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11. 发明授权

US4981969A Polyalkylpiperidine-substituted tetrahydropyridones and use thereof 失效
标题翻译：聚烷基哌啶取代的四氢吡啶酮及其用途
公开(公告)号：US4981969A
公开(公告)日：1991-01-01
申请号：US443478
申请日：1989-11-30
申请人： Alexander Aumueller , Peter Neumann , Hubert Trauth
发明人： Alexander Aumueller , Peter Neumann , Hubert Trauth
IPC分类号： C07D211/78 , C07D211/90 , C07D401/14 , C08K5/3412 , C08K5/3435 , C09D7/12
CPC分类号： C07D401/14 , C07D211/90 , C08K5/3435
摘要： Tetrahydropyridones which in one of their tautomeric forms conform to the general formula (I) ##STR1## where R.sup.1 and R.sup.2 are each independently of the other C.sub.1 -C.sub.12 -alkyl, which may be oxygen-interrupted, C.sub.5 -C.sub.6 -cycloalkyl or C.sub.7 -C.sub.12 -phenylalkyl where the phenyl is unsubstituted or monosubstituted, disubstituted or trisubstitued by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, fluorine, chlorine or bromine, or ##STR2## is a from 5- to 12-membered cycloaliphatic ring which may be monosubstituted, disubstituted, trisubstituted or tetrasubstituted by C.sub.1 -C.sub.4 -alkyl, andR.sup.3 is hydrogen, substituted or unsubstituted alkyl or phenyl alkyl or alkanoyl, are effective stabilizers for plastics and coatings.
摘要翻译：以其互变异构形式之一的四氢吡啶酮符合通式（I）其中R 1和R 2各自独立地为可被氧中断的C 1 -C 12 - 烷基，C 5 -C 6 - 环烷基或C 7 -C 12 - 苯基烷基，其中苯基是未取代的或被C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，氟，氯或溴单取代，二取代或三取代，或者是＆lt; IMAGE＆gt;是5至12元环脂族环可以被C1-C4-烷基单取代，三取代或四取代，R3是氢，取代或未取代的烷基或苯基烷基或烷酰基，是塑料和涂料的有效稳定剂。

12. 发明授权

US4980476A Polyalkylpiperidine-substituted lactams and use thereof as stabilizers for plastics 失效
标题翻译：聚烷基哌啶取代的内酰胺及其作为塑料稳定剂的用途
公开(公告)号：US4980476A
公开(公告)日：1990-12-25
申请号：US438795
申请日：1989-11-20
申请人： Alexander Aumueller , Peter Neumann , Hubert Trauth
发明人： Alexander Aumueller , Peter Neumann , Hubert Trauth
IPC分类号： C07D401/14 , C08K5/3432 , C08K5/3435 , C09K15/22
CPC分类号： C07D401/14 , C08K5/3435
摘要： Compound of the formula (I) ##STR1## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each alkyl or R.sup.1 and R.sup.2 or R.sup.3 and R.sup.4 are together tetra- or pentamethylene and R.sup.5 is hydrogen, alkanoyl, alkyl, cyanoalkyl, hydroxyalkyl, aminoalkyl or phenylalkyl, in which the phenyl nucleus may be substituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or halogen, and the acid addition salts and hydrates of these compounds are useful stabilizers for organic materials, in particular plastics.
摘要翻译：式（I）的化合物其中R 1，R 2，R 3和R 4各自为烷基或R 1，R 2或R 3和R 4一起为四或五亚甲基，R 5为氢，烷酰基，烷基，氰基烷基，羟基烷基，氨基烷基或苯基烷基，其中苯基核可以被C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基或卤素取代，并且这些化合物的酸加成盐和水合物是有机材料，特别是塑料的有用的稳定剂。

13. 发明授权

US4976889A 4-formylaminopiperidine derivatives, their use as stabilizers and organic material stabilized with the said derivatives 失效
标题翻译： 4-甲酰氨基哌啶衍生物，它们用作稳定剂和用所述衍生物稳定的有机物质
公开(公告)号：US4976889A
公开(公告)日：1990-12-11
申请号：US270806
申请日：1988-11-14
申请人： Alexander Aumueller , Peter Neumann , Hubert Trauth
发明人： Alexander Aumueller , Peter Neumann , Hubert Trauth
IPC分类号： C07D211/58 , C07D221/20 , C07D401/12 , C07D405/12 , C07D409/12 , C08K5/3435
CPC分类号： C07D401/12 , C07D211/58 , C07D405/12
摘要： 4-Formylaminopiperidine derivatives of the formula (I) ##STR1## where n is 1 or 2, R.sup.1 to R.sup.4 are each alkyl or R.sup.1 and R.sup.2 or R.sup.3 and R.sup.4 are tetra- or pentamethylene, R.sup.5 is hydrogen or alkyl, R.sup.6 is hydrogen, unsubstituted or substituted alkyl, alkenyl, aralkyl or acyl, and, when n is 1, Y is hydrogen, unsubstituted or substituted alkyl, alkenyl, cycloalkyl, bicycloalkyl, aralkyl, aryl, alkyl containing heterocyclic radicals, or ##STR2## or, when n is 2, Y is alkylene, cycloalkylene, aralkylene or arylene or is alkylene which is interrupted by oxygen, nitrogen, sulfur or a 5-membered or 6-membered heterocyclic structure, and their acid addition salts have very good stabilizing properties in plastics.
摘要翻译：式（I）的4-甲酰氨基哌啶衍生物其中n为1或2，R 1至R 4各自为烷基或R 1，R 2或R 3和R 4为四或五亚甲基，R 5为氢或烷基，R 6为当n为1时，Y为氢，未取代或取代的烷基，链烯基，环烷基，双环烷基，芳烷基，芳基，含烷基的杂环基，或当n为2时，Y为亚烷基，亚环烷基，亚芳基或亚芳基，或为被氧，氮，硫或5元或6元杂环结构中断的亚烷基，其酸加成盐具有非常好的稳定性塑料。

14. 发明授权

US4925888A Mixture for stabilizing polyurethanes 失效
标题翻译：用于稳定聚氨酯的混合物
公开(公告)号：US4925888A
公开(公告)日：1990-05-15
申请号：US260612
申请日：1988-10-21
申请人： Alexander Aumueller , Peter Neumann , Peter Spang , Guenter Matzke , Hubert Trauth
发明人： Alexander Aumueller , Peter Neumann , Peter Spang , Guenter Matzke , Hubert Trauth
IPC分类号： C08G18/38 , C08G18/30 , C08G65/32 , C08K5/1545 , C08K5/34 , C08K5/3435 , C08K5/3475 , C08L71/02 , C08L75/00 , C08L75/04
CPC分类号： C08K5/3435 , C08K5/3475
摘要： A mixture for stabilizing polyurethanes contains(a) an amine of the formula I ##STR1## (b) a mixture of the benzotriazoles II and III ##STR2## in which n is chosen so that the mean molecular weight of the mixture is greater than 600, and(c) .alpha.-tocopherol, if necessary mixed with tris-(nonylphenyl) phosphite, and polyurethanes contain from 0.005 to 5.0% by weight, based on the material to be stabilized, of this mixture.
摘要翻译：用于稳定聚氨酯的混合物包含（a）式I的胺（I）（b）苯并三唑II和III的混合物（II）图像（III）图像，其中n 被选择使得混合物的平均分子量大于600，和（c）如果需要，与三（壬基苯基）亚磷酸酯混合的α-生育酚和基于该材料的聚氨酯含有0.005-5.0重量％要稳定的混合物。

15. 发明授权

US5504211A Polyalkylpiperidinyl-containing .beta.-aminoacrylic ester derivatives 失效
标题翻译：含聚烷基哌啶基的β-氨基丙烯酸酯衍生物
公开(公告)号：US5504211A
公开(公告)日：1996-04-02
申请号：US244202
申请日：1994-05-31
申请人： Alexander Aumueller , Alfred Krause , Hubert Trauth
发明人： Alexander Aumueller , Alfred Krause , Hubert Trauth
IPC分类号： C07D211/58 , C07D211/94 , C08G63/685 , C08K5/3432 , C08K5/3435 , C07D211/00 , C07D401/00 , C08K5/34
CPC分类号： C07D211/58 , C08G63/6858 , C08K5/3435
摘要： A polyalky-piperidinyl-containing .beta.-aminoacrylic ester derivative represented by the formula I ##STR1## is useful in stabilizing plastic and paints against light, oxygen and heat.
摘要翻译： PCT No.PCT / EP92 / 02672 Sec。 371日期1994年5月31日 102（e）日期1994年5月31日PCT提交1992年11月20日PCT公布。公开号WO93 / 11111 日期：1993年6月10日。由式I表示的含有亚烷基 - 哌啶基的β-氨基丙烯酸酯衍生物可用于稳定针对光，氧和热的塑料和油漆。

16. 发明授权

US5434202A N-(.beta.-carbony- and .beta.-cyanovinyl)-2,2,6,6-tetramethyl-piperidine derivatives 失效
标题翻译： N-（β-羰基 - 和β-氰基乙烯基）-2,2,6,6-四甲基 - 哌啶衍生物
公开(公告)号：US5434202A
公开(公告)日：1995-07-18
申请号：US244209
申请日：1994-06-03
申请人： Alfred Krause , Alexander Aumueller , Hubert Trauth
发明人： Alfred Krause , Alexander Aumueller , Hubert Trauth
IPC分类号： C07D211/46 , C07D211/54 , C07D211/58 , C07D401/04 , C07D405/06 , C07D409/06 , C08K5/3432 , C08K5/3435
CPC分类号： C07D211/58 , C07D211/46 , C08K5/3435
摘要： N-(.beta.-carbonyl- and .beta.-cyanovinyl)-2,2,6,6-tetramethylpiperidine derivatives of the formula I ##STR1## where R.sup.1 is COOR.sup.3, COR.sup.4, CONR.sup.4 R.sup.5 or CN,R.sup.2 has the meanings of R.sup.1 or is C.sub.1 -C.sub.12 -alkyl or hydrogen,R.sup.3 is hydrogen, C.sub.1 -C.sub.8 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl, C.sub.3 -C.sub.5 -alkenyl or phenyl which can be mono- to trisubstituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkoxycarbonyl, halogen, hydroxyl, phenoxy, phenyl, tolyl or xylyl,R.sup.4 and R.sup.5 are each hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl or phenyl which can be mono- to trisubstituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkoxycarbonyl, halogen, hydroxyl, phenoxy, phenyl, tolyl or xylyl,n is 1-4,X and A for each individual n have been defined in the specification.
摘要翻译： PCT No.PCT / EP92 / 02733 Sec。 371日期：1994年6月3日 102（e）日期1994年6月3日PCT提交1992年11月27日PCT公布。出版物WO93 / 11109 日期：6月10日，1993.N-（β-羰基 - 和β-氰基乙酰基）-2,2,6,6-四甲基哌啶衍生物，其中R1是COOR3，COR4，CONR4R5或CN，R2 具有R 1的意义或是C 1 -C 12 - 烷基或氢，R 3是氢，C 1 -C 8 - 烷基，C 5 -C 8 - 环烷基，C 3 -C 5 - 烯基或苯基，其可以被C1-C4- 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷氧基羰基，卤素，羟基，苯氧基，苯基，甲苯基或二甲苯基，R 4和R 5各自为氢，C 1 -C 12烷基，C 5 -C 8环烷基或苯基， - 被C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷氧基羰基，卤素，羟基，苯氧基，苯基，甲苯基或二甲苯基三取代，n为1-4，各个n的X和A定义在规范中。

17. 发明授权

US5710228A Maleimide/.alpha.-olefin copolymers and their use as light stabilizers and stabilizers for organic material 失效
标题翻译：马来酰亚胺/α-烯烃共聚物及其用作有机材料的光稳定剂和稳定剂
公开(公告)号：US5710228A
公开(公告)日：1998-01-20
申请号：US644123
申请日：1996-05-10
申请人： Alfred Krause , Walter Denzinger , Albert Hettche , Alexander Aumueller , Hubert Trauth
发明人： Alfred Krause , Walter Denzinger , Albert Hettche , Alexander Aumueller , Hubert Trauth
IPC分类号： C08F2/06 , C08F8/32 , C08F210/14 , C08F222/40 , C08F210/00
CPC分类号： C08F8/32 , C08F210/14
摘要： Maleimide/.alpha.-olefin copolymers are composed of structural units I ##STR1## where R.sup.1 is a tetramethylpiperidinyl radical of the formula II ##STR2## R.sup.3 is hydrogen, C.sub.1 -C.sub.6 -alkyl, formyl, C.sub.2 -C.sub.6 -alkanoyl, C.sub.1 -C.sub.12 -alkoxy, C.sub.5 - or C.sub.6 -cycloalkoxy, cyanomethyl, 2-hydroxyethyl, benzyl or a radical of the formula --CR.sup.4 =CH--CO--OR.sup.5, R.sup.4 is hydrogen, C.sub.1 -C.sub.6 -alkyl or a radical of the formula --CO--OR.sup.5, and R.sup.5 is C.sub.5 -C.sub.18 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl, C.sub.7 -C.sub.18 -aralkyl, phenyl or tolyl, and up to 8 mol %, based on II, of R.sup.1 may furthermore be hydrogen, C.sub.1 -C.sub.22 -alkyl or C.sub.5 -C.sub.8 -cycloalkyl, and R.sup.2 is a mixture of C.sub.14 -C.sub.28 -alkyl groups, where two of these alkyl groups, which may differ by no more than two carbon atoms, each account for at least 30% of this mixture, having an average molecular weight of from 1,000 to 50,000. The copolymers described are suitable as light stabilizers and stabilizers for organic material, in particular plastics and coatings.
摘要翻译：马来酰亚胺/α-烯烃共聚物由结构单元Ⅰ（II）组成，其中R 1是式II的四甲基哌啶基，其中R 3是氢，C 1 -C 6烷基，甲酰基，C 2 -C 6 - 烷酰基，C 1 -C 12 - 烷氧基，C 5 - 或C 6 - 环烷氧基，氰基甲基，2-羟乙基，苄基或式-CR 4 = CH-CO-OR 5基团，R 4是氢，C 1 -C 6烷基或式-CO-OR5和R5是C5-C18-烷基，C5-C8-环烷基，C7-C18-芳烷基，苯基或甲苯基，并且基于II的至多8摩尔％的R 1还可以是氢， C 1 -C 22 - 烷基或C 5 -C 8 - 环烷基，并且R 2是C 14 -C 28 - 烷基的混合物，其中两个可以不超过两个碳原子的烷基各自占据至少30％的该混合物，其平均分子量为1,000至50,000。所述的共聚物适合用作有机材料的光稳定剂和稳定剂，特别是塑料和涂料。

18. 发明授权

US5496877A Amino compounds as processing stabilizers for thermoplastic materials 失效
标题翻译：氨基化合物作为热塑性材料的加工稳定剂
公开(公告)号：US5496877A
公开(公告)日：1996-03-05
申请号：US313115
申请日：1994-10-12
申请人： Alexander Aumueller , Hubert Trauth
发明人： Alexander Aumueller , Hubert Trauth
IPC分类号： C07D233/61 , C08K5/17 , C08K5/34 , C08K5/3445 , C08K5/3462 , C08L101/00 , C08K3/20
CPC分类号： C08K5/3462 , C08K5/17 , C08K5/3445
摘要： Compounds of the general formula (I) or (II) ##STR1## where m is 2 or 3,n is an integer from 1 to 6,R.sup.1 and R.sup.2 are, independently of one another, hydrogen, C.sub.1 - to C.sub.18 -alkyl, C.sub.3 - to C.sub.8 -alkenyl or C.sub.5 - to C.sub.12 cycloalkyl, R.sup.4 and R.sup.5 are, independently of one another, hydrogen, C.sub.1 - to C.sub.18 -alkyl, C.sub.3 - to C.sub.8 -alkenyl, C.sub.5 - to C.sub.12 -cycloalkyl or C.sub.7 - to C.sub.12 -phenylalkyl, in which the phenyl ring may be substituted by up to 3 C.sub.1 - to C.sub.12 -alkyl or C.sub.1 - to C.sub.12 -alkoxy groups,X is oxygen or NR.sup.3,R.sup.3 is an R.sup.1 radical or a group of the formula ##STR2## B completes a 3- to 12-membered heterocycle, A when n=1 is an aliphatic radical or unsubstituted or substituted phenyl, andA when n>1 is a divalent organic radical, are used as processing stabilizers for thermoplastic materials.
摘要翻译： PCT No.PCT / EP93 / 00951 Sec。 371日期：1994年10月12日 102（e）日期1994年10月12日PCT提交1993年4月20日PCT公布。公开号WO93 / 22376 （I）或（II）的化合物其中m为2或3，n为1至6的整数，R 1和R 2为彼此独立地为氢，C 1至C 18烷基，C 3至C 8链烯基或C 5至C 12环烷基，R 4和R 5彼此独立地为氢，C 1 -C 18 - 烷基，C 3 - C 8 - 烯基，C 5 - 至C 12 - 环烷基或C 7 - 至C 12 - 苯基烷基，其中苯环可被至多3个C 1 -C 12 - 烷基或C 1 -C 12烷氧基取代，X为氧或NR 3 R 3为R 1基团或式VIII所示基团，当n = 1是脂族基团或未取代或取代的苯基时，A完成3至12元杂环，当n> 1是二价有机基团用作热塑性材料的加工稳定剂。

19. 发明授权

US5266320A Aminovinyl-substituted heterocyclic compounds as stabilizers for organic materials 失效
标题翻译：氨基乙烯基取代的杂环化合物作为有机材料的稳定剂
公开(公告)号：US5266320A
公开(公告)日：1993-11-30
申请号：US835483
申请日：1992-02-14
申请人： Martin Holderbaum , Alexander Aumueller , Hubert Trauth
发明人： Martin Holderbaum , Alexander Aumueller , Hubert Trauth
IPC分类号： A61K8/00 , A61K8/49 , A61Q17/04 , C07D235/12 , C07D235/14 , C07D235/16 , C07D263/56 , C07D277/64 , C08K5/3442 , C08K5/3447 , C08K5/3465 , C08K5/353 , C08K5/45 , C08K5/46 , C08K5/47 , C09D7/12 , C09K3/00 , C09K15/30 , A61K7/42 , A61K7/027
CPC分类号： A61Q17/04 , A61K8/49 , A61K8/4946 , C07D235/16 , C07D263/56 , C07D277/64 , C08K5/3447 , C08K5/353 , C08K5/47 , C09D7/1241 , Y10S514/944 , Y10S514/945 , Y10S514/972
摘要： The use of an aminovinyl-substituted heterocyclic compound of the general formula I ##STR1## in which R.sup.1 denotes hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, or halogen, and, if more than one radical R.sup.1 are present, these may be the same or different,R.sup.2 denotes cyano or C.sub.1 -C.sub.20 -alkoxycarbonyl or C.sub.3 -C.sub.6 -cycloalkoxycarbonyl,R.sup.3 denotes hydrogen, C.sub.1 -C.sub.18 -alkyl, C.sub.1 -C.sub.18 -alkoxy, halogen, cyano, C.sub.1 -C.sub.20 -alkoxycarbonyl, or C.sub.3 -C.sub.6 -cycloalkoxycarbonyl, and, if more than one radical R.sup.3 are present, these may be the same or different,X denotes NH, O or S,m is equal to 1 or 2, andn is an integer from 1 to 5,as a stabilizer for organic materials.
摘要翻译：使用通式I的氨基乙烯基取代的杂环化合物，其中R 1表示氢，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基或卤素，并且如果存在多于一个基团R 1，这些可以相同或不同，R2表示氰基或C1-C20-烷氧基羰基或C3-C6-环烷氧基羰基，R3表示氢，C1-C18-烷基，C1-C18-烷氧基，卤素，氰基，C1-C20-烷氧基羰基，或C 3 -C 6 - 环烷氧基羰基，如果存在多于一个基团R 3，它们可以相同或不同，X表示NH，O或S，m等于1或2，并且n是1至 5，作为有机材料的稳定剂。

20. 发明授权

US4837403A Novel polyalkylpiperidine derivatives having alkylene bridges, use thereof as stabilizers, and intermediates 失效
标题翻译：具有亚烷基桥的新型聚烷基哌啶衍生物，其作为稳定剂的用途和中间体
公开(公告)号：US4837403A
公开(公告)日：1989-06-06
申请号：US132331
申请日：1987-12-14
申请人： Alexander Aumueller , Peter Neuman , Hubert Trauth
发明人： Alexander Aumueller , Peter Neuman , Hubert Trauth
IPC分类号： C07D487/22 , C08K5/3477
CPC分类号： C07D487/22 , C08K5/3477
摘要： Compounds useful as stabilizers have the general formula I ##STR1## where the radicals are as defined in claim 1.
摘要翻译：可用作稳定剂的化合物具有通式I CABA（I），其中基团如权利要求1中所定义。

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