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11. 发明授权

US5507174A Polarographic sensor 失效
标题翻译：极谱传感器
公开(公告)号：US5507174A
公开(公告)日：1996-04-16
申请号：US211569
申请日：1994-08-02
申请人： Karl-Hermann Friese , Hermann Dietz , Werner Gruenwald
发明人： Karl-Hermann Friese , Hermann Dietz , Werner Gruenwald
IPC分类号： G01N27/41 , F02B1/04 , G01N27/407 , G01N27/416 , G01M15/00 , G01N27/48
CPC分类号： G01N27/4071 , F02B1/04
摘要： A polarographic sensor for determining concentration of certain components including oxygen or combustible fractions, such as hydrocarbons, hydrogen and carbon monoxide, in the exhaust gas of an internal combustion engine, includes a pump cell having an anode, a cathode, and an oxygen ion-conducting solid electrolyte provided between the anode and the cathode, wherein the cathode is provided with a diffusion barrier, wherein the anode is provided with a diffusion barrier, and wherein the concentration of the certain components is determined by measurement of a limiting current through the electrolyte and across one of the diffusion barriers to the corresponding anode or cathode.
摘要翻译： PCT No.PCT / DE93 / 00674 Sec。 371日期1994年8月2日 102（e）日期1994年8月2日PCT提交1993年7月31日PCT公布。第WO94 / 04911号公报日本3月3日，1994.用于确定内燃机废气中某些组分（包括氧气或可燃组分）如烃，氢气和一氧化碳的浓度的极谱传感器包括具有阳极，阴极和设置在阳极和阴极之间的氧离子传导固体电解质，其中阴极设置有扩散阻挡层，其中阳极设置有扩散阻挡层，并且其中某些组分的浓度通过测量确定限制电流通过电解质，并穿过一个扩散屏障到相应的阳极或阴极。

12. 发明授权

US4305803A Gas sensor construction, particularly to determine oxygen content combustion exhaust gases, particularly from internal combustion engines 失效
标题翻译：气体传感器结构，特别是确定氧含量燃烧废气，特别是内燃机
公开(公告)号：US4305803A
公开(公告)日：1981-12-15
申请号：US184085
申请日：1980-09-04
申请人： Barbara Beyer , Hermann Dietz , Karl Friese
发明人： Barbara Beyer , Hermann Dietz , Karl Friese
IPC分类号： G01N27/41 , G01N27/407 , G01N27/413 , G01N27/48 , G01N27/58
CPC分类号： G01N27/4071
摘要： To facilitate manufacture of a sensor, particularly a polarographic sensor which has no sealing or heat expansion difficulties and only low heat capacity in the measuring range and electrical connections, a solid electrolyte (17) is formed as a plate extending transversely across a bottom opening (13) of a preferably ceramic tube (11), the plate having two electrodes (16,21) applied to its major sides. The side facing the opening (13) is covered with a ceramic layer (20) having a predetermined diffusion or migration resistance to oxygen molecules. The electrical connections are formed by a conductive track (15) extending on the inside of the ceramic tube, in contact with the sensing electrode on one side of the plate; and a counter head (23) connected to a conductive bolt or pin (24) and resiliently spring pressed against the electrode, and holding the plate (17) and the diffusion barrier (20) thereon in position in the sensor. The test gas is applied to the diffusion resistance layer through a ceramic heat storage plate, for instance, having openings therethrough, which has a film-type heater applied thereto, connected to a current source by conductive tracks (31, 31'; 32, 32') positioned on the outside of the ceramic tube.
摘要翻译：为了便于制造传感器，特别是在测量范围和电气连接中没有密封或热膨胀困难并且仅具有低热容量的极谱传感器，固体电解质（17）形成为横向延伸穿过底部开口的板（ 13），该板具有应用于其主要侧面的两个电极（16,21）。面向开口（13）的一侧被对氧分子具有预定的扩散或迁移阻力的陶瓷层（20）覆盖。电连接由导电轨道（15）形成，导电轨道（15）在陶瓷管的内侧延伸，与板的一侧的感测电极接触; 以及连接到导电螺栓或销（24）并且弹性弹簧压靠在电极上并将板（17）和扩散壁（20）保持在传感器中的适当位置的相对头（23）。测试气体通过陶瓷储热板（例如具有开口的陶瓷储热板）施加到扩散阻力层，该陶瓷储能板具有施加到其上的膜型加热器，通过导电轨道（31,31'; 32， 32'）位于陶瓷管的外侧。

13. 发明授权

US5310472A Sensor element for limiting current sensors to determine the lambda value of gas mixtures 失效
标题翻译：用于限制电流传感器以确定气体混合物的λ值的传感器元件
公开(公告)号：US5310472A
公开(公告)日：1994-05-10
申请号：US700141
申请日：1991-05-16
申请人： Hermann Dietz , Werner Grunwald , Claudio de la Prieta
发明人： Hermann Dietz , Werner Grunwald , Claudio de la Prieta
IPC分类号： G01N27/41 , F02D41/14 , G01N27/406 , G01N27/407 , G01N27/416 , G01N27/419
CPC分类号： G01N27/4071 , G01N27/4072
摘要： Sensor element for limiting current sensors to determine the lambda value of gas mixtures, in particular of exhaust gases of internal combustion engines, having inner and outer pump electrodes disposed on a ceramic substrate, the inner pump electrode of which is accessible for the measurement gas supplied through a diffusion layer acting as a diffusion barrier; having a gas-tight cover layer above the diffusion layer and having conductor tracks for the pump electrodes is described, in which the diffusion layer is adjustable, to calibrate the sensor element. This adjustability is advantageously attained by embodying the side of the diffusion layer 5 oriented toward the measurement gas inlet opening as a zigzag-shaped adjustment zone 8, from which parts can be separated mechanically or by laser cuts. The invention makes comparatively simple calibration of sensor elements possible.
摘要翻译： PCT No.PCT / DE89 / 00731 Sec。 371日期1991年5月16日 102（e）日期1991年5月16日PCT提交1989年11月17日PCT公布。公开号WO90 / 06506 日期1990年6月14日。用于限制电流传感器以确定气体混合物，特别是内燃机废气的λ值的传感器元件，其具有设置在陶瓷基板上的内部和外部泵电极，其内部泵浦电极可用于通过作为扩散阻挡层的扩散层供应的测量气体; 描述了在扩散层上方具有气密性覆盖层并且具有用于泵电极的导体轨迹，其中扩散层是可调节的，以校准传感器元件。有利地通过将扩散层5的朝向测量气体入口开口的侧面作为锯齿形调整区8来实现，这可以通过机械方式或通过激光切割来分离这些部分。本发明使得传感器元件的相对简单的校准成为可能。

14. 发明授权

US3930890A Storage battery gas recombination catalyst device 失效
标题翻译：储存电池气体重整催化装置
公开(公告)号：US3930890A
公开(公告)日：1976-01-06
申请号：US469779
申请日：1974-05-14
申请人： Hermann Dietz
发明人： Hermann Dietz
IPC分类号： H01M10/52 , H01M2/12 , B01J8/00
CPC分类号： H01M10/52
摘要： A lightweight catalyst body bearing a finely divided metal of the platinum group is encased in a porous PTFE shell which is impermeable to the electrolyte because of its hydrophobic surface properties. Several small bodies of this kind, each containing about 1 mg of palladium are inserted in each cell of a vehicle storage battery and float on the electrolyte surface. They not only recombine hydrogen and oxygen to water and return the water to the electrolyte efficiently, even at high ambient temperatures, but the efficiency of the catalyst is not reduced under conditions causing considerable generation of stibine. The core material on which the catalyst is provided, with or without an additional carrier, may be activated charcoal, hollow glass spheres, a porous ceramic or a synthetic resin foam. The porous hydrophobic shell may be sintered or unsintered or may be made of superimposed sintered and unsintered layers.

15. 发明授权

US5849175A Method and circuit arrangement for acutating a measuring sensor to determine an oxygen concentration in a gas mixture 失效
标题翻译：用于对测量传感器进行补偿以确定气体混合物中的氧气浓度的方法和电路装置
公开(公告)号：US5849175A
公开(公告)日：1998-12-15
申请号：US809569
申请日：1997-03-24
申请人： Hermann Dietz , Werner Gruenwald
发明人： Hermann Dietz , Werner Gruenwald
IPC分类号： G01N27/406 , G01N27/41 , G01N27/419
CPC分类号： G01N27/419 , G01N27/4065
摘要： The invention relates to a method and a circuit arrangement for actuating a measuring sensor for determining an oxygen concentration in a gas mixture, particularly in exhaust gases of internal combustion engines, wherein a detector voltage corresponding to the oxygen concentration and supplied by a reference probe is transferred into a pump voltage for a measuring probe by a circuit arrangement. It is provided that a curve of the detector voltage (U.sub.D) is used directly for determining the curve of the pump voltage (U.sub.P), with a first input (38) of the circuit arrangement (36) being connected to a first input (46) of an adder (48) at whose second input (50) an add voltage is applied and whose output (54) is connected to the second input (40) of the circuit arrangement (36) via an amplifier (58).
摘要翻译： PCT No.PCT / DE95 / 01181 Sec。 371日期1997年3月24日 102（e）1997年3月24日PCT PCT 1995年9月1日PCT公布。公开号WO96 / 09536 日期：1996年3月28日本发明涉及一种用于致动测量传感器以确定气体混合物，特别是内燃机排气中的氧气浓度的方法和电路装置，其中检测器电压对应于氧浓度并提供通过参考探头通过电路布置被传送到用于测量探针的泵电压。提供了检测器电压（UD）的曲线直接用于确定泵电压（UP）的曲线，其中电路装置（36）的第一输入端（38）连接到第一输入端（46）），其第二输入端（50）施加相加电压，并且其输出端（54）经由放大器（58）连接到电路装置（36）的第二输入端（40）。

16. 发明授权

US5702580A Measuring sensor for determining the oxygen content of gas mixtures 失效
标题翻译：用于测定气体混合物氧含量的测量传感器
公开(公告)号：US5702580A
公开(公告)日：1997-12-30
申请号：US617873
申请日：1996-03-21
申请人： Hermann Dietz , Werner Gruenwald , Claudio De La Prieta , Gert Lindemann , Ulrich Eisele , Carmen Schmiedel
发明人： Hermann Dietz , Werner Gruenwald , Claudio De La Prieta , Gert Lindemann , Ulrich Eisele , Carmen Schmiedel
IPC分类号： G01N27/41 , G01N27/417 , G01N27/419 , G01N27/407
CPC分类号： G01N27/417
摘要： A measuring sensor for determining oxygen content in a gas mixture including exhaust gases of internal combustion engines, includes a base substrate which is comprised of a base material and which is electrically insulating; and an electrochemical measuring probe and an electrochemical reference probe arranged separate from each other on the base substrate. The measuring probe includes at least one internal electrode; at least one solid electrolyte island; and at least one external electrode. The measuring probe additionally includes a diffusion barrier. Further base material layers composed of the base material are provided so as to embed at least the diffusion barrier, the at least one internal electrodes for the measuring probe and the internal electrode for the reference probe. A diffusion hole is defined between the measuring probe and the reference probe which extends from the base substrate through the diffusion barrier and respective base material layers, and out to the gas mixture to be measured. Thermal stress and the accompanying tendency to cracking is reduced by providing the solid electrolyte as islands. Separate disposition of the measuring probe and the reference probe, i.e., without a common electrode, permits construction as individual layers using, for example, screen printing.
摘要翻译： PCT No.PCT / DE95 / 01305 Sec。 371日期1996年3月21日 102（e）日期1996年3月21日PCT提交1995年9月22日PCT公布。公开号WO96 / 11394 日期1996年04月18日用于测定包括内燃机废气的气体混合物中的氧含量的测量传感器包括由基材构成并且是电绝缘的基底，以及在基底基板上彼此分离设置的电化学测量探针和电化学参考探针。测量探头包括至少一个内部电极; 至少一个固体电解质岛; 和至少一个外部电极。测量探头还包括扩散阻挡层。提供由基材构成的其他基材层，以便至少嵌入扩散阻挡层，至少一个用于测量探针的内部电极和用于参考探针的内部电极。在测量探针和参考探针之间限定了扩散孔，该探针从基底基底通过扩散阻挡层和相应的基底层层延伸出来，并且进入待测量的气体混合物。通过提供固体电解质作为岛来减少热应力和伴随的开裂倾向。测量探针和参考探针的单独布置，即没有公共电极，可以使用例如丝网印刷将结构设计为单独的层。

17. 发明授权

US5505837A Sensor arrangement for determining gas components and/or gas concentrations of gas mixtures 失效
标题翻译：用于确定气体组分和/或气体混合物气体浓度的传感器装置
公开(公告)号：US5505837A
公开(公告)日：1996-04-09
申请号：US290704
申请日：1994-12-12
申请人： Karl-Hermann Friese , Hermann Dietz , Werner Gruenwald , Gerhard Hoetzel , Harald Neumann , Johann Riegel , Bernd Schumann
发明人： Karl-Hermann Friese , Hermann Dietz , Werner Gruenwald , Gerhard Hoetzel , Harald Neumann , Johann Riegel , Bernd Schumann
IPC分类号： G01N27/12 , G01N27/416 , G01N27/419 , G01N27/26
CPC分类号： G01N27/419
摘要： A sensor arrangement for determining at least one of gas components and gas concentrations of gas mixtures including CO, NO.sub.x and HC in exhaust gases of internal combustion engines, includes a measuring element which has a sensitive region; and a pump cell that includes a solid electrolyte and inner and outer pump electrodes which are opposingly disposed at least on the solid electrolyte and which effect an oxygen transfer to the measuring element, wherein the pump cell and the measuring element are spatially separated from one another, are located in different temperature zones during operation of the sensor arrangement, and are connected to one another by a diffusion segment through which oxygen can diffuse from the pump cell to the measuring element.
摘要翻译： PCT No.PCT / DE94 / 00289 Sec。 371日期1994年12月12日第 102（e）日期1994年12月12日PCT 1994年3月17日PCT公布。公开号WO94 / 24550 PCT 日期：1994年10月27日。一种用于确定内燃机废气中的CO，NO x和HC气体混合气体组分和气体浓度中的至少一种的传感器装置，包括具有敏感区域的测量元件; 以及泵电池，其包括固体电解质和内部和外部泵电极，所述内部和外部泵电极相对设置在至少在所述固体电解质上并且对所述测量元件进行氧传递，其中所述泵浦单元和所述测量元件在空间上彼此分离位于传感器装置的操作期间的不同温度区域中，并且通过扩散段彼此连接，通过该扩散段，氧气可以从泵电池扩散到测量元件。

18. 发明授权

US5302275A Sensor element for an oxygen limiting current probe in order to determine the .lambda. value of gas mixtures 失效
标题翻译：用于氧气限制电流探头的传感器元件，以确定气体混合物的λ值
公开(公告)号：US5302275A
公开(公告)日：1994-04-12
申请号：US934489
申请日：1992-09-14
申请人： Hermann Dietz , Barbara Beyer , Werner Gruenwald , Claudio Da La Prieta
发明人： Hermann Dietz , Barbara Beyer , Werner Gruenwald , Claudio Da La Prieta
IPC分类号： G01N27/41 , G01N27/26 , G01N27/407 , G01N27/409 , G01N27/416 , G01N27/417 , G01N27/419
CPC分类号： G01N27/417 , G01N27/4072
摘要： A sensor element is proposed for an oxygen limiting current probe for the determination of the .lambda. value of gas mixtures, particularly the exhaust gases of internal-combustion engines, whose oxygen supply is provided by a short-circuit cell disposed upstream of the pumping cell of the sensor element. In this way the CO.sub.2 and H.sub.2 O transverse sensitivity of the sensor element is made ineffective. In order to obtain at the pumping cell a limiting current that is a linear function of the O.sub.2 partial pressure, a diffusion barrier must additionally be disposed between the short-circuit cell and the pumping cell.
摘要翻译： PCT No.PCT / DE91 / 00166 Sec。 371日期：1992年9月14日 102（e）日期1992年9月14日PCT 1991年2月27日提交PCT公布。 WO91 / 14174 PCT出版物日期为1991年9月19日。为了确定气体混合物（特别是内燃机的废气）的（λ）值，提出了一种用于氧气限制电流探针的传感器元件，其内燃机的氧气供应由短路设置在传感器元件的泵浦单元的上游的电路单元。以这种方式，传感器元件的CO2和H2O横向灵敏度无效。为了在泵浦单元处获得作为O 2分压的线性函数的极限电流，扩散势垒必须另外设置在短路单元和泵浦单元之间。

19. 发明授权

US4130695A Lead-acid storage battery and electrode therefor 失效
标题翻译：铅酸蓄电池及其电极
公开(公告)号：US4130695A
公开(公告)日：1978-12-19
申请号：US853431
申请日：1977-11-21
申请人： Hermann Dietz , Siegfried Ziegler
发明人： Hermann Dietz , Siegfried Ziegler
IPC分类号： H01M4/14 , H01M4/62 , H01M10/06
CPC分类号： H01M4/14 , H01M4/62
摘要： Between 0.001 and 0.5% by weight of polytetrafluoroethylene powder is incorporated in the composite electrochemically active mass carried on the lead plates of a lead-acid storage battery. In the case of the positive electrodes, the result is to lengthen the service life in terms of cycles of charging and discharging. In the case of the negative electrodes, the effect is to raise the low-current yield and the low-temperature high-current yield. The density of the composite mass is reduced and its water-holding properties increased.
摘要翻译：在铅酸蓄电池的铅板上携带的复合电化学活性物质中加入0.001〜0.5重量％的聚四氟乙烯粉末。在正极的情况下，结果是延长充电和放电循环的使用寿命。在负极的情况下，其效果是提高低电流产率和低温大电流产率。复合材料的密度降低，其保水性提高。

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