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11. 发明申请

US20110190419A1 BLENDS COMPRISING EPOXY RESINS AND MIXTURES OF AMINES WITH GUANIDINE DERIVATIVES 有权
标题翻译：包含环氧树脂的混合物和与胍衍生物的胺的混合物
公开(公告)号：US20110190419A1
公开(公告)日：2011-08-04
申请号：US13055174
申请日：2009-07-17
申请人： Lars Wittenbecher , Michael Henningsen , Gregor Daun , Dieter Flick , Joerg-Peter Geisler , Juergen Schillgalies , Erhard Jacobi
发明人： Lars Wittenbecher , Michael Henningsen , Gregor Daun , Dieter Flick , Joerg-Peter Geisler , Juergen Schillgalies , Erhard Jacobi
IPC分类号： C08G59/56 , B29C35/02 , C08L63/00
CPC分类号： C08G59/02 , C07C279/04 , C07C279/16 , C08G59/4021 , C08G59/50 , C08G59/56 , C08L63/00 , Y10T428/24994 , Y10T428/31511
摘要： The present invention provides a blend comprising one or more epoxy resins and a mixture which comprises 0.3 to 0.9 amine equivalent, per equivalent of epoxide of the epoxy resin used, of a hardener component a) and as hardener component b) a compound of the formula I, a process for preparing this blend, the use of the blend of the invention for producing cured epoxy resin, and an epoxy resin cured with the blend of the invention.
摘要翻译：本发明提供了包含一种或多种环氧树脂和包含0.3至0.9胺当量，每当量使用的环氧树脂的环氧化物，固化剂组分a）和作为固化剂组分的混合物的混合物b）式 I，制备该共混物的方法，本发明共混物用于生产固化的环氧树脂的用途以及用本发明的共混物固化的环氧树脂。

12. 发明申请

US20110130524A1 MIXTURES OF AMINES WITH GUANIDINE DERIVATIVES 有权
标题翻译：含有衍生物的胺的混合物
公开(公告)号：US20110130524A1
公开(公告)日：2011-06-02
申请号：US13054945
申请日：2009-07-17
申请人： Lars Wittenbecher , Michael Henningsen , Gregor Daun , Dieter Flick , Joerg-Peter Geisler , Juergen Schillgalies , Erhard Jacobi
发明人： Lars Wittenbecher , Michael Henningsen , Gregor Daun , Dieter Flick , Joerg-Peter Geisler , Juergen Schillgalies , Erhard Jacobi
IPC分类号： C08G59/14 , C09K3/00
CPC分类号： C07C211/36 , C07C279/04 , C08G59/4021 , C08G59/50 , C09J163/00
摘要： The present invention provides a mixture comprising at least three hardener components a1), a2), and b), the ratio of hardener component a1) to a2) being in the range from 0.1 to 10:1, and hardener component b) being present at 5% to 55% by weight, based on the mixture, a process for preparing this mixture, the use of the mixture of the invention for curing epoxy resins, the use of the mixture of the invention with epoxy resins as adhesives, and an epoxy resin cured with the mixture of the invention.
摘要翻译：本发明提供包含至少三种硬化剂组分a1），a2）和b）的混合物，硬化剂组分a1）至a2）的比例为0.1-10:1，并且硬化剂组分b）存在基于该混合物的5重量％至55重量％，制备该混合物的方法，使用本发明混合物固化环氧树脂，本发明混合物与环氧树脂作为粘合剂的用途，以及用本发明的混合物固化的环氧树脂。

13. 发明授权

US09328058B2 Mixtures of amines with guanidine derivatives 有权
标题翻译：胺与胍衍生物的混合物
公开(公告)号：US09328058B2
公开(公告)日：2016-05-03
申请号：US13054945
申请日：2009-07-17
申请人： Lars Wittenbecher , Michael Henningsen , Gregor Daun , Dieter Flick , Joerg-Peter Geisler , Juergen Schillgalies , Erhard Jacobi
发明人： Lars Wittenbecher , Michael Henningsen , Gregor Daun , Dieter Flick , Joerg-Peter Geisler , Juergen Schillgalies , Erhard Jacobi
IPC分类号： C09K3/00 , C08L63/00 , C08G59/14 , C07C211/36 , C07C279/04 , C08G59/40 , C08G59/50 , C09J163/00
CPC分类号： C07C211/36 , C07C279/04 , C08G59/4021 , C08G59/50 , C09J163/00
摘要： The present invention provides a mixture comprising at least three hardener components a1), a2), and b), the ratio of hardener component a1) to a2) being in the range from 0.1 to 10:1, and hardener component b) being present at 5% to 55% by weight, based on the mixture, a process for preparing this mixture, the use of the mixture of the invention for curing epoxy resins, the use of the mixture of the invention with epoxy resins as adhesives, and an epoxy resin cured with the mixture of the invention.
摘要翻译：本发明提供包含至少三种硬化剂组分a1），a2）和b）的混合物，硬化剂组分a1）至a2）的比例为0.1-10:1，并且硬化剂组分b）存在基于该混合物的5重量％至55重量％，制备该混合物的方法，使用本发明混合物固化环氧树脂，本发明混合物与环氧树脂作为粘合剂的用途，以及用本发明的混合物固化的环氧树脂。

14. 发明授权

US08399596B2 Epoxy resin compositions and process for preparing them 失效
标题翻译：环氧树脂组合物及其制备方法
公开(公告)号：US08399596B2
公开(公告)日：2013-03-19
申请号：US12518175
申请日：2007-11-30
申请人： Michael Henningsen , Lars Wittenbecher
发明人： Michael Henningsen , Lars Wittenbecher
IPC分类号： C08G59/00
CPC分类号： C07D301/28 , C07D303/28 , C08G59/24
摘要： The preparation of epoxy resin compositions which comprise glycidyl ethers comprising cyclohexyl groups and have a low oligomer content is carried out by distillation of compositions which are obtainable by ring hydrogenation of compounds of the general formula (I) where —X— is —CR2—, —CO—, —O, —S—, —SO2—, the radicals R are each, independently of one another, H, C1-6-alkyl, C3-6-cycloalkyl, in which one or more H atoms can be replaced by halogen, the radicals R′ are each, independently of one another, C1-4-alkyl, halogen, the indices n are each, independently of one another, 0, 1, 2 or 3, and subsequent reaction of the hydroxyl groups with epichlorohydrin, in thin film evaporators or short path evaporators at a temperature in the range from 150 to 270° C. and a pressure in the range from 0.001 to 1 mbar.
摘要翻译：包含环己基并且具有低低聚物含量的缩水甘油醚的环氧树脂组合物的制备通过蒸馏可通过环化氢化通式（I）的化合物获得的组合物进行，其中-X-为-CR 2 - -CO - ， - O - ， - S - ， - SO 2 - ，基团R各自独立地为氢，C 1-6 - 烷基，C 3-6 - 环烷基，其中一个或多个H原子可以被替换通过卤素，基团R'各自独立地为C 1-4 - 烷基，卤素，指数n各自彼此独立地为0,1,2或3，随后羟基与表氯醇，薄膜蒸发器或短程蒸发器，温度范围为150至270℃，压力范围为0.001至1毫巴。

15. 发明申请

US20130143984A1 PRODUCTION OF CURED EPOXY RESINS WITH FLAME-RETARDANT PHOSPHONATES 审中-公开
标题翻译：生产具有阻燃磷酸盐的固化环氧树脂
公开(公告)号：US20130143984A1
公开(公告)日：2013-06-06
申请号：US13491074
申请日：2012-06-07
申请人： Michael Henningsen , Achim Kaffee , Jean-Francois Stumbe , Manfred Doering , Alexander Schmidt , Lin Zang , Volker Altstaedt , Johannes Kraemer
发明人： Michael Henningsen , Achim Kaffee , Jean-Francois Stumbe , Manfred Doering , Alexander Schmidt , Lin Zang , Volker Altstaedt , Johannes Kraemer
IPC分类号： C08K5/5373 , C08K5/5333
CPC分类号： C08K5/5373 , C08G59/4021 , C08K5/5317 , C08K5/5333 , C08L63/00
摘要： The invention relates to curable compositions which comprise epoxy resins, amino hardeners, and a phosphonate of the formula I. Addition of phosphonate of the formula I can give cured epoxy resins which have not only improved flame retardants but also an increased glass transition temperature when comparison is made with the corresponding resins without said addition.
摘要翻译：本发明涉及包含环氧树脂，氨基硬化剂和式I的膦酸酯的可固化组合物。加入式I的膦酸酯可以得到固化的环氧树脂，其不仅具有改进的阻燃剂，而且当比较时，玻璃化转变温度升高用相应的树脂制成而没有加入。

16. 发明申请

US20130203898A1 HYPERBRANCHED POLYMERS FOR MODIFYING THE TOUGHNESS OF CURED EPOXY RESIN SYSTEMS 审中-公开
标题翻译：用于改性固化环氧树脂体系的韧性的高分子聚合物
公开(公告)号：US20130203898A1
公开(公告)日：2013-08-08
申请号：US13754120
申请日：2013-01-30
申请人： Anna MUELLER-CRISTADORO , Jean-Francois Stumbe , Guenter Scherr , Michael Henningsen , Bernd Bruchmann , Monika Haberecht , Miran Yu , Chunhong Yin , Achim Kaffee
发明人： Anna MUELLER-CRISTADORO , Jean-Francois Stumbe , Guenter Scherr , Michael Henningsen , Bernd Bruchmann , Monika Haberecht , Miran Yu , Chunhong Yin , Achim Kaffee
IPC分类号： C08G59/10
CPC分类号： C08G59/10 , C08G59/5006 , C08G59/5073 , C08J5/24 , C08J2363/00 , C08J2400/202 , C08L63/00 , C08L101/005
摘要： The invention relates to a curable composition comprising one or more epoxy compounds, one or more amino hardeners, and an addition of one or more dendritic polymers selected from the group of the dendritic polyester polymers, where the dendritic polyester polymers can be produced through an Ax+By synthesis route.
摘要翻译：本发明涉及包含一种或多种环氧化合物，一种或多种氨基硬化剂和加入一种或多种选自树枝状聚酯聚合物的树枝状聚合物的可固化组合物，其中树枝状聚酯聚合物可以通过Ax +通过综合路线。

17. 发明授权

US07368464B2 Preparation for the production of 1,2,4-triazolylmethyl-oxiranes 失效
标题翻译：制备1,2,4-三唑基甲基环氧乙烷
公开(公告)号：US07368464B2
公开(公告)日：2008-05-06
申请号：US10516727
申请日：2003-06-06
申请人： Rainer Noack , Michael Sander , Michael Henningsen
发明人： Rainer Noack , Michael Sander , Michael Henningsen
IPC分类号： A61K31/41 , C07D249/08
CPC分类号： C07D249/08 , C07D231/12 , C07D233/56
摘要： The present invention relates to a process for the preparation of 1,2,4-triazol-1-ylmethyloxiranes of the formula I in which A and B are identical or different and, independently of one another, are C1-C4-alkyl, phenyl-C1-C2-alkyl, C3-C6-cycloalkyl, C3-C6-cycloalkenyl, tetrahydropyranyl, tetrahydrofuranyl, dioxanyl or phenyl, where the phenyl radical can carry one to three substituents chosen from the group: halogen, nitro, C1-C4-alkyl, Cl-C4-alkyloxy, phenoxy, amino, C1-C2-haloalkyl or phenylsulfonyl, which comprises reacting a) an oxirane of the formula II in which A and B have the meanings given above and L is a nucleophilically substitutable leaving group, with 4-amino-1,2,4-triazole of the formula III to give 4-amino-1,2,4-triazolium salts of the formula IV and b) deaminating the 4-amino-1,2,4-triazolium salts IV with alkali metal nitrites and acid or organic nitrites to give 1,2,4-triazol-1-ylmethyloxiranes of the formula I, and to 4-aminotriazolium salts of the formula IV as intermediates.
摘要翻译：本发明涉及制备式I的1,2,4-三唑-1-基甲基环氧烷的方法，其中A和B相同或不同，且彼此独立地为C 1〜 C 1 -C 4 - 亚烷基，苯基-C 1 -C 2 - 烷基，C 3 -C C 6 -C 6 - 环烷基，C 3 -C 6 - 环烯基，四氢吡喃基，四氢呋喃基，二烷基或苯基，其中苯基可以携带一至三个选自以下的取代基：卤素，硝基，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，苯氧基，氨基，C 1 -C 2 - 卤代烷基或苯基磺酰基，其包括使a）式A的环氧乙烷与A和B具有式 L是具有式III的4-氨基-1,2,4-三唑的亲核可取代的离去基团，得到式IV的4-氨基-1,2,4-三唑鎓盐，和b）脱氨基具有碱金属元素的4-氨基-1,2,4-三唑鎓盐IV l亚硝酸盐和酸或有机亚硝酸盐，得到式I的1,2,4-三唑-1-基甲基环氧乙烷和作为中间体的式IV的4-氨基三唑鎓盐。

18. 发明授权

US07105662B2 Method of producing N-substituted 2,6-dialkylmorpholines 有权
标题翻译：制备N-取代2,6-二硫代吗啉的方法
公开(公告)号：US07105662B2
公开(公告)日：2006-09-12
申请号：US10471550
申请日：2002-03-15
申请人： Michael Henningsen , Andreas Kusche , Michael Hüllmann , Lothar Rüb , Stefan Käshammer , Till Gerlach
发明人： Michael Henningsen , Andreas Kusche , Michael Hüllmann , Lothar Rüb , Stefan Käshammer , Till Gerlach
IPC分类号： C07D265/30
CPC分类号： C07D295/027 , C07D295/023 , C07D295/03
摘要： The present invention relates to a process for the preparation of N-substituted 2,6-dialkylmorpholines of the formula I in which R1 and R2, independently of one another, are hydrogen, alkyl or cycloalkyl, or R1 and R2 together with the carbon atom to which they are bonded are a 5- to 14-membered carbocycle, and R3 and R4, independently of one another, are alkyl or cycloalkyl, by reacting at least one carbonyl compound of the formula II in which R1 and R2 have the meanings given above, with at least one morpholine of the formula III in which R3 and R4 have the meanings given above, in the presence of hydrogen and at least one metal-containing catalyst, wherein the active component of the catalyst consists essentially of platinum group metals.
摘要翻译：本发明涉及一种其中R 1和R 2彼此独立地制备式I的N-取代的2,6-二硫代吗啉的方法，是氢，烷基或环烷基，或R 1和R 2与它们所键合的碳原子一起为5至14元碳环，通过使至少一种式II的羰基化合物与其中R 1，R 2，R 3和R 4彼此独立地是烷基或环烷基，和R 2具有上面给出的含义，其中至少一个式III的吗啉其中R 3和R 4具有给定的含义在氢气和至少一种含金属的催化剂的存在下，催化剂的活性组分基本上由铂族金属组成。

19. 发明申请

US20050239848A1 Dithianon-based fungicidal mixtures 失效
标题翻译：基于Dithianon的杀真菌混合物
公开(公告)号：US20050239848A1
公开(公告)日：2005-10-27
申请号：US10517209
申请日：2003-06-30
申请人： Eberhard Ammermann , Reinhard Stierl , Ulrich Schofl , Klaus Schelberger , Maria Scherer , Michael Henningsen , Randall Gold
发明人： Eberhard Ammermann , Reinhard Stierl , Ulrich Schofl , Klaus Schelberger , Maria Scherer , Michael Henningsen , Randall Gold
IPC分类号： A01N25/06 , A01N43/32 , A01N43/40
CPC分类号： A01N43/32 , A01N2300/00
摘要： Fungicidal mixtures, comprising A) the compound of the formula I B) a biphenylamide of the formula II, in which Z is a pyridyl ring or a five-membered heteroaryl ring which, in addition to carbon atoms, contains one or two nitrogen atoms or one nitrogen atom and one oxygen or sulfur atom, where Z carries one to three identical or different substituents from the group consisting of halogen, methyl and trifluoromethyl, and X is halogen, in a synergistically effective amount, methods for controlling harmful fungi using mixtures of the compounds I and II and the use of the compounds I and II for preparing such mixtures are described.
摘要翻译：杀真菌混合物，其包含A）式IB化合物）式II的联苯酰胺，其中Z是除碳原子之外还含有一个或两个氮原子或一个氮原子的吡啶环或五元杂芳基环氮原子和一个氧或硫原子，其中Z携带一至三个相同或不同的取代基，由卤素，甲基和三氟甲基组成的组，X为卤素，协同有效量的方法，使用描述了化合物I和II以及化合物I和II用于制备这种混合物的用途。

20. 发明授权

US06042799A Coproduction of acetylene and hydrocyanic acid from acrylonitrile 失效
标题翻译：从丙烯腈生产乙炔和氢氰酸
公开(公告)号：US06042799A
公开(公告)日：2000-03-28
申请号：US34274
申请日：1998-03-04
申请人： Klaus Halbritter , Michael Henningsen , Manfred Julius , Wolf Stegmaier
发明人： Klaus Halbritter , Michael Henningsen , Manfred Julius , Wolf Stegmaier
IPC分类号： C01C3/02 , C07C1/32 , C01C3/08 , C07C2/00 , C07C2/02
CPC分类号： C01C3/0245 , C07C1/323
摘要： In the process for preparing acetylene and hydrocyanic acid by pyrolyzing acrylonitrile in a reactor, the gaseous reaction products of the pyrolysis are quenched down to less than 100.degree. C. immediately, advantageously within seconds, preferably within .ltoreq.1 s, of leaving the pyrolysis zone.
摘要翻译：在通过在反应器中热解丙烯腈制备乙炔和氢氰酸的方法中，将热分解的气态反应产物立即下降至小于100℃，有利地在几秒钟内，优选在<1s内离开热解区。

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