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    • 12. 发明授权
    • Nanoporous ceramics with catalytic functionality
    • 具有催化功能的纳米多孔陶瓷
    • US5852088A
    • 1998-12-22
    • US578084
    • 1995-12-27
    • John P. DismukesJack Wayne JohnsonJohn Stewart Bradley
    • John P. DismukesJack Wayne JohnsonJohn Stewart Bradley
    • B01J35/10C04B38/00C08K5/00
    • C04B38/0022B01J35/1014B01J35/1019B01J35/1038B01J35/1057C04B2111/00801C04B2111/0081
    • The present invention provides for amorphous, nanoporous, catalytic metal-containing ceramic material having a surface area in excess of 70 m.sup.2 /gm and characterized by a high content of open microporous cell structure wherein the micropores have a mean width of less than 20 Angstroms and wherein said microporous structure comprises a volume of greater than about 0.03 cm.sup.3 /gm of the ceramic. The invention also provides for a preceramic composite intermediate composition comprising a mixture of a ceramic precursor and from about 0.5 up to about 65 wt % of an organometallic compound containing a metal of Group IB, II, III, IV, IV, V, VIB, VIIA or VIII of the Periodic Table, including rare earth metals, whose pyrolysis product in ammonia or an inert atmosphere at temperatures of up to less than about 1100.degree. C. gives rise to the nanoporous catalytic ceramics of the invention. Also provided is a process for the preparation of the nanoporous ceramics of the invention involving pyrolysis of the ceramic intermediate under controlled conditions of heating up to temperatures of less than about 1100.degree. C. to form a nanoporous ceramic product useful in catalytic and membrane separation processes.
    • 本发明提供了具有超过70m 2 / gm的表面积的无定形,纳米孔,催化含金属的陶瓷材料,其特征在于高含量的开孔微孔孔结构,其中微孔的平均宽度小于20埃, 其中所述微孔结构包括大于约0.03cm 3 / gm的陶瓷体积。 本发明还提供了一种预陶瓷复合中间体组合物,其包含陶瓷前体和约0.5至约65重量%的含有IB,II,III,IV,IV,V,VIB族金属的金属的有机金属化合物的混合物, 包括稀土金属的元素周期表VIIA或VIII,它们的热解产物在氨或惰性气氛中,温度高达约1100℃,产生本发明的纳米多孔催化陶瓷。 还提供了制备本发明的纳米多孔陶瓷的方法,其包括在加热到低于约1100℃的温度的受控条件下陶瓷中间体的热解,以形成可用于催化和膜分离过程的纳米多孔陶瓷产物 。
    • 17. 发明授权
    • Pyrolysis of ceramic precursors to nanoporous ceramics
    • 陶瓷前体热解为纳米多孔陶瓷
    • US5872070A
    • 1999-02-16
    • US778531
    • 1997-01-03
    • John Pickett DismukesJack Wayne JohnsonJames L. Pizzulli
    • John Pickett DismukesJack Wayne JohnsonJames L. Pizzulli
    • C01B33/12C04B38/00C04B38/06
    • C04B38/0022Y10S977/831
    • The present invention provides for amorphous, nanoporous, ceramic material having a surface area in excess of 70 m.sup.2 /gm and characterized by a high content of open microporous cell structure wherein the micropores have a mean width of less than 20 Angstroms and wherein said microporous structure comprises a volume of greater than about 0.03 cm.sup.3 /gm of the ceramic. The invention also provides a process for the preparation of such nanoporous ceramics wherein a ceramic precursor polymer or oligomer is gradually heated in the presence of an inert gas or vacuum up to a maximum temperature in the range of greater than 400.degree. C. up to about 650.degree. C. Optionally, the process may also include a crosslinking step conducted prior to the heating step wherein the precursor polymer or oligomer is heated in the presence of a crosslinking agent capable of undergoing addition or substitution reactions with backbone atoms present in said precursor material, at an intermediate temperature of about 100.degree. to 400.degree. C. for a period of time sufficient to crosslink said precursor material, followed by pyrolysis of the crosslinked material.
    • 本发明提供了具有超过70m 2 / gm的表面积的无定形纳米多孔陶瓷材料,其特征在于高含量的开孔微孔孔结构,其中微孔具有小于20埃的平均宽度,并且其中所述微孔结构 包括大于约0.03cm 3 / gm的陶瓷体积。 本发明还提供了一种制备这种纳米多孔陶瓷的方法,其中陶瓷前体聚合物或低聚物在惰性气体或真空存在下逐渐加热至高达400℃至最高约400℃的最高温度 任选地,该方法还可以包括在加热步骤之前进行的交联步骤,其中前体聚合物或低聚物在能够与存在于所述前体材料中的骨架原子进行加成或取代反应的交联剂存在下加热 在约100-400℃的中间温度下搅拌一段足以交联所述前体材料的时间,然后热解交联的材料。