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11. 发明授权

US4094826A Fluorinated graft cation exchange copolymers 失效
标题翻译：氟化接枝阳离子交换共聚物
公开(公告)号：US4094826A
公开(公告)日：1978-06-13
申请号：US827018
申请日：1977-08-23
申请人： Masayoshi Tatemoto , Sinji Tamaru
发明人： Masayoshi Tatemoto , Sinji Tamaru
IPC分类号： B01J39/20 , B01D15/04 , C08F14/00 , C08F14/22 , C08F18/00 , C08F18/02 , C08F259/00 , C08F259/08 , C08J5/20 , C08J5/22
CPC分类号： C08F259/08
摘要： Ion exchanger comprising a water-insoluble copolymer prepared by post-polymerizing at least one fluoroolefin monomer to a perfluorovinylacetic acid-vinylidene fluoride copolymer containing not less than 25% by mole of the perfluorovinylacetic acid unit in an aqueous solution of said copolymer in the presence of an organic or inorganic peroxide. The ion exchanger has excellent heat and chemical resistances and dimensional stability.
摘要翻译：离子交换剂，其包含通过使至少一种氟代烯烃单体在含有不少于25％摩尔全氟乙烯基乙酸单元的全氟乙烯基乙酸 - 偏二氟乙烯共聚物中在所述共聚物的水溶液中存在下制备的水不溶性共聚物有机或无机过氧化物。离子交换器具有优异的耐热和耐化学性和尺寸稳定性。

12. 发明申请

US20060194703A1 Liquid fluoropolymer composition, process for producing organosol, film, and fuel cell 审中-公开
标题翻译：液体含氟聚合物组合物，生产有机溶胶，薄膜和燃料电池的方法
公开(公告)号：US20060194703A1
公开(公告)日：2006-08-31
申请号：US10547770
申请日：2004-03-03
申请人： Masayoshi Tatemoto , Tadashi Ino , Takuya Arase , Atsushi Sakakura
发明人： Masayoshi Tatemoto , Tadashi Ino , Takuya Arase , Atsushi Sakakura
IPC分类号： C10M107/38
CPC分类号： C08F8/00 , C08J3/09 , C08J5/2237 , C08J2327/12 , C08K5/00 , C09D127/12 , H01M8/1023 , H01M8/1039 , H01M8/1058 , H01M8/1081 , Y02P70/56 , C08F14/18
摘要： The invention provides a fluoropolymer liquid composition comprising a fluoropolymer and a film-forming auxiliary, said fluoropolymer comprising acid/acid salt fluorovinyl ether units represented by the general formula (I): said film-forming auxiliary being an organic liquid which is compatible with water and has a boiling point higher than 100° C. but not higher than 300° C., said fluoropolymer liquid composition being a fluoropolymer dispersion composition comprising said film-forming auxiliary and a fluoropolymer fine particle comprising said fluoropolymer, said fluoropolymer fine particle containing, at the proportion of at least 25% by mass thereof, a spherical fluoropolymer fine particle, and said spherical fluoropolymer fine particle being substantially spherical.
摘要翻译：本发明提供含氟聚合物和成膜助剂的含氟聚合物液体组合物，所述含氟聚合物包含由通式（I）表示的酸/酸盐氟乙烯基醚单元：所述成膜助剂是与水相容的有机液体并且具有高于100℃但不高于300℃的沸点，所述含氟聚合物液体组合物是包含所述成膜助剂和包含所述含氟聚合物的含氟聚合物细颗粒的含氟聚合物分散体组合物，所述含氟聚合物细颗粒含有其比例为至少25质量％，球状含氟聚合物细颗粒，并且所述球形含氟聚合物细颗粒基本上为球形。

13. 发明申请

US20050228127A1 Fluoropolymer dispersion and process for producing fluoropolymer dispersion 审中-公开
标题翻译：含氟聚合物分散体和生产含氟聚合物分散体的方法
公开(公告)号：US20050228127A1
公开(公告)日：2005-10-13
申请号：US10518052
申请日：2003-06-16
申请人： Masayoshi Tatemoto , Takuya Arase , Tadashi Ino
发明人： Masayoshi Tatemoto , Takuya Arase , Tadashi Ino
IPC分类号： B01D67/00 , B01D69/10 , B01D69/12 , B01D69/14 , B01D71/32 , B01D71/82 , C08F6/00 , C08F6/14 , C08F6/16 , C08F8/00 , C08K3/00 , C08L27/12
CPC分类号： C08F2/10 , B01D67/0009 , B01D67/0011 , B01D69/10 , B01D69/12 , B01D69/141 , B01D71/32 , B01D71/82 , B01D2323/06 , B01D2323/46 , B01D2325/10 , B01D2325/14 , B01D2325/42 , C08F6/003 , C08F6/14 , C08F8/44 , C08F2800/10 , H01M8/1004 , H01M8/1025 , H01M8/1039 , H01M8/1072 , H01M2300/0082 , Y02E60/522 , Y02E60/523 , Y02P70/56 , C08L27/12 , C08F8/12 , C08F214/262
摘要： A fluoropolymer solid composition which contains a fine particle comprising a fluoropolymer, said fluoropolymer having an acid/acid salt group, said acid/acid salt group being a sulfonic acid group, —SO2NR17R18, a carboxyl group, —SO3NR1R2R3R4, —SO3M11/L, —COONR5R6R7R8 or —COOM21/L (in which R17 and R18 are the same or different and each represents a hydrogen atom, an alkali metal, an alkyl group or a sulfonyl-containing group, R1, R2, R3 and R4 are the same or different and each represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, R5, R6, R7 and R8 are the same or different and each represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, M1 and M2 are the same or different and each represents a metal whose valence is L, and said metal whose valence is L is a metal belonging to the group 1, 2, 4, 8, 11, 12 or 13 of the periodic table); said fine particle comprising the fluoropolymer containing, at the proportion of at least 25% by mass thereof, a spherical fluoropolymer fine particle, and said spherical fluoropolymer fine particle being substantially spherical.
摘要翻译：一种含氟聚合物固体组合物，其含有包含含氟聚合物的细颗粒，所述含氟聚合物具有酸/酸盐基团，所述酸/酸盐基团是磺酸基，-SO 2 NR 17 羧基，-SO 3，NR 1，R 2，R 2，R 2， 3/4，3/3，1 / L，-COONR＆lt; 3＆gt; 5 6 /其中R 17和R 18相同或不同，各自表示氢原子，碱金属，烷基或含磺酰基的基团 R 1，R 2，R 3和R 4相同或不同，并且各自表示氢原子或碳原子数1〜4的烷基，R 5，R 6，R 7，R 8， >相同或不同，各自表示氢原子或碳原子数1〜4的烷基，M 1和M 2 2价元素相同或不同，分别表示价数为L的金属，所述金属价为L的是金属属于第1,2,4,8,11,12或13族金属的周期表）; 所述含有氟聚合物的微粒子以至少25质量％的比例含有球状含氟聚合物细粒，所述球状含氟聚合物微粒基本上为球形。

14. 发明授权

US06274677B1 Process for the producing perfluorovinyl ethersulfonic acid derivatives and copolymer of the same 有权
标题翻译：制备全氟乙烯基醚磺酸衍生物及其共聚物的方法
公开(公告)号：US06274677B1
公开(公告)日：2001-08-14
申请号：US09402168
申请日：1999-09-30
申请人： Masayoshi Tatemoto
发明人： Masayoshi Tatemoto
IPC分类号： C08F1418
CPC分类号： C08F289/00 , C07C303/22 , C08F16/30 , C08F259/08 , C08F293/005 , C07C309/10
摘要： A compound of the formula (1): FSO2CFXCF2O(CFXCF2O)nCF—(CF2Y)COF in which X is a fluorine atom, a chlorine atom or a trifluoromethyl group, Y is a fluorine atom, a chlorine atom, a bromine atom or an iodine atom, and n is a number of 0 to 5, preferably 0, 1 or 2, is converted to a compound of the formula (2): MOSO2CFXCF2O(CFXCF2O)2CF(CF2Y)COOM1 in which X, Y and n are the same as defined above, and M and M1 independently represent an alkali metal atom or an alkaline earth metal atom, and then a compound of the formula (2) is pyrolyzed at a temperature of 150 to 250° C. to obtain a compound of the formula (3): ASO2CFXCF2O(CFXCF2O)nCF═CF2 in which A is MO—, a hydroxyl group or a fluorine atom, and X and n are the same as defined above.
摘要翻译：式（1）化合物：其中X为氟原子，氯原子或三氟甲基的FSO 2 CFXCF 2 O（CFXCF 2 O）n CF-（CF 2 Y）COF，Y为氟原子，氯原子，溴原子或碘原子，n为0〜5，优选为0,1或2的数，转化为式（2）的化合物：其中X，Y和n分别为（O），（X）和（X））的MOSO2CFXCF2O（CFXCF2O）2CF（CF2Y）COOM1 M和M1独立地表示碱金属原子或碱土金属原子，然后在150〜250℃的温度下热解式（2）的化合物，得到化合物式（3）：ASO2CFXCF2O（CFXCF2O）nCF = CF2，其中A为MO-，羟基或氟原子，X和n与上述定义相同。

15. 发明授权

US5198136A Iodine-containing compound, preparation thereof and block copolymer comprising the same 失效
标题翻译：含碘化合物，其制备方法和含有该化合物的嵌段共聚物
公开(公告)号：US5198136A
公开(公告)日：1993-03-30
申请号：US487865
申请日：1990-03-05
申请人： Masayoshi Tatemoto , Yuji Yutani , Koji Fujiwara
发明人： Masayoshi Tatemoto , Yuji Yutani , Koji Fujiwara
IPC分类号： C08F293/00 , C08G65/00 , C08G65/22 , C08G65/321 , C08G65/323 , C08G65/324 , C10M107/38 , C10M107/50 , C10M111/04 , C10M119/22 , C10M119/30 , C10M147/04 , C10M155/02 , C10M169/02 , G11B5/725
CPC分类号： C10M107/38 , C08F293/00 , C08G65/005 , C08G65/223 , C08G65/321 , C08G65/3233 , C08G65/324 , C10M107/50 , C10M111/04 , C10M119/22 , C10M119/30 , C10M147/04 , C10M155/02 , C10M169/02 , G11B5/725 , C10M2203/003 , C10M2207/044 , C10M2207/046 , C10M2207/08 , C10M2211/022 , C10M2211/06 , C10M2213/00 , C10M2213/02 , C10M2213/023 , C10M2213/04 , C10M2213/043 , C10M2213/06 , C10M2213/0606 , C10M2213/062 , C10M2213/0623 , C10M2215/04 , C10M2215/08 , C10M2215/082 , C10M2215/26 , C10M2215/28 , C10M2229/051 , C10N2240/00 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106 , C10N2240/20 , C10N2240/201 , C10N2240/202 , C10N2240/203 , C10N2240/204 , C10N2240/205 , C10N2240/22 , C10N2240/30 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66
摘要： An iodine-containing compound consisting of at least two repeating units selected from the formulae:--(CH.sub.2 CF.sub.2 CF.sub.2 O).sub.a ----(CHClCF.sub.2 CF.sub.2 O).sub.b ----(CCl.sub.2 CF.sub.2 CF.sub.2 O).sub.c ----(CHFCF.sub.2 CF.sub.2 O).sub.d ----(CFClCF.sub.2 CF.sub.2 O).sub.e ----(CF.sub.2 CF.sub.2 CF.sub.2 O).sub.f --wherein a, b, c, d, e and f are each 0 or a positive integer and satisfy the following equations:2.ltoreq.a+b+c+d+e+f.ltoreq.200 and1.ltoreq.a+c+d+fand an iodine atom at at least one end of a molecule, which can provide a block copolymer which is useful as a grease.
摘要翻译：由至少两个选自下式的重复单元组成的含碘化合物： - （CH 2 CF 2 CF 2 O）a - （CHClCF 2 CF 2 O）b - （CCl 2 CF 2 CF 2 O）c - （CHFCF 2 CF 2 O）d - （CFClCF 2 CF 2 O）e - （CF 2 CF 2 CF 2 O ）f-其中a，b，c，d，e和f各自为0或正整数，并且满足以下等式：2 = a + b + c + d + e + f = 200和1 < / = a + c + d + f和分子至少一端的碘原子，其可以提供可用作油脂的嵌段共聚物。

16. 发明授权

US4962236A Novel iodine-containing compound, preparation thereof and block copolymer comprising the same 失效
标题翻译：新型含碘化合物及其制备方法和含有它们的嵌段共聚物
公开(公告)号：US4962236A
公开(公告)日：1990-10-09
申请号：US345571
申请日：1989-05-01
申请人： Masayoshi Tatemoto , Yuji Yutani , Koji Fujiwara
发明人： Masayoshi Tatemoto , Yuji Yutani , Koji Fujiwara
IPC分类号： C08F293/00 , C08G65/00 , C08G65/22 , C08G65/321 , C08G65/323 , C08G65/324 , C08L53/00 , C08L71/02 , C10M107/38 , C10M107/50 , C10M111/04 , C10M119/22 , C10M119/30 , C10M147/04 , C10M155/02 , C10M169/02 , G11B5/725
CPC分类号： G11B5/725 , C08F293/00 , C08G65/005 , C08G65/223 , C08G65/321 , C08G65/3233 , C08G65/324 , C08L53/00 , C08L71/02 , C10M107/38 , C10M107/50 , C10M111/04 , C10M119/22 , C10M119/30 , C10M147/04 , C10M155/02 , C10M169/02 , C10M2203/003 , C10M2207/044 , C10M2207/046 , C10M2207/08 , C10M2211/022 , C10M2211/06 , C10M2213/00 , C10M2213/02 , C10M2213/023 , C10M2213/04 , C10M2213/043 , C10M2213/06 , C10M2213/0606 , C10M2213/062 , C10M2213/0623 , C10M2215/04 , C10M2215/08 , C10M2215/082 , C10M2215/26 , C10M2215/28 , C10M2229/025 , C10M2229/0405 , C10M2229/0415 , C10M2229/0425 , C10M2229/0435 , C10M2229/0445 , C10M2229/0455 , C10M2229/0465 , C10M2229/0475 , C10M2229/0485 , C10M2229/0505 , C10M2229/051 , C10M2229/0515 , C10M2229/0525 , C10M2229/0535 , C10M2229/0545 , C10N2240/00 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106 , C10N2240/20 , C10N2240/201 , C10N2240/202 , C10N2240/203 , C10N2240/204 , C10N2240/205 , C10N2240/22 , C10N2240/30 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66
摘要： An iodine-containing compound consisting of at least two repeating units selected from the formulae:--(CH.sub.2 CF.sub.2 CF.sub.2 O).sub.a ----(CHClCF.sub.2 CF.sub.2 O).sub.b ----(CCl.sub.2 CF.sub.2 CF.sub.2 O).sub.c ----(CHFCF.sub.2 CF.sub.2 O).sub.d ----(CFClCF.sub.2 CF.sub.2 O).sub.e ----(CF.sub.2 CF.sub.2 CF.sub.2 O).sub.f --wherein a, b, c, d, e and f are each 0 or a positive integer and satisfy the following equations:2.ltoreq.a+b+c+d+e+f.ltoreq.200 and1.ltoreq.a+c+d+fand an iodine atom at at least one end of a molecule, which can provide a block copolymer which is useful as a grease.

17. 发明授权

US4379901A Polyfluoroallyl ethers and their production and use 失效
标题翻译：聚氟烯醚及其生产和使用
公开(公告)号：US4379901A
公开(公告)日：1983-04-12
申请号：US306352
申请日：1981-09-28
申请人： Yoshio Amimoto , Masayoshi Tatemoto
发明人： Yoshio Amimoto , Masayoshi Tatemoto
IPC分类号： C08F14/00 , B01J39/20 , C07C67/00 , C07C253/00 , C07C255/13 , C07C255/16 , C08F14/18 , C08F16/00 , C08F16/12 , C08F16/24 , C08F16/28 , C08F214/18 , C08J5/20 , C08L27/12 , C08L29/10 , C09J4/00 , C09J127/12 , C09J129/00 , C09J133/22 , C07C121/34
CPC分类号： C07C255/00 , C08F16/28
摘要： A polyfluoroallyl ether of the formula: ##STR1## wherein each X, which is the same or different, is a chlorine atom or a fluorine atom and each Y, which is the same or different, is a hydrogen atom, a chlorine atom or a fluorine atom, which is useful as a modifier for polymers.
摘要翻译：一种下式的聚氟烯丙醚：其中每个相同或不同的X是氯原子或氟原子，每个相同或不同的Y是氢原子，氯原子或氟原子，其可用作聚合物的改性剂。

18. 发明授权

US07847001B2 Liquid fluoropolymer composition and process for producing crosslinked fluorochemical 有权
标题翻译：液态含氟聚合物组合物和交联含氟化合物的制备方法
公开(公告)号：US07847001B2
公开(公告)日：2010-12-07
申请号：US12629817
申请日：2009-12-02
申请人： Takuya Arase , Masayoshi Tatemoto
发明人： Takuya Arase , Masayoshi Tatemoto
IPC分类号： C08K5/41
CPC分类号： H01M8/106 , C08K5/18 , C09D127/12 , H01M8/0289 , H01M8/1023 , H01M8/1039 , H01M8/1081 , H01M8/1088 , Y02P70/56 , C08L27/12
摘要： A fluoropolymer liquid composition including a fluoropolymer liquid (A) which includes a liquid medium and a crosslinkable functional group-containing crosslinkable fluoropolymer. The fluoropolymer liquid (A) is a fluoropolymer liquid dispersion (AD) having, dispersed in a liquid dispersion medium, particles of a crosslinkable fluoropolymer (PD) containing acid/acid salt groups or organic groups capable of undergoing hydrolysis and thus being converted to carboxyl groups, or a fluoropolymer solution (AS) having, dissolved in a fluorosolvent or an alcohol/water mixed solvent, a crosslinkable fluoropolymer (PS) containing acid/acid salt groups or acid/acid salt groups precursors. Further, the crosslinkable functional group is a cyano group, —I or —Br.
摘要翻译：一种含氟聚合物液体（A）的含氟聚合物液体组合物，其包含液体介质和可交联官能团的可交联含氟聚合物。含氟聚合物液体（A）是在液体分散介质中分散有含有能够进行水解的酸/酸盐基团或有机基团的可交联含氟聚合物（PD）的颗粒并因此转化成羧基的含氟聚合物液体分散体（AD）基团或具有溶解在氟溶剂或醇/水混合溶剂中的含有酸/酸盐基团或酸/酸盐前体的可交联含氟聚合物（PS）的含氟聚合物溶液（AS）。此外，可交联官能团是氰基-I或-Br。

19. 发明授权

US07482415B2 Process for producing fluoroionomer, method for purification and concentration of the ionomer, and method of film formation 有权
标题翻译：氟代离聚物的制造方法，离聚物的净化和浓缩方法以及成膜方法
公开(公告)号：US07482415B2
公开(公告)日：2009-01-27
申请号：US10182737
申请日：2001-02-16
申请人： Masayoshi Tatemoto , Tadashi Ino , Kenji Ishii , Takuji Ishikawa , Takuya Arase
发明人： Masayoshi Tatemoto , Tadashi Ino , Kenji Ishii , Takuji Ishikawa , Takuya Arase
IPC分类号： C08F30/04
CPC分类号： C08F216/1466 , C08F6/003 , C08L27/12
摘要： The present invention provides a process for producing a fluorinated ionomer, comprising copolymerizing, in the presence of a polymerization initiator, (i) a compound represented by Formula (I) (M)1/LOSO2CFY(CF2)mO(CFXCF2O)nCF═CF2 (I) wherein M is H or a metal with a valence of L (L is 1, 2 or 3), X is F, Cl or CF3, Y is halogen, m is 1 to 5, and n is 0 to 5, (ii) tetrafluoroethylene and (iii) at least one third monomer selected from the group consisting of hexafluoropropylene, chlorotrifluoroethylene, vinylidene fluoride, CF2═CFORf (Rf is C1 to C5 perfluoroalkyl) and ethylene. The present invention further provides a method for purifying and concentrating a fluorinated ionomer, comprising ultrafiltration or dialysis of a fluorinated ionomer solution or dispersion, and a method for forming a film of the fluorinated ionomer.
摘要翻译：本发明提供一种制备氟化离聚物的方法，包括在聚合引发剂存在下共聚合（ⅰ）由式（Ⅰ）表示的化合物<？在线式描述=“在线式”末端 =“铅”→（M）1 / LOSO2CFY（CF2）mO（CFXCF2O）nCF-CF2（I）<βin-line-formula description =“In-line Formulas”end =“tail”？> H或化合价L（L为1,2或3）的金属，X为F，Cl或CF 3，Y为卤素，m为1至5，n为0至5，（ii）四氟乙烯和（ iii）至少一种选自六氟丙烯，三氟氯乙烯，偏二氟乙烯，CF 2 -CFOR f（R f为C 1至C 5全氟烷基）和乙烯的第三单体。本发明还提供了一种用于纯化和浓缩氟化离聚物的方法，其包括氟离聚物溶液或分散体的超滤或透析，以及形成氟化离聚物膜的方法。

20. 发明授权

US5439980A Process for preparing polymer 失效
标题翻译：制备聚合物的方法
公开(公告)号：US5439980A
公开(公告)日：1995-08-08
申请号：US169753
申请日：1993-12-20
申请人： Yuji Yutani , Masayoshi Tatemoto
发明人： Yuji Yutani , Masayoshi Tatemoto
IPC分类号： C08F2/00 , C08F20/12 , C08F293/00 , C08F259/08
CPC分类号： C08F20/12 , C08F2/00 , C08F293/005
摘要： A polymer comprising at least one polymer chain is produced by polymerizing, in the presence of a radical generating source and an iodide compound, at least one monomer M.sub.1 having a radically polymerizable unsaturated bond between a carbon atom and an iodine atom constituting a carbon-iodine bond of the iodide compound to form at least one polymer chain between the carbon atom and the iodine atom, wherein the polymerization reaction is carried out in the presence of a monomer M.sub.2 which is different from the monomer M.sub.1 and has a larger addition reactivity with a carbon radical which is generated by cleavage of the carbon-iodine bond of the iodine compound than that of the monomer M.sub.1.
摘要翻译：包含至少一个聚合物链的聚合物通过在自由基产生源和碘化合物的存在下聚合至少一种在碳原子和构成碳 - 碘的碘原子之间具有自由基聚合性不饱和键的单体M1 碘化合物键在碳原子和碘原子之间形成至少一个聚合物链，其中聚合反应在不同于单体M1的单体M2存在下进行，并且与通过裂解碘化合物的碳 - 碘键而产生的碳自由基比单体M1的碳自由基。

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