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    • 14. 发明授权
    • Method for making a lithographic printing plate according to the silver
salt diffusion transfer process
    • 根据银盐扩散转移法制造平版印刷版的方法
    • US5536618A
    • 1996-07-16
    • US395100
    • 1995-02-27
    • Rene De KeyzerPaul CallantJean-Marie DewanckeleMarcel Monbaliu
    • Rene De KeyzerPaul CallantJean-Marie DewanckeleMarcel Monbaliu
    • G03C8/06G03C8/36G03F7/07G03F7/32G03C5/38
    • G03F7/07G03C8/365
    • The present invention provides a method for making a lithographic printing plate according to the silver salt diffusion transfer process comprising the steps of exposing and developing an imaging element comprising on a support a silver halide emulsion layer and an image-receiving layer in the presence of a silver halide solvents corresponding to the following formula:Z.sup.1 --(R.sup.1 --X.sup.1).sub.n --(R.sup.2 --X.sup.2)--L--(X.sup.3 --R.sup.3)--(X.sup.4 --R.sup.4).sub.m --Z.sup.2 (I)wherein X.sup.1, X.sup.2, X.sup.3 and X.sup.4 each independently represents --S--, --NH-- or --N(R.sup.5 --Z.sup.3)--, R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 each independently represents an alkylene, an alkenylene or an alkynylene, n and m each independently represents an integer from 0 to 4, Z.sup.1, Z.sup.2 and Z.sup.3 each independently represents hydrogen, an alkyl group, an amino group, an ammonium group, a hydroxyl, a sulfo group, a carboxyl, an aminocarbonyl or an aminosulfonyl, and L represents an ethylene or a C.sub.3 -C.sub.4 divalent linking chain, having a group preventing free rotation within this divalent linking chain, X.sup.2 and X.sup.3 being in the thermodynamically most stable conformation of said compound in a favorable position for complexation with a silver ion.
    • 本发明提供了一种根据银盐扩散转移方法制备平版印刷版的方法,该方法包括以下步骤:在含有卤化银乳剂层和图像接收层的存在下,在载体上曝光和显影成像元件 对应于下式的卤化银溶剂:Z1-(R1-X1)n-(R2-X2)-L-(X3-R3) - (X4-R4)m-Z2(Ⅰ)其中X1,X2,X3和 X4各自独立地表示-S-,-NH-或-N(R5-Z3) - ,R1,R2,R3,R4和R5各自独立地表示亚烷基,亚烯基或亚炔基,n和m各自独立地表示整数 0至4,Z 1,Z 2和Z 3各自独立地表示氢,烷基,氨基,铵基,羟基,磺基,羧基,氨基羰基或氨基磺酰基,L表示乙烯或 具有在该二价连接链中自由旋转的基团的C 3 -C 4二价连接链,X 2和X 3在其中 所述化合物在与银离子络合的有利位置的热力学最稳定构象。