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11. 发明授权

US4507448A Process for the production of polyolefins 失效
标题翻译：生产聚烯烃的方法
公开(公告)号：US4507448A
公开(公告)日：1985-03-26
申请号：US374627
申请日：1982-05-04
申请人： Nobuyuki Kuroda , Toru Nakamura , Yutaka Shikatani , Kazuo Matsuura , Mitsuji Miyoshi
发明人： Nobuyuki Kuroda , Toru Nakamura , Yutaka Shikatani , Kazuo Matsuura , Mitsuji Miyoshi
IPC分类号： C08F4/00 , C08F4/50 , C08F4/58 , C08F4/60 , C08F4/62 , C08F4/64 , C08F10/00 , C08F4/02
CPC分类号： C08F10/00 , Y10S526/901 , Y10S526/906
摘要： A process for the homopolymerization or copolymerization of olefins is disclosed, which is carried out in the presence of a catalyst system comprising the combination of at least one organometallic compound with a component resulting from the reaction of (a) a magnesium halide, (b) a compound represented by the formula, Al(OR).sub.n X.sub.3-n, where R is a hydrocarbon residual group having 1 to 20 carbon atoms, X is a hydrogen atom, and n is 0.ltoreq.n.ltoreq.3, (c) a compound represented by the formula, Si(OR').sub.m X.sub.4-m, where R' is a hydrocarbon residual group having 1 to 20 carbon atoms, X is a halogen atom, and m is 0.ltoreq.m.ltoreq.4, and (d) a titanium compound and/or a vanadium compound. The resulting polymers have a large bulk density and a narrow range of molecular weight distribution.
摘要翻译：公开了一种用于烯烃均聚或共聚的方法，该催化剂体系包括至少一种有机金属化合物与由（a）卤化镁反应得到的组分的组合的催化剂体系，（b）由式Al（OR）nX3-n表示的化合物，其中R是具有1至20个碳原子的烃残基，X是氢原子，n是0

12. 发明授权

US4315999A Process for preparing polyolefins 失效
标题翻译：聚烯烃的制备方法
公开(公告)号：US4315999A
公开(公告)日：1982-02-16
申请号：US189823
申请日：1980-09-23
申请人： Kazuo Matsuura , Takeichi Shiraishi , Etsuo Kawamata , Nobuyuki Kuroda , Mituji Miyoshi
发明人： Kazuo Matsuura , Takeichi Shiraishi , Etsuo Kawamata , Nobuyuki Kuroda , Mituji Miyoshi
IPC分类号： C08F4/02 , C08F4/65 , C08F4/76 , C08F10/00
CPC分类号： C08F10/00 , C08F4/022 , C08F2410/04 , Y10S526/906
摘要： An olefin is polymerized using a catalyst obtained by contacting (1) at least one of silicon or aluminum dioxide, (2) a compound of the formula ROH wherein R is a hydrocarbon radical having 1 to 20 carbon atoms, and (3) a substance obtained by supporting a titanium or a vanadium compound on a magnesium or manganese halide.
摘要翻译：使用通过使（1）硅或二氧化铝中的至少一种与（2）式ROH的化合物（其中R是具有1至20个碳原子的烃基）的化合物和（3）物质通过在镁或锰卤化物上负载钛或钒化合物获得。

13. 发明授权

US4076923A Process for preparing polyolefins 失效
标题翻译：聚烯烃的制备方法
公开(公告)号：US4076923A
公开(公告)日：1978-02-28
申请号：US669299
申请日：1976-03-22
申请人： Kazuo Matsuura , Masaomi Matsuzaki , Fumiaki Oshimi , Nobuyuki Kuroda , Mituji Miyoshi
发明人： Kazuo Matsuura , Masaomi Matsuzaki , Fumiaki Oshimi , Nobuyuki Kuroda , Mituji Miyoshi
IPC分类号： C08F4/00 , C08F4/60 , C08F4/64 , C08F10/00 , C08F10/10 , C08F4/02 , C08F10/02
CPC分类号： C08F10/00 , C08F10/10
摘要： According to the present invention, there is provided a process for preparing polyolefins which comprises polymerizing or copolymerizing olefins using as catalyst a component consisting of a solid carrier and a titanium compound and/or a vanadium compound supported thereon, and an organometallic compound, said solid carrier consisting of a product obtained by mixing and heating an aluminum oxide and an ammonium sulfate.
摘要翻译：根据本发明，提供了一种制备聚烯烃的方法，其包括使用作为催化剂的烯烃聚合或共聚烯烃，所述组分由固体载体和/或其上负载的钒化合物和/或有机金属化合物组成，所述固体载体由通过混合和加热氧化铝和硫酸铵获得的产物组成。

14. 发明授权

US4414369A Continuous process for the preparation of polyolefins having widely distributed molecular weights 失效
标题翻译：用于制备具有广泛分布分子量的聚烯烃的连续方法
公开(公告)号：US4414369A
公开(公告)日：1983-11-08
申请号：US138104
申请日：1980-04-07
申请人： Nobuyuki Kuroda , Tatsuo Horie , Kazuo Matsuura , Kunimichi Kubo , Mituji Miyoshi
发明人： Nobuyuki Kuroda , Tatsuo Horie , Kazuo Matsuura , Kunimichi Kubo , Mituji Miyoshi
IPC分类号： C08F10/00 , C08F2/14 , C08F4/66
CPC分类号： C08F10/00 , Y10S526/905
摘要： Polyolefins having a wide distribution of molecular weights are prepared in a plural stage process, by initially polymerizing the olefins in the presence of a solvent, hydrogen and a highly active Ziegler type catalyst under pressure, and beneath a gas phase containing an inert gas, to form in the first stage a polymer having a relatively high molecular weight. The polymerization reaction mixture from the first stage is continuously flowed to a second stage reactor. The second stage reactor is maintained at a relatively lower pressure, such that the flow is driven by the higher pressure in the first stage. The second stage is agitated and the polymerization reaction mixture is maintained beneath an atmosphere containing olefins and hydrogen gas. Polymers of relatively low molecular weight are formed in the second stage. The product continuously removed from the second stage contains a polymer having a wide distribution of molecular weight.
摘要翻译：通过在溶剂，氢气和高活性齐格勒型催化剂的存在下，在压力下，在含有惰性气体的气相之下，在烯烃存在下，首先使烯烃聚合，在多级方法中制备分子量分布广泛的聚烯烃，在第一阶段形成具有相对较高分子量的聚合物。将来自第一阶段的聚合反应混合物连续流入第二级反应器。第二级反应器保持在相对较低的压力下，使得流在第一级中被较高的压力驱动。搅拌第二阶段，聚合反应混合物保持在含有烯烃和氢气的气氛下。在第二阶段形成相对低分子量的聚合物。从第二阶段连续除去的产物含有分子量分布广泛的聚合物。

15. 发明授权

US3991260A Process for preparing polyolefins 失效
标题翻译：聚烯烃的制备方法
公开(公告)号：US3991260A
公开(公告)日：1976-11-09
申请号：US512989
申请日：1974-10-07
申请人： Kazuo Matsuura , Nobuyuki Kuroda , Takeichi Shiraishi , Mituji Miyoshi
发明人： Kazuo Matsuura , Nobuyuki Kuroda , Takeichi Shiraishi , Mituji Miyoshi
IPC分类号： C08F4/02 , C08F4/638 , C08F4/68 , C08F10/00 , C08F110/02 , C08F210/16 , C08F10/02
CPC分类号： C08F10/00 , C08F4/022 , Y10S526/906
摘要： Process for preparing polyolefins by polymerizing or copolymerizing olefins in the presence of an organometallic compound and a catalyst comprising magnesium, titanium and aluminum or magnesium, vanadium and aluminum, the catalysts being prepared by copulverizing a magnesium dihalide, an aluminum alkoxide and a titanium or vanadium compound.
摘要翻译：通过在有机金属化合物和包含镁，钛和铝或镁，钒和铝的催化剂存在下聚合或共聚烯烃制备聚烯烃的方法，催化剂是通过将二卤化镁，铝醇盐和钛或钒复合。

16. 发明授权

US4410670A Process for preparing polyolefins 失效
标题翻译：聚烯烃的制备方法
公开(公告)号：US4410670A
公开(公告)日：1983-10-18
申请号：US45961
申请日：1979-06-06
申请人： Yoshio Tajima , Kazuo Matsuura , Nobuyuki Kuroda , Mituji Miyoshi
发明人： Yoshio Tajima , Kazuo Matsuura , Nobuyuki Kuroda , Mituji Miyoshi
IPC分类号： C08F10/00 , C08F4/66
CPC分类号： C08F10/00
摘要： This invention provides a process for preparing polyolefins using a new catalyst. According to this invention, .alpha.-olefins can be polymerized or copolymerized to have good stereoregularity and at a high activity by the use of such new catalyst. The new catalyst used in this invention consists of [A] a solid component obtained by contacting (1) a magnesium oxide, (2) an aluminum trihalide, (3) a hydroxy compound represented by the general formula ROH wherein R is an organic radical having 1 to 20 carbon atoms and (4) a titanium halide and/or an addition product of a titanium halide and an aromatic carboxylic acid ester, and [B] an organometallic compound and/or an addition product of an organometallic compound and an aromatic carboxylic acid ester; or it consists of the solid component of the above [A], the organometallic compound and/or the addition product of an organometallic compound and an aromatic carboxylic acid ester of the above [B], and [C] an aromatic carboxylic acid ester. The said catalyst is prepared, in one of the most preferred embodiments thereof, by using the solid component of the above [A] which is obtained by first co-pulverizing the compounds of the above (1),(2) and (3), then washing the co-pulverized product with an aromatic compound, separating the liquid phase to give a solid substance (a) and contacting the latter with the compound and/or the addition product of the above (4).
摘要翻译：本发明提供使用新催化剂制备聚烯烃的方法。根据本发明，通过使用这种新的催化剂，α-烯烃可以聚合或共聚以具有良好的立构规整性和高活性。本发明中使用的新型催化剂由[A]一种固体组分组成，该固体组分通过使（1）氧化镁，（2）三卤化铝，（3）由通式ROH表示的羟基化合物，其中R是有机基团具有1至20个碳原子和（4）卤化钛和/或卤化钛和芳族羧酸酯的加成产物，和[B]有机金属化合物和/或有机金属化合物和芳族化合物的加成产物羧酸酯; 或者由上述[A]的固体组分，有机金属化合物和/或上述[B]的有机金属化合物和芳族羧酸酯的加成产物和[C]芳族羧酸酯组成。所述催化剂在其最优选的实施方案之一中，通过使用上述[A]的固体成分，其是通过首先共混上述（1），（2）和（3）的化合物而获得的，，然后用芳族化合物洗涤共粉碎产物，分离液相，得到固体物质（a），并使其与上述（4）的化合物和/或加成产物接触。

17. 发明授权

US4209602A Process for the production of polyolefins 失效
标题翻译：生产聚烯烃的方法
公开(公告)号：US4209602A
公开(公告)日：1980-06-24
申请号：US887009
申请日：1978-03-16
申请人： Nobuyuki Kuroda , Takeichi Shiraishi , Akio Itoh , Kazuo Matsuura , Mituji Miyoshi
发明人： Nobuyuki Kuroda , Takeichi Shiraishi , Akio Itoh , Kazuo Matsuura , Mituji Miyoshi
IPC分类号： C08F4/02 , C08F10/00 , C08F10/02
CPC分类号： C08F10/00 , C08F4/022 , Y10S526/906
摘要： The present invention discloses improved catalysts for polymerizing or copolymerizing olefins and a process for the production of polyolefins comprising a polymerization or copolymerization of olefins by the use of said catalysts. According to the invention there is provided a process for the production of polyolefins by polymerizing or copolymerizing olefins using as the catalyst a solid component containing a titanium compound and/or a vanadium compound and an organometallic compound, said solid component comprising a substance obtained by co-pulverizing (1) a metal halide selected from the group consisting of magnesium halides and manganese halides, (2) a compound represented by the general formula Mg(OR).sub.n X.sub.2-n in which n is a number of the range 0
摘要翻译：本发明公开了用于聚合或共聚烯烃的改进的催化剂和用于生产聚烯烃的方法，其包括通过使用所述催化剂聚合或共聚烯烃。根据本发明，提供了一种通过使用作为催化剂使含有钛化合物和/或钒化合物和有机金属化合物的固体组分作为催化剂聚合或共聚烯烃的方法，所述固体组分包含通过共聚物获得的物质粉碎（1）选自卤化镁和卤化锰的金属卤化物，（2）由通式Mg（OR）nX2-n表示的化合物，其中n是0

18. 发明授权

US4396534A Olefin polymerizing catalyst 失效
标题翻译：烯烃聚合催化剂
公开(公告)号：US4396534A
公开(公告)日：1983-08-02
申请号：US360662
申请日：1982-03-22
申请人： Kazuo Matsuura , Takeichi Shiraishi , Etsuo Kawamata , Mitsuo Okamoto , Nobuyuki Kuroda , Mituji Miyoshi
发明人： Kazuo Matsuura , Takeichi Shiraishi , Etsuo Kawamata , Mitsuo Okamoto , Nobuyuki Kuroda , Mituji Miyoshi
IPC分类号： C08F4/00 , C08F4/60 , C08F4/62 , C08F4/64 , C08F10/00
CPC分类号： C08F10/00
摘要： In an olefin polymerizing catalyst comprising a solid catalyst component and an organometallic compound, there is used, as the solid catalyst component, a substance obtained by contacting and reacting the following compounds with one another:(1) a silicon oxide and/or an aluminum oxide,(2) a magnesium halide,(3) a compound represented by the general formula Me(OR).sub.n X.sub.z--n wherein Me is an element belonging to Groups I through IV in the Periodic Table, z is the valence of the element Me, n is 0
摘要翻译：在包含固体催化剂组分和有机金属化合物的烯烃聚合催化剂中，使用通过使下列化合物彼此接触和反应获得的物质作为固体催化剂组分：（1）氧化硅和/或铝氧化物，（2）卤化镁，（3）由通式Me（OR）n Xz-n表示的化合物，其中Me是元素周期表中第I至IV族的元素，z是元素Me的化合价，n为0

19. 发明授权

US4252929A Process for preparing polyolefins 失效
标题翻译：聚烯烃的制备方法
公开(公告)号：US4252929A
公开(公告)日：1981-02-24
申请号：US97791
申请日：1979-11-27
申请人： Nobuyuki Kuroda , Takeichi Shiraishi , Akio Itoh , Kazuo Matsuura , Mituji Miyoshi
发明人： Nobuyuki Kuroda , Takeichi Shiraishi , Akio Itoh , Kazuo Matsuura , Mituji Miyoshi
IPC分类号： C08F4/00 , C08F4/02 , C08F4/60 , C08F4/64 , C08F10/00 , C08F10/02
CPC分类号： C08F10/00 , C08F4/022 , Y10S526/906
摘要： According to the present invention, there is provided a process for preparing polyolefins comprising polymerizing or copolymerizing olefins using as catalyst a titanium-containing solid and an organometallic compound of a metal of Groups I to IV of the Periodic Table, said titanium-containing solid consisting of a reaction product obtained by copulverizing (1) a magnesium halide and/or a manganese halide, (2) an organohalide and (3) a tetravalent and/or a trivalent titanium compound(s).
摘要翻译：根据本发明，提供了一种制备聚烯烃的方法，其包括使用含钛固体和周期表第I至IV族金属的有机金属化合物作为催化剂聚合或共聚烯烃，所述含钛固体包括通过共混（1）卤化镁和/或卤化锰得到的反应产物，（2）有机卤化物和（3）四价和/或三价钛化合物。

20. 发明授权

US4209601A Process for the production of polyolefins 失效
标题翻译：生产聚烯烃的方法
公开(公告)号：US4209601A
公开(公告)日：1980-06-24
申请号：US887008
申请日：1978-03-16
申请人： Nobuyuki Kuroda , Takeichi Shiraishi , Akio Itoh , Kazuo Matsuura , Mituji Miyoshi
发明人： Nobuyuki Kuroda , Takeichi Shiraishi , Akio Itoh , Kazuo Matsuura , Mituji Miyoshi
IPC分类号： C08F4/02 , C08F10/00 , C08F10/02
CPC分类号： C08F10/00 , C08F4/022 , Y10S526/906
摘要： The present invention discloses improved catalysts for polymerizing or copolymerizing olefins and a process for the production of polyolefins comprising a polymerization or copolymerization of olefins by the use of said catalysts. According to the invention there is provided a process for the production of polyolefins by polymerizing or copolymerizing olefins using as the catalyst a solid component containing a titanium compound and/or a vanadium compound and an organometallic compound, said solid component comprising a substance obtained by co-pulverizing (1) a metal halide selected from the group consisting of magnesium halides and manganese halides, (2) a compound represented by the general formula B(OR).sub.n X.sub.3-n X3 in which n is a number of the range 0
摘要翻译：本发明公开了用于聚合或共聚烯烃的改进的催化剂和用于生产聚烯烃的方法，其包括通过使用所述催化剂聚合或共聚烯烃。根据本发明，提供了一种通过使用作为催化剂使含有钛化合物和/或钒化合物和有机金属化合物的固体组分作为催化剂聚合或共聚烯烃的方法，所述固体组分包含通过共聚物获得的物质粉碎（1）选自卤化镁和卤化锰的金属卤化物，（2）由通式B（OR）nX3-n X3表示的化合物，其中n是0

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