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11. 发明授权

US06284210B1 Combustion catalyst and combustion process using such a catalyst 失效
标题翻译：燃烧催化剂和使用这种催化剂的燃烧过程
公开(公告)号：US06284210B1
公开(公告)日：2001-09-04
申请号：US08857072
申请日：1997-05-15
申请人： Patrick Euzen , Eric Tocque , Stephane Rebours , Gil Mabilon
发明人： Patrick Euzen , Eric Tocque , Stephane Rebours , Gil Mabilon
IPC分类号： B01J802
CPC分类号： F23C13/00 , B01J23/894
摘要： A combustion catalyst comprising a monolithic substrate, a porous support based on refractory inorganic oxide and an active phase formed by cerium, iron and at least one metal selected from the group formed by palladium and platinum, the content of porous support being between 100 and 400 g per liter of catalyst; the content of cerium being between 0.3 and 20% by weight with respect to the porous support; the content of iron being between 0.01 and 3.5% of iron by weight with respect to the porous support; and the content of palladium and/or platinum being between 3 and 20 g per liter of catalyst. The catalyst of the invention is used in particular in processes for the catalytic combustion of hydrocarbons, carbon monoxide, hydrogen or mixtures thereof, in processes involving one or more catalytic stages.
摘要翻译：一种燃烧催化剂，其包含整体式基体，基于耐火无机氧化物的多孔载体和由铈，铁和选自钯和铂形成的基团中的至少一种金属形成的活性相，多孔载体的含量为100-400 g每升催化剂; 相对于多孔载体，铈的含量为0.3〜20重量％铁的含量相对于多孔载体为铁的重量的0.01％至3.5％; 钯和/或铂的含量为3至20克/升催化剂。本发明的催化剂特别用于烃，一氧化碳，氢气或其混合物的催化燃烧方法中，涉及一种或更多的催化阶段。

12. 发明授权

US5972204A Phosphorous-containing zeolite with structural type CON, its preparation and its use for catalytic cracking 失效
标题翻译：具有结构型CON的含磷沸石，其制备及其用于催化裂化
公开(公告)号：US5972204A
公开(公告)日：1999-10-26
申请号：US014424
申请日：1998-01-27
申请人： Avelino Corma Canos , Eric Benazzi , Herve Caufriez , Maria Jose Diaz Cabanas , Maria Sol Grande Casas , Miguel Angel Camblor Fernandez , Gil Mabilon
发明人： Avelino Corma Canos , Eric Benazzi , Herve Caufriez , Maria Jose Diaz Cabanas , Maria Sol Grande Casas , Miguel Angel Camblor Fernandez , Gil Mabilon
IPC分类号： B01J29/85 , B01J29/86 , B01J35/00 , C01B39/12 , C01B39/48 , C10G11/05 , B01J29/70
CPC分类号： C01B39/12 , B01J29/85 , B01J29/86 , B01J35/0006 , C01B39/48 , C10G11/05
摘要： A phosphorous-containing zeolite with structural type CON in its aluminosilicate or borosilicate form contains at most 10% by weight of phosphorous. A process for its preparation is described, starting from existing zeolites (SSZ-26, SSZ-33 or CIT-1) or from beta zeolites and an organic structuring agent or template which is 1-N,N,N-trimethyl adamantammonium hydroxide or 2-N,N,N-trimethyl adamantammonium hydroxide. The zeolite is used for catalytic cracking of hydrocarbon feeds.
摘要翻译：具有硅铝酸盐或硼硅酸盐形式的结构型CON的含磷沸石含有至多10重量％的磷。描述了其制备方法，从现有的沸石（SSZ-26，SSZ-33或CIT-1）或β沸石和作为1-N，N，N-三甲基金刚烷基氢氧化铵的有机结构剂或模板开始， 2-N，N，N-三甲基金刚烷基氢氧化铵。沸石用于烃进料的催化裂化。

13. 发明授权

US5108978A Multifunctional catalysts containing cerium, uranium and at least one other metal, for converting pollutants emitted by internal combustion engines, and their preparation 失效
标题翻译：含有CERIUM，URANIUM和至少一种其他金属的多功能催化剂，用于转换内燃机引发的污染物及其制备
公开(公告)号：US5108978A
公开(公告)日：1992-04-28
申请号：US527778
申请日：1990-05-24
申请人： Daniel Durand , Gil Mabilon , Philippe Courty , Richard Doziere
发明人： Daniel Durand , Gil Mabilon , Philippe Courty , Richard Doziere
IPC分类号： F01N3/28 , B01D53/86 , B01D53/94 , B01J23/56 , B01J23/63 , B01J23/66 , B01J29/06
CPC分类号： B01D53/945 , B01J23/63 , Y02T10/22
摘要： The invention concerns a multifunctional catalyst containing cerium, uranium and at least one metal, for converting pollutants emitted by internal combustion engines, and their preparation.A catalyst comprises a porous layer containingfrom about 20% to about 99% of at least one refractory oxidefrom about 0.8% to about 70% of at least one cerium oxidefrom about 0.1% to about 50% of at least one uranium oxidefrom about 0.1% to about 20% of a metal selected from the group made up of Pt, Rh, Pd, Ru, Ir and Au, and mixtures thereof.Applications are in the catalytic converter industry.
摘要翻译：本发明涉及含有铈，铀和至少一种金属的多功能催化剂，用于转化内燃机排放的污染物及其制备。催化剂包括含有约20％至约99％的至少一种难熔氧化物的至少一种耐火氧化物的多孔层，约0.8％至约70％的至少一种氧化铈约0.1％至约50％的至少一种氧化铀来自选自Pt，Rh，Pd，Ru，Ir和Au中的金属的约0.1％至约20％，以及它们的混合物。应用在催化转化器行业。

14. 发明申请

US20100041935A1 USE OF A CATALYST BASED ON ITQ-6 ZEOLITE TO ISOMERIZE AN AROMATIC C8 CUT 审中-公开
标题翻译：使用基于ITQ-6沸石的催化剂，以同化一种芳香C8 CUT
公开(公告)号：US20100041935A1
公开(公告)日：2010-02-18
申请号：US12302115
申请日：2007-05-10
申请人： Gil Mabilon , Emmanuelle Guillon , Eric Sanchez
发明人： Gil Mabilon , Emmanuelle Guillon , Eric Sanchez
IPC分类号： C07C5/22
CPC分类号： C10G45/62 , B01J23/42 , B01J27/045 , B01J29/70 , B01J37/14 , B01J37/18 , B01J2229/16 , C07C5/2708 , C10G45/64 , Y02P20/52 , C07C15/08
摘要： A process for isomerizing an aromatic C8 cut uses a catalyst which comprises: at least one ITQ-6 zeolite; at least one metal from group VIII of the periodic table; at least one binder; optionally, at least one metal selected from the group formed by elements from groups IIIA, IVA and VIIB of the periodic table; and optionally, sulphur.
摘要翻译：芳族C8馏分异构化的方法使用的催化剂包括：至少一种ITQ-6沸石; 至少一种元素周期表第VIII族金属; 至少一个粘合剂; 选自至少一种选自元素周期表IIIA，IVA和VIIB族元素形成的金属; 和任选的硫。

15. 发明授权

US06551564B1 Process for eliminating oxides of nitrogen 失效
标题翻译：消除氮氧化物的方法
公开(公告)号：US06551564B1
公开(公告)日：2003-04-22
申请号：US09707772
申请日：2000-11-08
申请人： Thierry Becue , Gil Mabilon , Philippe Villeret
发明人： Thierry Becue , Gil Mabilon , Philippe Villeret
IPC分类号： B01D5356
CPC分类号： B01J20/2808 , B01D53/02 , B01D53/9481 , B01D2255/1021 , B01D2255/2061 , B01D2255/207 , B01D2258/012 , B01J20/041 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/18 , B01J20/28057 , B01J20/28095 , B01J20/3078 , B01J20/3433 , B01J20/3483 , B01J23/02 , B01J23/34
摘要： The invention concerns materials for eliminating oxides of nitrogen NO and NO2 present in exhaust gases, in particular from the internal combustion engines of automotive vehicles operating in a medium which is super-stoichiometric in oxidising agents, which can adsorb oxides of nitrogen then desorb the oxides of nitrogen by elevating the temperature with respect to the adsorption temperature or by passage of rich mixture, said materials comprising mixed oxides the metals of which are in octahedral coordination, with the octahedra connecting together so that the structure generates micropores in the form of channels. These materials adsorb oxides of nitrogen by insertion and do not become poisoned in contact with oxides of sulphur and carbon contained in the gases. In the presence of a group VIII metal, these materials are capable of eliminating oxides of nitrogen absorded by reduction during passage of a rich mixture.
摘要翻译：本发明涉及用于消除废气中存在的氮和NO 2的氧化物的材料，特别是来自在氧化剂中超化学计量的介质中运行的机动车辆的内燃机，其可以吸附氮氧化物然后解吸氧化物的氮气通过相对于吸附温度升高或通过富混合物通过，所述材料包括其金属为八面体配位的混合氧化物，八面体连接在一起，使得该结构以通道的形式产生微孔。这些材料通过插入吸附氮的氧化物，并且不会与气体中所含的硫和碳的氧化物接触而中毒。在VIII族金属的存在下，这些材料能够消除富集混合物通过期间通过还原而被除去的氮的氧化物。

16. 发明授权

US06306286B1 IM-5 phosphorus zeolite, catalytic composition, its preparation and its use in catalytic cracking 有权
标题翻译： IM-5磷沸石，催化剂组成，其制备及其在催化裂化中的应用
公开(公告)号：US06306286B1
公开(公告)日：2001-10-23
申请号：US09569303
申请日：2000-05-11
申请人： Samuel Mignard , Avelino Corma Canos , Joaquin Martinez Triguero , Eric Benazzi , Sylvie Lacombe , Gil Mabilon
发明人： Samuel Mignard , Avelino Corma Canos , Joaquin Martinez Triguero , Eric Benazzi , Sylvie Lacombe , Gil Mabilon
IPC分类号： C01G1105
CPC分类号： C10G11/05 , B01J29/005 , B01J29/084 , B01J29/70 , B01J29/85 , B01J2229/183 , B01J2229/26 , B01J2229/30 , B01J2229/36 , B01J2229/42 , C01B39/026 , C10G2400/20
摘要： An IM-5 zeolite that is modified by adding phosphorus that is optionally dealuminified, preferably in aluminosilicic form, and that contains at most 10% by weight of phosphorus, a composition that contains it, its processes for preparation and its application to catalytic cracking of hydrocarbon feedstocks are described.
摘要翻译：通过添加任选脱磷的铝，优选以铝硅酸盐形式，并且含有至多10重量％的磷的磷，含有它的组合物，其制备方法及其在催化裂化中的应用而改性的IM-5沸石描述了烃原料。

17. 发明授权

US5736482A Catalysts for reducing nitrogen oxides to molecular nitrogen in a superstoichiometric medium of oxidizing compounds, process for preparation, and uses 失效
标题翻译：用于在氧化化合物的超化学计量介质中将氮氧化物还原成分子氮的催化剂，其制备方法和用途
公开(公告)号：US5736482A
公开(公告)日：1998-04-07
申请号：US598828
申请日：1996-02-05
申请人： Daniel Durand , Gil Mabilon , Paul Mouchot
发明人： Daniel Durand , Gil Mabilon , Paul Mouchot
IPC分类号： B01D53/86 , B01D53/94 , B01J21/00 , B01J23/63 , B01J23/64 , B01J23/656 , B01J23/68 , B01J23/83 , B01J23/89 , B01J29/44 , B01J37/02 , B01J23/00 , B01J8/00 , B01J23/02
CPC分类号： B01J37/0205 , B01D53/9418 , B01J23/63 , B01J23/83 , B01D2255/1021 , B01D2255/1023 , B01D2255/204 , B01D2255/2063 , B01D2255/2066 , B01D2255/20746 , B01D2255/504 , B01D2255/9202 , B01D2255/9207 , B01D2258/012 , Y02C20/10
摘要： Described is catalyst that is active and selective for reducing to molecular nitrous oxides contained in a superstoichiometric medium of oxidizing agents, said reduction being conducted with agents such as carbon monoxide, hydrogen, hydrocarbons, alcohols, ethers, and other oxidized organic compounds and also with ordinary fuels such as gasolines, gas oils, liquefied gases, and compressed natural gases, whereby said catalyst comprises: at least one refractory inorganic oxide, including alumina; at least one element (A) that belongs to the group of rare earths; at least one element (B) that belongs to groups VIB, VIIB, VIII and IB of transition metals; at least one metal (C) that belongs to the group of precious metals of the platinum family, and optionally at least one element (D) that belongs to group IIA of alkaline-earths; at least a portion of elements (A) is combined with alumina to form at the surface of the latter a microlayer of rare-earth aluminate.
摘要翻译：描述了对氧化剂的超化学计量介质中含有的还原成分子氧化物的活性和选择性的催化剂，所述还原是用试剂如一氧化碳，氢，烃，醇，醚和其它氧化的有机化合物进行还原，普通燃料如汽油，瓦斯油，液化气体和压缩天然气，其中所述催化剂包括：至少一种耐火无机氧化物，包括氧化铝; 至少一种属于稀土元素的元素（A）; 属于过渡金属组VIB，VIIB，VIII和IB的至少一种元素（B）; 至少一种属于铂族贵族金属的金属（C）和任选的至少一种属于碱土金属IIA族的元素（D）; 元素（A）的至少一部分与氧化铝组合，在其表面形成稀土铝酸盐的微层。

18. 发明授权

US4628130A Process for producing alcohols by hydrogenolysis of carboxylic acid esters in the presence of a catalyst containing nickel and tin, germanium or lead 失效
标题翻译：在含有镍和锡，锗或铅的催化剂存在下，通过羧酸酯的氢解制备醇的方法
公开(公告)号：US4628130A
公开(公告)日：1986-12-09
申请号：US763596
申请日：1985-08-08
申请人： Jean-Paul Bournonville , Jean-Pierre Candy , Gil Mabilon
发明人： Jean-Paul Bournonville , Jean-Pierre Candy , Gil Mabilon
IPC分类号： C07C29/136 , B01J23/00 , B01J23/825 , B01J23/835 , C07B31/00 , C07B41/02 , C07B61/00 , C07C27/00 , C07C29/149 , C07C31/02 , C07C67/00 , C07C37/055
CPC分类号： C07C29/149 , Y02P20/52
摘要： The invention has as an object the production of alcohols by hydrogenolysis of carboxylic acid esters, under hydrogen pressure, in the presence of a catalyst resulting from the incorporation of at least one compound of at least one metal from the group consisting of germanium, tin and lead to Raney nickel or to a nickel-containing carrier. The reaction is preferably conducted at a temperature from 180.degree. to 330.degree. C. and under a pressure from 1 to 10 MPa.
摘要翻译：本发明的目的是通过在氢气压力下，在催化剂存在下，通过羧酸酯的氢解来生产醇，所述催化剂是由至少一种至少一种由锗，锡和导致阮内镍或含镍载体。反应优选在180至330℃的温度和1至10MPa的压力下进行。

19. 发明申请

US20080207437A1 Platinum-based, bimetallic catalyst, and a second group VIII metal used for the opening of cyclic compounds 失效
标题翻译：铂金双金属催化剂和用于开环的化合物的第二族Ⅷ族金属
公开(公告)号：US20080207437A1
公开(公告)日：2008-08-28
申请号：US11979637
申请日：2007-11-06
申请人： Gil Mabilon , Patrice Marecot , Denis Uzio , Catherine Especel , Florence Epron
发明人： Gil Mabilon , Patrice Marecot , Denis Uzio , Catherine Especel , Florence Epron
IPC分类号： B01J23/42 , B01J23/46 , B01J27/13 , C07C5/00
CPC分类号： B01J23/42 , B01J21/04 , B01J23/464 , B01J23/89 , B01J37/0205 , B01J37/06 , B01J37/16 , C07C5/31 , C07C2521/04 , C07C2523/42 , C07C2523/46 , C07C2527/13 , C10G45/62 , C07C9/14
摘要： A description is given of a catalyst comprising at least one porous support, at least some platinum, and at least a second group VIII metal which is different from platinum and iridium, said catalyst having been prepared in accordance with a process comprising a) impregnation of the support with at least one solution containing a platinum precursor, b) activation in a neutral or oxidising atmosphere, at a temperature of between 120 and 800° C., c) activation in a reducing medium, at a temperature of between 0 and 800° C., d1) impregnation with an aqueous solution and d2) treatment with at least one hydrogen donor compound, at a temperature of less than 200° C., e) the impregnation of the support, which has already been impregnated with the platinum, with at least one solution containing a precursor of said second group VIII metal, and f) activation in a neutral, reducing, or oxidising atmosphere, at a temperature of between 100 and 800° C.
摘要翻译：给出了包含至少一种多孔载体，至少一些铂和至少一种与铂和铱不同的第Ⅷ族金属的催化剂的描述，所述催化剂是按照以下方法制备的：a）将含有至少一种含有铂前体的溶液的载体，b）在中性或氧化性气氛中在120〜800℃的温度下活化，c）在还原介质中在0〜800℃的温度下进行活化 ℃），d1）用水溶液浸渍，和d2）在低于200℃的温度下用至少一种氢供体化合物处理，e）已经浸渍有铂的载体的浸渍与至少一种含有所述第二族VIII族金属的前体的溶液，和f）在中性，还原性或氧化性气氛中在100至800℃的温度下活化。

20. 发明授权

US06797247B2 Material with a channel structure for eliminating oxides of nitrogen 失效
标题翻译：具有消除氮氧化物的通道结构的材料
公开(公告)号：US06797247B2
公开(公告)日：2004-09-28
申请号：US10141785
申请日：2002-05-10
申请人： Thierry Becue , Gil Mabilon , Philippe Villeret
发明人： Thierry Becue , Gil Mabilon , Philippe Villeret
IPC分类号： B01D5356
CPC分类号： B01J20/2808 , B01D53/02 , B01D53/9481 , B01J20/041 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/18 , B01J20/28057 , B01J20/28095 , B01J20/3078 , B01J20/3433 , B01J20/3483 , B01J23/02 , B01J23/34
摘要： The invention concerns materials for eliminating oxides of nitrogen NO and NO2 present in exhaust gases, in particular from the internal combustion engines of automotive vehicles operating in a medium that is super-stoichiometric in oxidizing agents, which can adsorb oxides of nitrogen then desorb the oxides of nitrogen by elevating the temperature with respect to the adsorption temperature or by passage of a rich mixture, the materials comprising mixed oxides the metals of which are in octahedral co-ordination, with the octahedra connecting together so that the structure generates micropores in the form of channels. The channel width of the materials is such that the sides are composed of 2 and/or 3 octahedra. These materials adsorb oxides of nitrogen by insertion and do not become poisoned in contact with oxides of sulfur and carbon contained in the gases. In the presence of a group VIII metal or another suitable element such as iron, zinc or aluminum, these materials are capable of eliminating oxides of nitrogen adsorbed by reduction during passage of a rich mixture.
摘要翻译：本发明涉及用于消除废气中NO，NO 2的氧化物的材料，特别是从在氧化剂中超化学计量的介质中操作的机动车的内燃机中，其可以吸附氮氧化物，然后解吸氧化物的氮气通过相对于吸附温度升高温度或通过富混合物通过，其中包含其金属为八面体配位的混合氧化物的材料与八面体连接在一起，使得该结构产生形式的微孔的渠道。材料的通道宽度使得侧面由2和/或3个八面体组成。这些材料通过插入吸附氮的氧化物，并且不会与气体中所含的硫和碳的氧化物接触而中毒。在第VIII族金属或其他合适的元素如铁，锌或铝的存在下，这些材料能够通过富集混合物通过期间的还原而除去吸附的氮的氧化物。

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