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11. 发明授权

US07402675B2 Process for the synthesis of amine ethers from secondary amino oxides 有权
公开(公告)号：US07402675B2
公开(公告)日：2008-07-22
申请号：US10919776
申请日：2004-08-17
申请人： Andreas Hafner , Hans Jürg Kirner , Franz Schwarzenbach , Paul Adriaan Van Der Schaaf , Peter Nesvadba
发明人： Andreas Hafner , Hans Jürg Kirner , Franz Schwarzenbach , Paul Adriaan Van Der Schaaf , Peter Nesvadba
IPC分类号： C07D211/54
CPC分类号： C07D401/14 , C04B35/632 , C07D209/44 , C07D211/94 , C07D217/26 , C07D241/08 , C07D401/12 , C07D405/12 , C08K5/3412
摘要： An amine ether of formula A wherein a is 1 or 2; and when a is 1, E is E′; when a is 2, E is L; E′ is C1-C36 alkyl; C3-C18 alkenyl; C2-C18 alkinyl; C5-C18 cycloalkyl; C5-C18 cycloalkenyl; a radical of a saturated or unsaturated aliphatic bicyclic or tricyclic hydrocarbon of 7 to 12 carbon atoms; C2-C7alkyl or C3-C7alkenyl substituted by halogen; C7-C15 aralkyl or C7-C15 aralkyl substituted by C1-C4 alkyl or phenyl; or E′ is a radical of formula (VII) as explained in claim 1; T′ is tertiary C4-C18alkyl or phenyl, each of which are unsubstituted or substituted by halogen, OH, COOR21 or C(O)—R22; or T′ is C5-C12cycloalkyl; C5-C12cycloalkyl which is interrupted by at least one O or —NR18—; a polycyclic alkyl radical having 7-18 carbon atoms, or the same radical which is interrupted by at least one O or —NR18—; or T′ is —C(G1)(G2)-T″; or C1-C18alkyl or C5-C12cycloalkyl substituted by T″ is hydrogen, halogen, NO2, cyano, or is a monovalent organic radical comprising 1-50 carbon atoms; or T″ and T′ together form a divalent organic linking group completing, together with the hindered amine nitrogen atom and the quaternary carbon atom substituted by G1 and G2, an optionally substituted five- or six-membered ring structure; and all other residues are as defined in claim 1, are obtained in good yield from the corresponding N-oxyl hindered amine precursor by reaction with a hydrocarbon E1-H or H-L-H in the presence of an organic hydroperoxide and a catalytic amount of copper or a copper compound. The products of present process find utility as polymerization regulators and/or light stabilizers for organic material.

12. 发明授权

US06900328B2 Process for the synthesis of amine ethers from secondary amino oxides 有权
公开(公告)号：US06900328B2
公开(公告)日：2005-05-31
申请号：US10296107
申请日：2001-05-17
申请人： Andreas Hafner , Hans Jürg Kirner , Franz Schwarzenbach , Paul Adriaan Van Der Schaaf , Peter Nesvadba
发明人： Andreas Hafner , Hans Jürg Kirner , Franz Schwarzenbach , Paul Adriaan Van Der Schaaf , Peter Nesvadba
IPC分类号： B01J27/122 , C07B61/00 , C07D209/44 , C07D211/94 , C07D217/26 , C07D241/08 , C07D401/12 , C07D401/14 , C07D405/12 , C08F4/00 , C08K5/3412 , C08K5/3435 , C08L101/00 , C09K15/30 , C09K21/10 , C07D211/54
CPC分类号： C07D401/14 , C04B35/632 , C07D209/44 , C07D211/94 , C07D217/26 , C07D241/08 , C07D401/12 , C07D405/12 , C08K5/3412
摘要： An amine ether of formula (A) wherein a is 1 or 2; and when a is 1, E is E′; when a is 2, E is L; E′ is C1-C36 alkyl; C3-C18 alkenyl; C2-C18 alkinyl; C5-C18 cycloalkyl; C5-C18 cycloalkenyl; a radical of a saturated or unsaturated aliphatic bicyclic or tricyclic hydrocarbon of 7 to 12 carbon atoms; C2-C7alkyl or C3-C7alkenyl substituted by halogen; C7-C15aralkyl or C7-C15 aralkyl substituted by C1-C4 alkyl or phenyl; or E′ is a radical of formula (VII) as explained in claim 1; T′ is tertiary C4-C18alkyl or phenyl, each of which are unsubstituted or substituted by halogen, OH, COOR21 or C(O)—R22; or T′ is C5-C12cycloalkyl; C5-C12cacloalkyl which is interrupted by at least one O or —NR18—; a polycyclic alkyl radical having 7-18 carbon atoms, or the same radical which is interrupted by at least one O or —NR18—; or T′ is —C(G1)(G2)—T″; or C1-C18alkyl or C5-C12cycloalkyl substituted by F(I)T″ is hydrogen, halogen, NO2, cyano, or is a monovalent organic radical comprising 1-50 carbon atoms; or T″ and T′ together form a divalent organic linking group completing, together with the hindered amine nitrogen atom and the quaternary carbon atom substituted by G1 and G2, an optionally substituted five- or six-membered ring structure; and all other residues are as defined in claim 1, are obtained in good yield from the corresponding N-oxyl hindered amine precursor by reaction with a hydrocarbon E1—H or H—L—H in the presence of an organic hydroperoxide and a catalytic amount of copper or a copper compound. The products of present process find utility as polymerization regulators and/or light stabilizers for organic material

13. 发明授权

US06407190B1 Ruthenium and osmium carbene catalysts 有权
标题翻译：钌和铯卡因催化剂
公开(公告)号：US06407190B1
公开(公告)日：2002-06-18
申请号：US09445909
申请日：1999-12-15
申请人： Paul Adriaan Van Der Schaaf , Andreas Hafner , Andreas Mühlebach
发明人： Paul Adriaan Van Der Schaaf , Andreas Hafner , Andreas Mühlebach
IPC分类号： C08F480
CPC分类号： B01J31/2404 , B01J31/182 , B01J31/2204 , B01J31/2265 , B01J31/24 , B01J2231/14 , B01J2231/543 , B01J2531/821 , B01J2531/825 , C07F15/002 , C07F15/0046 , C08G61/02
摘要： The invention relates to penta- and hexacoordinated ruthenium and osmium carbene catalysts, in which a sulfur, oxygen or nitrogen atom is attached to the carbene group which is coordinated with the central ruthenium or osmium atom, to their preparation and to their use for synthesizing polymers, for ring-closing metathesis of olefins and for isomerizing olefins.
摘要翻译：本发明涉及五价和六配位的钌和锇卡宾催化剂，其中硫，氧或氮原子连接至与中心钌或锇原子配位的卡宾基团，其制备及其用于合成聚合物，用于烯烃的闭合复分解和异构化烯烃。

14. 发明授权

US06281307B1 Polymerizable composition, process for producing cross linked polymers, and cross-linkable polymers 失效
标题翻译：可聚合组合物，交联聚合物的生产方法和可交联聚合物
公开(公告)号：US06281307B1
公开(公告)日：2001-08-28
申请号：US08875529
申请日：1997-07-31
申请人： Andreas Mühlebach , Andreas Hafner , Paul Adriaan Van Der Schaaf
发明人： Andreas Mühlebach , Andreas Hafner , Paul Adriaan Van Der Schaaf
IPC分类号： C08F480
CPC分类号： C08G18/6204 , B33Y70/00 , C08G61/00
摘要： Composition comprising (a) catalytic amounts of a one-component catalyst for metathesis polymerization and (b) at least one polymer with strained cycloalkenylene radicals bonded in the polymer backbone, alone or as a mixture with strained cycloolefins. The composition can be polymerized thermally or photochemically by metathesis polymerization and is suitable for the production of shaped articles, coatings and relief images. The catalyst is selected from Ruthenium and Osmium compounds.
摘要翻译：组合物，其包含（a）催化量的用于复分解聚合的单组分催化剂和（b）至少一种具有结合在聚合物主链中的应变亚链烯基的聚合物，单独或作为与应变环烯烃的混合物。组合物可以通过复分解聚合进行热或光化学聚合，并且适用于生产成形制品，涂层和浮雕图像。催化剂选自钌和锇化合物。

15. 发明申请

US20110159050A1 AMPHIPHILIC PROTEINS AS MORPHOLOGY MODIFIERS 审中-公开
标题翻译：大分子蛋白作为形态修饰剂
公开(公告)号：US20110159050A1
公开(公告)日：2011-06-30
申请号：US13002777
申请日：2009-06-23
申请人： Andreas Hafner , Andreas Buthe , Paul Adriaan Van Der Schaaf , Franz Kaufmann , Gordon Bradley
发明人： Andreas Hafner , Andreas Buthe , Paul Adriaan Van Der Schaaf , Franz Kaufmann , Gordon Bradley
IPC分类号： A61K9/14 , C07C233/25 , A61K31/167 , C07C233/65 , A61K31/166 , C07D207/34 , A61K31/40 , C07C215/64 , A61K31/137
CPC分类号： B01D9/005 , A61K9/1688 , C07K14/37
摘要： Disclosed is a process for modifying the morphology and/or polymorphism of an organic substance, which process comprises treating the solid substance, or a solution or dispersion thereof, with one or more amphiphilic proteins.
摘要翻译：公开了一种用于改变有机物质的形态和/或多态性的方法，该方法包括用一种或多种两亲性蛋白质处理固体物质或其溶液或分散体。

16. 发明授权

US06235856B1 Polymerization of dicyclopentadiene 失效
标题翻译：二环戊二烯的聚合
公开(公告)号：US06235856B1
公开(公告)日：2001-05-22
申请号：US08860268
申请日：1997-06-19
申请人： Andreas Hafner , Paul Adriaan Van Der Schaaf , Andreas Mühlebach
发明人： Andreas Hafner , Paul Adriaan Van Der Schaaf , Andreas Mühlebach
IPC分类号： C08F480
CPC分类号： C08G61/08 , B33Y70/00
摘要： Composition of (a) dicyclopentadiene, by itself or in a mixture with a strained cycloolefin, and (b) a catalytic amount of at least one carbene-free, divalent-cationic ruthenium or osmium compound as a single-component catalyst, which contains at least one phosphine group and a total of 2 to 5 ligands bonded to the metal atom, and which contains acid anions for charge balancing. The compositions can be polymerized by means of heat (metathesis polymerization) and are suitable for the production of shaped articles and coatings.
摘要翻译：（a）二环戊二烯本身或与应变环烯烃的混合物的组成，和（b）催化量的至少一种不含有无碳原子的二价阳离子钌或锇化合物作为单组分催化剂，其含有至少一个膦基和总共2至5个与金属原子键合的配体，并且其含有用于电荷平衡的酸阴离子。组合物可以通过热（易位聚合）聚合，并且适用于成型制品和涂料的生产。

17. 发明授权

US06306987B1 Ruthenium and osmium catalysts 有权
标题翻译：钌和锇催化剂
公开(公告)号：US06306987B1
公开(公告)日：2001-10-23
申请号：US09446052
申请日：1999-12-16
申请人： Paul Adriaan Van Der Schaaf , Andreas Hafner , Andreas Mühlebach
发明人： Paul Adriaan Van Der Schaaf , Andreas Hafner , Andreas Mühlebach
IPC分类号： C08F480
CPC分类号： B01J31/181 , B01J31/1825 , B01J31/2265 , B01J31/2282 , B01J31/24 , B01J31/2404 , B01J2231/14 , B01J2231/543 , B01J2531/821 , B01J2531/825 , C07F15/0013 , C07F15/002 , C08G61/08
摘要： Disclosed is a compound of formula (I), and its use in preparing metathesis polymers of dicyclopentadiene and/or other strained cycloolefins in which Me is ruthenium or osmium; X1 and X2 independently of one another are anionic ligands, or X1 and X2 together are a bis-anionic ligand; Y is oxygen, sulfur or the groups —NR7— or —PR7—, where R7 is hydrogen or a substituent selected from the group C1-C6alkyl, C6-C13aralkyl, sulfonyl and —C(═O)Rs2 and Rs2 is hydrogen or a substituent selected from the group C1-C12alkyl, C2-C12alkenyl, C3-C12cycloalkyl, C3-C12cycloalkenyl, C2-C11heterocycloalkyl, C2-C11heterocycloalkenyl, C5-C12aryl, C1-C9heteroaryl, C6-C14aralkyl, C2-C13heteroaralkyl, C6-C14aralkenyl and C3-C13heteroaralkenyl; n is 0 or 1; L1 is tertiary phosphine; and L2 is a neutral e− donor ligand which is coordinated to the metal atom and is attached via the bridge group C* to the carbon atom of the carbene group if n is 0 and to Y if n is 1.
摘要翻译：公开了式（I）化合物及其用于制备Me是钌或锇的二环戊二烯和/或其它应变环烯烃的复分解聚合物; X1和X2彼此独立的是阴离子配体，或者X1和X2一起是双 - 阴离子配体; Y是氧，硫或基团-NR7-或-PR7-，其中R7是氢或选自C1-C6烷基，C6-C13芳烷基，磺酰基和-C（= O）Rs2和Rs2 是选自C 1 -C 12烷基，C 2 -C 12烯基，C 3 -C 12环烷基，C 3 -C 12环烯基，C 2 -C 11杂环烷基，C 2 -C 11杂环烯基，C 5 -C 12芳基，C 1 -C 9杂芳基，C 6 -C 14芳烷基，C 2 -C 13杂芳烷基，C 6 -C14链烯基和C3-C13杂碳烯基; n为0或1; L1为叔膦; L2为与金属原子配位并通过桥基C *连接至卡宾的碳原子的中性e-供体配体如果n为0，则为组，如果n为1则为Y。

18. 发明授权

US06204347B1 Two-component catalyst for ROMP 失效
标题翻译： ROMP双组分催化剂
公开(公告)号：US06204347B1
公开(公告)日：2001-03-20
申请号：US09376453
申请日：1999-08-18
申请人： Andreas Hafner , Paul Adriaan Van Der Schaaf , Andreas Mühlebach
发明人： Andreas Hafner , Paul Adriaan Van Der Schaaf , Andreas Mühlebach
IPC分类号： C08F426
CPC分类号： C08G61/08 , B01J31/1805 , B01J31/185 , B01J31/2295 , B01J31/24 , B01J31/2404 , B01J2231/14 , B01J2531/821
摘要： A catalyst system for the ring-opening metathesis polymerization, which consists of at least two components (a) and (b), wherein (a) is a ruthenium compound of formula I or II RuX2(L1)m(L2)n(L3)o(L4)p (I), ARuX2(L1)r(L2)s (II), wherein L1, L2, L3 and L4 are each independently of the other C1-C18alkylcyanide, C8-C24-aralkylcyanide, tertiary amine, tertiary phosphine which does not contain any secondary alkyl or cycloalkyl radicals bound to the phosphorus atom, or phosphite, X is halogen, A is arene, m, n, o and p are integers from 0 to 4, where 2≦m+n+o+p≦4, r and s are integers from 0 to 2, where 1≦r+s≦2, and (b) is a tertiary phosphine containing at least one secondary alkyl radical or cycloalkyl radical bound to the phosphorus atom, is particularly suitable for the polymerization of strained cycloolefins by the RIM process.
摘要翻译：一种用于开环易位聚合的催化剂体系，其由至少两种组分（a）和（b）组成，其中（a）是式I或II的钌化合物，其中L1，L2，L3和L4各自独立地为不含任何与磷原子键合的仲烷基或环烷基的其它C1-C18烷基氰化物，C8-C24-芳烷基氰化物，叔胺，叔膦，或亚磷酸酯，X是卤素，A是芳烃，m，n，o和 p是从0到4的整数，其中2 <= m + n + o + p <= 4，r和s是从0到2的整数，其中1 <= r + s <= 2，（b）含有至少一个与磷原子键合的仲烷基或环烷基的叔膦特别适用于通过RIM方法聚合应变的环烯烃。

19. 发明授权

US06465554B1 Ruthenium and osmium carbene carbonyl catalysts 有权
标题翻译：钌和咔咔羰基催化剂
公开(公告)号：US06465554B1
公开(公告)日：2002-10-15
申请号：US09647031
申请日：2000-09-25
申请人： Paul Adriaan Van Der Schaaf , Roman Kolly , Andreas Mühlebach , Andreas Hafner
发明人： Paul Adriaan Van Der Schaaf , Roman Kolly , Andreas Mühlebach , Andreas Hafner
IPC分类号： C08K318
CPC分类号： C07F15/002 , C07F15/0046 , C08G61/06 , C08G61/08
摘要： The invention relates to compositions of hexacoordinated ruthenium and osmium carbenes with a carbonyl group as ligand and a vinyl group as substituent on the carbene group as catalysts for the photoinduced ring-opening metathesis of strained cycloolefins. It also relates to novel hexacoordinated ruthenium and osmium carbenes having a carbonyl group as ligand and a vinyl group as substituent on the carbene group, to compositions of the catalyst with cycloolefins, and to the polymerization process.
摘要翻译：本发明涉及六配位的钌和咔唑碳组合物，其中羰基作为配体，乙烯基作为卡宾的取代基，作为应变环烯烃的光诱导开环复分解的催化剂。它还涉及具有羰基作为配体和乙烯基作为卡宾基团上的取代基的新型六配位钌和咔啉，催化剂与环烯烃的组成以及聚合方法。

20. 发明授权

US06417363B1 Heterocyclyl ligand containing ruthenium and osmium catalysts 有权
标题翻译：含钌和锇催化剂的杂环配体
公开(公告)号：US06417363B1
公开(公告)日：2002-07-09
申请号：US09555308
申请日：2000-05-26
申请人： Paul Adriaan Van Der Schaaf , Andreas Mühlebach , Andreas Hafner , Roman Kolly
发明人： Paul Adriaan Van Der Schaaf , Andreas Mühlebach , Andreas Hafner , Roman Kolly
IPC分类号： B01J3124
CPC分类号： C08G61/06 , C07F15/002 , C07F15/0046
摘要： Penta- and hexa-coordinated, bridged ruthenium and osmium catalysts of the formula wherein Me is ruthenium or osmium; L1 and L2 are neutral ligands having electron donor properties; X is an anionic ligand; Y is oxygen or sulphur; A is a direct bond, C1-C4alkylene or C2-C4alkylidene; Z is a direct bond, oxygen, sulphur or the groups wherein R1 and R2 are hydrogen or hydrocarbon radicals; their preparation and their us in the synthesis of polymers, in the ring-closure metathesis of diolefins, in the cross metathesis of olefins and in the isomerisation of olefins are disclosed.
摘要翻译：锑化合物Me的五和六配位的桥联钌和锇催化剂是钌或锇; L1和L2是具有电子给体性质的中性配体; X是阴离子配体; Y是氧或硫; A是直接键，C1-C4亚烷基或C2-C4亚烷基; Z是直接键，氧，硫或其中R1和R2是氢或烃基的基团; 公开了它们在聚合物的合成，二烯烃的闭环复分解，烯烃的交叉复分解和烯烃异构化中的制备及其制备。

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