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11. 发明申请

US20080293859A1 CURABLE FLUOROPOLYETHER COMPOSITION AND INTEGRAL MOLDED RESIN/RUBBER ARTICLES 有权
标题翻译：可固化氟聚乙烯组合物和一体成型树脂/橡胶制品
公开(公告)号：US20080293859A1
公开(公告)日：2008-11-27
申请号：US12124436
申请日：2008-05-21
申请人： Hiromasa Yamaguchi , Mikio Shiono
发明人： Hiromasa Yamaguchi , Mikio Shiono
IPC分类号： C08K5/541
CPC分类号： C08G65/007 , C08G65/336 , C08G77/12 , C08G77/24 , C08G2650/48 , C08L71/02 , C08L83/04 , C08L2205/02 , Y10T428/31663 , Y10T428/31786 , C08L83/00
摘要： Curable fluoropolyether compositions comprising (a) a polyfluorodialkenyl compound, (b) a fluorinated organohydrogenpolysiloxane, (c) a platinum catalyst, (d) hydrophobic silica powder, (e) a tackifier in the form of a specific silicon compound, and (f) an organosiloxane having a SiH group, an epoxy and/or trialkoxysilyl group, and a perfluoroalkyl or perfluoropolyether group cure to thermoplastic resins to form a durable tight bond at a low temperature within a short time and are readily releasable from metal molds.
摘要翻译：固化氟聚醚组合物，其包含（a）多氟二烯基化合物，（b）氟化有机氢聚硅氧烷，（c）铂催化剂，（d）疏水性二氧化硅粉末，（e）特定硅化合物形式的增粘剂，和（f）具有SiH基团，环氧基和/或三烷氧基甲硅烷基的有机硅氧烷和全氟烷基或全氟聚醚基固化成热塑性树脂，以在短时间内在低温下形成耐久的紧密结合，并且容易从金属模上释放。

12. 发明申请

US20080132653A1 Coating composition 有权
标题翻译：涂料组成
公开(公告)号：US20080132653A1
公开(公告)日：2008-06-05
申请号：US11979555
申请日：2007-11-05
申请人： Mikio Shiono , Kenichi Fukuda
发明人： Mikio Shiono , Kenichi Fukuda
IPC分类号： C09D183/05 , C08L83/05 , C08L83/04
CPC分类号： C09D183/04 , C08G65/005 , C08G2650/48 , C08J7/047 , C08J2427/00 , C08K5/02 , C08K5/54 , C09D171/02 , C08L83/00
摘要： A coating composition comprises a fluoroelastomer composition and a diluent solvent consisting of a perfluoroalkyl-substituted aromatic compound and a perfluoro organic compound, the fluoroelastomer composition comprising (A) a linear perfluoropolyether compound, (B) a fluorinated organohydrogensiloxane, (C) a platinum catalyst, and (D) an organopolysiloxane containing an SiH group and an epoxy or trialkoxysilyl group. The composition cures into a fluoroelastomer having excellent characteristics and achieves a firm adhesion to a broad range of substrates by brief heating at relatively low temperatures.
摘要翻译：涂料组合物包含含氟弹性体组合物和由全氟烷基取代的芳族化合物和全氟有机化合物组成的稀释剂溶剂，该含氟弹性体组合物包含（A）直链全氟聚醚化合物，（B）氟化有机氢硅氧烷，（C）铂催化剂，（D）含有SiH基和环氧基或三烷氧基甲硅烷基的有机聚硅氧烷。该组合物固化成具有优异特性的含氟弹性体，并通过在较低温度下短暂加热而实现对宽范围基材的牢固粘附。

13. 发明授权

US06962752B2 Curable composition for forming low bleeding gel type cured product 有权
标题翻译：用于形成低出血凝胶型固化产品的可固化组合物
公开(公告)号：US06962752B2
公开(公告)日：2005-11-08
申请号：US10338706
申请日：2003-01-09
申请人： Kenichi Fukuda , Mikio Shiono
发明人： Kenichi Fukuda , Mikio Shiono
IPC分类号： C08L71/00 , C08G65/00 , C08G65/336 , C08K5/5419 , C08L83/05 , H01L23/29 , H01L23/31 , B32B27/04 , C08L101/04
CPC分类号： C08G65/336 , C08G65/007 , C08G77/12 , C08L83/04 , Y10T428/3154 , Y10T428/31544 , Y10T428/31663 , C08L2666/14
摘要： A curable composition comprising:(A) a branched polyfluorodialkenyl compound represented by a general formula (1): CH2═CH—(X)a-Rf1-(X′)a—CH═CH2 (1) wherein, X and X′ are bivalent groups such as —CH2— and —CH2O—, a represents, independently, either 0 or 1, and Rf1 is a specific bivalent fluorine-containing group, (B) a branched polyfluoromonoalkenyl compound represented by a general formula (2): Rf2-(X′)a—CH═CH2 (2) wherein, X′ and a are as defined above, and Rf2 is a specific fluorine-containing group, (C) an organohydrogensiloxane compound with at least two hydrogen atoms bonded to silicon atoms, and (D) a platinum group metal catalyst; as well as a low bleeding gel type cured product obtained by curing such a composition, and an electrical or electronic component sealed or encapsulated using such a cured product. The gel type cured product displays very little bleeding of free oil constituents from the gel as a result of stress such as pressure fluctuation or heat history.
摘要翻译：一种可固化组合物，其包含：（A）由通式（1）表示的支链多氟联苯基化合物：<？in-line-formula description =“In-line formula”end =“lead”？> CH 2 （X）a - （X）a - （X'）a-CH 2 CH 2 >（1）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中X和X'是二价基团，例如-CH 2 - CH 2 O-，a独立地表示0或1，Rf 1是特定的二价含氟基团，（B）支化多氟单链烯基化合物通式（2）：<？in-line-formula description =“In-line formula”end =“lead”？> Rf <2> - （X'） > -CH-CH 2（2）<？in-line-formula description =“In-line formula”end =“tail”？>其中，X'和a如上定义，和 Rf 2是特定的含氟基团，（C）具有至少两个与硅原子键合的氢原子的有机氢硅氧烷化合物，和（D）平台 inum组金属催化剂; 以及通过固化这种组合物获得的低出血凝胶型固化产物，以及使用这种固化产物密封或包封的电气或电子部件。由于应力如压力波动或热历史，凝胶型固化产物显示出很少的游离油成分从凝胶中渗出。

14. 发明授权

US06624231B2 Fluorinated hydrosilylation-curable elastomer composition 失效
标题翻译：氟化氢化硅烷化固化弹性体组合物
公开(公告)号：US06624231B2
公开(公告)日：2003-09-23
申请号：US10046173
申请日：2002-01-16
申请人： Mikio Shiono
发明人： Mikio Shiono
IPC分类号： C08G7712
CPC分类号： C08L83/04 , C08G65/007 , C08G65/336 , C08G77/12 , C08G77/16 , C08G77/18 , C08G77/20 , C08G77/24 , C08K3/36 , C08K5/5406 , C08L83/14 , Y10T428/2995 , C08L83/08 , C08L2666/14 , C08L83/00
摘要： A curable composition comprising (A) a fluorinated amide compound having alkenyl radicals, (B) a fluorinated organohydrogensiloxane having SiH radicals, (C) a platinum group compound, (D) a silica powder, (E) an organosilane or organosiloxane having a monovalent perfluorooxyalkyl or perfluoroalkyl, divalent perfluorooxyalkylene or perfluoroalkylene radical and a hydroxy and/or alkoxy radical, and (F) an organosilane or organosiloxane having an alkenyl radical, a monovalent perfluorooxyalkyl or perfluoroalkyl, divalent perfluorooxyalkylene or perfluoroalkylene radical, and a hydroxy and/or alkoxy radical cures into a fluorinated elastomer that has good solvent resistance, chemical resistance, heat resistance, low-temperature properties, mold release, water and oil repellency and weather resistance as well as significantly improved mechanical strength and compression set.
摘要翻译：一种可固化组合物，其包含（A）具有烯基的氟化酰胺化合物，（B）具有SiH基团的氟化有机氢硅氧烷，（C）铂族化合物，（D）二氧化硅粉末，（E）有机硅烷或具有一价全氟氧烷基或全氟烷基，二价全氟氧化烯或全氟亚烷基和羟基和/或烷氧基，和（F）具有烯基，一价全氟氧烷基或全氟烷基，二价全氟氧化烯或全氟亚烷基的有机硅烷或有机硅氧烷，以及羟基和/或烷氧基自由基固化成耐溶剂性，耐化学性，耐热性，低温性，脱模性，拒水拒油性和耐候性以及显着改善的机械强度和压缩永久变形性的氟化弹性体。

15. 发明授权

US06576737B2 Curable compositions of fluorinated amide compounds 失效
标题翻译：氟化酰胺化合物的可固化组合物
公开(公告)号：US06576737B2
公开(公告)日：2003-06-10
申请号：US09969829
申请日：2001-10-04
申请人： Mikio Shiono , Takashi Matsuda , Masatoshi Arai
发明人： Mikio Shiono , Takashi Matsuda , Masatoshi Arai
IPC分类号： C08G7724
CPC分类号： C08L71/02 , C08G65/007 , C08L83/08 , C08L83/14 , C08L83/00
摘要： A curable composition comprising (A) a fluorinated amide compound having at least one alkenyl radical, (B) a fluorinated organohydrogensiloxane, (C) a platinum group compound, (D) a first organosiloxane having at least one SiH radical and at least one epoxy and/or trialkoxysilyl radical, and (E) a second organosiloxane having at least one SiH radical, at least one cyclic carboxylic anhydride residue, and at least one monovalent perfluorooxyalkyl or perfluoroalkyl radical cures into a fluorinated elastomer that not only has good solvent resistance, chemical resistance, heat resistance, low-temperature properties, low moisture permeability and electrical properties, but also firmly bonds to a variety of substrates including PPS, polyamide and polyimide resins.
摘要翻译：一种可固化组合物，其包含（A）具有至少一个烯基的氟化酰胺化合物，（B）氟化有机氢硅氧烷，（C）铂族化合物，（D）具有至少一个SiH基团和至少一个环氧基的第一有机硅氧烷和/或三烷氧基甲硅烷基，和（E）具有至少一个SiH基，至少一个环状羧酸酐残基和至少一个一价全氟氧烷基或全氟烷基的第二有机硅氧烷固化成不仅耐溶剂性良好的氟化弹性体，耐化学性，耐热性，低温性，低透湿性和电性能，而且牢固地粘合到各种基材，包括PPS，聚酰胺和聚酰亚胺树脂。

16. 发明授权

US06417311B1 Curable compositions of fluorinated amide polymers 有权
标题翻译：氟化酰胺聚合物的固化组合物
公开(公告)号：US06417311B1
公开(公告)日：2002-07-09
申请号：US09654520
申请日：2000-09-01
申请人： Kenichi Fukuda , Mikio Shiono
发明人： Kenichi Fukuda , Mikio Shiono
IPC分类号： C08G7724
CPC分类号： C08L83/14 , C08G65/007 , C08G65/336 , C08K5/20 , C08L83/08 , C08L2666/14 , C08L2666/34
摘要： A curable composition contains (A) a fluorinated amide compound having at least one alkenyl radical, (B) a fluorinated organohydrogensiloxane, (C) a platinum group compound, (D) an organosiloxane having at least one hydrogen atom directly attached to a silicon atom, and at least one epoxy and/or trialkoxysilyl radical attached to a silicon atom through a carbon atom or a carbon atom and an oxygen atom, and (E) a carboxylic anhydride. The composition firmly bonds to a variety of substrates such as PPS and nylon while curing into a fluorinated elastomer.
摘要翻译：固化性组合物含有（A）具有至少一个烯基的氟化酰胺化合物，（B）氟化有机氢硅氧烷，（C）铂族化合物，（D）具有至少一个氢原子直接与硅原子连接的有机硅氧烷和通过碳原子或碳原子和氧原子连接到硅原子的至少一个环氧基和/或三烷氧基甲硅烷基，和（E）羧酸酐。当固化成氟化弹性体时，组合物牢固地粘合到各种基材如PPS和尼龙。

17. 发明授权

US5064891A Curable silicone compositions 失效
标题翻译：可固化硅胶组合物
公开(公告)号：US5064891A
公开(公告)日：1991-11-12
申请号：US525047
申请日：1990-05-18
申请人： Hironao Fujiki , Mikio Shiono , Toshiaki Takahashi
发明人： Hironao Fujiki , Mikio Shiono , Toshiaki Takahashi
IPC分类号： A61K6/10 , C08L83/04 , C08L83/07 , G02B1/04
CPC分类号： A61K6/10 , C08L83/04 , G02B1/043 , C08G77/12 , C08G77/20 , C08G77/46 , Y10S524/912
摘要： A curable silicone composition comprising:(A) an organopolysiloxane having at least two silicon-bonded aliphatic unsaturated hydrocarbon radicals in its molecule;(B) an organohydrogenpolysiloxane having at least three silicon-bonded hydrogen atoms in its molecule;(C) a platinum family metal catalyst; and(D) a nonionic surface active agent having a hydrophobic silicone portion and at least one hydrophilic polyol portion in its molecule. The curable silicone composition gives cured products having good hydrophilic properties and dimensional stability, and are especially suitable for use as a dental impression material.

18. 发明授权

US08440777B2 Addition-cure fluoropolyether adhesive composition 有权
标题翻译：加成固化氟聚醚粘合剂组合物
公开(公告)号：US08440777B2
公开(公告)日：2013-05-14
申请号：US13007134
申请日：2011-01-14
申请人： Hidenori Koshikawa , Mikio Shiono
发明人： Hidenori Koshikawa , Mikio Shiono
IPC分类号： C08G77/42
CPC分类号： C09J171/02 , C08G65/007 , C08G77/12 , C08G77/14 , C08G77/18 , C08G77/24 , C08G2650/48 , C08K5/56 , C08L83/04
摘要： A fluoropolyether adhesive composition comprising (A) a linear polyfluoro compound having at least two alkenyl groups and a perfluoropolyether structure in its main chain, (B) a fluorinated organohydrogensiloxane containing at least two SiH groups, but not alkoxy and epoxy groups, (C) a platinum group metal-based catalyst, (D) an organosilicon compound having at least one silicon-bonded alkoxy group, and (E) a hydrolytic catalyst can be cured to metal and plastic substrates through addition reaction.
摘要翻译：一种氟聚醚粘合剂组合物，其包含（A）在其主链中具有至少两个烯基和全氟聚醚结构的线性多氟化合物，（B）含有至少两个SiH基但不包括烷氧基和环氧基的氟化有机氢硅氧烷，（C）铂族金属类催化剂，（D）具有至少一个与硅键合的烷氧基的有机硅化合物，（E）水解催化剂可以通过加成反应固化成金属和塑料基材。

19. 发明授权

US08314190B2 RT curable fluoropolyether base rubber composition and cured product 有权
标题翻译： RT固化氟聚醚基橡胶组合物和固化产物
公开(公告)号：US08314190B2
公开(公告)日：2012-11-20
申请号：US12874768
申请日：2010-09-02
申请人： Mitsuo Muto , Takashi Matsuda , Mikio Shiono
发明人： Mitsuo Muto , Takashi Matsuda , Mikio Shiono
IPC分类号： C08G77/00 , C08L83/00
CPC分类号： C08G65/007 , C08G2650/48 , C08L71/02 , C08L83/00
摘要： A fluoropolyether base rubber composition comprising (a) a linear fluoropolyether compound containing at least two ester groups in a molecule and a divalent perfluoroalkyl ether structure in its backbone, and having a Mn of 3,000-100,000, and (b) a siloxane polymer containing at least three amino groups in a molecule cures at room temperature into a product having heat resistance, low-temperature performance, chemical resistance, solvent resistance and oil resistance.
摘要翻译：一种含氟聚醚基橡胶组合物，其包含（a）在分子中含有至少两个酯基的直链含氟聚醚化合物和其主链中的二价全氟烷基醚结构，并且具有3,000-100,000的Mn，和（b）含有分子中至少三个氨基在室温下固化成具有耐热性，低温性能，耐化学性，耐溶剂性和耐油性的产品。

20. 发明申请

US20110257315A1 ADHESIVE COMPOSITION 有权
标题翻译：粘合剂组合物
公开(公告)号：US20110257315A1
公开(公告)日：2011-10-20
申请号：US13085510
申请日：2011-04-13
申请人： Mikio Shiono , Noriyuki Koike
发明人： Mikio Shiono , Noriyuki Koike
IPC分类号： C09J183/07 , C09J185/00 , C09J11/06
CPC分类号： C09D183/08 , C08G77/24 , C08L71/02
摘要： An adhesive composition is provided comprising (A) a fluorinated amide compound containing at least two vinyl groups and having a polyfluoro structure, (B) a fluorinated organosilicon compound containing a fluorinated organic group, at least two SiH groups, and an alkyl, aryl or aralkyl group, and (C) a platinum catalyst, and (D) an organosiloxane containing a SiH group and an epoxy and/or trialkoxysilyl group. The composition is cured on brief heating into a product which achieves adhesion to various substrates and has solvent resistance, chemical resistance, heat resistance, low-temperature properties, low moisture permeability, electric insulation, and acid resistance.
摘要翻译：提供一种粘合剂组合物，其包含（A）含有至少两个乙烯基并具有多氟结构的氟化酰胺化合物，（B）含氟化有机基团的氟化有机硅化合物，至少两个SiH基团和烷基，芳基或芳族烷基，（C）铂催化剂，（D）含有SiH基和环氧基和/或三烷氧基甲硅烷基的有机硅氧烷。该组合物在短暂加热下固化成实现对各种基材的粘合性的产品，并具有耐溶剂性，耐化学性，耐热性，低温性，低透湿性，电绝缘性和耐酸性。

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