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11. 发明申请

US20110060169A1 HYDROGENATION CATALYST AND PROCESS FOR PREPARING ALCOHOLS BY HYDROGENATION OF CARBONYL COMPOUNDS 审中-公开
标题翻译：加氢催化剂及其制备方法通过加氢处理碳化合物
公开(公告)号：US20110060169A1
公开(公告)日：2011-03-10
申请号：US12674910
申请日：2008-07-07
申请人： Alfred Kaizik , Thomas Quandt , Hans-Gerd Lueken , Wilfried Bueschken
发明人： Alfred Kaizik , Thomas Quandt , Hans-Gerd Lueken , Wilfried Bueschken
IPC分类号： C07C29/141 , B01J21/06 , B01J21/04 , B01J37/08
CPC分类号： B01J23/26 , B01J21/04 , B01J23/78 , B01J23/866 , B01J23/868 , B01J35/1019 , B01J35/1042 , B01J37/0207 , C07C29/141 , C07C29/145 , C07C31/125
摘要： The invention relates to a hydrogenation catalyst which comprises a support material and at least one hydrogenation-active metal and in which the support material is based on titanium dioxide, zirconium dioxide, aluminium oxide, silicon oxide or mixed oxides thereof and the hydrogenation-active metal is at least one element from the group consisting of copper, cobalt, nickel, chromium, wherein the support material contains the element barium.The invention further relates to a process for preparing alcohols by hydrogenation of carbonyl compounds, in which the hydrogenation is carried out in the presence of such a hydrogenation catalyst.
摘要翻译：本发明涉及一种氢化催化剂，其包含载体材料和至少一种氢化活性金属，其中载体材料基于二氧化钛，二氧化锆，氧化铝，氧化硅或其混合氧化物，氢化活性金属是由铜，钴，镍，铬组成的组中的至少一种元素，其中载体材料含有元素钡。本发明还涉及通过氢化羰基化合物制备醇的方法，其中氢化在这种氢化催化剂的存在下进行。

12. 发明授权

US08581008B2 Process for preparing α,β-unsaturated C10-aldehydes 有权
标题翻译：制备α，β-不饱和C10醛的方法
公开(公告)号：US08581008B2
公开(公告)日：2013-11-12
申请号：US13256116
申请日：2010-02-23
申请人： Alfred Kaizik , Dirk Fridag , Hans-Gerd Lueken , Wilfried Bueschken
发明人： Alfred Kaizik , Dirk Fridag , Hans-Gerd Lueken , Wilfried Bueschken
IPC分类号： C07C45/45
CPC分类号： C07C45/74 , Y02P20/582 , C07C47/21
摘要： The invention relates to a method for continuously producing α,β-unsaturated C10-aldehydes from aliphatic C5-aldehydes, comprising the following steps: aldol-condensing aliphatic C5-aldehydes into α,β-unsaturated C10-aldehydes in the presence of an aqueous base in a tube reactor; phase separating the output of the tube reactor into an aqueous catalyst phase and an organic product phase; separating the organic product phase into α,β-unsaturated C10-aldehydes, aliphatic C5-aldehydes, and auxiliary products; discharging a part of the aqueous catalyst phase to remove the reaction water and supplementing said part with liquor solution and subsequently returning said part to the tube reactor. The task of the invention is to improve a method of said kind in a way such that it requires lower energy input. This is achieved in that the aliphatic C5-aldehydes and/or the α,β-unsaturated C10-aldehydes are dispersed in the aqueous base as drops, wherein the average Sauter diameter of the drops is between 0.2 mm and 2 mm.
摘要翻译：本发明涉及一种从脂肪族C5醛连续生产α，β-不饱和C10醛的方法，包括以下步骤：将脂族C 5 - 醛缩合成α，β-不饱和C10醛在水溶液基于管式反应器; 将管式反应器的输出相分离成水性催化剂相和有机产物相; 将有机产物相分离成α，β-不饱和C10醛，脂族C5醛和辅助产物; 排出一部分水性催化剂相以除去反应水并用液体溶液补充所述部分，随后将所述部分返回到管式反应器。本发明的任务是改进所述种类的方法，使其需要较低的能量输入。这是因为脂族C 5 - 醛和/或α，β-不饱和C 10 - 醛以水滴的形式分散在水性碱中，其中液滴的平均Sauter直径在0.2mm与2mm之间。

13. 发明授权

US08563782B2 Producing α,β-unsaturated aldehydes by means of a reaction mixing pump 有权
标题翻译：通过反应混合泵生产α，β-不饱和醛
公开(公告)号：US08563782B2
公开(公告)日：2013-10-22
申请号：US13498690
申请日：2010-08-03
申请人： Alfred Kaizik , Hans-Gerd Lueken , Dirk Fridag , Wilfried Bueschken , Dirk Mackowiak , Frank Brocksien
发明人： Alfred Kaizik , Hans-Gerd Lueken , Dirk Fridag , Wilfried Bueschken , Dirk Mackowiak , Frank Brocksien
IPC分类号： C07C45/72
CPC分类号： C07C45/74 , Y02P20/582 , C07C47/21
摘要： The invention relates to a method for producing α,β-unsaturated aldehydes, wherein a catalytic aldol condensation of charged aldehydes is carried out in the presence of an aqueous base within a continuous-flow reactor. The aim of the invention is to provide a method for aldolizing aldehydes that can be carried out in a particularly economical manner. The aim is achieved by using a reaction mixing pump as the reactor.
摘要翻译：本发明涉及一种生产α，β-不饱和醛的方法，其中带电醛的催化醛醇缩合在连续流反应器内的碱性水溶液存在下进行。本发明的目的是提供一种可以以特别经济的方式进行醛脱醛化的方法。目的是通过使用反应混合泵作为反应器来实现。

14. 发明授权

US08258325B2 Mixture of diesters of dianhydrohexitol derivatives with carboxylic acids of the empirical formula C8H17COOH, process for preparing these diesters, and use of these mixtures 有权
标题翻译：二脱水己糖醇衍生物的二酯与经验式C8H17COOH的羧酸的混合物，制备这些二酯的方法以及这些混合物的使用
公开(公告)号：US08258325B2
公开(公告)日：2012-09-04
申请号：US12523906
申请日：2007-12-21
申请人： Michael Grass , Norbert Scholz , Alfred Kaizik , Wilfried Bueschken , Hans-Gerd Lueken
发明人： Michael Grass , Norbert Scholz , Alfred Kaizik , Wilfried Bueschken , Hans-Gerd Lueken
IPC分类号： C07D307/93 , C07D493/00 , C08G73/06
CPC分类号： C07D493/04 , C08K5/1535 , C08L27/06
摘要： The present invention relates to a mixture comprising diesters of the formula (I) where R1 to R8═H or alkyl group having from 1 to 6 carbon atoms, where the R1 to R8 radicals may be the same or different, which is characterized in that at least two different diesters I are present in the mixture, said diesters differing in the structure of at least one of the carboxylic acid radicals C8H17COO present, to a process for preparing diesters of an isosorbide derivative of the formula I, in which a hexahydric alcohol and/or a monoanhydro or dianhydro derivative of the alcohol is esterified with a mixture of at least two different carboxylic acids of the empirical formula C8H17COOH, and to the use of these mixtures in paints, inks or coatings, in plastisols, adhesives or adhesive components, in sealants, as plasticizers in polymers or polymer components, as solvents, as lubricant oil components and as assistants in metal processing, and also PVC compositions or plastisols comprising PVC and from 5 to 250 parts by mass of the mixture per 100 parts by mass of PVC.
摘要翻译：本发明涉及包含式（I）的二酯的混合物，其中R 1至R 8 = H或具有1至6个碳原子的烷基，其中R 1至R 8基团可以相同或不同，其特征在于混合物中存在至少两种不同的二酯I，所述二酯在存在的羧酸基团C 8 H 17 COO中的至少一种的结构上不同，制备式I的异山梨醇衍生物的二酯的制备方法，其中六元醇和/或醇的单酐或二氢衍生物与经验式C 8 H 17 COOH的至少两种不同羧酸的混合物酯化，并且在涂料，油墨或涂料中，在增塑溶胶，粘合剂或粘合剂组分中使用这些混合物在密封剂中，作为聚合物或聚合物组分中的增塑剂，作为溶剂，作为润滑油组分和作为金属加工助剂，以及PVC组合物或增塑溶胶，其包含PVC和相对于100质量份的PVC，为5〜250质量份的混合物。

15. 发明申请

US20120190895A1 PRODUCING ALPHA,BETA-UNSATURATED ALDEHYDES BY MEANS OF A REACTION MIXING PUMP 有权
标题翻译：通过反应混合泵生产ALPHA，BETA不饱和醛
公开(公告)号：US20120190895A1
公开(公告)日：2012-07-26
申请号：US13498690
申请日：2010-08-03
申请人： Alfred Kaizik , Hans-Gerd Lueken , Dirk Fridag , Wilfried Bueschken , Dirk Mackowiak , Frank Brocksien
发明人： Alfred Kaizik , Hans-Gerd Lueken , Dirk Fridag , Wilfried Bueschken , Dirk Mackowiak , Frank Brocksien
IPC分类号： C07C45/72
CPC分类号： C07C45/74 , Y02P20/582 , C07C47/21
摘要： The invention relates to a method for producing α,β-unsaturated aldehydes, wherein a catalytic aldol condensation of charged aldehydes is carried out in the presence of an aqueous base within a continuous-flow reactor. The aim of the invention is to provide a method for aldolizing aldehydes that can be carried out in a particularly economical manner. The aim is achieved by using a reaction mixing pump as the reactor.
摘要翻译：本发明涉及一种生产α，β-不饱和醛的方法，其中在连续流动反应器内的碱性水溶液存在下进行带电醛的催化醛醇缩合。本发明的目的是提供一种可以以特别经济的方式进行醛脱醛化的方法。目的是通过使用反应混合泵作为反应器来实现。

16. 发明申请

US20110130595A1 PROCESS FOR PREPARING C5 ALDEHYDE MIXTURES WITH A HIGH N-PENTANAL CONTENT 有权
标题翻译：制备具有高N-PENTANAL CONTENT的C5醛类混合物的方法
公开(公告)号：US20110130595A1
公开(公告)日：2011-06-02
申请号：US12995800
申请日：2009-04-28
申请人： Hans-Gerd Lueken , Dirk Fridag , Udo Lenz , Hermann-Josef Schulte-Althoff , Klaus-Diether Wiese , Alfred Kaizik , Patrick Muhlack , Wilfried Bueschken , Frank Hoeper
发明人： Hans-Gerd Lueken , Dirk Fridag , Udo Lenz , Hermann-Josef Schulte-Althoff , Klaus-Diether Wiese , Alfred Kaizik , Patrick Muhlack , Wilfried Bueschken , Frank Hoeper
IPC分类号： C07C45/00
CPC分类号： B01J31/0237 , B01J31/185 , B01J2231/321 , B01J2531/822 , C07C45/50 , Y02P20/582 , C07C47/02
摘要： A process for preparing a C5 aldehyde mixture from a hydrocarbon mixture comprising at least one linear butene by terminal hydroformylation under isomerizing conditions, using a catalyst system comprising rhodium, a bisphosphite ligand, and an amine.
摘要翻译：一种通过使用包含铑，二亚磷酸酯配位体和胺的催化剂体系在异构化条件下通过末端加氢甲酰基化从包含至少一个直链丁烯的烃混合物制备C5醛混合物的方法。

17. 发明申请

US20090301348A1 MIXTURE OF DIESTERS OF DIANHYDROHEXITOL DERIVATIVES WITH CARBOXYLIC ACIDS OF THE EMPIRICAL FORMULA C8H17COOH, PROCESS FOR PREPARING THESE DIESTERS, AND USE OF THESE MIXTURES 有权
标题翻译：二恶烷衍生物与实施方案C8H17COOH的羧酸的混合物，制备这些柴油的方法和这些混合物的使用
公开(公告)号：US20090301348A1
公开(公告)日：2009-12-10
申请号：US12523906
申请日：2007-12-21
申请人： Michael Grass , Norbert Scholz , Alfred Kaizik , Wilfried Bueschken , Hans-Gerd Lueken
发明人： Michael Grass , Norbert Scholz , Alfred Kaizik , Wilfried Bueschken , Hans-Gerd Lueken
IPC分类号： C09D5/08 , C09K3/00 , C08L27/06
CPC分类号： C07D493/04 , C08K5/1535 , C08L27/06
摘要： The present invention relates to a mixture comprising diesters of the formula (I) where R1 to R8═H or alkyl group having from 1 to 6 carbon atoms, where the R1 to R8 radicals may be the same or different, which is characterized in that at least two different diesters I are present in the mixture, said diesters differing in the structure of at least one of the carboxylic acid radicals C8H17COO present, to a process for preparing diesters of an isosorbide derivative of the formula I, in which a hexahydric alcohol and/or a monoanhydro or dianhydro derivative of the alcohol is esterified with a mixture of at least two different carboxylic acids of the empirical formula C8H17COOH, and to the use of these mixtures in paints, inks or coatings, in plastisols, adhesives or adhesive components, in sealants, as plasticizers in polymers or polymer components, as solvents, as lubricant oil components and as assistants in metal processing, and also PVC compositions or plastisols comprising PVC and from 5 to 250 parts by mass of the mixture per 100 parts by mass of PVC.
摘要翻译：本发明涉及包含式（I）的二酯的混合物，其中R 1至R 8 -H或具有1至6个碳原子的烷基，其中R 1至R 8基团可以相同或不同，其特征在于混合物中存在至少两种不同的二酯I，所述二酯在存在的羧酸基团C 8 H 17 COO中的至少一种的结构上不同，制备式I的异山梨醇衍生物的二酯的制备方法，其中六元醇和/或醇的单酐或二氢衍生物与经验式C 8 H 17 COOH的至少两种不同羧酸的混合物酯化，并且在涂料，油墨或涂料中，在增塑溶胶，粘合剂或粘合剂组分中使用这些混合物，作为聚合物或聚合物组分中的增塑剂，作为溶剂，作为润滑油组分和金属加工助剂，以及包含PVC和f的PVC组合物或增塑溶胶相对于100质量份的PVC为5〜250质量份的混合物。

18. 发明授权

US07154012B2 Process for preparing alcohols from olefins by hydroformylation and hydrogenation 有权
公开(公告)号：US07154012B2
公开(公告)日：2006-12-26
申请号：US11296310
申请日：2005-12-08
申请人： Hans-Gerd Lueken , Alfred Kaizik , Wilfried Bueschken , Andreas Stenert
发明人： Hans-Gerd Lueken , Alfred Kaizik , Wilfried Bueschken , Andreas Stenert
IPC分类号： C07C29/14
CPC分类号： C07C45/50 , C07C29/141 , C07C31/125 , C07C47/02
摘要： A process for preparing aliphatic alcohols that includes cobalt-catalyzed hydroformylation of olefins, treatment of a hydroformylation mixture with oxygen-containing gases in the presence of acidic, aqueous cobalt(II) salt solutions, separation of a mixture into an aqueous phase comprising cobalt salts and an organic phase comprising the aliphatic aldehydes, and hydrogenation of an aldehyde-containing organic phase wherein the organic phase and treatment with an adsorbent to separate off cobalt compounds prior to hydrogenation.

19. 发明申请

US20120123169A1 PROCESS FOR PREPARING ALPHA,BETA-UNSATURATED C10-ALDEHYDES 有权
标题翻译：制备ALPHA，不饱和C10-醛缩合物的方法
公开(公告)号：US20120123169A1
公开(公告)日：2012-05-17
申请号：US13256116
申请日：2010-02-23
申请人： Alfred Kaizik , Dirk Fridag , Hans-Gerd Lueken , Wilfried Bueschken
发明人： Alfred Kaizik , Dirk Fridag , Hans-Gerd Lueken , Wilfried Bueschken
IPC分类号： C07C45/45
CPC分类号： C07C45/74 , Y02P20/582 , C07C47/21
摘要： The invention relates to a method for continuously producing α,β-unsaturated C10-aldehydes from aliphatic C5-aldehydes, comprising the following steps: aldol-condensing aliphatic C5-aldehydes into α,β-unsaturated C10-aldehydes in the presence of an aqueous base in a tube reactor; phase separating the output of the tube reactor into an aqueous catalyst phase and an organic product phase; separating the organic product phase into α,β-unsaturated C10-aldehydes, aliphatic C5-aldehydes, and auxiliary products; discharging a part of the aqueous catalyst phase to remove the reaction water and supplementing said part with liquor solution and subsequently returning said part to the tube reactor. The task of the invention is to improve a method of said kind in a way such that it requires lower energy input. This is achieved in that the aliphatic C5-aldehydes and/or the α,β-unsaturated C10-aldehydes are dispersed in the aqueous base as drops, wherein the average Sauter diameter of the drops is between 0.2 mm and 2 mm.
摘要翻译：本发明涉及从脂肪族C5醛连续生产α，β-不饱和C10醛的方法，包括以下步骤：将脂族C 5 - 醛缩合成α，β-不饱和C10醛，在管式反应器中的水性碱; 将管式反应器的输出相分离成水性催化剂相和有机产物相; 将有机产物相分离成α，β-不饱和C10醛，脂肪族C5醛和辅助产物; 排出一部分水性催化剂相以除去反应水并用液体溶液补充所述部分，随后将所述部分返回到管式反应器。本发明的任务是改进所述种类的方法，使其需要较低的能量输入。这是通过脂肪族C5醛和/或α，β-不饱和C10醛以水滴的形式分散在水性基质中，其中液滴的平均Sauter直径在0.2mm和2mm之间。

20. 发明授权

US06720457B2 Process for the hydroformylation of higher olefins using cobalt compounds as catalyst 有权
标题翻译：使用钴化合物作为催化剂的高级烯烃的羰基化方法
公开(公告)号：US06720457B2
公开(公告)日：2004-04-13
申请号：US10200752
申请日：2002-07-24
申请人： Stefan Drees , Bernhard Scholz , Alfred Kaizik , Walter Toetsch , Wilfried Bueschken , Martin Trocha
发明人： Stefan Drees , Bernhard Scholz , Alfred Kaizik , Walter Toetsch , Wilfried Bueschken , Martin Trocha
IPC分类号： C07C4549
CPC分类号： C07C29/16 , C07C45/50 , C07C31/125 , C07C47/02
摘要： Olefins having from 5 to 24, in particular from 5 to 12, carbon atoms are hydroformylated by reacting an olefin or a mixture of olefins in the presence of an unmodified cobalt catalyst in a single-stage process in a reactor at a temperature of from 100° C. to 220° C. and a pressure of from 100 bar to 400 bar, to obtain an aldehyde, an alcohol or a mixture thereof. An aqueous bottom phase and an organic phase are present in the reactor, the aqueous bottom phase is mixed with the organic phase, and a concentration of the cobalt catalyst, calculated as metallic cobalt, in the aqueous bottom phase is in the range from 0.4 to 1.7% by mass based on the total weight of the aqueous bottom phase. A level of the aqueous bottom phase in the reactor is kept constant during steady-state operation.
摘要翻译：具有5至24个，特别是5至12个碳原子的烯烃通过使烯烃或烯烃混合物在未改性的钴催化剂存在下在反应器中的单级方法中在100℃的温度下进行加氢甲酰化 ℃至220℃，压力为100巴至400巴，得到醛，醇或其混合物。含水底相和有机相存在于反应器中，底部水相与有机相混合，在底部水相中以钴金属计算的钴催化剂浓度在0.4至相对于底部水相的总重量为1.7质量％。在稳态运行期间，反应器中的底部水相的水平保持恒定。

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