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    • 11. 发明授权
    • Reactive dye composition: mixture of reactive copper phthalocyanine
dyes: dichloro-triazinyl dye and vinyl sulphonyl type dye
    • 活性染料组成:活性铜酞菁染料的混合物:二氯三嗪基染料和乙烯基磺酰基染料
    • US4711641A
    • 1987-12-08
    • US839030
    • 1986-03-12
    • Toshio NakamatsuTetsuya MiyamotoKunihiko Imada
    • Toshio NakamatsuTetsuya MiyamotoKunihiko Imada
    • C09B62/10C09B67/22C09B67/24D06P1/38
    • C09B67/0035C09B62/10C09B67/0072Y10S8/918
    • A reactive blue dye composition, which comprises a phthalocyanine dye represented by a free acid of the following formula (I), ##STR1## wherein CuPc is a copper phthalocyanine nucleus, W is a C.sub.2 -C.sub.4 alkylene group or a 1,3- or 1,4-phenylene group having one or two sulfo groups, R.sub.1 and R.sub.2 are independently a hydrogen atom or a lower alkyl group, 1 is a number of 1 to 3, m is a number of 0 to 2, and n is a number of 1 to 3, provided that the total number of 1, m and n is 4 or less, and a phthalocyanine dye represented by a free acid of the following formula (II), ##STR2## wherein CuPc, 1, m and n are as defined above, Y.sub.1 and Y.sub.2 are independently a hydrogen atom or a methyl, methoxy or sulfo group, R.sub.3 is a hydrogen atom or a lower alkyl group, and Q is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Z in which Z is a splittable group by the action of an alkali, the mixing weight ratio of the dyes (I) to (II) in terms of a copper content being from 80 through 20 to from 20 through 80, which is useful for dyeing or printing fiber materials also in a blend with other color dyes such as yellow and red dyes to give dyed or printed products of a brilliant color excellent in fastness properties with high reproducibility.
    • 一种反应性蓝色染料组合物,其包含由下式(I)的游离酸表示的酞菁染料,其中CuPc是铜酞菁核,W是C 2 -C 4亚烷基或1,3-或 具有一个或两个磺基的1,4-亚苯基,R 1和R 2独立地为氢原子或低级烷基,1为1〜3的数,m为0〜2的数,n为数 (II)的游离酸所代表的酞菁染料,其中CuPc,1,m(ⅰ)为1〜3, 和n如上所定义,Y 1和Y 2独立地为氢原子或甲基,甲氧基或磺基,R 3为氢原子或低级烷基,Q为-SO 2 CH = CH 2或-SO 2 CH 2 CH 2 Z,其中Z为 通过碱的作用可裂解组,染料(I)至(II)的混合重量比以铜含量为80至20至20至80,其用于染色 或者也可以与其它彩色染料如黄色和红色染料的混合物印刷纤维材料,以得到具有优异的耐色牢度和高再现性的辉煌色彩的染色或印刷产品。
    • 14. 发明授权
    • Anthrapyridone compounds, their production process and their use
    • 蒽吡啶酮化合物,其生产工艺及其用途
    • US5367075A
    • 1994-11-22
    • US167443
    • 1993-12-14
    • Toshio NakamatsuYoshitugu EgashiraYasuyuki Suzuki
    • Toshio NakamatsuYoshitugu EgashiraYasuyuki Suzuki
    • C08K5/3437C09B5/14
    • C08K5/3437C09B5/14
    • An anthrapyridone compound of the following formula (I) and which is useful for coloring resins: ##STR1## wherein X.sup.1 is hydrogen, --NHCOR.sup.1, --CONR.sup.2 R.sup.3, --COR.sup.4, --SO.sub.2 R.sup.5 or --SO.sub.2 NR.sup.6 R.sup.7, in which R.sup.1 and R.sup.4 are each C.sub.1-4 alkyl, R.sup.2 and R.sup.3 are each hydrogen or C.sub.1-4 alkyl, R.sup.5 is C.sub.1-4 alkyl or hydroxyethyl, R.sup.6 and R.sup.7 are each hydrogen or C.sub.1-4 alkyl, X.sup.2 is hydrogen or imidomethyl of the formula (II): ##STR2## wherein n is a number of 1 to 2, X.sup.4 is hydrogen or carboxylic acid C.sub.1-4 alkyl-ester, X.sup.3 is hydrogen, halogen, hydroxyl, C.sub.1-4 alkyl or C.sub.1-4 alkoxyl, with the proviso that X.sup.1 is --NHCOR.sup.1, --CONR.sup.2 R.sup.3, --COR.sup.4, --SO.sub.2 R.sup.5 or --SO.sub.2 NR.sup.6 R.sup.7 when X.sup.2 is hydrogen, X.sup.2 is the imidomethyl of the formula (II) when X.sup.1 is the hydrogen, is provided, which is prepared by allowing an .alpha.-haloanthraquinone compound with an acylated primary aromatic amine compound in a nonaqueous medium in the presence of metallic copper or a copper compound.
    • 用于着色树脂的下式(I)的蒽并吡啶酮化合物:其中X 1是氢,-NHCOR 1,-CONR 2 R 3,-COR 4,-SO 2 R 5或-SO 2 NR 6 R 7,其中R 1和R 4是 每个C 1-4烷基,R 2和R 3各自为氢或C 1-4烷基,R 5为C 1-4烷基或羟乙基,R 6和R 7各自为氢或C 1-4烷基,X 2为氢或式(II)的亚氨基甲基) :其中n为1至2的数,X 4为氢或羧酸C 1-4烷基酯,X 3为氢,卤素,羟基,C 1-4烷基或C 1-4烷氧基,其中 条件是当X 2为氢时,X 1为-NHCOR 1,-CONR 2 R 3,-COR 4,-SO 2 R 5或-SO 2 NR 6 R 7,X 1为氢时,X 2为式(II)的亚氨基甲基,其通过使α - 卤代蒽醌化合物与非水介质中的酰化伯芳族胺化合物在金属铜或铜化合物的存在下反应。