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    • 15. 发明授权
    • Ink composition, ink jet recording method and recorded article
    • 墨水组成,喷墨记录方法和记录文章
    • US07303616B2
    • 2007-12-04
    • US10533731
    • 2004-09-28
    • Yasuhiro OkiKazuhiko KitamuraHiroko Hayashi
    • Yasuhiro OkiKazuhiko KitamuraHiroko Hayashi
    • C09D11/00C09D11/02B41J2/01
    • C09D11/328
    • It is an object of the present invention to provide an ink composition using a metal phthalocyanine type cyan dye, according to which the indoor storability (gas resistance) of images created using the ink composition can be improved. The present invention provides an ink composition containing water, metal phthalocyanine type cyan dye, and aromatic compound having a sulfo group and/or salt thereof represented by undermentioned general formula (1) and/or (2). Moreover, the present invention provides an ink jet recording method comprising carrying out recording by discharging droplets of an ink composition and attaching the droplets to a recording medium, wherein the ink jet recording method uses an ink composition as described above as the ink composition. Furthermore, the present invention provides a recorded article characterized by being obtained by recording using an ink composition as described above. (In the formula, M1 represents a counter ion forming a salt, X represents an integer from 1 to 3, and R1 and R2 each represents a hydrogen atom, an alkyl group having 1 to 6 carbon atoms or an alkoxy group having 1 to 6 carbon atoms, and R1 and R2 may be the same or different.) (In the formula, M2 represents a counter ion forming a salt, Y represents an integer from 1 to 4, and R3 and R4 each represents a hydrogen atom, an alkyl group having 1 to 6 carbon atoms or an alkoxy group having 1 to 6 carbon atoms, and R3 and R4 may be the same or different.)
    • 本发明的目的是提供一种使用金属酞菁型青色染料的油墨组合物,根据该油墨组合物可以提高使用该油墨组合物产生的图像的室内储存性(气体阻力)。 本发明提供一种含有水,金属酞菁型青色染料和由下述通式(1)和/或(2)表示的具有磺基和/或其盐的芳族化合物的油墨组合物。 此外,本发明提供了一种喷墨记录方法,包括通过排出油墨组合物的液滴并将液滴附着到记录介质上进行记录,其中喷墨记录方法使用如上所述的油墨组合物作为油墨组合物。 此外,本发明提供了一种记录制品,其特征在于通过使用如上所述的油墨组合物进行记录而获得。
    • 16. 发明授权
    • Ink composition, ink cartridge, inkjet recording method, and recorded matter
    • 墨水组合物,墨盒,喷墨记录方法和记录物
    • US07279034B2
    • 2007-10-09
    • US11311869
    • 2005-12-19
    • Yasuhiro OkiKazuhiko Kitamura
    • Yasuhiro OkiKazuhiko Kitamura
    • C09D11/00C09D11/02B41J2/01
    • C09D11/328
    • It is an object of the present invention to provide an ink composition with which the indoor storage stability (gas resistance) of an image produced with an ink composition featuring a phthalocyanine-based cyan dye can be increased without causing any additive precipitation or bronzing. The present invention provides an ink composition containing at least water, a phthalocyanine-based cyan dye, and a lithium salt of an aromatic compound having a sulfo group and expressed by General Formulas 1 and/or 2 in the claims. The present invention also provides an ink composition containing at least water, a phthalocyanine-based cyan dye, and a lithium salt of an aromatic compound having a sulfo group and expressed by General Formulas 5 and/or 6 in the claims. The present invention further provides an ink composition containing at least water, a phthalocyanine-based cyan dye, and a lithium salt of an aromatic compound having a sulfo group and expressed by General Formulas 1 and/or 2 in the claims or a lithium salt of an aromatic compound having a sulfo group and expressed by General Formulas 5 and/or 6 in the claims, wherein the phthalocyanine-based cyan dye is expressed by Formula 3 in the claims.
    • 本发明的目的是提供一种油墨组合物,其可以增加由具有酞菁类青色染料的油墨组合物产生的图像的室内储存稳定性(气体阻力),而不会引起任何添加剂沉淀或烫金。 本发明提供一种油墨组合物,其至少含有水,酞菁系青色染料和具有磺基的芳香族化合物的锂盐,并且在权利要求书中由通式1和/或2表示。 本发明还提供一种油墨组合物,其至少含有水,酞菁类青色染料和具有磺基的芳族化合物的锂盐,并且在权利要求书中由通式5和/或6表示。 本发明还提供一种油墨组合物,其至少含有水,酞菁系青色染料和具有磺基的芳香族化合物的锂盐,并且由权利要求1中的通式1和/或2表示,或 在权利要求中具有磺基并由通式5和/或6表示的芳族化合物,其中所述酞菁系青色染料由权利要求中的式3表示。
    • 17. 发明授权
    • Ink composition, inkjet recording method and recorded matter
    • 油墨成分,喷墨记录方法和记录物
    • US07276111B2
    • 2007-10-02
    • US11042832
    • 2005-01-25
    • Yasuhiro OkiKazuhiko Kitamura
    • Yasuhiro OkiKazuhiko Kitamura
    • C09D11/00C09D11/02B41J2/01
    • C09D11/328C09D11/32
    • An object of the present invention is to provide an ink composition that can improve the preservation characteristics (gas fastness) of an image produced by an ink composition which uses phthalocyanine group cyan dye. The present invention provides an ink composition wherein at least water, the phthalocyanine group cyan dye indicated by the general formula (I), and an aromatic compound having a sulfone group and/or the salt thereof represented by the general formulae (a) and/or (b) are contained; and an ink composition wherein at least water, the phthalocyanine group cyan dye indicated by the general formula (VIII), and an aromatic compound having a sulfone group and/or the salt thereof represented by the general formulae (a) and/or (b) are contained. Moreover, the present invention provides an inkjet recording method in which recording is conducted by discharging ink droplets of an ink composition and causing the ink droplets to adhere to a recording medium, wherein as said ink composition, the aforementioned ink composition is used. Further, the present invention provides a record which is obtained by using the aforementioned ink composition.
    • 本发明的目的是提供一种油墨组合物,其可以提高由使用酞菁基青色染料的油墨组合物产生的图像的保存特性(耐气体性)。 本发明提供一种油墨组合物,其中至少水,由通式(I)表示的酞菁基青色染料和具有通式(a)和/或(a)表示的具有砜基团的芳族化合物和/或其盐, 或(b); 以及油墨组合物,其中至少水,由通式(VIII)表示的酞菁基青色染料和由通式(a)和/或(b)表示的具有砜基的芳族化合物和/或其盐 )。 此外,本发明提供一种喷墨记录方法,其中通过排出油墨组合物的墨滴并使墨滴附着到记录介质上进行记录,其中使用上述油墨组合物作为所述油墨组合物。 此外,本发明提供通过使用上述油墨组合物获得的记录。
    • 19. 发明申请
    • Ink Composition, and Ink Jet Recording Method and Recorded Matter Using the Same
    • 油墨组合物和喷墨记录方法和使用其的记录物质
    • US20080022895A1
    • 2008-01-31
    • US10573797
    • 2004-09-30
    • Yasuhiro OkiKazuhiko KitamuraHiroko HayashiKeiichi TateishiShigeaki TanakaYoshiharu Yabuki
    • Yasuhiro OkiKazuhiko KitamuraHiroko HayashiKeiichi TateishiShigeaki TanakaYoshiharu Yabuki
    • C09D11/00B41J2/04
    • C09D11/328
    • Problem to be Solved:To provide an ink composition capable of giving printed matter excellent in gas fastness and light fastness and free from generation of a bronzing phenomenon, an inkjet recording method using the ink composition, and recorded matter which is recorded by the recording method.Means to Solve the Problem:An ink composition comprising at least water, a cyan dye represented by the formula shown below and an aromatic compound having a carboxyl group and/or a salt thereof; an inkjet recording method using the composition; and recorded matter which is recorded by the recording method. [wherein M represents a hydrogen atom, a metal element, a metal oxide, a metal hydroxide or a metal halide, R1 to R4 each independently represents —SO2Z, and Z represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted aryl group or a substituted or unsubstituted heterocyclic group, provided that at least one of four Z's has an ionic hydrophilic group as a substituent].
    • 要解决的问题:提供一种能够赋予耐气性和耐光性优异且不产生烫金现象的印刷品的油墨组合物,使用该油墨组合物的喷墨记录方法和通过记录方法记录的记录物质 。 解决问题的手段:至少含有水,由下述式表示的青色染料和具有羧基的芳族化合物和/或其盐的油墨组合物; 使用该组合物的喷墨记录方法; 以及通过记录方法记录的记录物。 [其中M表示氢原子,金属元素,金属氧化物,金属氢氧化物或金属卤化物,R 1至R 4各自独立地表示-SO Z,Z表示取代或未取代的烷基,取代或未取代的环烷基,取代或未取代的烯基,取代或未取代的芳烷基,取代或未取代的芳基或取代或未取代的芳基 杂环基团,条件是四个Z中的至少一个具有离子性亲水基团作为取代基]。