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    • 13. 发明授权
    • Continuous production process of particulate polymer and control method
of the particle size of said polymer
    • 颗粒聚合物的连续生产过程和合成聚合物颗粒尺寸的控制方法
    • US5064938A
    • 1991-11-12
    • US617265
    • 1990-11-23
    • Fumio SuzukiHideaki HabaraYutaro FukudaHaruki SatoHiromasa Inada
    • Fumio SuzukiHideaki HabaraYutaro FukudaHaruki SatoHiromasa Inada
    • C08F6/22C08J3/16
    • C08J3/16C08F6/22
    • The invention discloses a process for the production of a particulate polymer which contains few fine particles and has a narrow particle size distribution and a controlled bulk specific gravity. Characteristic features of the process of this invention reside in that a polymer latex obtained by emulsion polymerization is successively processed through the following steps (I) and (II):Step (I) The polymer latex is coagulated into a slurry in which particles thus coagulated are dispersed in water.Step (II) The slurry obtained in Step (I), an organic liquid almost insoluble in water and incapable of dissolving the polymer and water are mixed for granulation under the conditions that(a) The proportion of water in the whole mixture is 50-85 wt. %,(b) The amount of the organic liquid is 15-150 parts by weight per 100 parts by weight of the polymer in the polymer latex, and(c) The temperature T (.degree.C.) of the whole mixture is maintained for 0.5 minute to 1 hour on average within the range of the following equation:A-40.ltoreq.T.ltoreq.A wherein A means the azeotropic temperature (.degree.C.) of the mixture.In the above process, control of the interfacial tension between the organic liquid and the dispersion medium of the slurry within a specific range has made it possible to control the particle size of the resulting particulate polymer to a desired level.
    • 本发明公开了一种生产微粒聚合物的方法,该颗粒聚合物含有很少的细颗粒,并且具有窄的粒度分布和受控的体积比重。 本发明方法的特征在于通过乳液聚合获得的聚合物胶乳通过以下步骤(I)和(II)连续加工:步骤(I)将聚合物胶乳凝结成浆料,其中由此凝结的颗粒 分散在水中。 步骤(II)将步骤(I)中获得的浆料,几乎不溶于水并且不能溶解聚合物和水的有机液体在以下条件下混合制粒,(a)整个混合物中的水的比例为50- 85重量% %,(b)有机液体的量相对于聚合物胶乳中的聚合物每100重量份为15-150重量份,(c)保持整个混合物的温度T(℃)为 在下列等式的范围内平均0.5分钟至1小时:A-40