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11. 发明授权

US08309634B2 Polyvinylidene chloride compositions and their use in monofilament structures 有权
标题翻译：聚偏二氯乙烯组合物及其在单丝结构中的应用
公开(公告)号：US08309634B2
公开(公告)日：2012-11-13
申请号：US13059461
申请日：2009-08-06
申请人： Douglas E. Beyer , Valerie Renard
发明人： Douglas E. Beyer , Valerie Renard
IPC分类号： C08K5/1515 , B28B3/20
CPC分类号： D01F6/32
摘要： The present invention includes a monofilament obtainable by extruding a composition comprising: (a) at least one vinylidene chloride polymer/methyl acrylate interpolymer having at most about 6 weight percent methyl acrylate mer units in the polymer; and (b) at least about three weight percent total plasticizer, of which about 0.5 weight percent based on total composition weight is an epoxy plasticizer or combination thereof through a die such that monofilament is formed. Optionally, and preferably in extruders wherein the composition of (a) and (b) exhibits less uniformity in extrusion than is desired, at least one methacrylic polymer is also added. The invention also includes a process of extruding a composition of at least (a) and (b) to form a monofilament.
摘要翻译：本发明包括通过挤出组合物可获得的单丝，所述组合物包含：（a）在聚合物中至多约6重量％的丙烯酸甲酯单体单元的至少一种偏二氯乙烯聚合物/丙烯酸甲酯互聚物; 和（b）至少约3重量％的总增塑剂，其中基于总组合物重量的约0.5重量％是环氧增塑剂或其组合，通过模头形成单丝。任选地，优选在挤出机中，其中（a）和（b）的组合物在挤出中的均匀性显示出比所需的更小的均匀性，还加入至少一种甲基丙烯酸类聚合物。本发明还包括挤出至少（a）和（b）的组合物以形成单丝的方法。

12. 发明申请

US20090123678A1 Plasticzer in Alkyl Acrylate Vinylidene Chloride Polymer 有权
标题翻译：烷基丙烯酸酯偏二氯乙烯聚合物的塑化剂
公开(公告)号：US20090123678A1
公开(公告)日：2009-05-14
申请号：US11663374
申请日：2005-09-26
申请人： Douglas E. Beyer , Steven R. Jenkins , Eric K.C. Lee
发明人： Douglas E. Beyer , Steven R. Jenkins , Eric K.C. Lee
IPC分类号： B32B1/00 , B29C47/00
CPC分类号： C08J5/18 , B29C55/28 , B29K2027/08 , B29K2033/04 , B29K2105/0038 , B29K2105/0085 , B29L2023/002 , C08J2327/08 , C08K5/0016 , Y10T428/1324 , Y10T428/1345 , Y10T428/1379 , Y10T428/1397 , C08L27/08
摘要： Articles comprise a monolayer blown film prepared from a composition comprising at least one vinylidene chloride polymer and at least one plasticizer wherein at least one vinylidene chloride polymer comprises vinylidene chloride and at least one alkyl acrylate, selected from methyl acrylate, ethyl acrylate, or butyl acrylate or a combination thereof in an amount of from 2.5 to 9 mole percent of the monomer content of the vinylidene chloride polymer and wherein the plasticizer is present in an amount of from 1 to 15 parts by weight per hundred parts of polymer, wherein the article is selected from a package, a container, a laminate, sausage casing or combination thereof, particularly a sausage casing, wherein at least 4 of designated characteristics are present. The invention also includes processes for making articles of the invention and films used therein.
摘要翻译：制品包括由包含至少一种偏二氯乙烯聚合物和至少一种增塑剂的组合物制备的单层吹塑薄膜，其中至少一种偏二氯乙烯聚合物包含偏二氯乙烯和至少一种选自丙烯酸甲酯，丙烯酸乙酯或丙烯酸丁酯的丙烯酸烷基酯或其组合，其量为偏二氯乙烯聚合物的单体含量的2.5至9摩尔％，并且其中增塑剂的存在量为每100份聚合物1至15重量份，其中制品为选自包装，容器，层压体，香肠肠衣或其组合，特别是香肠肠衣，其中存在至少4个指定特征。本发明还包括制造本发明的制品和其中使用的薄膜的方法。

13. 发明授权

US4877826A Weatherable styrenic polymer blend comprising polyalkylene glycol 失效
标题翻译：包含聚亚烷基二醇的耐候性苯乙烯聚合物共混物
公开(公告)号：US4877826A
公开(公告)日：1989-10-31
申请号：US254176
申请日：1988-10-05
申请人： Douglas E. Beyer
发明人： Douglas E. Beyer
IPC分类号： C08L25/02 , C08L25/12 , C08L25/16 , C08L33/18 , C08L33/20 , C08L51/00 , C08L51/04 , C08L51/06 , C08L71/00 , C08L71/02
CPC分类号： C08L51/003 , C08L25/12 , C08L25/16 , C08L51/04 , C08L2205/02 , C08L71/02
摘要： Improved plasticization and stabilization of poly(styrene-acrylonitrile)/grafted diene rubber blends is obtained by use of polyalkylene glycol stabilizers.
摘要翻译：通过使用聚亚烷基二醇稳定剂获得聚（苯乙烯 - 丙烯腈）/接枝二烯橡胶共混物的改进的增塑和稳定化。

14. 发明授权

US07754300B2 Plasticzer in alkyl acrylate vinylidene chloride polymer 有权
标题翻译：丙烯酸烷基酯偏氯乙烯聚合物中的塑化剂
公开(公告)号：US07754300B2
公开(公告)日：2010-07-13
申请号：US11663374
申请日：2005-09-26
申请人： Douglas E. Beyer , Steven R. Jenkins , Eric K. C. Lee
发明人： Douglas E. Beyer , Steven R. Jenkins , Eric K. C. Lee
IPC分类号： A22C13/00
CPC分类号： C08J5/18 , B29C55/28 , B29K2027/08 , B29K2033/04 , B29K2105/0038 , B29K2105/0085 , B29L2023/002 , C08J2327/08 , C08K5/0016 , Y10T428/1324 , Y10T428/1345 , Y10T428/1379 , Y10T428/1397 , C08L27/08
摘要： Articles comprise a monolayer blown film prepared from a composition comprising at least one vinylidene chloride polymer and at least one plasticizer wherein at least one vinylidene chloride polymer comprises vinylidene chloride and at least one alkyl acrylate, selected from methyl acrylate, ethyl acrylate, or butyl acrylate or a combination thereof in an amount of from 2.5 to 9 mole percent of the monomer content of the vinylidene chloride polymer and wherein the plasticizer is present in an amount of from 1 to 15 parts by weight per hundred parts of polymer, wherein the article is selected from a package, a container, a laminate, sausage casing or combination thereof, particularly a sausage casing, wherein at least 4 of designated characteristics are present. The invention also includes processes for making articles of the invention and films used therein.
摘要翻译：制品包括由包含至少一种偏二氯乙烯聚合物和至少一种增塑剂的组合物制备的单层吹塑薄膜，其中至少一种偏二氯乙烯聚合物包含偏二氯乙烯和至少一种选自丙烯酸甲酯，丙烯酸乙酯或丙烯酸丁酯的丙烯酸烷基酯或其组合，其量为偏二氯乙烯聚合物的单体含量的2.5至9摩尔％，并且其中增塑剂的存在量为每100份聚合物1至15重量份，其中制品为选自包装，容器，层压体，香肠肠衣或其组合，特别是香肠肠衣，其中存在至少4个指定特征。本发明还包括制造本发明的制品和其中使用的薄膜的方法。

15. 发明授权

US4946894A Blend comprising large proportions of a EPDM graft terpolymer and relatively smaller proportions of an acrylate rubber 失效
标题翻译：共混物包括大比例的EPDM接枝三元共聚物和相对较小比例的丙烯酸酯橡胶
公开(公告)号：US4946894A
公开(公告)日：1990-08-07
申请号：US232268
申请日：1988-08-15
申请人： David E. Henton , Douglas E. Beyer
发明人： David E. Henton , Douglas E. Beyer
IPC分类号： C08L51/00 , C08L25/12 , C08L51/04 , C08L51/06
CPC分类号： C08L25/12 , C08L51/003 , C08L51/04 , C08L51/06
摘要： Rubber reinforced thermoplastic resins are provided comprising specific proportions of grafted EPDM terpolymer elastomers and grafted arcylate elastomers.
摘要翻译：提供了橡胶增强的热塑性树脂，其包括特定比例的接枝EPDM三元共聚物弹性体和接枝的甲氧基弹性体。

16. 发明授权

US09828475B2 Printable monolayer polyvinylidene chloride structures 有权
公开(公告)号：US09828475B2
公开(公告)日：2017-11-28
申请号：US12941609
申请日：2010-11-08
申请人： Douglas E. Beyer , Steven R. Jenkins , William R. LaFollette
发明人： Douglas E. Beyer , Steven R. Jenkins , William R. LaFollette
IPC分类号： C08J5/18 , B41M1/30 , C08L27/08 , C08K5/00 , C08K5/11 , C08L27/06 , C08L33/12 , C08L33/10 , C08L33/08
CPC分类号： C08J5/18 , B41M1/30 , C08J2327/08 , C08K5/0016 , C08K5/11 , C08L27/06 , C08L27/08 , C08L33/08 , C08L33/10 , C08L33/12 , C08L2666/04
摘要： The present invention includes a polymer composition of at least one vinylidene chloride/alkyl acrylate polymer having from about 3.4 to about 6.7 percent mole percent of mer units derived from at least one alkyl acrylate monomer polymerized with the vinylidene chloride and comprising a plasticizer and having at least one of the following compositional characteristics (1) and (2): (1) at least one low molecular weight vinyl chloride polymer having a molecular weight of at most about 70,000 Daltons in an amount sufficient to increase affinity for at least one ink; and (2) at least one methacrylic polymer in an amount sufficient to increase the affinity for at least one ink. Surfaces comprising such a composition and articles having such surfaces are surprisingly printable and are aspects of the invention as is printing thereon.

17. 发明申请

US20110144249A1 POLYVINYLIDENE CHLORIDE COMPOSITIONS AND THEIR USE IN MONOFILAMENT STRUCTURES 有权
标题翻译：聚乙烯氯化物组合物及其在单体结构中的应用
公开(公告)号：US20110144249A1
公开(公告)日：2011-06-16
申请号：US13059461
申请日：2009-08-06
申请人： Douglas E. Beyer , Valerie Renard
发明人： Douglas E. Beyer , Valerie Renard
IPC分类号： C08K5/1515 , B28B3/20
CPC分类号： D01F6/32
摘要： The present invention includes a monofilament obtainable by extruding a composition comprising: (a) at least one vinylidene chloride polymer/methyl acrylate interpolymer having at most about 6 weight percent methyl acrylate mer units in the polymer; and (b) at least about three weight percent total plasticizer, of which about 0.5 weight percent based on total composition weight is an epoxy plasticizer or combination thereof through a die such that monofilament is formed. Optionally, and preferably in extruders wherein the composition of (a) and (b) exhibits less uniformity in extrusion than is desired, at least one methacrylic polymer is also added. The invention also includes a process of extruding a composition of at least (a) and (b) to form a monofilament.
摘要翻译：本发明包括通过挤出组合物获得的单丝，所述组合物包含：（a）聚合物中至少具有约6重量％的丙烯酸甲酯单体单元的至少一种偏二氯乙烯聚合物/丙烯酸甲酯互聚物; 和（b）至少约3重量％的总增塑剂，其中基于总组合物重量的约0.5重量％是环氧增塑剂或其组合，通过模头形成单丝。任选地，优选在挤出机中，其中（a）和（b）的组合物在挤出中的均匀性显示出比所需的更小的均匀性，还加入至少一种甲基丙烯酸类聚合物。本发明还包括挤出至少（a）和（b）的组合物以形成单丝的方法。

18. 发明申请

US20110124780A1 PRINTABLE MONOLAYER POLYVINYLIDENE CHLORIDE STRUCTURES 有权
标题翻译：可打印单层聚氯乙烯氯化物结构
公开(公告)号：US20110124780A1
公开(公告)日：2011-05-26
申请号：US12941609
申请日：2010-11-08
申请人： Douglas E. Beyer , Steven R. Jenkins , William R. LaFollette
发明人： Douglas E. Beyer , Steven R. Jenkins , William R. LaFollette
IPC分类号： C08K5/1515 , C08L33/10 , C08L31/06 , B41F33/00
CPC分类号： C08J5/18 , B41M1/30 , C08J2327/08 , C08K5/0016 , C08K5/11 , C08L27/06 , C08L27/08 , C08L33/08 , C08L33/10 , C08L33/12 , C08L2666/04
摘要： The present invention includes a polymer composition of at least one vinylidene chloride/alkyl acrylate polymer having from about 3.4 to about 6.7 percent mole percent of mer units derived from at least one alkyl acrylate monomer polymerized with the vinylidene chloride and comprising a plasticizer and having at least one of the following compositional characteristics (1) and (2): (1) at least one low molecular weight vinyl chloride polymer having a molecular weight of at most about 70,000 Daltons in an amount sufficient to increase affinity for at least one ink; and (2) at least one methacrylic polymer in an amount sufficient to increase the affinity for at least one ink. Surfaces comprising such a composition and articles having such surfaces are surprisingly printable and are aspects of the invention as is printing thereon.
摘要翻译：本发明包括至少一种偏二氯乙烯/丙烯酸烷基酯聚合物的聚合物组合物，其具有约3.4至约6.7％摩尔百分数的衍生自至少一种与偏二氯乙烯聚合的丙烯酸烷基酯单体的聚合单体，并且包含增塑剂并具有以下组成特征（1）和（2）中的至少一个：（1）至少一种分子量至多为约70,000道尔顿的至少一种低分子量氯乙烯聚合物，其量足以增加对至少一种油墨的亲和力; 和（2）至少一种甲基丙烯酸聚合物，其量足以增加对至少一种油墨的亲和力。包含这种组合物和具有这种表面的制品的表面是令人惊奇的可打印的，并且是在其上印刷的本发明的方面。

19. 发明授权

US5491194A Thermally processable blends of high modulus polyurethanes and mass polymerized ABS resins 失效
标题翻译：高模量聚氨酯和大量聚合ABS树脂的热可加工共混物
公开(公告)号：US5491194A
公开(公告)日：1996-02-13
申请号：US484367
申请日：1995-06-07
申请人： David E. Henton , Augustin Chen , Paul J. Moses , Benjamin S. Ehrlich , Douglas E. Beyer
发明人： David E. Henton , Augustin Chen , Paul J. Moses , Benjamin S. Ehrlich , Douglas E. Beyer
IPC分类号： C08G18/32 , C08L51/04 , C08L55/02 , C08L75/00 , C08L75/04
CPC分类号： C08L55/02 , C08G18/3212 , C08L75/04
摘要： The toughness of a thermoplastic, rigid polyurethane is markedly improved by incorporating a mass ABS resin such as styrene/butadiene rubber grafted with a copolymer of styrene and acrylonitrile. This toughened polyurethane is particularly useful in making structural automotive body parts and housings for electrical appliances.
摘要翻译：热塑性硬质聚氨酯的韧性通过掺入接枝有苯乙烯和丙烯腈共聚物的ABS / ABS树脂等ABS树脂显着提高。这种增韧的聚氨酯在制造用于电器的结构汽车车身部件和外壳中特别有用。

20. 发明授权

US4200718A Multifunctional lithium containing initiator 失效
公开(公告)号：US4200718A
公开(公告)日：1980-04-29
申请号：US859356
申请日：1977-12-12
申请人： Lu H. Tung , Grace Y-S. Lo , Joseph W. Rakshys , Douglas E. Beyer
发明人： Lu H. Tung , Grace Y-S. Lo , Joseph W. Rakshys , Douglas E. Beyer
IPC分类号： C07F1/02 , C07F17/02 , C08F4/48 , C08F36/04
CPC分类号： C07F17/02 , C07F1/02 , C08F36/04
摘要： Highly desirable multifunctional lithium containing initiators are prepared by reacting a compound such as an organo lithium with an organic compound containing at least two 1,1-diphenylethylene groups. Such initiators can be prepared in the absence of polar solvents and are very desirable for the polymerization of dienes such as butadiene to a desirable 1,4 configuration. Several di-lithium compounds have been employed to initiate polymerization of various unsaturated organic monomers.

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