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11. 发明授权

US07674939B2 Method for producing fluorinated organic compounds 有权
标题翻译：氟化有机化合物的制备方法
公开(公告)号：US07674939B2
公开(公告)日：2010-03-09
申请号：US11592761
申请日：2006-11-03
申请人： Sudip Mukhopadhyay , Haridasan K. Nair , Hsueh S. Tung , Michael Van Der Puy , Daniel C. Merkel , Rajesh K. Dubey , Jing Ji Ma
发明人： Sudip Mukhopadhyay , Haridasan K. Nair , Hsueh S. Tung , Michael Van Der Puy , Daniel C. Merkel , Rajesh K. Dubey , Jing Ji Ma
IPC分类号： C07C17/25 , C07C21/185 , C07C21/18
CPC分类号： C07C17/04 , C07C17/00 , C07C17/06 , C07C17/206 , C07C17/25 , C07C17/26 , C07C17/269 , C07C17/272 , C07C17/278 , C07C21/18 , C07C19/08 , C07C19/10
摘要： Disclosed are methods for producing fluorinated organic compounds, including hydrofluoropropenes, which preferably comprises converting at least one compound of formula (I): CF3CHXCH2X (I) to at least one compound of formula (II) CF3CZCHZ (II). where X is independently Cl, Br, I or F, and Z independently is H or F. In certain preferred embodiments, each Z is different.
摘要翻译：公开了生产氟化有机化合物的方法，包括氢氟丙烯，其优选包括将至少一种式（I）化合物：CF 3 CHXCH 2 X（I）转化为至少一种式（II）CF 3 CZCHZ（II）化合物。其中X独立地为Cl，Br，I或F，Z独立地为H或F.在某些优选实施方案中，每个Z不同。

12. 发明授权

US07659434B2 Method for producing fluorinated organic compounds 有权
标题翻译：氟化有机化合物的制备方法
公开(公告)号：US07659434B2
公开(公告)日：2010-02-09
申请号：US11592415
申请日：2006-11-03
申请人： Sudip Mukhopadhyay , Haridasan K. Nair , Hsueh S. Tung , Michael Van Der Puy , Daniel C. Merkel , Rajesh K. Dubey , Jing Ji Ma , Barbara A. Light , Kim M. Fleming , Cheryl L. Bortz , Richard Udy
发明人： Sudip Mukhopadhyay , Haridasan K. Nair , Hsueh S. Tung , Michael Van Der Puy , Daniel C. Merkel , Rajesh K. Dubey , Jing Ji Ma , Barbara A. Light , Kim M. Fleming , Cheryl L. Bortz , Richard Udy
IPC分类号： C07C21/18
CPC分类号： C07C17/00 , C07C17/02 , C07C17/04 , C07C17/10 , C07C21/18 , C07C19/08 , C07C19/10
摘要： A method for preparing fluorinated organic compounds comprising contacting hydrogen fluoride with at least one compound of formula I: CX3CXYCH3 I where each X is independently Cl, I or Br, and each Y is independently H or F, said contacting step being carried out under conditions effective to produce a compound of formula II CF3CZCH2 II where Z is Cl, I, Br, or F.
摘要翻译：一种制备氟化有机化合物的方法，包括使氟化氢与至少一种式I化合物：CX3CXYCH3I接触，其中每个X独立地为Cl，I或Br，每个Y独立地为H或F，所述接触步骤在条件有效地制备式II化合物CF 3 CZCH 2 II，其中Z是Cl，I，Br或F.

13. 发明授权

US07371904B2 Processes for synthesis of 1,3,3,3-tetrafluoropropene 有权
标题翻译：合成1,3,3,3-四氟丙烯的方法
公开(公告)号：US07371904B2
公开(公告)日：2008-05-13
申请号：US11118504
申请日：2005-04-29
申请人： Jing Ji Ma , Sudip Mukhopadhyay , Haridasan K. Nair , Hsueh S. Tung , Michael Van Der Puy
发明人： Jing Ji Ma , Sudip Mukhopadhyay , Haridasan K. Nair , Hsueh S. Tung , Michael Van Der Puy
IPC分类号： C07C21/18 , C07C17/26 , C07C17/263 , C07C17/269
CPC分类号： C07C17/206 , C07C17/00 , C07C17/26 , C07C17/269 , C07C17/272 , C07C17/278 , C07C21/18
摘要： Disclosed is a process for the synthesis of 1,3,3,3-tetrafluoropropene which comprises, in one embodiment, reacting a compound of CF3X1 with a compound of CX2H═CHX3, wherein X1, X2, and X3 are each independently selected from the group consisting of fluorine, chlorine, bromine and iodine, to produce a reaction product comprising a compound of CF3CH═CHX3, wherein X3 is as described above; and when X3 is not fluorine, fluorinating the compound to produce 1,3,3,3-tetrafluoropropene. The process in another embodiment comprises preparing tetrafluoropropene comprising thermally cracking one or more compounds capable of producing a reaction mixture which preferably comprises diflurocarbene radicals and vinylidene fluoride, and converting said reaction mixture into—tetrafluoropropene (1,3,3,3-tetrafluoropropene).
摘要翻译：公开了一种用于合成1,3,3,3-四氟丙烯的方法，其包括在一个实施方案中使CF 3 N 1 X 1的化合物与 CX 2 H-CHX 3其中X 1，X 2和X 3， SUP>各自独立地选自氟，氯，溴和碘，以产生包含CF 3 CH-CH 3 3的化合物的反应产物，其中 X 3如上所述; 当X 3不是氟时，氟化该化合物以产生1,3,3,3-四氟丙烯。在另一个实施方案中的方法包括制备四氟丙烯，其包括热裂化一种或多种能够产生反应混合物的化合物，所述化合物优选包含二氟甲基和偏二氟乙烯，并将所述反应混合物转化为四氟丙烯（1,3,3,3-四氟丙烯）。

14. 发明授权

US07026520B1 Catalytic conversion of hydrofluoroalkanol to hydrofluoroalkene 有权
标题翻译：氢氟烷醇催化转化成氢氟烯烃
公开(公告)号：US07026520B1
公开(公告)日：2006-04-11
申请号：US11006922
申请日：2004-12-08
申请人： Sudip Mukhopadhyay , HsuehSung Tung , Haridasan K. Nair
发明人： Sudip Mukhopadhyay , HsuehSung Tung , Haridasan K. Nair
IPC分类号： C07C17/00 , C07C17/08 , C07C21/18 , C07C23/00 , C07C25/13
CPC分类号： C07C17/00 , C07C17/25 , C07C21/18
摘要： Methane is used as the selective dehydrating agent for the production of 2,3,3,3-tetrafluoro-1-propene (R1234yf) from 2,2,3,3,3-pentafluoro-1-propanol. Supported transition metal catalysts are prepared and used for this reaction with high activity. Almost 58% selectivity to R1234yf is obtained at an alcohol conversion level of 60% using unsupported Ni-mesh as the catalyst. Pd and Pt show almost similar level of conversion; however, the selectivity to the desired product is low. The activity of the metal catalyst was found to be a function of the type of support material, activated carbon showing better activity than alumina. Different important process parameters such as temperature, pressure, and contact time are studied to optimize the process. High pressure and temperature are deleterious to the rate of 1234yf formation; yet, the highest yield to 1234yf is obtained while performing a reaction at 494° C. with a contact time of 23 sec.
摘要翻译：甲烷用作用于从2,2,3,3,3-五氟-1-丙醇生产2,3,3,3-四氟-1-丙烯（R1234yf）的选择性脱水剂。制备负载型过渡金属催化剂，并以高活性用于该反应。使用未负载的Ni-网作为催化剂，在60％的醇转化率下获得对R1234yf几乎58％的选择性。 Pd和Pt显示几乎相似的转化水平; 然而，对所需产物的选择性低。发现金属催化剂的活性是支撑材料的类型的函数，活性炭表现出比氧化铝更好的活性。研究了不同的重要工艺参数，如温度，压力和接触时间，以优化工艺。高压和高温对于1234yf的形成是有害的; 然而，在494℃下以23秒的接触时间进行反应，获得了对1234yf的最高产率。

15. 发明授权

US08530708B2 Processes for selective dehydrohalogenation of halogenated alkanes 有权
标题翻译：用于卤代烷烃选择性脱卤化氢的方法
公开(公告)号：US08530708B2
公开(公告)日：2013-09-10
申请号：US11588465
申请日：2006-10-27
申请人： Haiyou Wang , Hsueh Sung Tung , Sudip Mukhopadhyay
发明人： Haiyou Wang , Hsueh Sung Tung , Sudip Mukhopadhyay
IPC分类号： C07C17/25
CPC分类号： C07C17/206 , C07C17/25 , C07C19/08 , C07C21/18
摘要： Disclosed are processes for producing halogenated olefins, and preferably tetrafluorinated propene(s), from one or more alkanes having both fluorine substituents and non-fluorine substituents, preferably with a high degree of conversion and selectivity. Preferably the process comprises the use of a catalyzed reaction in which the catalyst is selected from the group consisting of activated carbons, halogentated mono- and di-valent metal oxides, mono- and di-valent Lewis acid metal halides, zero-valent metals, and combinations of these.
摘要翻译：公开了一种或多种具有氟取代基和非氟取代基的烷烃的卤代烯烃，优选四氟化丙烯的制备方法，优选具有高转化率和选择性。优选地，该方法包括使用催化反应，其中催化剂选自活性炭，卤化的一价和二价金属氧化物，一价和二价路易斯酸金属卤化物，零价金属，以及这些的组合。

16. 发明授权

US07071367B1 Direct one-step synthesis of CF3-I 失效
标题翻译：直接一步合成CF3-I
公开(公告)号：US07071367B1
公开(公告)日：2006-07-04
申请号：US11007919
申请日：2004-12-09
申请人： Sudip Mukhopadhyay , Hsueh Sung Tung
发明人： Sudip Mukhopadhyay , Hsueh Sung Tung
IPC分类号： C07C17/00
CPC分类号： C07C17/093 , C07C17/158 , C07C17/204 , C07C19/16
摘要： The present invention provides a process for the preparation of trifluoromethyl iodide. The process includes the step of: contacting in a reactor a compound represented by the formula: CF3—W and a compound represented by the formula: Z-I wherein W is selected from CF3, hydrogen and bromine; Z is selected from hydrogen, iodine and chlorine. The step of contacting is carried out, optionally in the presence of a catalyst and further optionally in the presence of air, at a temperature, pressure and for a length of time sufficient to produce the trifluoromethyl iodide.
摘要翻译：本发明提供了制备三氟甲基碘的方法。该方法包括以下步骤：在反应器中接触由下式表示的化合物：<？in-line-formula description =“In-line Formulas”end =“lead”？> CF 3 - W <？in-line-formula description =“In-line Formulas”end =“tail”？>和由以下公式表示的化合物：<？in-line-formula description =“In-line Formulas”end =“lead “？”ZI <？in-line-formula description =“In-line Formulas”end =“tail”？>其中W选自CF 3，氢和溴; Z选自氢，碘和氯。任选地在催化剂存在下进一步任选地在空气存在下，在足以产生三氟甲基碘的温度，压力和一段时间内进行接触步骤。

17. 发明授权

US09040759B2 Preparation of fluorinated olefins via catalytic dehydrohalogenation of halogenated hydrocarbons 有权
标题翻译：通过卤代烃的催化脱卤化氢制备氟化烯烃
公开(公告)号：US09040759B2
公开(公告)日：2015-05-26
申请号：US12167159
申请日：2008-07-02
申请人： Haiyou Wang , Hsueh Sung Tung , Sudip Mukhopadhyay
发明人： Haiyou Wang , Hsueh Sung Tung , Sudip Mukhopadhyay
IPC分类号： C07C21/18 , B01J35/00 , B01J27/10 , B01J27/12 , B01J27/138 , C07B35/06 , C07C17/25
CPC分类号： C07C17/25 , B01J27/10 , B01J27/12 , B01J27/138 , B01J35/0006 , C07B35/06 , C07C21/18
摘要： A process for making a fluorinated olefin having the step of dehydrochlorinating a hydrochlorofluorocarbon having at least one hydrogen atom and at least one chlorine atom on adjacent carbon atoms, preferably carried out in the presence of a catalyst selected from the group consisting of (i) one or more metal halides, (ii) one or more halogenated metal oxides, (iii) one or more zero-valent metals/metal alloys, (iv) a combination of two or more of the foregoing.
摘要翻译：一种制备氟化烯烃的方法，该方法具有以下步骤：在相邻碳原子上具有至少一个氢原子和至少一个氯原子的氢氯氟烃脱氯化氢，优选在选自以下的催化剂的存在下进行：（i）一种或更多的金属卤化物，（ii）一种或多种卤化金属氧化物，（iii）一种或多种零价金属/金属合金，（iv）上述两种或更多种的组合。

18. 发明授权

US07132578B1 One-step synthesis of CF3-1 有权
标题翻译：一步合成CF3-1
公开(公告)号：US07132578B1
公开(公告)日：2006-11-07
申请号：US11181311
申请日：2005-07-14
申请人： Sudip Mukhopadhyay , Hsueh Sung Tung
发明人： Sudip Mukhopadhyay , Hsueh Sung Tung
IPC分类号： C07C17/00
CPC分类号： C07C17/204 , C07C17/093 , C07C17/10 , C07C17/158 , C07C17/361 , C07C19/07
摘要： A process for the preparation of trifluoromethyl iodide is provided. The process includes the step of contacting in a reactor a compound represented by the formula: CF3—W and a compound represented by the formula: IFn wherein W can be H, Br, Cl, COOH, COCl, COOCH3, COOC2H5, COCH3, COPh, CF3, Si(CH3)3, SPh, SCH3, SSCF3, SSPh, SSCH3, or SO2Cl, wherein n is 1, 3, 5, or 7, and wherein the step of contacting is carried out, at a temperature, pressure and for a length of time sufficient to produce trifluoromethyl iodide. The contacting step can be carried out in the presence or absence of a catalyst and the contacting step can be carried out in the presence or absence of air.
摘要翻译：提供了制备三氟甲基碘的方法。该方法包括在反应器中接触由下式表示的化合物的步骤：<？in-line-formula description =“In-line Formulas”end =“lead”？> CF 3 -W <？in-line-formula description =“In-line Formulas”end =“tail”？>和由下式表示的化合物：<？in-line-formula description =“In-line Formulas”end =“lead” 其中W可以是H，Br，Cl，COOH，COCl，COOCH _{CO 3，H 3，COCH 3，CO 2，CO 3，SO 3， 3，3个，3个，3个，3个，3个，3个，3个，3个，3个，3个，3个，3个，3个，3个， SUB或SO 2 Cl，其中n为1,3,5或7，并且其中接触步骤在温度，压力和时间长度下进行，足以产生三氟甲基碘。接触步骤可以在催化剂存在或不存在下进行，并且接触步骤可以在空气存在或不存在下进行。}

19. 发明授权

US07396965B2 Method for producing fluorinated organic compounds 有权
标题翻译：氟化有机化合物的制备方法
公开(公告)号：US07396965B2
公开(公告)日：2008-07-08
申请号：US11127892
申请日：2005-05-12
申请人： Sudip Mukhopadhyay , HsuehSung Tung , Haridasan Nair , Jingji Ma
发明人： Sudip Mukhopadhyay , HsuehSung Tung , Haridasan Nair , Jingji Ma
IPC分类号： C07C21/18
CPC分类号： B01J27/125 , B01J27/10 , B01J27/12 , C07C17/00 , C07C17/278 , C07C21/18 , C07C19/08
摘要： A method for preparing fluorinated organic compounds wherein at least one fluorinated olefin is reacted with methyl fluoride in the gas-phase and in the presence of a Lewis Acid catalyst to form at least one product having at least 3 carbon atoms.
摘要翻译：一种制备氟化有机化合物的方法，其中至少一种氟化烯烃在气相和路易斯酸催化剂存在下与甲基氟反应形成至少一种具有至少3个碳原子的产物。

20. 发明申请

US20060258891A1 Method for producing fluorinated organic compounds 有权
公开(公告)号：US20060258891A1
公开(公告)日：2006-11-16
申请号：US11127892
申请日：2005-05-12
申请人： Sudip Mukhopadhyay , HsuehSung Tung , Haridasan Nair , Jingji Ma
发明人： Sudip Mukhopadhyay , HsuehSung Tung , Haridasan Nair , Jingji Ma
IPC分类号： C07C17/266 , C07C21/18
CPC分类号： B01J27/125 , B01J27/10 , B01J27/12 , C07C17/00 , C07C17/278 , C07C21/18 , C07C19/08
摘要： A method for preparing fluorinated organic compounds wherein at least one fluorinated olefin is reacted with methyl fluoride in the gas-phase and in the presence of a Lewis Acid catalyst to form at least one product having at least 3 carbon atoms.

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