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    • 18. 发明申请
    • Method for preparing sic crystal and sic crystal
    • 制备晶体和晶体晶体的方法
    • US20050181627A1
    • 2005-08-18
    • US10508130
    • 2003-03-19
    • Isaho KamataHidekazu Tsuchida
    • Isaho KamataHidekazu Tsuchida
    • C30B25/02H01L21/31
    • C30B25/02C30B29/36
    • A process for closing hollow-core defects, called micropipes, during growth by CVD of a SiC crystal on a SiC single crystal substrate having hollow-core defects, and a crystal obtained according to the process, by contacting the SiC crystal with a source gas adjusted to a C/Si atom ratio range in which the crystal growth rate is determined by the carbon atom supply limitation, then epitaxially growing and laminating a plurality of SiC crystal layers, wherein hollow-core defects in the SiC single crystal substrate dissociate into a plurality of dislocations given by small Burgers vector in order not to propagate to the crystal surface. In addition, the present invention provides a fabrication process of a SiC crystal, wherein a first SiC crystal is made as a buffer layer, and a further SiC crystal is layered thereon using a source gas adjusted to be higher than that of the C/Si ratio when forming the buffer layer, whereby a desired film property is conferred.
    • 在具有中空芯缺陷的SiC单晶衬底上的SiC晶体的CVD生长期间闭合中空缺陷的方法,以及根据该工艺获得的晶体,通过使SiC晶体与源气体 调整为通过碳原子供给限制来确定晶体生长速率的C / Si原子比范围,然后外延生长并层叠多个SiC晶体层,其中SiC单晶衬底中的中空缺陷解离成 为了不传播到晶体表面,由小汉堡矢量给出多个位错。 另外,本发明提供一种SiC晶体的制造方法,其中使用第一SiC晶体作为缓冲层,并且使用调节为高于C / Si的源气体将另外的SiC晶体层叠在其上 形成缓冲层的比例,由此赋予所需的膜性质。
    • 20. 发明授权
    • Silicon carbide bipolar semiconductor device
    • 碳化硅双极半导体器件
    • US08154026B2
    • 2012-04-10
    • US12097019
    • 2006-12-13
    • Ryosuke IshiiKoji NakayamaYoshitaka SugawaraToshiyuki MiyanagiHidekazu TsuchidaIsaho KamataTomonori Nakamura
    • Ryosuke IshiiKoji NakayamaYoshitaka SugawaraToshiyuki MiyanagiHidekazu TsuchidaIsaho KamataTomonori Nakamura
    • H01L29/15
    • H01L29/1604H01L21/0465H01L21/047H01L29/0615H01L29/0619H01L29/0661H01L29/1608H01L29/6606H01L29/66068H01L29/8613
    • In a SiC bipolar semiconductor device with a mesa structure having a SiC drift layer of a first conductive type and a SiC carrier injection layer of a second conductive type that are SiC epitaxial layers grown from a surface of a SiC single crystal substrate, the formation of stacking faults and the expansion of the area thereof are prevented and thereby the increase in forward voltage is prevented. Further, a characteristic of withstand voltage in a reverse biasing is improved. An forward-operation degradation preventing layer is formed on a mesa wall or on a mesa wall and a mesa periphery to separate spatially the surface of the mesa wall from a pn-junction interface. In one embodiment, the forward-operation degradation preventing layer is composed of a silicon carbide low resistance layer of a second conductive type that is equipotential during the application of a reverse voltage. In another embodiment, the forward-operation degradation preventing layer is composed of a silicon carbide conductive layer of a second conductive type, and a metal layer that is equipotential during the application of a reverse voltage is formed on a surface of the silicon carbide conductive layer. In still another embodiment, the forward-operation degradation preventing layer is composed of a high resistance amorphous layer.
    • 在具有由SiC单晶衬底的表面生长的SiC外延层的具有第一导电类型的SiC漂移层和第二导电类型的SiC载流子注入层的台阶结构的SiC双极型半导体器件中,形成 防止堆垛层错及其面积的膨胀,从而防止正向电压的增加。 此外,提高了反向偏置中的耐受电压的特性。 在台面壁或台面壁和台面周边上形成正向操作降解防止层,以在空间上分离台面壁的表面与pn结界面。 在一个实施例中,正向操作降解防止层由在施加反向电压期间具有等电位的第二导电类型的碳化硅低电阻层构成。 在另一个实施方案中,正向操作降解防止层由第二导电类型的碳化硅导电层构成,并且在施加反向电压期间具有等电位的金属层形成在碳化硅导电层的表面上 。 在另一个实施方案中,正向操作降解防止层由高电阻非晶层组成。