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11. 发明申请

US20120107597A1 EMBEDDED ARRAYS OF VERTICALLY ALIGNED CARBON NANOTUBE CARPETS AND METHODS FOR MAKING THEM 有权
标题翻译：垂直对准碳纳米管地毯的嵌入阵列及其制备方法
公开(公告)号：US20120107597A1
公开(公告)日：2012-05-03
申请号：US12297115
申请日：2007-04-23
申请人： Myung Jong Kim , Nolan Walker Nicholas , W. Carter Kittrell , Howard K. Schmidt
发明人： Myung Jong Kim , Nolan Walker Nicholas , W. Carter Kittrell , Howard K. Schmidt
IPC分类号： B32B5/16 , B29C45/14 , H01B1/04 , B82Y30/00
CPC分类号： C01B31/0206 , B82Y10/00 , B82Y30/00 , B82Y40/00 , C01B32/15 , H01L51/0048 , Y10T428/249924
摘要： According to some embodiments, the present invention provides a system and method for supporting a carbon nanotube array that involve an entangled carbon nanotube mat integral with the array, where the mat is embedded in an embedding material. The embedding material may be depositable on a carbon nanotube. A depositable material may be metallic or nonmetallic. The embedding material may be an adhesive material. The adhesive material may optionally be mixed with a metal powder. The embedding material may be supported by a substrate or self-supportive. The embedding material may be conductive or nonconductive. The system and method provide superior mechanical and, when applicable, electrical, contact between the carbon nanotubes in the array and the embedding material. The optional use of a conductive material for the embedding material provides a mechanism useful for integration of carbon nanotube arrays into electronic devices.
摘要翻译：根据一些实施方案，本发明提供了一种用于支撑碳纳米管阵列的系统和方法，所述碳纳米管阵列涉及与所述阵列整合的缠结碳纳米管垫，其中所述垫嵌入嵌入材料中。嵌入材料可以沉积在碳纳米管上。可存放材料可以是金属或非金属的。嵌入材料可以是粘合剂材料。粘合剂材料可以任选地与金属粉末混合。嵌入材料可以由衬底支撑或自支撑。嵌入材料可以是导电的或非导电的。该系统和方法在阵列中的碳纳米管和嵌入材料之间提供优异的机械性能，并且在适用时提供电气接触。可选地使用用于嵌入材料的导电材料提供了用于将碳纳米管阵列集成到电子器件中的机制。

12. 发明申请

US20100284898A1 BULK CUTTING OF CARBON NANOTUBES USING ELECTRON BEAM IRRADIATION 失效
标题翻译：使用电子束辐照的碳纳米管的切割
公开(公告)号：US20100284898A1
公开(公告)日：2010-11-11
申请号：US12299634
申请日：2007-05-07
申请人： Kirk J. Ziegler , Urs Rauwald , Robert H. Hauge , Howard K. Schmidt , Irene Morin Marek , Zhenning Gu , W. Carter Kittrell
发明人： Kirk J. Ziegler , Urs Rauwald , Robert H. Hauge , Howard K. Schmidt , Irene Morin Marek , Zhenning Gu , W. Carter Kittrell
IPC分类号： D01F9/12
CPC分类号： C01B32/176 , C01B32/174 , C01B2202/02 , C01B2202/28 , C01B2202/34
摘要： According to some embodiments, the present invention provides a method for attaining short carbon nanotubes utilizing electron beam irradiation, for example, of a carbon nanotube sample. The sample may be pretreated, for example by oxonation. The pretreatment may introduce defects to the sidewalls of the nanotubes. The method is shown to produces nanotubes with a distribution of lengths, with the majority of lengths shorter than 100 tun. Further, the median length of the nanotubes is between about 20 nm and about 100 nm.
摘要翻译：根据一些实施方案，本发明提供了利用电子束照射来获得例如碳纳米管样品的短碳纳米管的方法。样品可以进行预处理，例如通过氧化。预处理可能在纳米管的侧壁上引入缺陷。该方法显示产生具有长度分布的纳米管，其大部分长度短于100μm。此外，纳米管的中值长度在约20nm和约100nm之间。

13. 发明申请

US20100140591A1 ELECTRICAL DEVICE FABRICATION FROM NANOTUBE FORMATIONS 失效
标题翻译：电子设备制造从NANOTUBE FORMATIONS
公开(公告)号：US20100140591A1
公开(公告)日：2010-06-10
申请号：US11910522
申请日：2007-02-02
申请人： Nolan Walker Nicholas , W Carter Kittrell , Myung Jong Kim , Howard K. Schmidt
发明人： Nolan Walker Nicholas , W Carter Kittrell , Myung Jong Kim , Howard K. Schmidt
IPC分类号： H01L51/10 , H01L51/40
CPC分类号： H01L51/057 , B82Y10/00 , H01L51/0048
摘要： A method for forming nanotube electrical devices, arrays of nanotube electrical devices, and device structures and arrays of device structures formed by the methods. Various methods of the present invention allow creation of semiconducting and/or conducting devices from readily grown SWNT carpets rather than requiring the preparation of a patterned growth channel and takes advantage of the self-controlling nature of these carpet heights to ensure a known and controlled channel length for reliable electronic properties as compared to the prior methods.
摘要翻译：用于形成纳米管电子器件的方法，纳米管电子器件的阵列，以及通过该方法形成的器件结构和器件结构的阵列。本发明的各种方法允许从容易生长的SWNT地毯制造半导体和/或导电装置，而不需要制备图案化的生长通道，并利用这些毯子高度的自我控制性质来确保已知和受控的通道与现有方法相比可靠的电子性能。

14. 发明申请

US20090283405A1 FLOW DIELECTROPHORETIC SEPARATION OF SINGLE WALL CARBON NANOTUBES 有权
标题翻译：单壁碳纳米管的流动电介质分离
公开(公告)号：US20090283405A1
公开(公告)日：2009-11-19
申请号：US12281444
申请日：2007-03-02
申请人： Howard K. Schmidt , Haiqing Peng , Manuel Joao Mendes , Matteo Pasquali
发明人： Howard K. Schmidt , Haiqing Peng , Manuel Joao Mendes , Matteo Pasquali
IPC分类号： C02F1/469
CPC分类号： B03C5/005 , B03C5/026 , B82Y30/00 , B82Y40/00 , C01B32/172 , C01B2202/02 , C01B2202/22 , Y10S977/742 , Y10S977/751
摘要： According to some embodiments, a method for separating a first fraction of a single wall carbon nanotubes and a second fraction of single wall carbon nanotubes includes, but is not limited to: flowing a solution comprising the nanotubes into a dielectrophoresis chamber; applying a DC voltage, in combination with an AC voltage, to the dielectrophoresis chamber; and collecting a first eluent from the dielectrophoresis chamber, wherein the first eluent comprises the first fraction and is depleted of the second fraction, wherein the first and second fractions differ by at least one of conductivity, diameter, length, and combinations thereof.
摘要翻译：根据一些实施方案，用于分离单壁碳纳米管和第二部分单壁碳纳米管的第一部分的方法包括但不限于：将包含纳米管的溶液流动到介电电泳室中; 将DC电压与AC电压组合施加到介电电泳室; 以及从所述介电电泳腔室收集第一洗脱液，其中所述第一洗脱液包含所述第一馏分并且耗尽所述第二馏分，其中所述第一和第二馏分通过传导率，直径，长度及其组合中的至少一个而不同。

15. 发明授权

US5354584A In situ low energy ion doping of materials grown by CVD 失效
标题翻译：通过CVD生长的材料的原位低能离子掺杂
公开(公告)号：US5354584A
公开(公告)日：1994-10-11
申请号：US59245
申请日：1993-05-07
申请人： Howard K. Schmidt
发明人： Howard K. Schmidt
IPC分类号： C23C14/48 , C23C16/27 , C23C16/44 , B05D3/06 , C23C16/00
CPC分类号： C23C16/278 , C23C14/48 , C23C16/27 , C23C16/271 , C23C16/44
摘要： A material growing by deposition is exposed to a low energy beam of ionized dopant. The ion beam energy is sufficient to implant the dopant in the growing surface of the material. This doping method will work well for any dopant that is substantially immobile in the material at the temperature necessary for deposition growth.
摘要翻译：通过沉积生长的材料暴露于电离掺杂剂的低能量束。离子束能量足以将掺杂剂注入材料的生长表面。该掺杂方法对于在沉积生长所需的温度下在材料中基本上不可移动的任何掺杂剂都将很好地工作。

16. 发明授权

US09963781B2 Carbon nanotubes grown on nanostructured flake substrates and methods for production thereof 有权
公开(公告)号：US09963781B2
公开(公告)日：2018-05-08
申请号：US12260561
申请日：2008-10-29
申请人： Howard K. Schmidt , Robert H. Hauge , Cary L. Pint , Sean T. Pheasant , Kent E. Coulter
发明人： Howard K. Schmidt , Robert H. Hauge , Cary L. Pint , Sean T. Pheasant , Kent E. Coulter
IPC分类号： C23C16/26 , B82Y30/00 , B82Y40/00 , C23C16/44 , C01B32/162
CPC分类号： C23C16/26 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/02 , C01B2202/04 , C01B2202/08 , C01B2202/34 , C01B2202/36 , C23C16/4417 , Y10T428/24612
摘要： Carbon nanotubes grown on nanostructured flake substrates are disclosed. The nanostructured flake substrates include a catalyst support layer and at least one catalyst layer. Carbon nanotubes grown on the nanostructured flake substrates can have very high aspect ratios. Further, the carbon nanotubes can be aligned on the nanostructured flake substrates. Through routine optimization, the nanostructured flake substrates may be used to produce single-wall, double-wall, or multi-wall carbon nanotubes of various lengths and diameters. The nanostructured flake substrates produce very high yields of carbon nanotubes per unit weight of substrate. Methods for making the nanostructured flake substrates and for using the nanostructured flake substrates in carbon nanotube synthesis are disclosed.

17. 发明授权

US08562935B2 Amplification of carbon nanotubes via seeded-growth methods 失效
标题翻译：通过种子生长方法扩增碳纳米管
公开(公告)号：US08562935B2
公开(公告)日：2013-10-22
申请号：US10575352
申请日：2004-10-14
申请人： Robert H. Hauge , Andrew R. Barron , James M. Tour , Howard K. Schmidt , W. Edward Billups , Christopher A. Dyke , Valerie C. Moore , Elizabeth Whitsitt , Robin E. Anderson , Ramon Colorado, Jr. , Michael P. Stewart , Douglas C. Ogrin , Irene M. Marek
发明人： Richard E. Smalley , Robert H. Hauge , Andrew R. Barron , James M. Tour , Howard K. Schmidt , W. Edward Billups , Christopher A. Dyke , Valerie C. Moore , Elizabeth Whitsitt , Robin E. Anderson , Ramon Colorado, Jr. , Michael P. Stewart , Douglas C. Ogrin
IPC分类号： D01F9/127
CPC分类号： B82Y40/00 , B01J23/881 , B01J27/22 , B82Y30/00 , C01B3/0021 , C01B32/162 , C01B32/172 , C01B32/176 , C01B2202/02 , C01B2202/04 , C01B2202/06 , C01B2202/36 , Y02E60/325
摘要： The present invention is directed towards methods (processes) of providing large quantities of carbon nanotubes (CNTs) of defined diameter and chirality (i.e., precise populations). In such processes, CNT seeds of a pre-selected diameter and chirality are grown to many (e.g., hundreds) times their original length. This is optionally followed by cycling some of the newly grown material back as seed material for regrowth. Thus, the present invention provides for the large-scale production of precise populations of CNTs, the precise composition of such populations capable of being optimized for a particular application (e.g., hydrogen storage). The present invention is also directed to complexes of CNTs and transition metal catalyst precurors, such complexes typically being formed en route to forming CNT seeds.
摘要翻译：本发明涉及提供大量具有规定直径和手性（即精确群体）的碳纳米管（CNT）的方法（方法）。在这种方法中，预先选择的直径和手性的CNT种子生长到其原始长度的许多（例如，数百）倍。随后可以将一些新生成的材料循环回种子材料再生。因此，本发明提供了大规模生产精确的碳纳米管群体，能够针对特定应用（例如，氢存储）优化的这些群体的精确组成。本发明还涉及CNT和过渡金属催化剂前体的复合物，这些络合物通常在形成CNT晶种途中形成。

18. 发明授权

US08269501B2 Methods for magnetic imaging of geological structures 失效
标题翻译：地质结构磁成像方法
公开(公告)号：US08269501B2
公开(公告)日：2012-09-18
申请号：US12350914
申请日：2009-01-08
申请人： Howard K. Schmidt , James M. Tour
发明人： Howard K. Schmidt , James M. Tour
IPC分类号： G01V3/00 , G01V3/08
CPC分类号： G01V3/26
摘要： Methods for imaging geological structures include injecting magnetic materials into the geological structures, placing at least one magnetic probe in a proximity to the geological structures, generating a magnetic field in the geological structures and detecting a magnetic signal. The at least one magnetic probe may be on the surface of the geological structures or reside within the geological structures. The methods also include injecting magnetic materials into the geological structures, placing at least one magnetic detector in the geological structures and measuring a resonant frequency in the at least one magnetic detector. Methods for using magnetic materials in dipole-dipole, dipole-loop and loop-loop transmitter-receiver configurations for geological structure electromagnetic imaging techniques are also disclosed.
摘要翻译：成像地质结构的方法包括将磁性材料注入到地质结构中，将至少一个磁探针放置在地质结构附近，在地质结构中产生磁场并检测磁信号。至少一个磁探针可以在地质结构的表面上或者位于地质结构内。所述方法还包括将磁性材料注入到地质结构中，将至少一个磁性检测器放置在地质结构中并测量至少一个磁性检测器中的谐振频率。还公开了在偶极偶极子中使用磁性材料的方法，用于地质结构电磁成像技术的偶极环和环路发射器 - 接收器配置。

19. 发明申请

US20110100440A1 Optical Rectification Device and Method of Making Same 审中-公开
标题翻译：光学整流装置及其制作方法
公开(公告)号：US20110100440A1
公开(公告)日：2011-05-05
申请号：US12673703
申请日：2008-08-14
申请人： Howard K. Schmidt , Juan Duque
发明人： Howard K. Schmidt , Juan Duque
IPC分类号： H01L31/06
CPC分类号： H01G9/2045 , H01L31/1085 , Y02E10/542 , Y02P70/521
摘要： A general approach is provided for producing devices that absorb optical photons (visible to near IR) and performs charge separation with a useful voltage between holes and electrons. These holes and electrons may be collected in electrodes for performing useful work outside the device. The described technology is generally based upon rectification of plasmons (collective electric excitations) generated by absorbing light with tuned metallic antennas. According to some embodiments, the present invention provides a spatial array of nanoscale conductors forming an optical rectenna that responds to an incident light source and generates a current offset that may be rectified by a rectification-inducing material. The present inventors foresee an extensive use of these optical rectennas as photovoltaic devices, as well as a wide interest in diverse fundamental research and applied technologies.
摘要翻译：提供了一种通常的方法来产生吸收光学光子的器件（对于近红外可见）并且利用空穴和电子之间的有用电压进行电荷分离。这些空穴和电子可以被收集在用于在器件外部进行有用工作的电极中。所描述的技术通常基于通过用调谐的金属天线吸收光而产生的等离子体（整体电激发）的整流。根据一些实施例，本发明提供形成光学整流天线的纳米级导体的空间阵列，其响应于入射光源并产生可由整流引导材料整流的电流偏移。本发明人预计这些光学矫直器作为光电器件的广泛使用，以及对各种基础研究和应用技术的广泛兴趣。

20. 发明申请

US20110030362A1 Hydraulic Geofracture Energy Storage System 有权
$Hydraulic Geofracture Energy Storage System$
标题翻译：液压地裂缝储能系统
公开(公告)号：US20110030362A1
公开(公告)日：2011-02-10
申请号：US12853066
申请日：2010-08-09
申请人： Howard K. Schmidt
发明人： Howard K. Schmidt
IPC分类号： F16D31/02
CPC分类号： F03B13/06 , F02C6/16 , F03D9/17 , F03D9/255 , F03D9/28 , Y02E10/22 , Y02E10/46 , Y02E10/72 , Y02E60/15 , Y02E60/17 , Y02P90/50
摘要： Energy is stored by injecting fluid into a hydraulic fracture in the earth and producing the fluid hack while recovering power. The method is particularly adapted to storage of large amounts of energy such as in grid-scale electric energy systems. The hydraulic fracture may be formed and treated with resin so as to limit fluid loss and to increase propagation pressure.
摘要翻译：能量通过将流体注入地球的水力裂缝并在回收功率的同时产生流体侵入而被储存。该方法特别适用于存储大量的能量，例如电网规模的电能系统。可以用树脂形成和处理水力破裂，以限制流体损失并增加传播压力。

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