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    • 12. 发明授权
    • Secondary battery
    • 二次电池
    • US5468571A
    • 1995-11-21
    • US412230
    • 1995-03-27
    • Masahisa FujimotoKoji NishioToshihiko Saito
    • Masahisa FujimotoKoji NishioToshihiko Saito
    • H01M4/133H01M4/1393H01M4/58H01M4/583H01M4/62H01M10/05
    • H01M4/587H01M4/621H01M4/622
    • Provided is a secondary battery with a negative electrode comprising a carbon powder capable of occluding and discharging cations, particles constituting the powder being consolidated with a binder, the binder consisting essentially of a polyimide or polyvinyl formal resin. In this battery, carbon particles are sufficiently consolidated and, are also adhered firmly to the negative electrode collector metal so that they hardly peel off from the negative electrode. As a result, the battery hardly decreases its capacity even when charge-discharge cycles are repeatedly run, thereby having a long cycle life. Furthermore, since the binder for the negative electrode comprises PI or PVF, containing no fluorine, there is little danger of the battery bursting or breaking even when the battery temperature becomes abnormally high, whereby the battery has high reliability.
    • 本发明提供一种具有负极的二次电池,该负极包含能够吸收和排出阳离子的碳粉末,构成粉末的颗粒被粘合剂固结,所述粘合剂基本上由聚酰亚胺或聚乙烯醇缩甲醛树脂组成。 在该电池中,碳粒子被充分固结,并且也牢固地粘附到负极集电体金属,使得它们几乎不从负极剥离。 结果,即使当充放电循环重复地运行时,电池几乎也不会降低其容量,从而具有长的循环寿命。 此外,由于负极用粘合剂包含不含氟的PI或PVF,即使电池温度异常高,也不会发生电池爆裂或断裂的危险,电池具有高可靠性。