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11. 发明申请

US20120090977A1 CATALYST/BIOMASS MIXING IN TRANSPORT REACTOR 有权
标题翻译：催化剂/生物质混合在运输反应堆
公开(公告)号：US20120090977A1
公开(公告)日：2012-04-19
申请号：US13264925
申请日：2010-05-05
申请人： Robert Bartek , Ronald Lee Cordle , Steve Yanik , Paul O'Connor
发明人： Robert Bartek , Ronald Lee Cordle , Steve Yanik , Paul O'Connor
IPC分类号： C10B53/02 , C10B7/10
CPC分类号： C10G1/08 , B01J8/0025 , B01J8/1845 , B01J2208/0038 , B01J2208/00752 , C10B49/22 , C10B53/02 , C10B57/06 , C10G1/02 , C10G11/18 , C10G2300/1014 , Y02E50/14 , Y02P30/20
摘要： A reactor and/or process is disclosed for fluidized cracking of solid particulate biomass material, including a first mixing zone where a particulate stream comprising solid particulate biomass is mixed with a lift gas and becomes fluidized, and including a second mixing zone where a heat carrier material is mixed with the fluidized solid particulate biomass material.
摘要翻译：公开了用于固体颗粒生物质材料的流化裂化的反应器和/或方法，包括第一混合区，其中包含固体颗粒生物质的颗粒物流与提升气体混合并变成流化的，并且包括第二混合区，其中热载体材料与流化固体颗粒生物质材料混合。

12. 发明授权

US08524959B1 Biomass catalytic conversion process and apparatus for use therein 有权
标题翻译：生物质催化转化方法及其中使用的装置
公开(公告)号：US08524959B1
公开(公告)日：2013-09-03
申请号：US12708241
申请日：2010-02-18
申请人： Paul O'Connor , Henrique Soares Cerqueira , Robert Bartek , Steve Yanik
发明人： Paul O'Connor , Henrique Soares Cerqueira , Robert Bartek , Steve Yanik
IPC分类号： C07C1/00
CPC分类号： C10G1/08 , C10G2300/1011 , Y02P30/20
摘要： Disclosed is a process for small-scale operation of biomass catalytic cracking. The process is suitable for lab scale and pilot plant operation, as well as for small-scale commercial operation. The process is suitable for simulating a continuous biomass catalytic cracking (BCC) process. The process comprises a biomass conversion cycle and a catalyst regeneration cycle.A fluid bed reactor and a reaction feed fluidizer suitable for use in the process are also disclosed.
摘要翻译：公开了一种生物质催化裂化小规模运行的方法。该过程适用于实验室规模和试点工厂运行，适用于小规模商业运行。该方法适用于模拟连续生物质催化裂化（BCC）工艺。该方法包括生物质转化循环和催化剂再生循环。还公开了适用于该方法的流化床反应器和反应进料流化器。

13. 发明授权

US08288599B2 Co-processing solid biomass in a conventional petroleum refining process unit 有权
标题翻译：在常规石油炼制过程单元中共同处理固体生物质
公开(公告)号：US08288599B2
公开(公告)日：2012-10-16
申请号：US12867214
申请日：2009-06-29
申请人： Steve Yanik , Paul O'Connor , Robert Bartek
发明人： Steve Yanik , Paul O'Connor , Robert Bartek
IPC分类号： C07C1/00
CPC分类号： C09K3/00 , C10G1/002 , C10G1/08 , C10G11/00 , C10G11/18 , C10G2300/1014 , C10G2300/1037 , C10G2300/4056 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/20 , C10G2400/28 , Y02P30/20
摘要： Preparing solid biomass particles for catalytic conversion includes agitating solid biomass particles and providing a biomass-catalyst mixture to a conventional petroleum refinery process unit. The biomass-catalyst mixture includes the solid biomass particles and a catalyst. Agitating solid biomass particles includes flowing a gas to provide a velocity to at least a portion of the solid biomass particles sufficient to reduce their sizes. Co-processing a biomass feedstock and a conventional petroleum feedstock includes liquefying at least a portion of a biomass-catalyst mixture and co-processing at least a portion of the liquefied biomass feedstock and a conventional petroleum feedstock in a conventional petroleum refinery process unit. The biomass feedstock includes a plurality of solid biomass particles and a catalyst, which is liquefied to produce a liquefied biomass feedstock.
摘要翻译：制备用于催化转化的固体生物质颗粒包括搅拌固体生物质颗粒并向传统的炼油工艺单元提供生物质 - 催化剂混合物。生物质 - 催化剂混合物包括固体生物质颗粒和催化剂。搅拌固体生物质颗粒包括使气体流动以提供足以减小其尺寸的至少一部分固体生物质颗粒的速度。共同处理生物质原料和常规石油原料包括液化生物质 - 催化剂混合物的至少一部分，并在常规的炼油工艺单元中共同处理至少一部分液化生物质原料和常规石油原料。生物质原料包括多个固体生物质颗粒和催化剂，其被液化以产生液化生物质原料。

14. 发明授权

US08137632B2 Biomass conversion process 有权
标题翻译：生物质转换过程
公开(公告)号：US08137632B2
公开(公告)日：2012-03-20
申请号：US12612378
申请日：2009-11-04
申请人： Robert Bartek , Steve Yanik , Paul O'Connor
发明人： Robert Bartek , Steve Yanik , Paul O'Connor
IPC分类号： F27B15/08 , C07C4/00
CPC分类号： C10L1/04 , C10G1/08 , C10G1/083 , C10G2300/1011 , C10G2300/4006 , C10G2300/708 , Y02E50/14 , Y02P30/20
摘要： A process is described including: contacting solid biomass with a first catalyst stream in a first reaction zone operated at a temperature T1 (from about 250 to about 400° C.), for conversion of a portion of the solid biomass and forming a first gaseous product stream; downwardly passing unconverted biomass to a second reaction zone for contact with a second catalyst stream charged to the second reaction zone operated at a temperature T2, for conversion to form a second gaseous product stream and a spent catalyst; burning coke off the spent catalyst in a regenerator to form a regenerated catalyst; charging a portion of the regenerated catalyst to each of the first and second reaction zones, as the first and second catalyst streams, respectively; upwardly passing the second gaseous product stream to the first reaction zone; and removing both first and second gaseous product streams from the first reaction zone.
摘要翻译：描述了一种方法，其包括：使第一催化剂流与第一反应区在温度T1（约250至约400℃）下操作，以使一部分固体生物质转化并形成第一气态产品流; 向下通过未转化的生物质到第二反应区，以与加入在温度T2下操作的第二反应区的第二催化剂流接触，以转化以形成第二气态产物流和废催化剂; 在再生器中燃烧焦炭废催化剂以形成再生催化剂; 将一部分再生催化剂分别装入第一和第二反应区中的第一和第二反应区，作为第一和第二催化剂流; 向上通过第二气态产物流到第一反应区; 以及从所述第一反应区域除去第一和第二气态产物流。

15. 发明申请

US20130068997A1 Co-Processing Solid Biomass In A Conventional Petroleum Refining Process Unit 有权
标题翻译：在常规石油炼制工艺装置中共同处理固体生物质
公开(公告)号：US20130068997A1
公开(公告)日：2013-03-21
申请号：US13617289
申请日：2012-09-14
申请人： Steve Yanik , Paul O'Connor , Robert Bartek
发明人： Steve Yanik , Paul O'Connor , Robert Bartek
IPC分类号： C09K3/00
CPC分类号： C09K3/00 , C10G1/002 , C10G1/08 , C10G11/00 , C10G11/18 , C10G2300/1014 , C10G2300/1037 , C10G2300/4056 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/20 , C10G2400/28 , Y02P30/20
摘要： Preparing solid biomass particles for catalytic conversion includes agitating solid biomass particles and providing a biomass-catalyst mixture to a conventional petroleum refinery process unit. The biomass-catalyst mixture includes the solid biomass particles and a catalyst. Agitating solid biomass particles includes flowing a gas to provide a velocity to at least a portion of the solid biomass particles sufficient to reduce their sizes. Co-processing a biomass feedstock and a conventional petroleum feedstock includes liquefying at least a portion of a biomass-catalyst mixture and co-processing at least a portion of the liquefied biomass feedstock and a conventional petroleum feedstock in a conventional petroleum refinery process unit. The biomass feedstock includes a plurality of solid biomass particles and a catalyst, which is liquefied to produce a liquefied biomass feedstock.
摘要翻译：制备用于催化转化的固体生物质颗粒包括搅拌固体生物质颗粒并向传统的炼油工艺单元提供生物质 - 催化剂混合物。生物质 - 催化剂混合物包括固体生物质颗粒和催化剂。搅拌固体生物质颗粒包括使气体流动以提供足以减小其尺寸的至少一部分固体生物质颗粒的速度。共同处理生物质原料和常规石油原料包括液化生物质 - 催化剂混合物的至少一部分，并在常规的炼油工艺单元中共同处理至少一部分液化生物质原料和常规石油原料。生物质原料包括多个固体生物质颗粒和催化剂，其被液化以产生液化生物质原料。

16. 发明申请

US20120022307A1 CO-PROCESSING SOLID BIOMASS IN A CONVENTIONAL PETROLEUM REFINING PROCESS UNIT 有权
标题翻译：常规石油精炼加工单元中加工固体生物质
公开(公告)号：US20120022307A1
公开(公告)日：2012-01-26
申请号：US12867214
申请日：2009-06-29
申请人： Steve Yanik , Paul O'Connor , Robert Bartek
发明人： Steve Yanik , Paul O'Connor , Robert Bartek
IPC分类号： C10G1/00 , B01J8/08 , C07C1/20
CPC分类号： C09K3/00 , C10G1/002 , C10G1/08 , C10G11/00 , C10G11/18 , C10G2300/1014 , C10G2300/1037 , C10G2300/4056 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/20 , C10G2400/28 , Y02P30/20
摘要： Preparing solid biomass particles for catalytic conversion includes agitating solid biomass particles and providing a biomass-catalyst mixture to a conventional petroleum refinery process unit. The biomass-catalyst mixture includes the solid biomass particles and a catalyst. Agitating solid biomass particles includes flowing a gas to provide a velocity to at least a portion of the solid biomass particles sufficient to reduce their sizes. Co-processing a biomass feedstock and a conventional petroleum feedstock includes liquefying at least a portion of a biomass-catalyst mixture and co-processing at least a portion of the liquefied biomass feedstock and a conventional petroleum feedstock in a conventional petroleum refinery process unit. The biomass feedstock includes a plurality of solid biomass particles and a catalyst, which is liquefied to produce a liquefied biomass feedstock.
摘要翻译：制备用于催化转化的固体生物质颗粒包括搅拌固体生物质颗粒并向传统的炼油工艺单元提供生物质 - 催化剂混合物。生物质 - 催化剂混合物包括固体生物质颗粒和催化剂。搅拌固体生物质颗粒包括使气体流动以提供足以减小其尺寸的至少一部分固体生物质颗粒的速度。共同处理生物质原料和常规石油原料包括液化生物质 - 催化剂混合物的至少一部分，并在常规的炼油工艺单元中共同处理至少一部分液化生物质原料和常规石油原料。生物质原料包括多个固体生物质颗粒和催化剂，其被液化以产生液化生物质原料。

17. 发明申请

US20100113849A1 BIOMASS CONVERSION PROCESS 有权
标题翻译：生物量转换过程
公开(公告)号：US20100113849A1
公开(公告)日：2010-05-06
申请号：US12612378
申请日：2009-11-04
申请人： Robert Bartek , Steve Yanik , Paul O'Connor
发明人： Robert Bartek , Steve Yanik , Paul O'Connor
IPC分类号： C10G1/00 , B01J8/04
CPC分类号： C10L1/04 , C10G1/08 , C10G1/083 , C10G2300/1011 , C10G2300/4006 , C10G2300/708 , Y02E50/14 , Y02P30/20
摘要： A process is disclosed including: contacting solid biomass with a first catalyst stream in a first reaction zone operated at a temperature T1 (from about 250 to about 400° C.), for conversion of a portion of the solid biomass and forming a first gaseous product stream; downwardly passing unconverted biomass to a second reaction zone for contact with a second catalyst stream charged to the second reaction zone operated at a temperature T2, for conversion to form a second gaseous product stream and a spent catalyst; burning coke off the spent catalyst in a regenerator to form a regenerated catalyst; charging a portion of the regenerated catalyst to each of the first and second reaction zones, as the first and second catalyst streams, respectively; upwardly passing the second gaseous product stream to the first reaction zone; and removing both first and second gaseous product streams from the first reaction zone.
摘要翻译：公开了一种方法，包括：使第一催化剂流与第一反应区在温度T1（约250至约400℃）下操作，以使一部分固体生物质转化并形成第一气态产品流; 向下通过未转化的生物质到第二反应区，以与加入在温度T2下操作的第二反应区的第二催化剂流接触，以转化以形成第二气态产物流和废催化剂; 在再生器中燃烧焦炭废催化剂以形成再生催化剂; 将一部分再生催化剂分别装入第一和第二反应区中的第一和第二反应区，作为第一和第二催化剂流; 向上通过第二气态产物流到第一反应区; 以及从所述第一反应区域除去第一和第二气态产物流。

18. 发明申请

US20130000183A1 CATALYST FOR THERMOCATALYTIC CONVERSION OF BIOMASS TO LIQUID FUELS AND CHEMICALS 有权
标题翻译：生物质热液转化为液体燃料和化学品的催化剂
公开(公告)号：US20130000183A1
公开(公告)日：2013-01-03
申请号：US13446926
申请日：2012-04-13
申请人： Bruce Adkins , Dennis Stamires , Robert Bartek , Michael Brady , John Hackskaylo
发明人： Bruce Adkins , Dennis Stamires , Robert Bartek , Michael Brady , John Hackskaylo
IPC分类号： B01J29/04 , C10L1/00
CPC分类号： B01J29/40 , B01J37/0009 , B01J37/28 , B01J2229/18 , B01J2229/42 , C10G3/49 , C10G3/57 , C10G2300/1014 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10L1/04 , C10L2200/0469 , C10L2290/02 , Y02P30/20
摘要： Catalyst compositions comprising a phosphorous-promoted ZSM-5 component and a silica-containing binder, and methods for making and using same, are disclosed. More specifically, processes for making a catalyst for biomass conversion are provided. The process includes: treating a ZSM-5 zeolite with a phosphorous-containing compound to form a phosphorous-promoted ZSM-5 component; preparing a slurry comprising the phosphorous-promoted ZSM-5 component and a silica-containing binder; and shaping the slurry into shaped bodies. Such catalysts can be used for the thermocatalytic conversion of particulate biomass to liquid products such as bio-oil, resulting in higher bio-oil yields and lower coke than conventional catalysts.
摘要翻译：公开了包含磷促进的ZSM-5组分和含二氧化硅的粘合剂的催化剂组合物及其制备和使用方法。更具体地，提供了用于制备用于生物质转化的催化剂的方法。该方法包括：用含磷化合物处理ZSM-5沸石以形成磷促进的ZSM-5组分; 制备包含磷促进的ZSM-5组分和含二氧化硅的粘合剂的浆料; 并将浆料成型为成型体。这种催化剂可用于将微生物量热生物转化为液体产物如生物油，导致比常规催化剂更高的生物油产率和较低的焦炭。

19. 发明授权

US08425766B2 Biomass pretreatment for fast pyrolysis to liquids 有权
标题翻译：用于快速热解为液体的生物质预处理
公开(公告)号：US08425766B2
公开(公告)日：2013-04-23
申请号：US13546271
申请日：2012-07-11
申请人： Robert Bartek , Michael Brady , Dennis Stamires
发明人： Robert Bartek , Michael Brady , Dennis Stamires
IPC分类号： C10C3/02
CPC分类号： C10B53/02 , C10B49/16 , C10B57/08 , C10C5/00 , C10G1/02 , C10G1/08 , C10G2300/1011 , C10L1/02 , Y02E50/14 , Y02E50/30 , Y02P30/20
摘要： Aspects of the present invention relate to methods, systems, and compositions for preparing a solid biomass for fast pyrolysis. The method includes contacting the solid biomass with an inorganic material present in an effective amount for increasing fast pyrolysis yield of an organic liquid product (e.g., bio-oil). In various embodiments, the inorganic material is selected from the group consisting of aluminum sulfate, aluminum nitrate, aluminum chloride, aluminum hydroxide, ammonium hydroxide, magnesium hydroxide, potassium hydroxide, and combinations thereof.
摘要翻译：本发明的方面涉及用于制备用于快速热解的固体生物质的方法，系统和组合物。该方法包括使固体生物质与有效量存在的无机材料接触，以提高有机液体产物（例如生物油）的快速热解产率。在各种实施方案中，无机材料选自硫酸铝，硝酸铝，氯化铝，氢氧化铝，氢氧化铵，氢氧化镁，氢氧化钾及其组合。

20. 发明授权

US09044741B2 Process for converting biomass to a fuel 有权
标题翻译：将生物质转化为燃料的方法
公开(公告)号：US09044741B2
公开(公告)日：2015-06-02
申请号：US13446926
申请日：2012-04-13
申请人： Bruce Adkins , Dennis Stamires , Robert Bartek , Michael Brady , John Hackskaylo
发明人： Bruce Adkins , Dennis Stamires , Robert Bartek , Michael Brady , John Hackskaylo
IPC分类号： C10L1/18 , B01J29/40 , C10G3/00
CPC分类号： B01J29/40 , B01J37/0009 , B01J37/28 , B01J2229/18 , B01J2229/42 , C10G3/49 , C10G3/57 , C10G2300/1014 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10L1/04 , C10L2200/0469 , C10L2290/02 , Y02P30/20
摘要： Catalyst compositions comprising a phosphorous-promoted ZSM-5 component and a silica-containing binder, and methods for making and using same, are disclosed. More specifically, processes for making a catalyst for biomass conversion are provided. The process includes: treating a ZSM-5 zeolite with a phosphorous-containing compound to form a phosphorous-promoted ZSM-5 component; preparing a slurry comprising the phosphorous-promoted ZSM-5 component and a silica-containing binder; and shaping the slurry into shaped bodies. Such catalysts can be used for the thermocatalytic conversion of particulate biomass to liquid products such as bio-oil, resulting in higher bio-oil yields and lower coke than conventional catalysts.
摘要翻译：公开了包含磷促进的ZSM-5组分和含二氧化硅的粘合剂的催化剂组合物及其制备和使用方法。更具体地，提供了用于制备用于生物质转化的催化剂的方法。该方法包括：用含磷化合物处理ZSM-5沸石以形成磷促进的ZSM-5组分; 制备包含磷促进的ZSM-5组分和含二氧化硅的粘合剂的浆料; 并将浆料成型为成型体。这种催化剂可用于将微生物量热生物转化为液体产物如生物油，导致比常规催化剂更高的生物油产率和较低的焦炭。

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