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    • 11. 发明授权
    • Duplex stainless steel
    • 双相不锈钢
    • US5849111A
    • 1998-12-15
    • US718574
    • 1996-11-06
    • Masaaki IgarashiKunio KondoKazuhiro OgawaMasakatsu UedaTomoki Mori
    • Masaaki IgarashiKunio KondoKazuhiro OgawaMasakatsu UedaTomoki Mori
    • C22C38/00C22C38/44C22C38/58
    • C22C38/44C22C38/001
    • A super duplex stainless steel with low susceptibility to weld cracks and high weldability, as well as the resistance to stress corrosion cracking and toughness of the weld zones. The steel is therefore suitable for a wide range of applications including heat exchangers exposed to sea water, brine-resistant equipment and structures, pipings in chemical plants, line pipes, and oil well pipes. The steel includes, in weight %, 2.0% or less Si, 2.0% or less Mn, 22.0-24.0% Cr, 4.5-6.5% Ni, 4.0-4.8% Mo, 0.001-0.15% Al, and 0.25-0.35% N, the remains of Fe and inevitable impurities including 0.03% or less C, 0.05% or less P and 0.005% or less S, and a RVS, the index of susceptibility to cracking on welding, 7 or less, and a PREW, the index of pitting resistance, greater than 40.
    • PCT No.PCT / JP95 / 00647 Sec。 371日期:1996年11月6日 102(e)日期1996年11月6日PCT 1995年4月4日PCT PCT。 公开号WO95 / 27090 日期1995年10月12日一种具有低焊接裂纹敏感性和高可焊性的超级双相不锈钢,以及耐应力腐蚀开裂和焊接区韧性。 因此,钢适用于广泛的应用,包括暴露于海水的热交换器,防盐水设备和结构,化工厂的管道,管道管道和油井管道。 钢的重量%包括2.0%以下的Si,2.0%以下的Mn,22.0-24.0%的Cr,4.5-6.5%的Ni,4.0-4.8%的Mo,0.001-0.15%的Al和0.25-0.35%的N ,余量为Fe和不可避免的杂质,包括0.03%以下的C,0.05%以下的P和0.005%以下的S,RVS,焊接开裂敏感性指数为7以下,PREW, 的耐点蚀性,大于40。
    • 12. 发明授权
    • Martensitic stainless steel suitable for use in oil wells
    • 马氏体不锈钢适用于油井
    • US5383983A
    • 1995-01-24
    • US45596
    • 1993-04-09
    • Kunio KondoTakahiro KushidaMasakatsu Ueda
    • Kunio KondoTakahiro KushidaMasakatsu Ueda
    • C22C38/00C22C38/44C22C38/50
    • C22C38/44
    • A martensitic stainless steel for use in oil wells has improved stability in strength and good resistance to sulfide stress corrosion cracking The steel has a chemical composition consisting essentially, on a weight basis, of: Si: not greater than 1.0%, Mn: not greater than 1.0%, Cr: 10.0-14.0%, Mo: 0.5-7.0%, Ni: 4.0-8.0%, Al: 0.001-0.1%, either Ti in an amount satisfying the following inequality (1) or Zr in an amount satisfying the following inequality (2), optionally one or both of Mg: 0.001-0.05% and Ce: 0.001-0.05%, and a balance of Fe and incidental impurities in which the contents of C, P, S, N, and V as impurities are limited to 0.05% or less, 0.04% or less, 0.005% or less, 0.05% or less, and 0.2% or less, respectively, the composition further satisfying the following inequalities (3) and (4):4(%C).ltoreq.%Ti.ltoreq.{-0.01/(%C+0.015))}+0.75 (1)10(%C).ltoreq.%Zr.ltoreq.2 0% (2)30(%Cr)+36(%Mo)+14(%Si)-28(%Ni).ltoreq.455 (3)21(%Cr)+25(%Mo)+17(%Si)+35(%Ni).ltoreq.731 (4).
    • 用于油井的马氏体不锈钢具有提高的强度稳定性和良好的耐硫化应力腐蚀开裂性。钢的化学组成基本上以重量计:Si:不大于1.0%,Mn:不大 1.0%,Cr:10.0〜14.0%,Mo:0.5〜7.0%,Ni:4.0〜8.0%,Al:0.001-0.1%,满足以下不等式(1)的Ti或满足 以下不等式(2),Mg:0.001-0.05%和Ce:0.001-0.05%中的任意一种或两种,以及C,P,S,N和V的含量的Fe和杂质的余量为 杂质分别限制在0.05%以下,0.04%以下,0.005%以下,0.05%以下,0.2%以下,进一步满足以下不等式(3)和(4):4(% C)
    • 18. 发明授权
    • Hydrogen sulfide corrosion resistant high-Cr and high-Ni alloys
    • 硫化氢耐腐蚀高Cr和高镍合金
    • US5879619A
    • 1999-03-09
    • US836108
    • 1997-05-05
    • Masakatsu Ueda
    • Masakatsu Ueda
    • C22C38/42C22C30/02C22C38/02
    • C22C38/42
    • A high-Cr and high-Ni alloy of the invention comprises the following chemical composition and has excellent corrosion resistance to hydrogen sulfide in an environment where a partial pressure of hydrogen sulfide is about 1 atm., or below and the temperature is about 150.degree. C. The alloy is free of any expensive Mo and W and is thus inexpensive, with the attendant feature that mass production is possible: Si: 0.05-1.0%, Mn: 0.1-1.5%, Cr: 20-30%, Ni: 20-40%, sol. Al: 0.01-0.3%, Cu: 0.5-5.0%, REM: 0-0.10%, Y: 0-0.20%, Mg: 0-0.10%, Ca: 0-0.10%, and balance: Fe and incidental impurities, provided that C, P and S in the incidental impurity are, respectively, 0.05% or below, 0.03% or below and 0.01% or below. As set out above, each of REM, Y, Mg and Ca do not have to be added at all. If these elements are used, one or more of REM, Y, Mg and Ca are added. Preferable ranges of the contents of these elements when added are such that REM: 0.001-0.10%, Y: 0.001-0.20%, Mg: 0.001-0.10%, and Ca: 0.001-0.10%.
    • PCT No.PCT / JP96 / 01672 Sec。 371日期:1997年5月5日 102(e)日期1997年5月5日PCT Filed 1996年6月17日PCT公布。 公开号WO97 / 48830 PCT 日期1997年12月24日本发明的高Cr和高镍合金具有以下化学成分,并且在硫化氢分压为1个大气压以下的环境中具有优异的耐硫化氢性, 温度约150℃,合金不含任何昂贵的Mo和W,因此成本低廉,具有大量生产的特点:Si:0.05-1.0%,Mn:0.1-1.5%,Cr:20- 30%,Ni:20-40%,溶胶。 Al:0.01-0.3%,Cu:0.5-5.0%,REM:0-0.10%,Y:0-0.20%,Mg:0-0.10%,Ca:0-0.10%,余量:Fe和附带杂质, 条件是杂质中的C,P和S分别为0.05%以下,0.03%以下,0.01%以下。 如上所述,REM,Y,Mg和Ca中的每一个根本不必加入。 如果使用这些元素,则添加REM,Y,Mg和Ca中的一种或多种。 这些元素的添加量优选为REM:0.001-0.10%,Y:0.001-0.20%,Mg:0.001-0.10%,Ca:0.001-0.10%。