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    • 16. 发明授权
    • Stable solid formulations of cyclohexenone oxime ether herbicides
    • 环己烯酮肟醚除草剂稳定的固体制剂
    • US5981440A
    • 1999-11-09
    • US913779
    • 1997-09-23
    • Matthias BratzKarl-Friedrich JagerRainer BerghausHans Ziegler
    • Matthias BratzKarl-Friedrich JagerRainer BerghausHans Ziegler
    • A01N25/12A01N25/22A01N35/10A01N43/16A01N43/18A01N43/76A01N43/56A01N37/00A01N43/02
    • A01N35/10A01N25/12A01N43/16A01N43/18
    • Crop protection active compound formulations, comprising a cyclohexenone oxime ether of the general formula I ##STR1## where the radicals R.sup.1 -R.sup.6 have the following meanings: R.sup.1 is ethyl or propyl;R.sup.2 is hydrogen or an equivalent of an agriculturally utilizable cation;R.sup.3 is 2-thioethylpropyl, tetrahydrothiopyran-3-yl, tetrahydrothiopyran-4-yl, tetrahydropyran-3-yl, tetrahydropyran-4-yl, 1-methylthiocyclopropyl, 5-isopropylisoxazol-3-yl, 2,5-dimethylpyrazol-3-yl, 2,4,6-trimethylphenyl or 2,4,6-trimethyl-3-butyrylphenyl;R.sup.4 and R.sup.5 independently of one another are hydrogen, methyl or methoxycarbonyl;Alk is CH.sub.2 CH.sub.2, CH.sub.2 CH(CH.sub.3), CH.sub.2 CH.dbd.CH, CH.sub.2 CH.dbd.C(Cl) or CH.sub.2 CH.sub.2 CH.dbd.CH;R.sup.6 is hydrogen, phenyl, halophenyl, dihalophenyl, phenoxy, halophenoxy or dihalophenoxy;and a water-soluble basic salt of an acid having a pK.sub.a of greater than 5, alkali metal hydroxides and alkali metal carbonates being excluded, their preparation and use as herbicides are described.
    • PCT No.PCT / EP96 / 01046 Sec。 371日期1997年9月23日 102(e)1997年9月23日PCT 1996年3月12日PCT公布。 公开号WO96 / 29869 日期1996年10月3日保护活性化合物制剂,其包含通式I的环己烯酮肟醚,其中基团R 1 -R 6具有以下含义:R 1是乙基或丙基; R2是氢或相当于农业上可用的阳离子; R 3是2-硫代乙基丙基,四氢噻喃-3-基,四氢噻喃-4-基,四氢吡喃-3-基,四氢吡喃-4-基,1-甲硫基环丙基,5-异丙基异恶唑-3-基,2,5-二甲基吡唑-3-基, 2,4,6-三甲基苯基或2,4,6-三甲基-3-丁酰苯基; R 4和R 5彼此独立地是氢,甲基或甲氧基羰基; Alk是CH 2 CH 2,CH 2 CH(CH 3),CH 2 CH = CH,CH 2 CH = C(Cl)或CH 2 CH 2 CH = CH; R6是氢,苯基,卤代苯基,二卤代苯基,苯氧基,卤代苯氧基或二卤代苯氧基; 和pKa大于5的酸的水溶性碱性盐,不包括碱金属氢氧化物和碱金属碳酸盐,它们作为除草剂的制备和用途被描述。