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    • 11. 发明授权
    • Curable composition for paint
    • 油漆组合物
    • US5344879A
    • 1994-09-06
    • US5130
    • 1993-01-15
    • Masaharu InoueYoshihiko OkimuraHirotoshi KawaguchiHisao Furukawa
    • Masaharu InoueYoshihiko OkimuraHirotoshi KawaguchiHisao Furukawa
    • C08G18/71C08K5/5419C09D143/04
    • C08G18/44C08G18/4277C08G18/718C08K5/5419C09D143/04
    • A curable composition for paint including(A) 10 to 99 parts by weight of a vinyl polymer having a number average molecular weight of not less than 2,000 and at least one silicon atom to which a hydrolyzable group is bonded at an end of the main chain and/or in a side chain thereof, in one molecule, wherein the main chain is substantially a vinyl polymer chain;(B) 1 to 90 parts by weight of a compound containing a carbonyldioxy group which is at least one of(i) a compound containing a hydrolyzable silyl group, the compound having at least one carbonyldioxy group in one molecule and at least one silicon atom to which a hydrolyzable group is bonded, in one molecule, and(ii) a polycarbonate polyol compound having at least one carbonyldioxy group and at least two hydroxyl groups in one molecule; and(C) 0.001 to 10 parts by weight of a curing catalyst on the basis of 100 parts by weight of the components (A) and (B) in total.This curable composition for paint has excellent high solid content and one package storage stability as well as superior scratch resistance and acid resistance.
    • 一种涂料用固化性组合物,其含有(A)10〜99重量份数均分子量为2000以上的乙烯基聚合物和至少一个可水解基团在主链末端键合的硅原子 和/或在其侧链中,在一个分子中,其中主链基本上是乙烯基聚合物链; (B)1〜90重量份含有羰基二氧基的化合物,其为(i)含有可水解甲硅烷基的化合物,在一个分子中具有至少一个羰基二氧基的化合物和至少一个硅原子 在一个分子中可水解基团键合的聚碳酸酯多元醇化合物,和(ii)在一个分子中具有至少一个羰基二氧基和至少两个羟基的聚碳酸酯多元醇化合物; 和(C)基于100重量份的组分(A)和(B)的总量,0.001至10重量份的固化催化剂。 这种涂料用可固化组合物具有优异的高固含量和一个包装储存稳定性以及优异的抗划伤性和耐酸性。
    • 13. 发明授权
    • Curable composition for topcoating and articles coated therewith
    • 用于表面涂层的固化组合物和用其涂覆的制品
    • US06383648B1
    • 2002-05-07
    • US09402821
    • 1999-12-30
    • Hitoshi TamaiMasaharu Inoue
    • Hitoshi TamaiMasaharu Inoue
    • B32B904
    • C08G18/6216C08G18/3893C08G18/6295C09D175/04Y10T428/31663
    • The present invention has its objects to provide a curable composition for top coating which has an excellent stain resistance, adhesiveness, solvent resistance and impact resistance. The present invention relates to a curable composition for top coating which comprises an acrylic copolymer (A) containing a reactive silyl group bound to a carbon atom as represented by the general formula (1) (wherein R1 represents a hydrogen atom or an alkyl group containing 1 to 10 carbon atoms, R2 represents a hydrogen atom or a univalent hydrocarbon group selected from among alkyl groups containing 1 to 10 carbon atoms, aryl groups and aralkyl groups and a represents an integer of 0 to 2), together with a hydroxyl group; 2 to 70 parts by weight, per 100 parts by weight of acrylic copolymer (A), of a silicon compound represented by the general formula (2) (wherein R3 represents a univalent hydrocarbon group selected from among alkyl groups containing 1 to 10 carbon atoms, aryl groups and aralkyl groups, R4 represents a univalent hydrocarbon group selected from among alkyl groups containing 1 to 10 carbon atoms, aryl groups and aralkyl groups and b represents 0 or 1), and/or a partial hydrolyzate condensate (B) thereof; and 0.1 to 50 parts by weight of a compound (C) containing two or more isocyanate groups which serves as a crosslinking agent.
    • 本发明的目的是提供一种具有优异的耐污性,粘合性,耐溶剂性和耐冲击性的顶涂层用固化性组合物。 本发明涉及一种顶涂剂用固化性组合物,其包含含有与通式(1)表示的碳原子结合的活性甲硅烷基的丙烯酸共聚物(A)(其中,R1表示氢原子或含有烷基的烷基 1〜10个碳原子,R2表示氢原子或选自含1〜10个碳原子的烷基,芳基和芳烷基,a表示0〜2的整数的一价烃基)和羟基; 2〜70重量份,相对于100重量份丙烯酸共聚物(A),由通式(2)表示的硅化合物(其中,R 3表示选自含有1〜10个碳原子的烷基中的一价烃基) ,芳基和芳烷基,R 4表示选自含有1至10个碳原子的烷基,芳基和芳烷基,b表示0或1)的一价烃基,和/或其部分水解产物缩合物(B); 和0.1〜50重量份含有两个以上作为交联剂的异氰酸酯基的化合物(C)。
    • 14. 发明授权
    • Curable composition for coating, and articles coated with it
    • 用于涂层的可固化组合物和用其涂覆的制品
    • US06265470B1
    • 2001-07-24
    • US09269962
    • 1999-04-08
    • Seigo NakamuraMasaharu InoueToshirou Nanbu
    • Seigo NakamuraMasaharu InoueToshirou Nanbu
    • C08K510
    • C09D163/00C08G59/42C08L2666/28
    • The curable composition for coating of the invention comprises (A) 100 parts by weight of a resin having at least 2 epoxy groups in one molecule and having an epoxy equivalent of from 200 to 2,000 g/mol, and (B) from 0.001 to 100 parts by weight of a compound having at least 2 carboxyl groups in one molecule, in a molar ratio of the epoxy group to the carboxyl group (epoxy group/carboxyl group) of from 0.2/1 to 5.0/1, and contains (C) at least one organic solvent selected from glycol monoalkyl ethers, vinyl ethers and cyclic ethers, and at least one selected from monoalkyl alcohol compounds and compounds capable of giving alcohols through hydrolysis, each in an amount of from 1.0 to 50 parts by weight relative to 100 parts by weight of the total solid resin content of the composition. The composition has good storage stability and good thermal curability, and the coating films from it have good acid resistance, scratch resistance and weather resistance.
    • 本发明的涂布用固化性组合物包含(A)100重量份在一分子中具有至少2个环氧基的树脂,其环氧当量为200〜2000g / mol,(B)0.001〜100 重量份在一分子中具有至少2个羧基的化合物,环氧基与羧基(环氧基/羧基)的摩尔比为0.2 / 1至5.0 / 1,并含有(C) 选自二醇单烷基醚,乙烯基醚和环醚的至少一种有机溶剂,以及选自单烷基醇化合物和能够通过水解产生醇的化合物中的至少一种,其量相对于100重量份为1.0至50重量份 占组合物总固体树脂含量的重量份。 该组合物具有良好的储存稳定性和良好的热固化性,并且其涂膜具有良好的耐酸性,耐擦伤性和耐候性。
    • 15. 发明授权
    • Simulation system and method for microcomputer program
    • 微机程序仿真系统及方法
    • US5963725A
    • 1999-10-05
    • US928433
    • 1997-09-12
    • Masaharu Inoue
    • Masaharu Inoue
    • G06F11/28G06F9/455G06F11/25G06F12/08
    • G06F12/0815G06F9/455
    • In a computer program simulation system, a simulation control unit calculates a simulation time until a machine language instruction execution simulation has an influence on a peripheral circuit simulation, and a simulation time notification unit provided in the simulation control unit notifies the calculated simulation time to a peripheral circuit simulation unit. The peripheral circuit simulation unit executes the peripheral circuit simulation for the notified simulation time. Thereafter, a machine language instruction execution simulation unit executes the machine language instruction execution simulation for the same time as the time in which the peripheral circuit simulation unit has executed the peripheral circuit simulation. Thus, the overhead such as communication between the simulation units and a preprocessing can be omitted so that the simulation processing speed can be elevated.
    • 在计算机程序模拟系统中,模拟控制单元计算机器语言指令执行模拟对外围电路模拟有影响的模拟时间,并且模拟控制单元中提供的模拟时间通知单元将计算出的模拟时间通知给 外围电路仿真单元。 外围电路仿真单元对通知的仿真时间执行外围电路仿真。 此后,机器语言指令执行模拟单元与外围电路模拟单元执行外围电路仿真的时间同时执行机器语言指令执行模拟。 因此,可以省略诸如模拟单元之间的通信和预处理的开销,从而可以提高模拟处理速度。
    • 16. 发明授权
    • Curable composition for paint
    • 油漆组合物
    • US5416165A
    • 1995-05-16
    • US138444
    • 1993-10-20
    • Yoshihiko OkimuraMasaharu InoueHirotoshi KawaguchiHisao Furukawa
    • Yoshihiko OkimuraMasaharu InoueHirotoshi KawaguchiHisao Furukawa
    • C09D133/14C08L43/04C09D133/04C09D137/00C09D143/04C09D183/04C09D201/00C09D201/10
    • C09D143/04C08L2205/02C08L43/04
    • A curable composition for paint containing:(A) 95 to 5 parts by weight of a vinyl copolymer having at least one specific hydrolyzable silyl group and at least one specific alcoholic hydroxyl group existing at an end of the main chain and/or in a side chain thereof in one molecule, in which the main chain contains substantially a vinyl copolymer chain and the alcoholic hydroxyl equivalent is from 180 to 2000 g/mol;(B) 5 to 95 parts by weight of a vinyl copolymer having at least one specific hydrolyzable silyl group at an end of the main chain and/or in a side chain thereof in one molecule and having no alcoholic hydroxyl group in the same molecule, in which the main chain contains substantially a vinyl copolymer chain; and(C) 0.001 to 10 parts by weight of a curing catalyst per 100 parts by weight of the total resin solids content.This curable composition for paint has well-balanced properties of good acid resistance, water resistance, scratch resistance, weathering resistance, and so forth.
    • 一种用于涂料的可固化组合物,其包含:(A)95至5重量份的具有至少一个特定的可水解甲硅烷基和至少一个特定的醇羟基的乙烯基共聚物,其存在于主链的末端和/或侧面 其中主链含有基本上乙烯基共聚物链,醇羟基当量为180-2000g / mol; (B)5〜95重量份在一分子中在主链末端和/或侧链具有至少一个特定的可水解甲硅烷基并且在同一分子中不含醇羟基的乙烯基共聚物, 其中主链含有基本上乙烯基共聚物链; 和(C)每100重量份总树脂固体含量为0.001〜10重量份的固化催化剂。 这种涂料用固化性组合物具有良好的耐酸性,耐水性,耐擦伤性,耐候性等特性。
    • 19. 发明授权
    • Detecting device for abnormal workpiece rotation in non-circular workpiece grinding machine
    • 非圆形工件磨床机械异常检测装置
    • US08142257B2
    • 2012-03-27
    • US12367755
    • 2009-02-09
    • Masaharu Inoue
    • Masaharu Inoue
    • B24B49/00
    • B24B19/125B24B49/00G05B19/184G05B19/406G05B2219/37277
    • In a non-circular workpiece grinding machine, a proximity sensor is arranged to face a non-circular portion of a workpiece for sensing a maximum diameter portion of the non-circular portion to detect that the maximum diameter portion is rotating in a detection phase section when the work spindle is rotating in a low speed rotational phase region in which the work spindle is controlled by a numerical controller to rotate at a low speed. Abnormality judging means is provided for judging that an abnormal workpiece rotation is occurring when the maximum diameter portion of the non-circular portion is not detected by the proximity sensor in the state that the work spindle is rotating in the low speed rotational phase region.
    • 在非圆形工件研磨机中,接近传感器布置为面对工件的非圆形部分,用于感测非圆形部分的最大直径部分,以检测最大直径部分在检测相位部分中旋转 当工作主轴在低速旋转相位区域中旋转时,其中工作主轴由数字控制器控制以低速旋转。 提供异常判定装置,用于在工作主轴在低速旋转相位区域中旋转的状态下判断在非圆形部分的最大直径部分未被接近传感器检测到时发生异常工件旋转。
    • 20. 发明授权
    • Curable composition for top coating and articles coated using the same
    • 用于顶涂层的可固化组合物和使用其涂覆的制品
    • US06265073B1
    • 2001-07-24
    • US09242147
    • 1999-02-09
    • Seigo NakamuraMasaharu InoueYoshiyuki KounoToshirou Nanbu
    • Seigo NakamuraMasaharu InoueYoshiyuki KounoToshirou Nanbu
    • B32B2738
    • C09D163/00C09D133/068Y10T428/31511Y10T428/31529Y10T428/31663C08L83/00C08L2666/02C08L2666/28C08L2666/44
    • The curable composition for coating of the invention comprises (A) 100 parts by weight of an epoxy group-having resin, (B) from 0.001 to 100 parts by weight of a carboxyl group-having compound or resin, and (C) from 1.0 to 100 parts by weight of a silicon compound of the following general formula (I) and/or its partially-hydrolyzed condensate: (R1O)4-aSiR2a  (I) wherein R1 represents a hydrogen atom, an alkyl group having from 1 to 10 carbon atoms, an aryl group having from 6 to 10 carbon atoms, or an aralkyl group having from 7 to 10 carbon atoms; R2 represents an alkyl group having from 1 to 10 carbon atoms, an aryl group having from 6 to 10 carbon atoms, an aralkyl group having from 7 to 10 carbon atoms, or an alkoxy group having from 1 to 10 carbon atoms; and a represents an integer of from 0 to 2. The composition has good thermal curability, and the coating films from the composition have excellent and well-balanced physical properties including excellent acid resistance, scratch resistance, weather resistance, appearance and recoating adhesiveness, and additionally have extremely excellent stain resistance.
    • 本发明的涂布用固化性组合物包含(A)100重量份的环氧基树脂,(B)0.001〜100重量份的含羧基化合物或树脂,(C)1.0 相对于100重量份的下述通式(I)的硅化合物和/或其部分水解缩合物:其中R1表示氢原子,具有1至10个碳原子的烷基,具有6个 至10个碳原子,或具有7至10个碳原子的芳烷基; R2表示碳原子数1〜10的烷基,碳原子数6〜10的芳基,碳原子数7〜10的芳烷基或碳原子数1〜10的烷氧基。 a表示0〜2的整数。该组合物具有良好的热固化性,并且来自该组合物的涂膜具有优异且平衡良好的物理性能,包括优异的耐酸性,耐刮擦性,耐候性,外观和重涂粘合性,以及 另外具有非常优异的耐污性。