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    • 13. 发明专利
    • ORGANOMETALLIC COMPOUND AND PRODUCTION METHOD THEREOF
    • SG176951A1
    • 2012-02-28
    • SG2011095031
    • 2010-06-30
    • MITSUI CHEMICALS INC
    • OCHIAI TAKASHIMAKIO HARUYUKI
    • It is an object of the present invention to provide a novel organometallic compound functioning usefully as a chain transfer agent and the like in polymerization reaction of adouble-bond containing compound. The present inventionprovides an organometallic compound represented by the following general formula (1) and a production method thereof. [err] (in the general formula (1), M is a magnesium atom, azinc atom, an A1-R[err] group, or a Ga -R[err] group; R[err] and R[err] are each independently a hydrocarbon group having 1 to 20 carbon atoms, or R[err] and R[err] may be united with each other to form a divalent connecting group (R[err]) having 4 or more carbon atomsand thus form a ring; R[err] to R[err] are each independently a hydrogen atom, or a hydrocarbon group having 1 to 20 carbon atoms; Q[err] and Q[err] are each independently a divalent hydrocarbon group; Q[err] is a divalent connecting group containing a linkage by a heteroatom excluding carbon; h, j, k, m, and p are eachindependently 0 or 1; n is an integer of 0 to 10; and r is an integer of 0 to 1000.
    • 20. 发明专利
    • Catalyst for use in polymerization of ethylenically unsaturated monomer, and method of polymerizing ethylenically unsaturated monomer using the catalyst
    • 用于乙烯基不饱和单体聚合的催化剂,以及使用催化剂聚合乙烯不饱和单体的方法
    • JP2007126686A
    • 2007-05-24
    • JP2007038420
    • 2007-02-19
    • Mitsui Chemicals Inc三井化学株式会社
    • DOI YASUSHIMAKIO HARUYUKIFUJITA TERUNORITSUTSUI TOSHIYUKI
    • C08F4/60
    • PROBLEM TO BE SOLVED: To provide a catalyst comprising a novel catalyst component and a transition metal compound, and a polymerization method using the catalyst. SOLUTION: The catalyst for use in polymerization of an ethylenically unsaturated monomer comprises (A) a compound of a transition metal selected from those belonging to the groups 3 to 12 in the periodic table, (B) a catalyst component, and (C) a specific organic aluminum compound, wherein component (B) is a catalyst component obtained by reacting, in any order, (i) a specific organic aluminum compound, (ii) H 2 O, R 4 NH 2 , etc. (R 4 represents a halogenated hydrocarbon group), and (iv) R 10 X, R 10 H, R 10 OH or R 10 COOH (R 10 represents a halogenated hydrocarbon group, and X represents a halogen atom), and then reacting the reaction product with (iii) triphenyl chloromethane, bis(η-cyclopentadienyl)iron-sulfate, N,N-dimethyl anilinium chloride or triethyl ammonium chloride. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供包含新型催化剂组分和过渡金属化合物的催化剂和使用该催化剂的聚合方法。 解决方案:用于烯键式不饱和单体聚合的催化剂包含(A)选自元素周期表中第3至12族的过渡金属化合物,(B)催化剂组分和( C)特定有机铝化合物,其中组分(B)是通过以任何顺序使(i)特定的有机铝化合物,(ii)H 2 SBO,R 2, SP> 4 NH 2 等(R 4 表示卤代烃基),和(iv)R 10 ,R 10,R 10,R 10,R 10,R 10,R 10,R 10,R 10, X表示卤素原子),然后使反应产物与(iii)三苯基氯甲烷,双(η-环戊二烯基)硫酸铁,N,N-二甲基苯胺氯化物或三乙基氯化铵反应。 版权所有(C)2007,JPO&INPIT