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11. 发明专利

JP2008264897A Hollow fiber type organic nanotube intercalated with low-molecular organic compound and method for producing the same 有权
标题翻译：中空纤维型有机纳米管与低分子有机化合物的交联及其制造方法
公开(公告)号：JP2008264897A
公开(公告)日：2008-11-06
申请号：JP2007107999
申请日：2007-04-17
申请人： National Institute Of Advanced Industrial & Technology , 独立行政法人産業技術総合研究所
发明人： ASAKAWA MASUMI , KAMEDA NAOHIRO , OGISO MAKI , MASUDA MITSUTOSHI , SHIMIZU TOSHIMI
IPC分类号： B82B1/00 , A61K47/36 , A61K47/42 , B82B3/00
CPC分类号： A61K9/1274 , A61K47/6919 , C07F9/106
摘要： PROBLEM TO BE SOLVED: To provide a clathrate enclosing an organic compound larger than 1 nm in a size, which can not be enclosed by a conventional cyclodextrin, and smaller than 3 nm in a size, which can not be stably enclosed by a hollow fiber type organic nanotube, and a method for producing the same. SOLUTION: A low-molecular organic compound combined with a glycolipid or a peptide-lipid is dissolved in a single solvent or a mixed solvent prepared by mixing some kinds of solvents, and a solution is allowed to stand still at room temperature or concentrated for self-assembly to form the hollow fiber type organic nanotube intercalated with the low-molecular organic compound in which the low-molecular organic compound is intercalated in a lipid bimolecular membrane composing the hollow fiber type organic nanotube. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供一种包围大于1nm的有机化合物的包合物，其尺寸不能被常规环糊精包围，并且尺寸小于3nm，不能被稳定地包围中空纤维型有机纳米管及其制造方法。解决方案：将与糖脂或肽 - 脂质组合的低分子有机化合物溶解在单一溶剂或通过混合某些溶剂制备的混合溶剂中，并将溶液在室温下静置，或集中用于自组装形成插入了低分子有机化合物的中空纤维型有机纳米管，其中低分子有机化合物插入构成中空纤维型有机纳米管的脂质双分子膜中。版权所有（C）2009，JPO＆INPIT

12. 发明专利

JP2005096014A Method of cutting fibrous self-aggregate 审中-公开
标题翻译：切割纤维自聚合的方法
公开(公告)号：JP2005096014A
公开(公告)日：2005-04-14
申请号：JP2003331309
申请日：2003-09-24
申请人： Japan Science & Technology Agency , National Institute Of Advanced Industrial & Technology , 独立行政法人産業技術総合研究所 , 独立行政法人科学技術振興機構
发明人： YO HIROSHI , SHIMIZU TOSHIMI , KAMIYA MASAKO
IPC分类号： B82B3/00 , A61K47/26
摘要： PROBLEM TO BE SOLVED: To reduce an aspect ratio by cutting a fibrous self-aggregate with a high aspect ratio by a simple means without breaking the basic structure of the assembly.
SOLUTION: A liquid medium containing the fibrous self-aggregate is agitated to cut the soft and long fibrous self-aggregate with the high aspect ratio by the turbulent flow of water. In a method of cutting the fibrous self-aggregate by agitating the liquid medium containing the fibrous self-aggregate, the aspect ratio of the fibrous self-aggregate before the execution of the method is 100 or more, and after the execution of the method, the aspect ratio of the fibrous self-aggregate is 100 or less, and the length is 10 μm or less.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：为了通过简单的方式通过以高纵横比切割纤维自聚集体来减小纵横比，而不破坏组件的基本结构。解决方案：搅拌含有纤维自聚集体的液体介质，通过水的湍流以高纵横比切割软和长纤维自聚集体。在通过搅拌含有纤维自聚集体的液体介质切割纤维状自聚集体的方法中，在方法执行之前纤维自聚集体的纵横比为100以上，在该方法执行之后，纤维状自聚集体的纵横比为100以下，长度为10μm以下。版权所有（C）2005，JPO＆NCIPI

13. 发明专利

JP2004083725A Noncovalent bond-type polymer using metal porphyrin complex having two crown ethers as binding molecule, and method for producing noncovalent bond-type polymer 有权
公开(公告)号：JP2004083725A
公开(公告)日：2004-03-18
申请号：JP2002246079
申请日：2002-08-27
申请人： National Institute Of Advanced Industrial & Technology , 独立行政法人産業技術総合研究所
发明人： ASAKAWA MASUMI , YAMANISHI HIROKO , SHIMIZU TOSHIMI
IPC分类号： C07D487/22 , C07C237/40 , C08G83/00
摘要： PROBLEM TO BE SOLVED: To provide a new macromolecular compound using two intermolecular interactions of metal coordination interaction and hydrogen bond interaction as a coupling scheme.
SOLUTION: The noncovalent bond-type polymer is represented by the general formula (wherein, M is a transition metal coordinating with four nitrogen atoms and two nitrogen atoms included in Q; Q is a functional group selected from the group consisting of a nitrogen-containing heterocyclic compound coordinatable with a metal, and a group consisting of an aromatic amine; P is a group selected from an aliphatic hydrocarbon and an aromatic hydrocarbon; R is a group selected from an aliphatic hydrocarbon which may be substituted with an ester group, an ether group or a tert-butyl group, and an aromatic hydrocarbon; Y is a group selected from an aliphatic hydrocarbon and an aromatic hydrocarbon; and X is an arbitrary anion).
COPYRIGHT: (C)2004,JPO

14. 发明专利

JP2004083472A Compound prepared by bonding two molecules of crown ether derivative containing crown ether derivative and secondary ammonium salt and its production method 有权
公开(公告)号：JP2004083472A
公开(公告)日：2004-03-18
申请号：JP2002246061
申请日：2002-08-27
申请人： National Institute Of Advanced Industrial & Technology , 独立行政法人産業技術総合研究所
发明人： ASAKAWA MASUMI , HIRAMOTO MAYUMI , SHIMIZU TOSHIMI
IPC分类号： C07D323/00
摘要： PROBLEM TO BE SOLVED: To provide a compound which has substituents capable of forming new noncovalent bonds and can be used in producing a noncovalently bonded polymer and a mechanically bonded polymer.
SOLUTION: The compound prepared by bonding two molecules of a crown ether derivative is anyone represented by the formula. In the formula, R is a reactive substituent; Q is a substituent; X is an arbitrary atomic or molecular anion, provided that R has such a structure that R is smaller than the inside diameter of dibenzo-24-crown-8-ether and is therefore can pass through the crown ether ring.
COPYRIGHT: (C)2004,JPO

15. 发明专利

JP2004083471A Noncovalently bonded aggregate and its production method 有权
标题翻译：非常粘结聚集体及其生产方法
公开(公告)号：JP2004083471A
公开(公告)日：2004-03-18
申请号：JP2002246059
申请日：2002-08-27
申请人： National Institute Of Advanced Industrial & Technology , 独立行政法人産業技術総合研究所
发明人： ASAKAWA MASUMI , HIRAMOTO MAYUMI , SHIMIZU TOSHIMI
IPC分类号： C07D323/00
摘要： PROBLEM TO BE SOLVED: To provide a noncovalently bonded aggregate and to provide its production method.
SOLUTION: The noncovalently bonded aggregate produced from a combination of a mixture of three isomers shown is represented by the formula. In the formula, Q is a substituent; and X is an arbitrary atomic or molecular anion. The aggregate comprises a mixture of three isomers (wherein l, m, and n are arbitrary numbers and can form any combination on condition that their sum is 5 or larger).
COPYRIGHT: (C)2004,JPO
摘要翻译：要解决的问题：提供非共价结合的骨料并提供其生产方法。解决方案：由所示的三种异构体的混合物的组合产生的非共价键合的聚集体由下式表示。在该式中，Q是取代基; X是任意的原子或分子阴离子。聚集体包含三种异构体的混合物（其中l，m和n是任意数，并且可以在其和为5或更大的条件下形成任何组合）。版权所有（C）2004，JPO

16. 发明专利

JP2003049154A Hydrogel-forming agent derived from sugar 有权
标题翻译：糖衍生的水凝胶剂
公开(公告)号：JP2003049154A
公开(公告)日：2003-02-21
申请号：JP2001239014
申请日：2001-08-07
申请人： Japan Science & Technology Corp , National Institute Of Advanced Industrial & Technology , 独立行政法人産業技術総合研究所 , 科学技術振興事業団
发明人： JONHOA JON , GEORGE JOHN , SHIMIZU TOSHIMI
IPC分类号： C07B61/00 , C07H15/203 , C09K3/00
CPC分类号： C07H15/203 , C09K3/00 , C40B40/00
摘要： PROBLEM TO BE SOLVED: To provide a gelling agent having gel-forming ability to both of organic solvents and water. SOLUTION: This hydrogen-forming agent is represented by the chemical formula (wherein A represents a sugar residue and R represents an alkyl group).
摘要翻译：要解决的问题：提供对有机溶剂和水都具有凝胶形成能力的胶凝剂。解决方案：该成氢剂由化学式（其中A表示糖残基，R表示烷基）表示。

17. 发明专利

JP2006232606A Transition metal oxide nanotube 有权
标题翻译：过渡金属氧化物纳米管
公开(公告)号：JP2006232606A
公开(公告)日：2006-09-07
申请号：JP2005048975
申请日：2005-02-24
申请人： Japan Science & Technology Agency , National Institute Of Advanced Industrial & Technology , 独立行政法人産業技術総合研究所 , 独立行政法人科学技術振興機構
发明人： OGISO MAKI , SHIMIZU TOSHIMI
IPC分类号： C01G1/02 , B82B1/00 , C01B13/32 , C01G3/02 , C01G45/02
CPC分类号： C01G1/00 , B82Y30/00 , C01B13/32 , C01G1/02 , C01P2004/13 , C01P2004/60
摘要： PROBLEM TO BE SOLVED: To provide a nanotube comprising transition metal oxides and a method for production thereof.
SOLUTION: The nanotube comprising transition metal oxides having the average diameter of about 10 to 1,000 nm and the average length of about 1 to 100 μm can be obtained by sintering, at a temperature of 300-600°C, a fibrous material formed by coexistence of transition metal ions and a peptidelipid represented by general formula, RCO(NHCH
2 CO)
m OH (R is a 6-18C hydrocarbon group; and m is an integer of 1 to 3) in water.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：待解决的问题：提供一种包含过渡金属氧化物的纳米管及其制造方法。解决方案：通过在300-600℃的温度下烧结纤维材料，可以获得包含平均直径为约10至1000nm且平均长度为约1至100μm的过渡金属氧化物的纳米管由过渡金属离子的共存和由通式RCO（NHCH 2 CO 2）表示的肽肽形成，其中R为6-18C烃基，m为 1〜3的整数）。版权所有（C）2006，JPO＆NCIPI

18. 发明专利

JP2006205280A Self-organizing film 审中-公开
标题翻译：自组织胶片
公开(公告)号：JP2006205280A
公开(公告)日：2006-08-10
申请号：JP2005017807
申请日：2005-01-26
申请人： National Institute Of Advanced Industrial & Technology , 独立行政法人産業技術総合研究所
发明人： ASAKAWA MASUMI , IKEDA TAICHI , SHIMIZU TOSHIMI , MIYAKE KOJI
IPC分类号： B82B1/00 , B82B3/00 , C07D487/22 , C07F15/00 , C09B47/00
摘要： PROBLEM TO BE SOLVED: To provide a novel self-organizing film and its manufacturing method, for regularly arranging two porphyrin or a phthalocyanine metallic complex and a sandwich type porphyrin phthalocyanine molecule rotating element composed of bidentate ligand on a substrate while keeping a sufficient distance. SOLUTION: This self-organizing film is formed by connecting an alkyl group-modified porphyrin metallic complex expressed by general formula (I) and arrangeable and fixable on the substrate, or an alkyl group-modified phthalocyanine metallic complex, with another one porphyrin or a phthalocyanine metallic complex derivative, through the bidentate ligand via coordinate linkage. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：为了提供一种新颖的自组织膜及其制造方法，用于在基板上规则地布置两个卟啉或酞菁金属络合物和由二齿配体组成的夹心型卟啉酞菁分子旋转元件，同时保持足够的距离解决方案：该自组织膜通过将由通式（I）表示的烷基改性卟啉金属络合物与基质或烷基改性酞菁金属络合物相互排列和固定而形成，卟啉或酞菁金属络合物衍生物，通过双齿配体通过配位键。版权所有（C）2006，JPO＆NCIPI

19. 发明专利

JP2005060304A Functional metal complex element 有权
标题翻译：功能金属复合元件
公开(公告)号：JP2005060304A
公开(公告)日：2005-03-10
申请号：JP2003292551
申请日：2003-08-12
申请人： National Institute Of Advanced Industrial & Technology , 独立行政法人産業技術総合研究所
发明人： ASAKAWA MASUMI , IKEDA TAICHI , SHIMIZU TOSHIMI , MIYAKE KOJI , OTSUKI MINORU , TAGUCHI TOSHIHARU
IPC分类号： C07D487/22 , C07F15/00
摘要： PROBLEM TO BE SOLVED: To provide a new functional metal complex element not only reversibly changing the structure by external stimulation such as heat and light but also having a space for securing free motion of each molecule; and to provide a new functional molecular element material obtained by immobilizing the metal complex element on a substrate, reversibly responding to the external stimulation such as the heat and the light, and having individual molecular ability capable of being optionally utilized and regulated.
SOLUTION: The external stimulation-responsible reversible molecule is the functional metal complex molecule represented by general formula (II) vertically immobilized by the center metal of a planar metal complex molecule represented by general formula (I) by a coordinate bond. (In the formulas, M is a transition metal ion; L is a planar polydentate ligand; R is a substituent containing a hydrocarbon group; A is a substituent capable of being reversibly converted to B by responding to the optional external stimulation; X is a substituent forming coordination linkage; and R is a substituent containing a hydrocarbon group).
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供新的功能金属复合元件，不仅可以通过诸如热和光的外部刺激可逆地改变结构，而且还具有确保每个分子的自由运动的空间; 并且提供通过将金属络合物元件固定在基底上而获得的新的功能性分子元素材料，其可逆地响应诸如热和光的外部刺激，并且具有能够任意使用和调节的各自的分子能力。解决方案：外部刺激负责的可逆分子是由通式（II）表示的由通式（II）表示的由通式（I）表示的平面金属络合物分子的中心金属通过配位键表示的官能金属络合物分子。（式中，M为过渡金属离子，L为平面状多齿配体; R为含有烃基的取代基; A为通过可选的外部刺激而可逆地转化为B的取代基; X为取代基形成配位键; R为含有烃基的取代基）。版权所有（C）2005，JPO＆NCIPI

20. 发明专利

JP2004358369A Method of manufacturing spherical microcapsule 有权
公开(公告)号：JP2004358369A
公开(公告)日：2004-12-24
申请号：JP2003160291
申请日：2003-06-05
申请人： National Institute Of Advanced Industrial & Technology , 独立行政法人産業技術総合研究所
发明人： MATSUZAWA YOKO , MATSUMOTO MUTSUYOSHI , OGISO MAKI , SHIMIZU TOSHIMI
IPC分类号： A23L1/00 , A61K9/50 , B01J13/04
摘要： PROBLEM TO BE SOLVED: To provide a method of easily manufacturing a spherical microcapsule including a hydrophilic core material by utilizing film formation with a bola-form compound. SOLUTION: In the method of manufacturing the spherical microcapsule including the hydrophilic core material, the microcapsule is obtained by dipping a hydrophilically treated base material in an aqueous solution in which a metallic salt of a compound expressed by general formula (1) and the hydrophilic core material are dissolved and settling the aqueous solution in an acidic atmosphere to be deposited. In the formula, R represents hydrogen atom or a 1-5C alkyl group, (n) is integers of 8-20 and (m) is integers of 1-3. COPYRIGHT: (C)2005,JPO&NCIPI

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