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    • 15. 发明申请
    • PLATINUM NICKEL CATALYST ALLOY
    • 铂金镍催化剂合金
    • US20130040227A1
    • 2013-02-14
    • US13643353
    • 2011-04-26
    • Mark K. DebeGeorge D. VernstromAndrew J. L. Steinbach
    • Mark K. DebeGeorge D. VernstromAndrew J. L. Steinbach
    • H01M4/92B01J23/89B82Y30/00
    • C22C30/00C22C5/04C22C19/03
    • A Pt—Ni catalyst is provided which demonstrates an unusually high oxygen reduction mass activity. In some embodiments, the Pt—Ni catalyst is a Pt—Ni binary alloy. In some embodiments, the catalyst may be characterized as having a Pt fcc lattice parameter of less than 3.71 Angstroms or 0.371 nm. In some embodiments the catalyst has a Pt fcc lattice parameter of between 3.69 Angstroms (or 0.369 nm) and 3.73 Angstroms (or 0.373 nm). In some embodiments, the catalyst may be characterized as having a composition of close to PtxNi(1-x), where x is between 0.2 and 0.4. In some embodiments the catalyst comprises nanostructured elements comprising microstructured support whiskers bearing a thin film of nanoscopic catalyst particles comprising a catalyst material described above. The catalyst may be particularly useful as a fuel cell catalyst and more specifically as a fuel cell cathode catalyst.
    • 提供了Pt-Ni催化剂,其表现出异常高的氧还原质量活性。 在一些实施方案中,Pt-Ni催化剂是Pt-Ni二元合金。 在一些实施方案中,催化剂的特征在于具有小于3.71埃或0.371nm的Pt fcc晶格参数。 在一些实施方案中,催化剂具有3.69埃(或0.369nm)和3.73埃(或0.373nm)之间的Pt fcc晶格参数。 在一些实施方案中,催化剂的特征在于具有接近PtxNi(1-x)的组成,其中x在0.2和0.4之间。 在一些实施方案中,催化剂包含纳米结构元素,其包含微结构化支撑晶须,其载有包含上述催化剂材料的纳米级催化剂颗粒的薄膜。 催化剂可以特别用作燃料电池催化剂,更具体地可用作燃料电池阴极催化剂。