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    • 12. 发明授权
    • NTC temperature sensor and process for producing NTC temperature sensing
elements
    • NTC温度传感器和生产NTC温度传感元件的工艺
    • US5142266A
    • 1992-08-25
    • US466286
    • 1990-03-26
    • Karl-Hermann FrieseGunther StecherHans-Martin Wiedenmann
    • Karl-Hermann FrieseGunther StecherHans-Martin Wiedenmann
    • G01K7/16G01K7/22G01N27/406G01N27/416H01C7/04
    • H01C7/043G01K7/223G01N27/4067
    • The NTC temperature sensor includes a NTC temperature sensing element having an NTC resistor and made of a laminated composite of ceramic films, which is so designed that the ambient air or oxygen supplied by electrolytic pumping has free access, via a channel in the laminated composite, to the NTC resistor. The NTC resistor is hermetically sealed from a gas being measured. Solid electrolyte films which conduct O.sup.-2 ions, and films based on Al.sub.2 O.sub.3 can be used to make the laminated composite. The NTC resistor characteristic curve is independent of the composition of the gas being measured. The laminated composite can be formed of at least three solid electrolyte ceramic films including a base film provided with punched-out interconnection holes and conductor tracks printed by thick film technology, an intermediate film having a punched-out channel and a channel enlargement around the ends of the conductor tracks forming the electrodes of the NTC resistor, and a covering film.
    • PCT No.PCT / DE88 / 00528 Sec。 371 1990年3月26日第 102(e)1990年3月26日PCT PCT公布1988年8月30日PCT。 出版物WO89 / 03115 日期2004年4月6日。NTC温度传感器包括NTC温度感测元件,其具有NTC电阻器并由陶瓷膜的层压复合材料制成,其被设计成使得通过电解泵送供应的环境空气或氧气可以自由通过, 一个通道在叠层复合材料中,到NTC电阻。 NTC电阻器与被测气体气密密封。 可以使用导电O-2离子的固体电解质膜和基于Al2O3的膜来制备层压复合材料。 NTC电阻特性曲线与被测气体的组成无关。 层压复合体可以由至少三个固体电解质陶瓷膜形成,该固体电解质陶瓷膜包括设置有冲孔互连孔的底膜和通过厚膜技术印刷的导体轨迹,具有冲压通道的中间膜和在端部周围的通道放大 的形成NTC电阻器的电极的导体轨迹以及覆盖膜。
    • 16. 发明授权
    • Electrochemical sensor
    • 电化学传感器
    • US5662786A
    • 1997-09-02
    • US807163
    • 1991-12-13
    • Karl-Hermann FrieseHelmut WeylWerner WielandHans-Martin Wiedenmann
    • Karl-Hermann FrieseHelmut WeylWerner WielandHans-Martin Wiedenmann
    • G01N27/407G01N27/409
    • G01N27/4075
    • The electrochemical sensor for determination of an oxygen content of exhaust gases, includes a probe element including a tube made from a raw material mixture consisting essentially of an ionically conductive solid electrolyte; an outer electrode located on the outer surface of the tube; a substantially pore-free conductor strip layer located on the outer surface, connected to the outer electrode, and extending toward the open end, the conductor strip layer having a portion in close proximity to the tube open end; and a substantially pore-free cover layer hermetically covering at least the portion of the pore-free conductor strip layer in close proximity to the open end of the tube, the cover layer being made from a cover layer material including the ionically conductive solid electrolyte. The cover layer material advantageously a sintering activity which is at least equal to that of the raw material mixture from which the tube is made. The conductor strip layer consists essentially of a ceramic supporting framework and an electron-conducting material. The ceramic ceramic binder has at least the same sintering activity as the cover layer material.
    • 用于确定废气氧含量的电化学传感器包括探针元件,其包括由基本上由离子导电固体电解质组成的原料混合物制成的管; 位于所述管的外表面上的外电极; 位于所述外表面上的基本上无孔的导体条带层,其连接到所述外电极并且朝向所述开口端延伸,所述导体带层具有紧邻所述管开口端的部分; 以及基本无孔的覆盖层,其至少密封地覆盖无孔导体带层的靠近管的开口端的部分,覆盖层由包括离子导电固体电解质的覆盖层材料制成。 覆盖层材料有利地是至少等于制造管的原料混合物的烧结活性。 导体带层基本上由陶瓷支撑框架和电子传导材料组成。 陶瓷陶瓷粘合剂具有与覆盖层材料至少相同的烧结活性。