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    • 11. 发明公开
    • Sealant composition
    • 密封组合物
    • EP0240044A3
    • 1988-05-04
    • EP87200331
    • 1987-02-25
    • SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.
    • St. Clair, David JohnChin, Steven SoohyunGelles, Richard
    • C08L51/00C09K03/10
    • C09K3/1018C08F287/00C09J151/003C09K2003/1071C09K2200/0615C09K2200/0642C08F230/08
    • 1. A sealant composition comprises:-
      (a) 100 parts by weight of a silane functionalized polymer component prepared by reacting silane of formula RR′ n SiY 3-n (where n = 0, 1 or 2 and R is a non-hydrolyzable organic group, capable of grafting onto the polymer, R′ is a non-hydrolyzable organic group incapable of grafting onto the polymer and Y is a hydrolyzable organic group) with a polymer component;
          said polymer component comprising an A′B′ block copolymer, a multiblock copolymer having at least two end blocks A and at least one midblock B, or mixtures of an A′B′ block copolymer and the multiblock copolymer wherein:
          the A′ and A blocks comprise monoalkenyl arene blocks and the B′ and B blocks comprise hydrogenated conjugated diene polymer blocks, and the average molecular weight of the A and A′ blocks is greater than the minimum molecular weight needed to obtain microphase separation and domain formation of the A and A′ blocks, and is less than the maximum molecular weight which would render the polymer incapable of being melt processed;
          the multiblock copolymer comprises a monoalkenyl arene content no more than the maximum weight per cent needed to retain a modulus suitable as a sealant in the resultant composition and no less than the minimum weight per cent needed to obtain the desired phase separation and the desired minimum cohesive strength for the resultant composition; and, if a B is present, (b) an amount of a midblock compatible component wherein said midblock compatible component is at a content to maintain the resultant composition in a plyable condition at room temperature and to maintain the glass transition temperature of the resultant composition below 10 °C.
    • 17. 发明公开
    • Sealant composition
    • Dichtungsmasse。
    • EP0240044A2
    • 1987-10-07
    • EP87200331.4
    • 1987-02-25
    • SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.
    • St. Clair, David JohnChin, Steven SoohyunGelles, Richard
    • C09K3/10C08L51/00
    • C09K3/1018C08F287/00C09J151/003C09K2003/1071C09K2200/0615C09K2200/0642C08F230/08
    • 1. A sealant composition comprises:-

      (a) 100 parts by weight of a silane functionalized polymer component prepared by reacting silane of formula RR′ n SiY 3-n (where n = 0, 1 or 2 and R is a non-hydrolyzable organic group, capable of grafting onto the polymer, R′ is a non-hydrolyzable organic group incapable of grafting onto the polymer and Y is a hydrolyzable organic group) with a polymer component;
          said polymer component comprising an A′B′ block copolymer, a multiblock copolymer having at least two end blocks A and at least one midblock B, or mixtures of an A′B′ block copolymer and the multiblock copolymer wherein:
          the A′ and A blocks comprise monoalkenyl arene blocks and the B′ and B blocks comprise hydrogenated conjugated diene polymer blocks, and the average molecular weight of the A and A′ blocks is greater than the minimum molecular weight needed to obtain microphase separation and domain formation of the A and A′ blocks, and is less than the maximum molecular weight which would render the polymer incapable of being melt processed;
          the multiblock copolymer comprises a monoalkenyl arene content no more than the maximum weight per cent needed to retain a modulus suitable as a sealant in the resultant composition and no less than the minimum weight per cent needed to obtain the desired phase separation and the desired minimum cohesive strength for the resultant composition; and, if a B is present,
      (b) an amount of a midblock compatible component wherein said midblock compatible component is at a content to maintain the resultant composition in a plyable condition at room temperature and to maintain the glass transition temperature of the resultant composition below 10 °C.
    • 1.一种密封剂组合物,其包含: - (a)100重量份通过使式RR min nSiY 3-n(其中n = 0,1或2)的硅烷与R是不可水解的有机物反应制备的硅烷官能化聚合物组分 基团,能够接枝到聚合物上,R min是不能水解的有机基团,不能用聚合物组分接枝到聚合物上,Y是可水解的有机基团) 所述聚合物组分包含A min B min嵌段共聚物,具有至少两个末端嵌段A和至少一个中间嵌段B的多嵌段共聚物或A min B min嵌段共聚物与多嵌段共聚物的混合物,其中:A min和A 嵌段包含单链烯基芳烃嵌段,B分子和B嵌段包括氢化共轭二烯聚合物嵌段,并且A和A min嵌段的平均分子量大于获得微相分离和A和的结构域形成所需的最小分子量, A分钟,并且小于使聚合物不能熔融加工的最大分子量; 多嵌段共聚物包含不超过在所得组合物中保持适合作为密封剂的模量所需的最大重量百分比的单烯基芳烃含量,并且不小于获得所需相分离所需的最小重量百分数,并且所需的最小粘性 所得组合物的强度; 并且如果存在B,则(b)一定量的中间嵌段相容性组分,其中所述中间嵌段相容性组分处于将所得组合物保持在可室温条件下在室温下并保持所得组合物的玻璃化转变温度的含量 低于10℃