekioka
    • Kiyoshi HimenoToshio HiharaRyouichi Sekioka
    • C09B29/00C09B29/08D06P3/54C09B29/033C09B29/09D06P3/36
    • C09B29/0813C09B29/0088D06P3/54Y10S8/922
    • A monoazo dye of the following formula (I): ##STR1## wherein R is phenyl, phenoxy or benzyl, and D is a group of the formula (D1), (D2), (D3) or (D4): ##STR2## wherein each of X.sup.1, X.sup.2 and X.sup.3, which are independent of one another, is hydrogen or chlorine, X.sup.4 is hydrogen, chlorine, methyl or --NHCOR.sup.1, wherein R.sup.1 is C.sub.1-4 alkyl or phenyl; ##STR3## wherein X.sup.4 is as defined above, Y.sup.1 is hydrogen, chlorine or C.sub.1-4 alkoxy; ##STR4## wherein X.sup.5 is hydrogen, halogen, methyl or --NHZ, wherein Z is C.sub.1-4 alkylsulfonyl, C.sub.1-4 alkylcarbonyl, phenylsulfonyl, phenylcarbonyl, C.sub.1-2 alkoxy C.sub.1-2 alkylcarbonyl or aminocarbonyl, Y.sup.2 is hydrogen, methyl or C.sub.1-2 alkoxy, and Q.sup.1 is cyano or C.sub.1-4 alkylcarbonyl; ##STR5## wherein P is formyl, nitro or cyano, Q.sup.2 is cyano or nitro, T is halogen, methyl, phenyl or methylsulfonyl, X.sup.5 is as defined above, and Y.sup.3 is hydrogen or C.sub.1-2 alkoxy. The dyes of the formula (I) are useful for dyeing polyester fibers, particularly fine denier polyester fibers.
    • 下式(I)的单偶氮染料:其中R是苯基,苯氧基或苄基,D是式(D1),(D2),(D3)或(D4)的基团: (D1)其中X 1,X 2和X 3彼此独立地为氢或氯,X 4为氢,氯,甲基或-NHCOR 1,其中R 1为C 1-4烷基或苯基; (D2)其中X4如上所定义,Y 1是氢,氯或C 1-4烷氧基; (D3)其中X5是氢,卤素,甲基或-NHZ,其中Z是C1-4烷基磺酰基,C1-4烷基羰基,苯基磺酰基,苯基羰基,C1-2烷氧基C1-2烷基羰基或氨基羰基,Y2是氢, 甲基或C 1-2烷氧基,Q 1为氰基或C 1-4烷基羰基; (D4)其中P是甲酰基,硝基或氰基,Q2是氰基或硝基,T是卤素,甲基,苯基或甲基磺酰基,X5如上所定义,Y 3是氢或C 1-2烷氧基。 式(I)的染料可用于染色聚酯纤维,特别是细旦尼尔聚酯纤维。
    • 17. 发明授权
    • Disperse dye mixture
    • 分散染料混合物
    • US5494493A
    • 1996-02-27
    • US346187
    • 1994-11-22
    • Kiyoshi HimenoToshio Hihara
    • Kiyoshi HimenoToshio Hihara
    • C09B67/22D06P1/18
    • C09B67/0051D06P1/18Y10S8/922
    • A disperse dye mixture comprising dye (I) and dye (II) blended at a ratio of from 0.1 to 10 times by weight of dye (II) to dye (I): ##STR1## wherein X is halogen, nitro, cyano, thiocyanate, methylsulfonyl, C.sub.1 or C.sub.2 alkylcarbonyl, C.sub.1 -C.sub.4 alkoxycarbonyl or vinylsulfonyl, Y is hydrogen, halogen, cyano, trifluoromethyl or methylsulfonyl, W is hydrogen, halogen, C.sub.1 or C.sub.2 alkyl or C.sub.1 or C.sub.2 alkoxy, and each of R.sup.1 and R.sup.2 which are independent of each other, is hydrogen, C.sub.1 --C.sub.8 alkyl, or C.sub.2 -C.sub.4 alkyl substituted by halogen, hydroxyl, cyano, alkoxy, alkoxyalkoxy, a hydroxyalkoxy, hydroxyalkoxyalkoxy, acyloxyalkoxy or acyloxyalkoxyalkoxy, provided that each alkoxy has from 1 to 4 carbon atoms.
    • 一种分散染料混合物,其包含染料(II)与染料(I)的重量比为0.1-10倍的染料(I)和染料(II):其中(I) X是卤素,硝基,氰基,硫氰酸酯,甲基磺酰基,C1或C2烷基羰基,C1-C4烷氧基羰基或乙烯基磺酰基,Y是氢,卤素,氰基,三氟甲基或甲磺酰基,W是氢,卤素,C1或C2烷基或C1或C2 烷氧基,卤素,羟基,氰基,烷氧基,烷氧基烷氧基,羟基烷氧基,羟基烷氧基烷氧基,酰氧基烷氧基或酰氧基烷氧基烷氧基取代的C 1 -C 8烷基或C 2 -C 4烷基, 条件是每个烷氧基具有1至4个碳原子。