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11. 发明授权

US4278809A Process for preparing 2-isocyanatoalkyl esters of organic carboxylic acids 失效
标题翻译：制备有机羧酸的2-异氰酸根合烷基酯的方法
公开(公告)号：US4278809A
公开(公告)日：1981-07-14
申请号：US806805
申请日：1977-06-15
申请人： Kenneth A. Burdett
发明人： Kenneth A. Burdett
IPC分类号： C07C265/04 , C07C67/00 , C07C67/18 , C07C241/00 , C07C263/10 , C07D263/12 , C07D263/14
CPC分类号： C07C263/08 , C07D263/12 , C07D263/14
摘要： 2-Isocyanatoalkyl esters of organic carboxylic acids are prepared by reacting (a) an aqueous solution of a 2-oxazoline with (b) an organic solution of phosgene dissolved in a water-immiscible organic solvent in the presence of (c) a hydrochloric acid acceptor. As an example, 2-isocyanatoethyl methacrylate was prepared by concurrently blending an aqueous stream of 2-isopropenyl-2-oxazoline, a methylene chloride stream of phosgene and an aqueous stream of sodium hydroxide at a temperature of from about 0.degree. C. to about 10.degree. C. The reaction rate is very high and the reaction is essentially complete upon blending the reactants.
摘要翻译：有机羧酸的2-异氰酸烷基酯通过在（c）盐酸存在下，使（a）2-恶唑啉的水溶液与（b）溶解在与水不混溶的有机溶剂中的光气的有机溶液反应受体。作为实例，通过在约0℃至约约0℃的温度下同时混合2-异丙烯基-2-恶唑啉的水流，光气的二氯甲烷流和氢氧化钠的水流，制备甲基丙烯酸2-异氰酸基乙酯 10℃。反应速率非常高，并且在混合反应物时反应基本上完成。

12. 发明申请

US20110060168A1 IMPROVED HYDROGENATION PROCESS 有权
标题翻译：改进加氢方法
公开(公告)号：US20110060168A1
公开(公告)日：2011-03-10
申请号：US12918814
申请日：2009-02-28
申请人： David C. Molzahn , Kenneth A. Burdett , William L. Gibson , Kriel J. Karel , James E. Mccreight , Indresh Mathur
发明人： David C. Molzahn , Kenneth A. Burdett , William L. Gibson , Kriel J. Karel , James E. Mccreight , Indresh Mathur
IPC分类号： C07C29/80 , C07C29/74 , C07C29/60
CPC分类号： C07C29/60 , C07C31/205
摘要： The present invention provides an improved hydrogenation processes wherein heat is efficiently managed so that catalyst productivity is optimized. More particularly, in the processes of the present invention, a nonaqueous solvent is added to a reactant to provide a nonaqueous solvent/reactant mixture that can act as a heat sink and absorb at least a portion of the heat generated within the reactor. Desirably, a reaction product, or a solvent with a minimal number of hydroxyl groups, is utilized so that the formation of unwanted byproducts can be minimized.
摘要翻译：本发明提供了一种改进的氢化方法，其中有效地管理热量，从而优化催化剂生产率。更具体地说，在本发明的方法中，向反应物中加入非水溶剂以提供非水溶剂/反应物混合物，其可用作散热器并吸收在反应器内产生的热量的至少一部分。期望地，使用具有最少数目羟基的反应产物或溶剂，使得可以最小化不想要的副产物的形成。

13. 发明申请

US20090143544A1 INTEGRATED CHEMICAL PROCESSES FOR INDUSTRIAL UTILIZATION OF SEED OILS 有权
标题翻译：种子油的工业化利用综合化学工艺
公开(公告)号：US20090143544A1
公开(公告)日：2009-06-04
申请号：US12328868
申请日：2008-12-05
申请人： Zenon Lysenko , Bob R. Maughon , Jozef Bicerano , Kenneth A. Burdett , Christopher P. Christenson , Clark H. Cummins , Marvin L. Dettloff , Alan K. Schrock , P. J. Thomas , Richard D. Varjian , Jerry E. White , John Michael Maher
发明人： Zenon Lysenko , Bob R. Maughon , Jozef Bicerano , Kenneth A. Burdett , Christopher P. Christenson , Clark H. Cummins , Marvin L. Dettloff , Alan K. Schrock , P. J. Thomas , Richard D. Varjian , Jerry E. White , John Michael Maher
IPC分类号： C08L63/08 , C07C51/43 , C07C59/42 , C07C31/18 , C07C215/00 , C08L79/02 , C08L67/04 , C07C229/00 , C07C69/732 , C07C1/00
CPC分类号： C07D303/42 , C07C67/31 , C07C67/333 , C07C67/347 , C07C67/56 , C07C69/533 , C07C227/08 , C07C227/18 , C07C229/08 , Y02P20/125 , C07C69/716 , C07C69/675
摘要： Integrated processes of preparing industrial chemicals starting from seed oil feedstock compositions containing one or more unsaturated fatty acids or unsaturated fatty acid esters, which are essentially free of metathesis catalyst poisons, particularly hydroperoxides; metathesis of the feedstock composition with a lower olefin, such as ethylene, to form a reduced chain olefin, preferably, a reduced chain α-olefin, and a reduced chain unsaturated acid or ester, preferably, a reduced chain α,ω-unsaturated acid or ester. The reduced chain unsaturated acid or ester may be (trans)esterified to form a polyester polyolefin, which may be epoxidized to form a polyester polyepoxide. The reduced chain unsaturated acid or ester may be hydroformylated with reduction to produce an α,ω-hydroxy acid or α,ω-hydroxy ester, which may be (trans)esterified with a polyol to form an α,ωpolyester polyol. Alternatively, the reduced chain unsaturated acid or ester may be hydroformylated with reductive amination to produce an α,ω-amino acid or α,ω-amino ester, which may be (trans)esterified to form an α,ω-polyester polyamine.
摘要翻译：从含有一种或多种不饱和脂肪酸或不饱和脂肪酸酯的种子油原料组合物制备工业化学品的综合方法，其基本上不含复分解催化剂毒物，特别是氢过氧化物; 原料组合物与低级烯烃如乙烯的复分解以形成还原链烯烃，优选还原链的α-烯烃和还原链不饱和酸或酯，优选还原链的α，ω-不饱和酸或酯。还原链不饱和酸或酯可以（反式）酯化以形成聚酯聚烯烃，其可以被环氧化以形成聚酯多环氧化物。还原链不饱和酸或酯可以通过还原加氢甲酰化以产生α，ω-羟基酸或α，ω-羟基酯，其可以与多元醇反应形成α，ω-聚酯多元醇。或者，还原链不饱和酸或酯可以通过还原胺化加氢甲酰化以产生α，ω-氨基酸或α，ω-氨基酯，其可以（反式）酯化形成α，ω-聚酯多胺。

14. 发明授权

US5329057A Process for the cyclodimerization of 1,3-butadienes to 4-vinylcyclohexenes 失效
标题翻译：将1,3-丁二烯环化为4-乙烯基环己烯的方法
公开(公告)号：US5329057A
公开(公告)日：1994-07-12
申请号：US954710
申请日：1992-09-30
申请人： Ronald W. Diesen , Kenneth A. Burdett , Ravi S. Dixit , Stanley S. T. King
发明人： Ronald W. Diesen , Kenneth A. Burdett , Ravi S. Dixit , Stanley S. T. King
IPC分类号： B01J29/072 , B01J29/06 , C07B61/00 , C07C2/52 , C07C13/20 , C07C2/50
CPC分类号： C07C2/52 , C07C2101/16 , C07C2529/08 , C07C2529/18 , C07C2529/60 , C07C2529/70
摘要： A process for the cyclodimerization of 1,3-butadienes to 4-vinylcyclohexenes. The process involves contacting butadiene with a copper (I)-aluminosilicate zeolite prepared by (a) an impregnation method, or (b) heating a solid mixture of a copper salt and the zeolite, or (c) contacting vapors of a copper salt with the zeolite. The catalysts exhibit long life and good activity in the claimed process. The impregnated Cu(I)-catalyst is claimed.
摘要翻译： 1,3-丁二烯环化为4-乙烯基环己烯的方法。该方法包括使丁二烯与（a）浸渍法制备的铜（I） - 硅铝酸盐沸石接触，或（b）加热铜盐和沸石的固体混合物，或（c）将铜盐的蒸气与沸石。催化剂在所要求保护的方法中表现出长寿命和良好的活性。浸渍的Cu（I） - 催化剂被要求保护。

15. 发明授权

US4062833A Biuret polyisocyanates 失效
标题翻译：缩二脲多异氰酸酯
公开(公告)号：US4062833A
公开(公告)日：1977-12-13
申请号：US716850
申请日：1976-08-23
申请人： Michael J. Van Eyck , Kenneth A. Burdett
发明人： Michael J. Van Eyck , Kenneth A. Burdett
IPC分类号： C07C275/62 , C08G18/78 , C07C119/042
CPC分类号： C07C275/62 , C08G18/7831
摘要： The biuret polyisocyanates correspond to the formula ##STR1## wherein R is --CH.sub.2 CH.sub.2 --O--CH.sub.2 CH.sub.2 -- and X is hydrogen or --C(O)--NX--R--NCO, and they have not more than six isocyanato groups per molecule. These compounds are prepared by reacting bis(2-isocyanatoethyl)ether with water in a mole ratio of at least 3 moles of diisocyanate per mole of water. The biuret polyisocyanates are particularly useful in the preparation of polyurethanes.
摘要翻译：缩二脲多异氰酸酯对应于下式：其中R是-CH 2 CH 2 -O-CH 2 CH 2 - ，X是氢或-C（O）-NX-R-NCO，它们每分子不超过六个异氰酸酯基。这些化合物通过双（2-异氰酸根合乙基）醚与摩尔比为每摩尔水至少3摩尔二异氰酸酯的水制备。缩二脲多异氰酸酯特别可用于制备聚氨酯。

16. 发明授权

US07812185B2 Metathesis process for preparing an alpha, omega-functionalized olefin 有权
标题翻译：用于制备α，ω-官能化烯烃的复分解方法
公开(公告)号：US07812185B2
公开(公告)日：2010-10-12
申请号：US11915794
申请日：2006-06-02
申请人： Kenneth A. Burdett , Morteza Mokhtarzadeh , Francis J. Timmers
发明人： Kenneth A. Burdett , Morteza Mokhtarzadeh , Francis J. Timmers
IPC分类号： C09F7/00
CPC分类号： C07C6/04 , C07C67/333 , C07C2531/24 , C07C11/02 , C07C69/533
摘要： A cross-metathesis process for preparing an α,ω-functionalized olefin, such as methyl 9-decenoate, and an α-olefin having three or more carbon atoms, such as 1-decene. The process involves contacting in a first reaction zone an α-functionalized internal olefin, such as methyl oleate, and an α-olefinic monomer having three or more carbon atoms, such as 1-decene, with a first metathesis catalyst to prepare an effluent stream containing the α,ω-functionalized olefin, such as methyl 9-decenoate, an unfunctionalized internal olefin, such as 9-octadecene, unconverted reactant olefins, and optionally, an α,ω-difunctionalized internal olefinic dimer, such as dimethyl 9-octadecen-1,18-dioate; separating said effluent streams; then contacting in a second reaction zone the unfunctionalized internal olefin with ethylene in the presence of a second metathesis catalyst to obtain a second product effluent containing the α-olefinic monomer having three or more carbon atoms; and cycling a portion of the α-olefinic monomer stream(s) to the first zone.
摘要翻译：用于制备α，ω-官能化烯烃如9-癸烯酸甲酯和具有三个或更多个碳原子的α-烯烃如1-癸烯的交叉复分解方法。该方法包括在第一反应区中使α-官能化的内烯烃如油酸甲酯和具有三个或更多个碳原子的α-烯烃单体如1-癸烯与第一复分解催化剂接触以制备流出物流含有α，ω-官能化的烯烃如9-癸烯酸甲酯，未官能化的内烯烃，如9-十八烯，未转化的反应物烯烃，以及任选的α，ω-双官能化的内烯烃二聚体，例如十九烷基二甲基 -1,18-二酸分离所述流出物流; 然后在第二反应区域中，在第二复分解催化剂的存在下使未官能化的内烯烃与乙烯接触，以获得含有具有三个或更多个碳原子的α-烯烃单体的第二产物流出物; 以及将一部分α-烯烃单体流循环到第一区。

17. 发明授权

US07745652B2 Integrated chemical processes for industrial utilization of seed oils 有权
标题翻译：种子油工业利用综合化学工艺
公开(公告)号：US07745652B2
公开(公告)日：2010-06-29
申请号：US12328868
申请日：2008-12-05
申请人： Zenon Lysenko , Bob R. Maughon , Jozef Bicerano , Kenneth A. Burdett , Christopher P. Christenson , Clark H. Cummins , Marvin L. Dettloff , Alan K. Schrock , P. J. Thomas , Richard D. Varjian , Jerry E. White , John Michael Maher
发明人： Zenon Lysenko , Bob R. Maughon , Jozef Bicerano , Kenneth A. Burdett , Christopher P. Christenson , Clark H. Cummins , Marvin L. Dettloff , Alan K. Schrock , P. J. Thomas , Richard D. Varjian , Jerry E. White , John Michael Maher
IPC分类号： C07C51/43
CPC分类号： C07D303/42 , C07C67/31 , C07C67/333 , C07C67/347 , C07C67/56 , C07C69/533 , C07C227/08 , C07C227/18 , C07C229/08 , Y02P20/125 , C07C69/716 , C07C69/675
摘要： Integrated processes of preparing industrial chemicals starting from seed oil feedstock compositions containing one or more unsaturated fatty acids or unsaturated fatty acid esters, which are essentially free of metathesis catalyst poisons, particularly hydroperoxides; metathesis of the feedstock composition with a lower olefin, such as ethylene, to form a reduced chain olefin, preferably, a reduced chain α-olefin, and a reduced chain unsaturated acid or ester, preferably, a reduced chain α,ω-unsaturated acid or ester. The reduced chain unsaturated acid or ester may be (trans)esterified to form a polyester polyolefin, which may be epoxidized to form a polyester polyepoxide. The reduced chain unsaturated acid or ester may be hydroformylated with reduction to produce an α,ω-hydroxy acid or α,ω-hydroxy ester, which may be (trans)esterified with a polyol to form an α,ω-polyester polyol. Alternatively, the reduced chain unsaturated acid or ester may be hydroformylated with reductive amination to produce an α,ω-amino acid or α,ω-amino ester, which may be (trans)esterified to form an α,ω-polyester polyamine.
摘要翻译：从含有一种或多种不饱和脂肪酸或不饱和脂肪酸酯的种子油原料组合物制备工业化学品的综合方法，其基本上不含复分解催化剂毒物，特别是氢过氧化物; 原料组合物与低级烯烃如乙烯的复分解以形成还原链烯烃，优选还原链α-烯烃和还原链不饱和酸或酯，优选还原链α，ω-不饱和酸或酯。还原链不饱和酸或酯可以（反式）酯化以形成聚酯聚烯烃，其可以被环氧化以形成聚酯多环氧化物。还原链不饱和酸或酯可以通过还原加氢甲酰化以产生α，ω-羟基酸或α，ω-羟基酯，其可以与多元醇反应形成α，ω-聚酯多元醇。或者，还原链不饱和酸或酯可以通过还原胺化加氢甲酰化以产生α，ω-氨基酸或α，ω-氨基酯，其可以（反式）酯化形成α，ω-聚酯多胺。

18. 发明申请

US20080103346A1 Membrane Separation Of A Metathesis Reaction Mixture 审中-公开
标题翻译：复分解反应混合物的膜分离
公开(公告)号：US20080103346A1
公开(公告)日：2008-05-01
申请号：US11665723
申请日：2005-10-14
申请人： Kenneth A. Burdett , Baymond M. Collins , Bob R. Maughon , Michael L. Tulchinsky
发明人： Kenneth A. Burdett , Baymond M. Collins , Bob R. Maughon , Michael L. Tulchinsky
IPC分类号： C07C7/144
CPC分类号： C07C7/144 , B01D61/027 , C07C6/04 , C07C2531/24
摘要： A process for separating a homogeneous metathesis catalyst and, optionally, one or more homogeneous metathesis catalyst degradation products from a metathesis reaction mixture containing in addition to said metathesis catalyst and said metathesis catalyst degradation product(s), one or more olefin metathesis products, one or more unconverted reactant olefins, and optionally, a solvent. The process involves contacting the metathesis reaction mixture with a nanofiltration membrane, such as a polyimide nanofiltration membrane, so as to recover a permeate containing a substantial portion of the olefin reaction products, the unconverted reactant olefins, and optional solvent, and a retentate containing the metathesis catalyst, and optionally, metathesis catalyst degradation product(s). In another aspect, this invention pertains to a continuous metathesis reaction-catalyst separation process, preferably, conducted in a nanofiltration membrane reactor.
摘要翻译：一种用于从包含所述复分解催化剂和所述复分解催化剂分解产物的复分解反应混合物中分离均相复分解催化剂和任选的一种或多种均化复分解催化剂降解产物的方法，一种或多种烯烃复分解产物，一种或更多未转化的反应物烯烃，以及任选的溶剂。该方法包括使复分解反应混合物与纳滤膜如聚酰亚胺纳滤膜接触，以回收含有大部分烯烃反应产物，未转化反应物烯烃和任选溶剂的渗透物，以及含有复分解催化剂和任选的复分解催化剂降解产物。另一方面，本发明涉及连续复分解反应 - 催化剂分离方法，优选在纳滤膜反应器中进行。

19. 发明授权

US08324434B2 Hydrogenation process 有权
标题翻译：氢化过程
公开(公告)号：US08324434B2
公开(公告)日：2012-12-04
申请号：US12918814
申请日：2009-02-28
申请人： David C. Molzahn , Kenneth A. Burdett , William L. Gibson , Karel J. Kriel , James E. McCreight , Indresh Mathur
发明人： David C. Molzahn , Kenneth A. Burdett , William L. Gibson , Karel J. Kriel , James E. McCreight , Indresh Mathur
IPC分类号： C07C27/00
CPC分类号： C07C29/60 , C07C31/205
摘要： The present invention provides an improved hydrogenation processes wherein heat is efficiently managed so that catalyst productivity is optimized. More particularly, in the processes of the present invention, a nonaqueous solvent is added to a reactant to provide a nonaqueous solvent/reactant mixture that can act as a heat sink and absorb at least a portion of the heat generated within the reactor. Desirably, a reaction product, or a solvent with a minimal number of hydroxyl groups, is utilized so that the formation of unwanted byproducts can be minimized.
摘要翻译：本发明提供了一种改进的氢化方法，其中有效地管理热量，从而优化催化剂生产率。更具体地说，在本发明的方法中，向反应物中加入非水溶剂以提供非水溶剂/反应物混合物，其可用作散热器并吸收在反应器内产生的热量的至少一部分。期望地，使用具有最少数目羟基的反应产物或溶剂，使得可以最小化不想要的副产物的形成。

20. 发明授权

US07696398B2 Stabilization of olefin metathesis product mixtures 失效
标题翻译：烯烃复分解产物混合物的稳定化
公开(公告)号：US07696398B2
公开(公告)日：2010-04-13
申请号：US10528472
申请日：2003-09-26
申请人： Kenneth A. Burdett , Rob R. Maughon , Patrick H. Au-Yeung
发明人： Kenneth A. Burdett , Rob R. Maughon , Patrick H. Au-Yeung
IPC分类号： C07C6/00 , C07C7/00
CPC分类号： C07C51/353 , B01J31/1658 , B01J31/2208 , B01J31/2265 , B01J31/2273 , B01J31/24 , B01J31/2404 , B01J31/28 , B01J2231/543 , B01J2531/821 , B01J2531/825 , C07C7/04 , C07C7/12 , C07C67/333 , Y02P20/127 , C07C11/02 , C07C57/03 , C07C69/533
摘要： A process of stabilizing an olefin metathesis product mixture, preferably, against double bond isomerization and thermal and chemical degradation. The process involves (a) contacting an olefin metathesis product mixture comprising one or more olefins produced in a metathesis process, a metathesis catalyst comprising a catalytic metal and one or more ligands, optionally, one or more metathesis catalyst degradation products, and optionally, one or more metals derived from sources other than the catalyst or catalyst degradation product(s), with an adsorbent, more preferably carbon; or alternatively, (b) subjecting the olefin metathesis product mixture to a two-step distillation, preferably, including short path wiped-film evaporation. A stabilized olefin metathesis product mixture to a two-step distillation, preferably, including short path wiped-film evaporation. A stabilized olefin metathesis product mixture is disclosed containing one or more olefins obtained in a metathesis process and having a total concentration of metal(s) of less than about 30 parts per million by weight.
摘要翻译：稳定烯烃复分解产物混合物的方法，优选地防止双键异构化和热和化学降解。该方法包括（a）使包含以复分解方法生产的一种或多种烯烃的烯烃复分解产物混合物，包含催化金属和一种或多种配体，任选的一种或多种复分解催化剂降解产物的复分解催化剂和任选的一种或更多来自除催化剂或催化剂分解产物之外的来源的金属，具有吸附剂，更优选碳; 或者（b）使烯烃复分解产物混合物进行两步蒸馏，优选包括短路擦拭膜蒸发。将稳定的烯烃复分解产物混合物进行两步蒸馏，优选包括短路径擦拭膜蒸发。公开了一种稳定的烯烃复分解产物混合物，其含有一种或多种以复分解方法获得的烯烃，其总金属浓度小于约30重量ppm。

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