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11. 发明授权

US08137632B2 Biomass conversion process 有权
标题翻译：生物质转换过程
公开(公告)号：US08137632B2
公开(公告)日：2012-03-20
申请号：US12612378
申请日：2009-11-04
申请人： Robert Bartek , Steve Yanik , Paul O'Connor
发明人： Robert Bartek , Steve Yanik , Paul O'Connor
IPC分类号： F27B15/08 , C07C4/00
CPC分类号： C10L1/04 , C10G1/08 , C10G1/083 , C10G2300/1011 , C10G2300/4006 , C10G2300/708 , Y02E50/14 , Y02P30/20
摘要： A process is described including: contacting solid biomass with a first catalyst stream in a first reaction zone operated at a temperature T1 (from about 250 to about 400° C.), for conversion of a portion of the solid biomass and forming a first gaseous product stream; downwardly passing unconverted biomass to a second reaction zone for contact with a second catalyst stream charged to the second reaction zone operated at a temperature T2, for conversion to form a second gaseous product stream and a spent catalyst; burning coke off the spent catalyst in a regenerator to form a regenerated catalyst; charging a portion of the regenerated catalyst to each of the first and second reaction zones, as the first and second catalyst streams, respectively; upwardly passing the second gaseous product stream to the first reaction zone; and removing both first and second gaseous product streams from the first reaction zone.
摘要翻译：描述了一种方法，其包括：使第一催化剂流与第一反应区在温度T1（约250至约400℃）下操作，以使一部分固体生物质转化并形成第一气态产品流; 向下通过未转化的生物质到第二反应区，以与加入在温度T2下操作的第二反应区的第二催化剂流接触，以转化以形成第二气态产物流和废催化剂; 在再生器中燃烧焦炭废催化剂以形成再生催化剂; 将一部分再生催化剂分别装入第一和第二反应区中的第一和第二反应区，作为第一和第二催化剂流; 向上通过第二气态产物流到第一反应区; 以及从所述第一反应区域除去第一和第二气态产物流。

12. 发明申请

US20110154720A1 Methods for Co-Processing of Biomass and Petroleum Feed 有权
标题翻译：生物质和石油饲料共同加工方法
公开(公告)号：US20110154720A1
公开(公告)日：2011-06-30
申请号：US12917988
申请日：2010-11-02
申请人： Robert Bartek , Michael Brady , Dennis Stamires , Steve Yanik , Paul O'Connor , Jacobus C. Rasser
发明人： Robert Bartek , Michael Brady , Dennis Stamires , Steve Yanik , Paul O'Connor , Jacobus C. Rasser
IPC分类号： C10L1/00 , B01J8/00
CPC分类号： C10G11/18 , C10G1/002 , C10G1/06 , C10G1/08 , C10G3/42 , C10G3/50 , C10G3/56 , C10G3/57 , C10G3/62 , C10G45/02 , C10G47/00 , C10G47/02 , C10G47/30 , C10G47/34 , C10G49/007 , C10G2300/1011 , C10G2300/1014 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , Y02P30/20
摘要： A process for producing fuel from biomass is disclosed herein. The process includes torrefying biomass material at a temperature between 80° C. to 400° C. to form particulated biomass having a mean average particle size between 1 μm and 1000 μm. The particulated biomass is mixed with a liquid hydrocarbon to form a suspension, wherein the suspension includes from 1 weight percent to 40 weight percent particulated biomass. The suspension is fed into a unit selected from the group consisting of a pyrolysis reactor, a fluid catalytic cracking unit, a delayed coker, a fluid coker, a hydroprocessing unit, and a hydrocracking unit, and then at least a portion of the particulated biomass of the suspension is converted into fuel.
摘要翻译：本文公开了一种从生物质生产燃料的方法。该方法包括在80℃至400℃的温度下焙烧生物质材料，以形成平均粒度为1μm至1000μm的颗粒状生物质。将颗粒状生物质与液体烃混合以形成悬浮液，其中悬浮液包括1重量％至40重量％的颗粒生物质。将悬浮液加入到选自热解反应器，流化催化裂化装置，延迟焦化器，流体焦化器，加氢处理装置和加氢裂化装置中的单元中，然后将至少一部分颗粒生物质的悬浮液转化为燃料。

13. 发明申请

US20130068997A1 Co-Processing Solid Biomass In A Conventional Petroleum Refining Process Unit 有权
标题翻译：在常规石油炼制工艺装置中共同处理固体生物质
公开(公告)号：US20130068997A1
公开(公告)日：2013-03-21
申请号：US13617289
申请日：2012-09-14
申请人： Steve Yanik , Paul O'Connor , Robert Bartek
发明人： Steve Yanik , Paul O'Connor , Robert Bartek
IPC分类号： C09K3/00
CPC分类号： C09K3/00 , C10G1/002 , C10G1/08 , C10G11/00 , C10G11/18 , C10G2300/1014 , C10G2300/1037 , C10G2300/4056 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/20 , C10G2400/28 , Y02P30/20
摘要： Preparing solid biomass particles for catalytic conversion includes agitating solid biomass particles and providing a biomass-catalyst mixture to a conventional petroleum refinery process unit. The biomass-catalyst mixture includes the solid biomass particles and a catalyst. Agitating solid biomass particles includes flowing a gas to provide a velocity to at least a portion of the solid biomass particles sufficient to reduce their sizes. Co-processing a biomass feedstock and a conventional petroleum feedstock includes liquefying at least a portion of a biomass-catalyst mixture and co-processing at least a portion of the liquefied biomass feedstock and a conventional petroleum feedstock in a conventional petroleum refinery process unit. The biomass feedstock includes a plurality of solid biomass particles and a catalyst, which is liquefied to produce a liquefied biomass feedstock.
摘要翻译：制备用于催化转化的固体生物质颗粒包括搅拌固体生物质颗粒并向传统的炼油工艺单元提供生物质 - 催化剂混合物。生物质 - 催化剂混合物包括固体生物质颗粒和催化剂。搅拌固体生物质颗粒包括使气体流动以提供足以减小其尺寸的至少一部分固体生物质颗粒的速度。共同处理生物质原料和常规石油原料包括液化生物质 - 催化剂混合物的至少一部分，并在常规的炼油工艺单元中共同处理至少一部分液化生物质原料和常规石油原料。生物质原料包括多个固体生物质颗粒和催化剂，其被液化以产生液化生物质原料。

14. 发明申请

US20120022307A1 CO-PROCESSING SOLID BIOMASS IN A CONVENTIONAL PETROLEUM REFINING PROCESS UNIT 有权
标题翻译：常规石油精炼加工单元中加工固体生物质
公开(公告)号：US20120022307A1
公开(公告)日：2012-01-26
申请号：US12867214
申请日：2009-06-29
申请人： Steve Yanik , Paul O'Connor , Robert Bartek
发明人： Steve Yanik , Paul O'Connor , Robert Bartek
IPC分类号： C10G1/00 , B01J8/08 , C07C1/20
CPC分类号： C09K3/00 , C10G1/002 , C10G1/08 , C10G11/00 , C10G11/18 , C10G2300/1014 , C10G2300/1037 , C10G2300/4056 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/20 , C10G2400/28 , Y02P30/20
摘要： Preparing solid biomass particles for catalytic conversion includes agitating solid biomass particles and providing a biomass-catalyst mixture to a conventional petroleum refinery process unit. The biomass-catalyst mixture includes the solid biomass particles and a catalyst. Agitating solid biomass particles includes flowing a gas to provide a velocity to at least a portion of the solid biomass particles sufficient to reduce their sizes. Co-processing a biomass feedstock and a conventional petroleum feedstock includes liquefying at least a portion of a biomass-catalyst mixture and co-processing at least a portion of the liquefied biomass feedstock and a conventional petroleum feedstock in a conventional petroleum refinery process unit. The biomass feedstock includes a plurality of solid biomass particles and a catalyst, which is liquefied to produce a liquefied biomass feedstock.
摘要翻译：制备用于催化转化的固体生物质颗粒包括搅拌固体生物质颗粒并向传统的炼油工艺单元提供生物质 - 催化剂混合物。生物质 - 催化剂混合物包括固体生物质颗粒和催化剂。搅拌固体生物质颗粒包括使气体流动以提供足以减小其尺寸的至少一部分固体生物质颗粒的速度。共同处理生物质原料和常规石油原料包括液化生物质 - 催化剂混合物的至少一部分，并在常规的炼油工艺单元中共同处理至少一部分液化生物质原料和常规石油原料。生物质原料包括多个固体生物质颗粒和催化剂，其被液化以产生液化生物质原料。

15. 发明申请

US20100113849A1 BIOMASS CONVERSION PROCESS 有权
标题翻译：生物量转换过程
公开(公告)号：US20100113849A1
公开(公告)日：2010-05-06
申请号：US12612378
申请日：2009-11-04
申请人： Robert Bartek , Steve Yanik , Paul O'Connor
发明人： Robert Bartek , Steve Yanik , Paul O'Connor
IPC分类号： C10G1/00 , B01J8/04
CPC分类号： C10L1/04 , C10G1/08 , C10G1/083 , C10G2300/1011 , C10G2300/4006 , C10G2300/708 , Y02E50/14 , Y02P30/20
摘要： A process is disclosed including: contacting solid biomass with a first catalyst stream in a first reaction zone operated at a temperature T1 (from about 250 to about 400° C.), for conversion of a portion of the solid biomass and forming a first gaseous product stream; downwardly passing unconverted biomass to a second reaction zone for contact with a second catalyst stream charged to the second reaction zone operated at a temperature T2, for conversion to form a second gaseous product stream and a spent catalyst; burning coke off the spent catalyst in a regenerator to form a regenerated catalyst; charging a portion of the regenerated catalyst to each of the first and second reaction zones, as the first and second catalyst streams, respectively; upwardly passing the second gaseous product stream to the first reaction zone; and removing both first and second gaseous product streams from the first reaction zone.
摘要翻译：公开了一种方法，包括：使第一催化剂流与第一反应区在温度T1（约250至约400℃）下操作，以使一部分固体生物质转化并形成第一气态产品流; 向下通过未转化的生物质到第二反应区，以与加入在温度T2下操作的第二反应区的第二催化剂流接触，以转化以形成第二气态产物流和废催化剂; 在再生器中燃烧焦炭废催化剂以形成再生催化剂; 将一部分再生催化剂分别装入第一和第二反应区中的第一和第二反应区，作为第一和第二催化剂流; 向上通过第二气态产物流到第一反应区; 以及从所述第一反应区域除去第一和第二气态产物流。

16. 发明授权

US09040761B2 Co-processing of biomass and synthetic polymer based materials in a pyrolysis conversion process 有权
标题翻译：在热解转化过程中共同处理生物质和合成聚合物基材料
公开(公告)号：US09040761B2
公开(公告)日：2015-05-26
申请号：US13578790
申请日：2011-02-11
申请人： Robert Bartek , Steve Yanik
发明人： Robert Bartek , Steve Yanik
IPC分类号： C07C1/20 , C10G1/06 , C10G1/00 , C10G1/08 , C10G1/10 , C10G3/00 , C07C1/207 , C07C1/213 , C10L1/00 , C10L1/14 , C10L1/16
CPC分类号： C10G1/06 , C10G1/00 , C10G1/08 , C10G1/10 , C10G3/42 , C10G2300/1011 , Y02P30/20
摘要： Disclosed is a process for biomass conversion which includes co-processing the biomass with thermoplastic and non-thermoplastic polymer based materials in a catalytic pyrolysis reactor to convert such to liquid hydrocarbons; wherein hydrogen atoms originating with the polymer materials can remove oxygen from oxygenated hydrocarbons produced in the conversion of the biomass in the reactor.
摘要翻译：公开了一种生物质转化方法，其包括在催化裂解反应器中将生物质与热塑性和非热塑性聚合物基材料共同加工以转化为液体烃; 其中源自聚合物材料的氢原子可以从反应器中的生物质转化中产生的氧化烃中除去氧气。

17. 发明申请

US20120160658A1 PROCESS CONTROL BY BLENDING BIOMASS FEEDSTOCKS 有权
标题翻译：通过混合生物量饲料进行过程控制
公开(公告)号：US20120160658A1
公开(公告)日：2012-06-28
申请号：US13284321
申请日：2011-10-28
申请人： Robert Bartek , Steve Yanik
发明人： Robert Bartek , Steve Yanik
IPC分类号： C10B57/00 , C10B45/00
CPC分类号： C10C5/00 , C10B53/02 , C10G2300/1014 , C10L1/02 , Y02E50/14 , Y02P20/145 , Y02P30/20
摘要： A process and system is disclosed for optimizing a key parameter of a biomass feedstock that enhances bio-oil production. The process and system involves optimizing the values of the key parameter in multiple biomass feedstocks by regulating their feed rates and blending those feedstocks to produce a cumulative biomass feedstock with an optimal value for the key parameter. The key parameter in the biomass feedstocks is measured and the feed rates of the multiple biomass feedstocks are adjusted in order to produce a cumulative biomass feedstock exhibiting optimal values for the desired key parameter. The key parameters can include compositional properties, such as lignin content or mineral content, and/or fluidization properties of the biomass materials, such as density, particle cohesion force, or particle size.
摘要翻译：公开了一种用于优化增强生物油生产的生物质原料的关键参数的方法和系统。该过程和系统包括通过调节其进料速率并混合这些原料以产生具有关键参数的最佳值的累积生物质原料来优化多个生物质原料中关键参数的值。测量生物质原料中的关键参数，并且调整多种生物质原料的进料速率以产生显示所需关键参数的最佳值的累积生物质原料。关键参数可以包括诸如木质素含量或矿物质含量的组合性质和/或生物质材料的流化性质，例如密度，颗粒内聚力或粒度。

18. 发明申请

US20110094147A1 Process for the Conversion of Solid Particulated Biomass Materials 有权
标题翻译：固体颗粒生物质材料转化工艺
公开(公告)号：US20110094147A1
公开(公告)日：2011-04-28
申请号：US12917980
申请日：2010-11-02
申请人： Robert Bartek , Steve Yanik
发明人： Robert Bartek , Steve Yanik
IPC分类号： C10L1/10
CPC分类号： C10G11/18 , C10G1/002 , C10G1/06 , C10G1/08 , C10G3/42 , C10G3/50 , C10G3/56 , C10G3/57 , C10G3/62 , C10G45/02 , C10G47/00 , C10G47/02 , C10G47/30 , C10G47/34 , C10G49/007 , C10G2300/1011 , C10G2300/1014 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , Y02P30/20
摘要： A process for producing bio-fuel from biomass is disclosed herein. The process includes processing the mean particle diameter of the biomass by mechanical processing to a size ranging from 1 μm to 1000 μm to form particulated biomass. The particulated biomass is mixed with a liquid hydrocarbon to form a suspension, wherein the suspension includes between 1 weight percent to 40 weight percent particulated biomass. The suspension is heated to a temperature between 50° C. and 550° C. The heated suspension is fed into a unit selected from the group consisting of a pyrolysis reactor, a fluid catalytic cracking unit, a delayed coker, a fluid coker, a hydroprocessing unit, and a hydrocracking unit; and then at least a portion of the particulated biomass of the heated suspension is converted into fuel.
摘要翻译：本文公开了一种从生物质生产生物燃料的方法。该方法包括通过机械加工将生物质的平均粒径加工至1μm至1000μm的尺寸以形成颗粒状生物质。将颗粒生物质与液体烃混合以形成悬浮液，其中悬浮液包含1重量％至40重量％的颗粒生物质。将悬浮液加热至50℃至550℃之间的温度。将加热的悬浮液加入到选自热解反应器，流化催化裂化装置，延迟焦化器，流体焦化器，加氢处理装置和加氢裂化装置; 然后加热的悬浮液的至少一部分微粒生物质被转化为燃料。

19. 发明授权

US08877015B2 Process control by blending biomass feedstocks 有权
标题翻译：通过混合生物质原料进行过程控制
公开(公告)号：US08877015B2
公开(公告)日：2014-11-04
申请号：US13284321
申请日：2011-10-28
申请人： Robert Bartek , Steve Yanik
发明人： Robert Bartek , Steve Yanik
IPC分类号： C10B53/02 , C10G1/00 , C10C5/00 , C10L1/02
CPC分类号： C10C5/00 , C10B53/02 , C10G2300/1014 , C10L1/02 , Y02E50/14 , Y02P20/145 , Y02P30/20
摘要： A process and system is disclosed for optimizing a key parameter of a biomass feedstock that enhances bio-oil production. The process and system involves optimizing the values of the key parameter in multiple biomass feedstocks by regulating their feed rates and blending those feedstocks to produce a cumulative biomass feedstock with an optimal value for the key parameter. The key parameter in the biomass feedstocks is measured and the feed rates of the multiple biomass feedstocks are adjusted in order to produce a cumulative biomass feedstock exhibiting optimal values for the desired key parameter. The key parameters can include compositional properties, such as lignin content or mineral content, and/or fluidization properties of the biomass materials, such as density, particle cohesion force, or particle size.
摘要翻译：公开了一种用于优化增强生物油生产的生物质原料的关键参数的方法和系统。该过程和系统包括通过调节其进料速率并混合这些原料以产生具有关键参数的最佳值的累积生物质原料来优化多个生物质原料中关键参数的值。测量生物质原料中的关键参数，并且调整多种生物质原料的进料速率以产生显示所需关键参数的最佳值的累积生物质原料。关键参数可以包括诸如木质素含量或矿物质含量的组合性质和/或生物质材料的流化性质，例如密度，颗粒内聚力或粒度。

20. 发明授权

US08344194B2 Process for the conversion of solid particulated biomass materials 有权
标题翻译：固体颗粒生物质材料转化工艺
公开(公告)号：US08344194B2
公开(公告)日：2013-01-01
申请号：US12917980
申请日：2010-11-02
申请人： Robert Bartek , Steve Yanik
发明人： Robert Bartek , Steve Yanik
IPC分类号： C07C1/00 , C10L1/00
CPC分类号： C10G11/18 , C10G1/002 , C10G1/06 , C10G1/08 , C10G3/42 , C10G3/50 , C10G3/56 , C10G3/57 , C10G3/62 , C10G45/02 , C10G47/00 , C10G47/02 , C10G47/30 , C10G47/34 , C10G49/007 , C10G2300/1011 , C10G2300/1014 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , Y02P30/20
摘要： A process for producing bio-fuel from biomass is disclosed herein. The process includes processing the mean particle diameter of the biomass by mechanical processing to a size ranging from 1 μm to 1000 μm to form particulated biomass. The particulated biomass is mixed with a liquid hydrocarbon to form a suspension, wherein the suspension includes between 1 weight percent to 40 weight percent particulated biomass. The suspension is heated to a temperature between 50° C. and 550° C. The heated suspension is fed into a unit selected from the group consisting of a pyrolysis reactor, a fluid catalytic cracking unit, a delayed coker, a fluid coker, a hydroprocessing unit, and a hydrocracking unit; and then at least a portion of the particulated biomass of the heated suspension is converted into fuel.
摘要翻译：本文公开了一种从生物质生产生物燃料的方法。该方法包括通过机械加工将生物质的平均粒径加工至1μm至1000μm的尺寸以形成颗粒状生物质。将颗粒生物质与液体烃混合以形成悬浮液，其中悬浮液包含1重量％至40重量％的颗粒生物质。将悬浮液加热至50℃至550℃之间的温度。将加热的悬浮液加入到选自热解反应器，流化催化裂化装置，延迟焦化器，流体焦化器，加氢处理装置和加氢裂化装置; 然后加热的悬浮液的至少一部分微粒生物质被转化为燃料。

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